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1. What is the maximum amount of MgCl2 that can be prepared from the reaction of 10.0g of HCl with 10.0 of Mg(OH)2 ?
(A) 9.26 g
(B) 13.1 g
(C) 16.3 g
(D) 17.5 g
2. Phenylflouroform contains 57.54% C, 3.45% H, and 39.01% F. Its molecular formula is the same as its simplest formula. How many carbon atoms
are in one molecule of Phenyflouroform ?
(A) 4
(B) 5
(C) 6
(D) 7
3. What is the most likely formula for a compound of gallium and sulfur ?
(A) GaS
(B) GaS2
(C) Ga2S3
(D) Ga3S2
4. A mixture of 2.30 x 1023 molecules N2 and 4.35 x 1023 molecules N2O has a total pressure of 2.00 atm. What is the partial pressure of N2 ?
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(A) Ca
(B) Rb
(C) Al
(D) Cl
6. An aqueous solution containing 1.00 mol H2SO4 is mixed with an aqueous solution containing 1.00 mol NaOH. The mixture is then evaporated to
dryness. What solid remains after evaporation ?
(A) H2SO4
(B) NaOH
(C) NaHSO4
(D) Na2SO4
(A) Rb
(B) Ag
(C) Sb
(D) I
8. At room temperature and 1 atm pressure the molecules are farthest apart in
(A) flourine
(B) bromine
(C) iodine
(D) water
9. What is the net-ionic equation for the reaction of aqueous solutions of BaCl2 and K2SO4?
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10. When 80.00 mL of 0.200 M HNO3 is added to 120.00 mL of 0.150 M KOH, the reaction
What volume of oxygen is required to burn 5.0 L of gaseous methonal measured at the same temperature and pressure ?
(A) 15.0 L
(B) 3.3 L
(C) 7.5 L
(D) 5.0 L
12. A 50 g sample of an ideal gas occupies a volume of 3.2 L at 40 °C and exerts a pressure of 2.6 atm. What is its molar mass ?
13. When sodium metal reacts with an excess of water the products are
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(A) volume
(B) pressure
(C) temperature
(D) chemical composition
15. Which pair of atoms should form the most polar bond ?
(A) B and F
(B) C and O
(C) O and F
(D) F and N
16. Which pair of ions should form the strongest ionic bond?
17. The kinetic-molecular theory predicts that two gases at the same temperature will have the same
18. Which factors do not affect the vapor pressure of a liquid at equilibrium?
(A) I only
(B) II only
(C) I and II only
(D) II and III only
21. Which oxide of chlorine exhibits the maximum oxidation state that really exists for chlorine?
(A) ClO
(B) ClO4
(C) Cl2O5
(D) Cl2O7
(A) Na
(B) Na+
(C) F¯
(D) Ne
23. What is the molarity of HCl if 450 mL of 2.3 M HCl is diluted to 1250 mL ?
(A) 0.36 M
(B) 0.50 M
(C) 0.83 M
(D) 1.8 M
24. The first five ionization energies in kJ mol¯1, for a particular element are shown.
(A) 1+
(B) 2+
(C) 3+
(D) 4+
25. Which compound, when dissolved in water, conducts electricity and forms a basic solution ?
(A) HCl
(B) CH3COOH
(C) CH3OH
(D) KOH
(A) SO3
(B) CaO
(C) P4O10
(D) CO2
(A) NH2¯
(B) Cl¯
(C) PO43¯
(D) NO2¯
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(A) NO
(B) NO2
(C) N2O3
(D) N2O5
(A) NaI
(B) KNO3
(C) BaCl2
(D) Na2CO3
32. The best acid for preparing a buffer of pH = 3.2 has a Ka near
(A) 2.40
(B) 2.70
(C) 3.00
(D) 11.30
34. Consider a solution that contains only one ion, Ag+, Pb2+, or Hg22+. The solution gave a precipitate with HCl that was insoluble in hot water but
was soluble in dilute ammonia solution. Which ion was present ?
(A) Pb2+
(B) Ag+
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(C) Hg22+
(D) The information is insufficient to identify the ion
35. What is the partial pressure of CO2(g) if Kp for the reaction is 1.04 atm ?
36. The Ksp values for CaSO4,BaSO4, and Ag2SO4 are 2.0 x 10¯4, 1.5 x 10¯9, and 1.5 x 10¯5 respectively. If 0.010 M Na2SO4 is slowly added to a
solution that contains Ca2+, Ba2+, and Ag+ (each 0.10M), which solid will precipitate last?
(A) CaSO4
(B) Ag2SO4
(C) BaSO4
(D) More information is required
37. The Ksp of AgCl is 1.8 x 10¯10. If 10.00 mL of 0.0010 M NaCl is combined with 20.00 mL of 0.0050 M AgNO3
39. Which value for an equilibrium constant, K, could indicate that the reaction
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(A) 1014
(B) 10¯14
(C) 1
(D) 0
(A) CF4
(B) Br2
(C) HCl
(D) BCl3
42. The sublimination of dry ice is an endothermic process. The energy absorbed is required to overcome
43. Compared to a 1.0 M aqueous solution of a nonelectrolyte, a 1.0 M solution of an electrolyte will have a
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(A) H3O+
(B) PCl3
(C) CO32¯
(D) NH4+
Given that ΔH°f for NH3(g) and H2O(g) are -46.0 and -242 kJ mol¯1 respectively.
(A) -1268 kJ
(B) -196 kJ
(C) +1268 kJ
(D) +196 kJ
46. A white, odorless, crystalline solid melts after about ten seconds in a burner flame. It is soluble in water and insoluble in carbon tetrachloride.
Neither the melt nor its aqueous solution conducts electricity. We conclude that the substance is
(A) 0.61 V
(B) 0.87 V
(C) 1.09 V
(D) 1.87 V
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48. A mixture of 0.10 mol H2 and 0.050 mol O2 are placed in a bomb calorimeter with a heat capacity of 5.1 x 104 J °C¯1. The initial temperature is
25.00 °C and the temperature after combustion is 25.56 °C. What is the ΔH°f for H2O(l)? (Assume 100% conversion to water.)
50. For BrF3, the orbital geometry of the central atom and the molecular geometry are, respectively,
51. How many electrons are needed to convert one nitrate ion into one ammonia molecule?
(A) 3
(B) 5
(C) 6
(D) 8
(A) CF4
(B) BF3
(C) N2O
(D) NO3¯
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53. What is the coefficient for H2O when the redox equation
(A) 1
(B) 2
(C) 3
(D) 4
55. Which will cause the value of the equilibrium constant for this reaction to increase?
56. Given
(A) +102 kJ
(B) -102 kJ
(C) +204 kJ
(D) -204 kJ
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57. Given
(A) 58.4 K
(B) 332 K
(C) 125 K
(D) -147 K
59. The half-life of 14C is 5570 years. How many years will it take for 90% of a sample to decompose?
60. A solution containg 2.10 g of Fe(NH4)2(SO4)2 . 6 H2O (M = 392.1 g mol¯1) was titrated with acidic Na2Cr2O7 solution, requiring 41.60 mL of
Na2Cr2O7 solution. What is the molarity of Na2Cr2O7?
(A) 0.0215 M
(B) 0.0387 M
(C) 0.0644 M
(D) 0.0744 M
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(A) 60
(B) 90
(C) 109
(D) 120
(A) sp
(B) sp2
(C) sp3
(D) p only
64. When a 5.0 g sample of an unknown compound is dissolved in 250.0 g of benzene, the freezing point of benzene decreased 1.4 °C. The freezing
point depression constant, Kf, for benzene is 5.12 °C m¯1. What is the approximate molar mass of the compound?
65.
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66. What is the maximum number of electrons that can occupy the 5d subshell?
(A) 2
(B) 6
(C) 10
(D) 14
67. For the isoelectronic series below, which species requires the least energy to remove an outer electron?
(A) K+
(B) Ar
(C) Cl¯
(D) S2¯
68. In aqueous solution, iodide ion (in basic solution) is oxidized by hypochlorite ion:
(A) 1
(B) 2
(C) 3
(D) 4
69. The dissociation of HI molecules, as shown below, occurs at a temperature of 629 K. The rate constant, k = 3.02 x 10¯5 M¯1 s¯1.
(A) 0
(B) 1
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(C) 2
(D) 3
70. A sodium vapor street lamp emits yellow light with a wavelength of 589 nm. What is the energy of this light per mole of protons?
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