21:36 226% 23.6% aan. ‘Atoms of all elements fundamental particl The mass of the elect © scanned with OKEN Scannerpe pec of He expt 10 BS Hine nee 1988), Rm © Na ©) He The vac, of Panel's constant TS ST "the way of He is SO. hat x Wich vale is eloses to the “Seslegt in mapomeres of 2guantum of Fgh wat egueny of 810% 52 2003] (sei @) arto! (3410 (210 ‘The value, of Planck's constant is G63» 10" J 5, The speed of light is 5 10” ams, Which vale is loses tothe ‘revelengin iemanomete of quanta of Hight with frequency of 1052 (2013) 9) 7% © 10 @) 2 ‘As parielar station of Al India Radio, New Dei broadeass on a fequency of 1368 i ler). The wavelength of the eetmpet adiion “ented by the {Spo e=30~ oh ma mB) 292m (©) 219m —(D) 2193m theory of radiation Forgiven ene, = 303 10” Jon {o, E = 3.03 + 10" Jo SE 208» 10" das (6126 103 se, 0=3 5 1 mice) ) [Lijse) (2021) © scanned with OKEN Scanner 2 See ai 50.08 on - i a wy 4 oe creer co faa Ee ‘sie Siete rang) we Sipe) AAD IO 9 tains 4.8 onn's adel for byron 0m te int ithe aio © Feet ofthe ist 1 eben a Ipod Hato om (Aye? (Bo ©) twin (D) bn nyde 1 bch tte flowing teres os rt ks ho es mel of yop Py 1198 w so egy f the lesen te ois re uted rae (0) ern in he tit near the es 1 Ss the lowest ener . (0 Meat rave it ferent obs a frond the noes re eon and seloty of hey g The ose he omit cannot te == Scermind sitaneosl. : 4, The energy of an electron in the n! Bohr orbit t afhydrogen tom is 0 ‘ ws be Bo oy Bhev @ Bev . © © Bev 4. The radius of hydrogen atom in the ground state . i033 A. Thermus of Lin (omic manor ina sim sates 19981 (a) 053A epoet © ora (D) 0.265 A 4, ha Beir mode of wom, when 26 ‘electron jumps from n= 1 to n= 3, how much ‘energy will be emitted or absorbed? [19961 \ (A) 2.389 10" ergs (B) 0.239 x 10" ergs. (C) 215% 10" ergs (D) 0.19365 10" ergs 6 What will be th Dn longest wavelength lin a (A) 546 nm wet [1996] (B) 656 nm, (C) 566 nm (IM ceea iz ey 380k the ae ‘ining ened ae”. yA (es mui be theory by ind aces pak" W9 (a Rahertord fo) tat (0) Sonera oy _ Inhyiogen atom, ener’ of fis excited ste I tes he find 8 KE of sae oi sriyaoge atom 2002) (yay (W) r680v) O Tieev —@) B60v 10. The fqueney_ of eainon eid when ee eccion is fom n= 4 ton = 1 i hydrogen atom will Be (Given zation srry f= 2.08510 Tato and 25«10"" 35) 2004] (ay 308 10s! (BY 2.00% 1085" {C) ste 10%s" — (D) 103 «10s! 11. The energy of second Bo obit ofthe hydrogen 328 KJ mol, hence the energy of| fourth Body orbit would be 12005] (@) -4lkimol! @) B12 mol (©) =T6tkimor (0) ~ 82K mot 12, According t the Bole theory, which of the 1B M4 following wanstons inthe hydrogen atom give rset the least energie photon? [2011] (4) a=60n=1 (8) n=Sw0 (©) n=60 ©) 2-50 Which ofthe following series of transitions in the spectrum of hydrogen atom falls invisible region? 2019) (A). Balmerseries (B)_Paschen series (©) Bracket series (D) Lyman series Itradus of second Bohr orbit of the He" ion is 105.8 pm, what is the radius of third Bohr orbit oF Li* ion? 12022] (A) 1587 pm (B) 15874 (©) 158.7 pm (0) 1587 pm Concept of shells and subshells ‘The maximum numberof eletons ina subse isgiven by the expression [1989] (a) 4-2 ® ai+2 {) 242 () WF ‘Maximum numberof electrons ina subshell of an atom is determined by the following 2009) 41-2 4142 (A) +1 By (C) 208 oy) 2.8 _Helsenbery's uncertainty 2 Ties ber of less # ut eof matters de Bronte The de Holic wavelength of pate with fis ta veloc 100 ms 9991 tay 6636 10% mB) 66ND (Bere 10m (Dy 66510" m tho. kg ball i moving with a speed of The asvocigted wavelength “is tho is ‘neg 0) og) SEM BY 66-1 (3 fosio%m (0) 1.0410" m tn hydrogen atm, the de Broglie wavelength of eke inthe second Boh obits [even that Bor radius, 9 = 52.9 pr) 1Odlisha 2019), (a) 1058 pm (B) 21.6 pm (C) 216xpm —— (D) 529 pm fof an electron Uncertainty in position (russ = 9.1 = 10 g) moving witha velocity fof» 10" ens accurate up 100.001 % will be ‘Tie Wits) in uncertainty expression where n= 6,626 x 10 erg second) 11995) (a) 566m (B) 384em (©) 19m (D) 768m “The positon of both an electron and helm om! is known within 1D mand the tromentum of the electron krown within 50x 10 kg ms", The minimum uncertainty inthe measurement ofthe moment of te helio atom is 1958) (a) SOkemat (8) 6okgms" (©) 80x 10% kgms* (D) 50x 10 kems! “The uncertainty in momentum of an ecton i 1x 10° kg mvs, The uncertainty in its position will be (h = 6.62 x 10°" kg m/s) _ 119991 (A) 1.05% 10%m_ —(B) 1.05 = 10m (©) $27 10"m — (Dy $.25= 10m Given: The mass of electron is 9.11» 10 " 1s, the Planck constant is 6.626 * 107 uncertainty involved in the meas Yelocity within a distance of 0.1 Ait. (B) 5.752 10%ms D)_ 5784 10's (A) 5.79% 108 ms! (©) 529% 10'ms' © scanned with OKEN ScannerSincornecr? A NeEgaion can be ed w ACEO Easton coma wien the eect anges i eon has 8 OTe ort = 1, te ok @ Fe it does for n= 6 sepnve exergy (8 SEEN an hat te leon is. ore Taeely found in the smallest allowed oi (©) The neguive sign in eqs simply rene tnt the energy feectron Bound {2th acleas ower tan it woud be it the clsvons were at the infinite dace fom the rules. (D) Larger the value ofr the larger isthe cbt rai. 2.10 Quantum numbers 1 fr mia gun as = 3, Sactlaecne hi 26 Oo Om 2 Te flog gat unbes e fotow many oben Se dameaa #1 @2 63 om oe 1 tn we ois ci io (A) principal quantum number (8) simutal quantum number (© spin quantum number Fenn 8 et 7 a #2 Te @ yon m3 vm « aw sie wb oa = wm 19 3 wn ‘ 1), 3, ge eilowing #68 OF Stra © Sg tare SB ea Gc and B Gpand Dy heaped 7 : te oloing #84 erin a 5. Wik ot remeonsinanaion ty ° mes y= O28 w ete Seer] @ praicame ae o G ickicamcose te “ tne often ey 6 eprint ofanaom it am NG Ie OO 4 " eal angular momentum of leon ‘ trae fom OF @ BE o o ws The CORRECT set of four quantum number Pe cOknence electrons of rubidium aon 5 @-3s DO &% S00AE 51,0712 © sun ©) $01,412 9, What is the maximum numbers of electrons ‘that can be associated with the following set of quantum numbers? fe3l=landm p01) 4 ® 2 © w 6 10, What is the maximum number of orbitals tht can be identified with the following quantum numbers? = 1,my=0 7 2014] ®2 ©3 MOF The angular momentum of electron in “d al nn, mal tea (A) Th (8) Oh aad 7 ° veh (@) vib Teer mine sane i [Phase-I 2016; (4) tamale (8) spin quentum number (D) magnetic q antum number © Penta ust number ie quantum niimhar © scanned with OKEN Scanner2.12 Rules for 1 2 Fmeuble, sales of magnet "gun Senko ers hen sok of emt omimgumer che ison ran at i w need? pM! 2.11 shape of orate pe nombe fel alr np eis ne ire by we © 1 sme ° vic fhe long pi of ental wi ARES Sy an the is [Phase 2061 dat Sede dnd ded © having 3 angular nodes and 3 tl odes [Odishs 2019] @ 6 @) s © M © 4 “The number of angular nodes and radial nodes ins orbital are: {Phase 2020] (A). Oand 1, respectively (B) Oand 2 respectively (©) Land, respectively (D) 3andO, respectively Identify the INCORRECT statement from the following (2022) (A) Ian atom, all the five 3d orbitals are equal in energy in fee stat. ‘The shapes Of day dye and dex orbitals ae similar to each other, and ds, and “ © 3. Onin ® 4. ate similar to each other. All the five Sd orbitals are different in size when compared tothe respective 4d orbitals: Al the five 44 orbitals have shapes similar tothe respective 3¢ orbit. oO @ ling electrons in orbitals ‘The total number of electrons that can be accommodated in all the orbitals having principal quantum number 2 and azimuthal 2 5 6 1 (quantum number I are [1990] (a) 2 ®) 4 © 6 () 8 ‘The order of filling of electrons inthe orbitals of an atom will be 1191) (A) 34,45, 4p, 40,58 (B) 4s, 3d, dp, 5,4 (©) $5 4p, 3d, 4d, 5s (D) 3d, 4p, 34, 4, 55 ‘nica ft (a) nae {8} Aatas pice cern peice Prt xehson pace Which of the following sete of four fantom tubers, an eleton will hve the Test ener? 1994), Peto os w 32 a @ 42 40 420 © 41 0 2 ) 5 0 0-12 It n= 6, the correct sequence fr filling of ‘letrons wl be rao (a0 27-day fs (n= 1d (a 2 mp feet 2y apn Ia fis np (w= I= 2Yh ® © ©) How many electrons can Fit in the orbital for ‘which n= Sand [= 1? [Phasett 2016] @ i @ 2 © 6 ©) 10 Which one is WRONG statement? (2018) (A). Total ocbital angular momentum of electron ins orbital sequal to zr ‘An ofbital is designated by three {quantum numbers while an electron in fn atom is designated by four quantum numbers (©) Theeectonic configuration of N atom is is 2e pk ph 2b (D) The value of m for dis zero. 8. 44, Sp, Sf and 6p orbitals are arranged inthe order of decreasing energy. The CORRECT option is 2019) (A) 6p>50> Sp> 4d (B) p> 31> 48> Sp (©) sf>6p>4d> 5p ® (D) 5i>6p>Sp>4d 2.13 Electronic configurations of toms. jumber of unpaired electrons in, Nis Naber of nmi 119891 Br mo oO! 3 ecto in the outers 2 fd 18 electror cen A) 1 oz Be © scanned with OKEN Scannerw Snes: | sa ee 6 ie ee ofc re et at meee see @ ; ° ; ww) mera ae ma Sea tent (©) asin : oO Loz ws OL ® ii wi we O iO? @3 £2? B28. os mew? IL D) 2 O) BA) © L 2 M3 £O2 ws O 1 O2 OH} O4 MS O8 O i ® LO. WA D4 BS 6 BF. 1. © 2 ® & © L@2 O33 04 @s w 12 B83 D4 Os Ws @7 1192 3 Bi Os B RONG statement? [2019 7 see pore m = mass oF CDE PATI = grou up velocity | ‘of the particle. The uncertainty principle is rae 25 ay ld eA re a freemen aa il Shan Tipp of 2p orbial incase of hydrogen Tike atoms. os % 1 (A) & (A) 9B) 10. (A) Or o 21 Fondant paris a 7 rn tons preset in cen ¥ a. of an atom ae clletvely known 2: ‘energy due to its ionic size. ie vel Ve Datos atomic thor, regarded te | _— fe sm a inate paris of mate ‘Atm fal ene cpa of 0 : feiitwin“NCOMEET | 22_Atnc umber an man sumer Ser cafe meemecsee | ane nk oth ees : mama soon, | feckceome van oh Hh Bets i me Tie ma so te seen om, 22029510" —Connser™ cep Ben clement show os vom popes, - CORRECT. © scanned with OKEN Scanner4 ‘Be and Li’ have same numberof electrons {@ electrons) and hence, they are isoelectronic species. ‘Atomic number, = 71, ‘Mass number, A= 175 Number of protons = Number of electrons = Z=71 23 Wave nature of light 1 24 Quantum theory of radiation Both He and Liv contain 2 electrons Therefore, their spectrum wil be same. dae = 30%10°ms" Ted's =2193m be E-= a BOOMS 656 am 442 104 2.5 _Bohe's model for hydrogen atom 2 Acconting to uncerainy principle, the postion and velocity of the electrons in the ‘Srbitcannot be determined simultaneously 4 ye osxBa For hydrogen: n= {and Z = 1, therefore 033A Por Li':Z= 3 and n= 1 therefore OTA 5. fs BeBe Be Beet =136-15= 121 «1.610 = 1936105 Now, | Joule = 10" erps 1.936% 10" 1= 0.1956. 10°" ergs 6 wavelength in Balmer series, Br 13 Fg” 686 « 10 em =656-nm 7. For Heatom, radius of 0” Bohe orbit = 05308 A Radius of second Bohr orbit = 0.530 (2) = 212A 9. Total energy = (Potential energy) Kinetic e Hence, kinetic energy ofthe same orbit n= 2) would be +3.4 eV. 10. Brsision ™ Be — Ey = Sey 82 kd mol 12, The energy difference will be minimum for ton 5 transition 1A, 14-0529 A= 529% pm For Li ion,Z=3 158.7 pm © scanned with OKEN Scanner 1-529 2 = 529%-216xpm 28 Hetsenbere'swncertainty principle Lo apes saw sp 9. 10% 30% 10 AS ap2273010 Hess. c= 133em Te pout of unceaints ia te poston the momentum 03 sib atomic price =p. Seer se for con and Sem, tbe se fr both the parce ie $0% 10" kgs gen) Acconling 0 Heisenberg's uncertainty Principle, 0 ace hae trem S| Lie totems cet ice pectin tebe pees? ery ape an ae pz yains a maximum of Each subshell con 201+ 1) electrons. For!™3, 2O/+ 1)=20x3+1)= 14 electrons 3.1/2 comespond 1024 subse while f= 12 indicates one ofthe 34 orbital, Hene, TomtnesnT = ym = +2 posible fr salyon ob Principal quantum number gives an idea about 1 position ofan electron around the nucleus. ‘Azimuthal quantum umber tells about the shape of sub-shell Magnetic quantum number represents the 4 ‘umber of permed orientations of sub-shell. Spin quantum number indicates the direction ‘of electron spin, indicates an electon in 3s orbital (i) For any value of n, I ean be from 0 to s (1). Hence, this set is not possible. (Gi) indicates an electton in 4f orbital () When !=0,m*=0. Hence this set is not possible, (9) When = 2,m=42, 41,0, -1,-2, and Not 3. Hence, this set s not possible. For a given value of *n atomic orbs ecu UL umber of © scanned with OKEN Scanner‘rb! agua men (La a leon Set al onto amr tyme ek wan BS errcbevwn = ek ar - 2 tectrgiccomfguraton of Ris ae ap Be 3B Sas ps $5 forthe valence sll electron (Ss!) 9, m3, 1 1 correspond t0 3p subse while indicates one ofthe 3p orbital. Hence, f= 1, my = -1 corresponds t0 which contains 2 electrons 1 = 1 comespond to 3p subshell while {tu O indicates one ofthe 3p orbital, Hence, = 1, my = 0, only one orbital ean be identified. 11. Angular momentum is given as YTD h Angular momentum = 2241) h = V6 h 2A Shapes of on 1. The number of spherical (radial) nodes in Sporbital =n=1=1 4, Number of radial nodes ~ 9— [Number of angular nodes = For 3s orbital, n= 3 and =0, [Number of radial nodes =3~ [Number of angular nodes = 0 S. Shapes of days dye and dy orbital are similar to each other, d,_ orbital has double dumb-bell shape in which the lobes lie along the eo- ordinate axes (x and y axes) while d, orbital jis dumb-bell shaped with a dough-nut shaped fing of high electron density around the releus in XY plane sfectrons in orbitals 12. Rules for n= 2, 1 = 1 represent 2p subshell whieh Contains 3 orbitals and hence, 2p subshell can accommodate 6 electrons. 213._Electrone configurations of atoms 1 2 orbital ‘Oba ae 3 ip. Sand ot of ese 48 hth ies eee For m= 6th sequence fr filing of lestrons ese Aoi an accommodate maxim of 0 ‘trons ony ‘The given cles coniguaion im option (©) ‘swicn Hand's rae The crest ‘Slvr entiation of 8 1e 2p 2} 208 i fi) Co 2ph 2m} 28 ff Ooo Cat ss 3 pet sp sft (aa at? Higher the value of (n+ 1) higher ste orbital ner. If (a+ 1) same fortwo orbitals, then ftbital with higher n value as more energy Henee, order is St> 6p > Sp 4 ‘The electronic configuration of Nis 1s282p!. Hence, the number of unpaired electrons = Electronic configuration of Cy 1s! 2623p Electronic configuratign of Cu" mls 26 2p! 383ph3d" ‘The outermost shell’ @E373d") of Ca! contain 18 electrons. 3S3ph3d 48! 4. Atomic number of caleium (Ca) is 20. The condensed eleetronie configuration of ealsium (Cais [Aa] 4 5. Observed electronic configuration of tani fs Ie 26 2p! 36 ph 4s! 30 ‘The 45 orbital is lower in eneray the 3 orbitals 2.14 Stability of halfsiied and compete compared 10 ed In hydrogen like atoms, 2s and 2p have same nergy, © scanned with OKEN Scanner