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Major Trace SR ND OnOffAxis 2016
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Major and trace element and Sr and Nd isotopic results from mantle diapirs in
the Oman ophiolite: Implications for off-axis magmatic processes
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Major and trace element and Sr and Nd isotopic results from mantle
diapirs in the Oman ophiolite: Implications for off-axis magmatic
processes
Marie Nicolle a,∗ , David Jousselin a , Laurie Reisberg a , Delphine Bosch b , Aurore Stephant a
a
Université de Lorraine, CRPG, 54501, Vandoeuvre-lès-Nancy, France
b
Université Montpellier II, Géosciences Montpellier, UMR-CNRS 5243, 34095 Montpellier cedex 5, France
a r t i c l e i n f o a b s t r a c t
Article history: The Oman ophiolite includes both a fossil fast spreading axis, defined by five mantle diapirs, and an
Received 5 August 2014 off-axis mantle diapir emplaced 30 km from the axis, providing a natural laboratory for the study of
Received in revised form 8 December 2015 off-axis magmatic processes. We compare field and petrological observations coupled with geochemical
Accepted 14 December 2015
and isotopic analyses of samples from the off-axis diapir with those of the nearest on-axis diapir, with
Available online 20 January 2016
a particular focus on the Moho Transition Zone (MTZ). Both diapirs are defined by the presence of
Editor: T. Elliott
steeply plunging lineations, but in the on-axis case, these lineations rotate gradually into parallelism
Keywords: with the horizontal magmatic lineations of the overlying crust, while in the off-axis case, a shear zone
mantle separates the steeply plunging lineations from the horizontal lineations of the surrounding mantle. In
ophiolite the on-axis diapir, the MTZ is 50 to 500 m thick and composed of dunite with layered gabbro lenses
off-axis magmatism whereas in the off-axis diapir, the MTZ is thicker and composed of dunite with massive (∼20% of MTZ)
pyroxenite clinopyroxenite lenses and a notable absence of plagioclase. Moreover, the off-axis diapir is associated
major and trace elements
with amphibole-bearing intrusions, consisting of Mg-rich gabbroic sills in the mantle peripheral to the
Sr and Nd isotopes
diapir, and microgabbroic lenses of broadly basaltic composition in the overlying crust. The ε Nd values
of the pyroxenites in the MTZ of the off-axis diapir fully overlap with those of the intrusions in the
surrounding mantle and crust, suggesting that they are genetically related. Calculated rare earth element
(REE) abundances of liquids in equilibrium with clinopyroxene imply that the magmas that traversed the
MTZ of the off-axis diapir were more depleted in highly incompatible elements than their counterparts
in the MTZ of the on-axis diapir. On the other hand, Nd isotopic compositions of the off-axis samples
(ε Nd = 6.2–7.9 in 18 of 19 samples) indicate derivation of their parental magmas from a less depleted
source than that which produced the magma associated with the on-axis gabbro (ε Nd = 7.8–9.2, 10
analyses).
To explain these observations, we suggest that the earliest magmas in the uprising off-axis diapir formed
from the partial melting of pyroxenite veins with less radiogenic Nd isotopic compositions than those of
the ambient peridotite. As the diapir traversed the cool, hydrated lithosphere these early melts interacted
with depleted harzburgites, lowering the incompatible element contents of the melt products while
having little effect on their Nd isotopic compositions. The great abundance of clinopyroxene in the off-
axis MTZ might be explained by the high pyroxene component in the original melt but perhaps also by
the presence of water in the lithosphere, which would favor the crystallization of clinopyroxene while
inhibiting that of plagioclase. The intrusions in the overlying crust could represent, to first order, the
secondary melts produced by the melt–harzburgite reaction, while the sills in the surrounding mantle
may be cumulates from such secondary melts.
These results shed light on processes occurring during interaction between rising off-axis material and
depleted, hydrated lithospheric mantle. Furthermore, if our interpretation is correct, the low ε Nd values
of the off-axis samples contribute to the growing body of evidence for the presence of pyroxenite veins
in the MORB mantle source.
© 2015 Elsevier B.V. All rights reserved.
1. Introduction
*
Corresponding author. Increasing evidence suggests that magmatic activity beneath
E-mail address: mnicolle@crpg.cnrs-nancy.fr (M. Nicolle).
mid-ocean ridges is not limited to the ridge axis. In the study of
http://dx.doi.org/10.1016/j.epsl.2015.12.005
0012-821X/© 2015 Elsevier B.V. All rights reserved.
M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149 139
Fig. 1. Map of the southern part of the Oman ophiolite showing the locations of the on-axis Maqsad and off-axis Mansah diapirs (open rectangles). As seen most clearly in
the Sumail massif, a system of dikes formed in a NW-SE ridge system crosscuts an older dike system oriented NE-SW. Plunging lineations (indicated by zones contoured in
deep yellow) define the mantle diapirs. I) Interpretative sketch of the ophiolite (circles: diapirs, dark gray: shear zones, thick blue lines: dike orientations, dashed line: ridge
axis). II–III) Schematic cross-sections of the on-axis Maqsad diapir and off-axis Mansah diapir, modified from Jousselin and Nicolas (2000). Horizontal straight lines in the
lithospheric harzburgite represent the frozen flow direction of the lithospheric mantle. Lines in the asthenospheric section represent flow orientations in each diapir. MTZ
denotes Moho Transition Zone. Each small letter references an illustration in Fig. 2. Adapted from Boudier et al. (1997). (For interpretation of the references to color in this
figure legend, the reader is referred to the web version of this article.)
Toomey et al. (2007), mantle melt upwelling was found 5 to 20 km and Nd isotope data for whole rocks and minerals from the MTZ
from the axis over nearly half of a 200 km first order segment in and around this off-axis diapir with similar data from the more
of the East Pacific Rise (EPR). The discovery of melt lenses in the classic MTZ section of a nearby on-axis diapir.
lower crust, up to 20 km from the rise (Crawford and Webb, 2002;
Crawford et al., 1999; Garmany, 1989), also shows that not all melt 2. Geological setting and field description of the diapirs
is focused beneath the ridge. Furthermore, seamount volcanism
provides direct evidence of off-axis magmatic processes. The Oman ophiolite, about 500 km long and 50 to 100 km wide,
When melt is delivered off-axis, its composition may be mod- was obducted on the Oman margin during the closure of the Neo-
ified by interaction with cool, hydrothermally altered lithospheric Tethys ocean 95 million years ago (Coleman, 1981; Hacker, 1994).
mantle (Bosch et al., 2004). However, assimilation and fractional Its continuous gabbroic crust indicates the presence of extensive,
crystallization in the crust may obscure the effects of sub-Moho long lived magma chambers along the ridge, suggesting that it
processes in erupted basalts. Off-axis magma may even be blocked is a relic of a fast spreading center (Nicolas and Boudier, 1995),
by the cold crustal barrier and not reach the surface. Thus the ori- as confirmed by high resolution dating indicating a half spread-
gin of off-axis magmatism may be more effectively investigated ing rate of 10 cm/yr (Rioux et al., 2012). The tectonic context of
by examining rocks beneath the Moho, which are preserved from the Oman ophiolite remains controversial, the two main hypothe-
complications occurring at higher levels. An ideal target is the ses being a Mid-Ocean Ridge (e.g. Boudier et al., 1988; Godard et
Moho Transition Zone (MTZ), the region immediately underlying al., 2006, 2003; Hacker, 1994; Nicolas and Boudier, 2003) and a
the crust–mantle interface, which is accessible almost exclusively Supra-Subduction Zone (SSZ) setting (e.g. Pearce and Cann, 1971;
in ophiolites (Boudier and Nicolas, 1995). Pearce et al., 1981; Shervais, 2001).
The Oman ophiolite presents relics of a former fast-spreading In the southern part of the ophiolite (the Rustaq, Sumail and
ridge, delineated by five on-axis diapirs (Boudier et al., 1997), Wadi Tayin massifs), a NW-SE dike system is observed over a
whose size and spacing match the distribution of melt upwelling width of 20–50 km, separating into two parts a NE-SW dike sys-
centers on the EPR (Toomey et al., 2007). An off-axis upwelling tem found in the outer parts of the massifs (Fig. 1). This ge-
center was also identified (Jousselin and Nicolas, 2000), providing ometry shows that a paleo-spreading center is preserved in the
a field laboratory to explore the contrasts between on and off-axis center of the massifs (Boudier et al., 1997), along an alignment
magmatism. Below, we compare major and trace element and Sr of five mantle diapirs (Fig. 1-I). Mantle diapirs, formed by local-
140 M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149
4.1. Whole rock major element compositions Trace element contents of individual phases (clinopyroxene,
plagioclase, amphibole) from a given rock were quite homogeneous
Major element abundances are consistent with rock types and (Table A.5) so only average REE compositions for each sample are
reflect modal variations (Fig. A.1), so only a few key observations plotted in the figures cited below.
are noted here. Harzburgites and dunites lacking melt impregna- All clinopyroxenes from on-axis gabbros, off-axis pyroxenites
tions have the same compositions on and off-axis. Nidab and Wasit and the gabbro–pyroxenite melange display flat HREE patterns and
off-axis intrusions differ from the on-axis MTZ gabbros, having depletion in LREE, with those from the off-axis pyroxenites having
higher FeO, MnO, TiO2 and Total Alkali (Na2 O + K2 O) contents. The globally lower REE contents (Fig. 4a) than those from the on-axis
Nidab intrusions have globally basaltic compositions, with higher gabbros (this study and Koga et al., 2001). Clinopyroxenes from
Al2 O3 and total alkalis and much lower MgO contents than the the Wasit sills (Fig. 4b) also have flat HREE patterns and show
Wasit sills. depletion in LREE, but this depletion is less marked than in the
142 M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149
Fig. 5. (a) ε Nd versus 87 Sr/86 Sr ratios of our unleached samples (solid triangles, circles, diamonds and squares). The black area represents the unaltered samples (Wadi Tayin
massif) from McCulloch et al. (1981). The dark gray and light gray areas represent the volcanics V1 and V2 from Godard et al. (2006). MORB field: O’Nions et al. (1977),
DePaolo and Wasserburg (1976), Mahoney et al. (1989), Staudigel et al. (1991), White et al. (1993). The isotopic compositions of Cretaceous seawater are from DePaolo and
Wasserburg (1976). The seawater mixing curve was constructed assuming a Sr/Nd ratio of 2.6 × 106 in seawater and of 23 in the rocks, based on the Sr/Nd ratios in our
pyroxenite samples. (b) Histogram of 87 Sr/86 Sr ratios of all the on and off-axis unleached samples. The light gray area represents the MORB field.
Fig. 6. (a) ε Nd versus 87 Sr/86 Sr ratios of on and off-axis leached whole rocks or clinopyroxene (cpx) separates. The ε Nd mean uncertainty (2σ ) including all identified sources
of error is indicated, mean uncertainties for Sr isotopic ratios are roughly the size of the symbols. For one sample, no 87 Sr/86 Sr ratio is available, as indicated by the horizontal
double arrow. Light gray area – Oman unaltered samples (McCulloch, 1981). References for MORB and Oman unaltered fields as in Fig. 5. (b) Inset showing all samples for
which Nd data are available, leached and unleached.
144 M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149
harzburgite is the expected result of diapirism beneath a spreading diapirs, indicating that the on-axis and off-axis magmas were not
axis, where lithosphere is absent. The off-axis MTZ is much thicker derived from the same source.
than the on-axis MTZ and totally free of gabbroic lenses, contain-
ing instead massive accumulations (around 20% of MTZ) of weakly 5.3. Melting of a pyroxenite-bearing source and resulting
deformed clinopyroxenite lacking both plagioclase and orthopyrox- melt–peridotite interaction
ene. The mantle and crust surrounding the off-axis diapir contain
intrusions bearing magmatic amphibole, suggesting crystallization The less radiogenic Nd isotopic compositions of the Mansah py-
from a hydrated melt. Clinopyroxene from off-axis MTZ pyroxenites roxenites, compared to those of rocks from the on-axis MTZ, may
have lower incompatible element abundances than those of on- indicate that the Mansah magmas contained a melt-component
axis MTZ gabbros, and are more depleted in LREE. However the Nd derived from pyroxenite veins. Such veins may originate directly
isotopic compositions of all off-axis lithologies are less radiogenic or indirectly from recycled oceanic crust (e.g. Allègre and Tur-
than those of the on-axis MTZ, and on average their Sr isotopic cotte, 1986), though several other origins, including delamination
compositions are slightly more radiogenic (Fig. 6). of lower crustal material or metasomatic segregation could also be
envisaged (Hirschmann and Stolper, 1996). The presence of such
5.2. Why is the off-axis diapir so rich in clinopyroxene? veins in the MORB source mantle has been postulated on the basis
of direct observations in ultramafic massifs and of coupled iso-
The key to understanding the differences between the on topic and trace element systematics in basalts (Hirschmann and
and off-axis diapirs is to determine the origin of the abun- Stolper, 1996; Niu et al., 1999; Prinzhofer et al., 1989; Stracke
dant clinopyroxenite in the off-axis MTZ. Several processes can et al., 2000). However, the signatures of hypothesized pyroxenite
form clinopyroxene concentrations. Bédard (1991, 1993, 2001) and vein components in MORB magmas are quite subtle, due to mixing
Lissenberg and Dick (2008) noted that pyroxenite can form in the and dilution with peridotite-derived melts. Rocks from the MTZ
lower oceanic crust by the reaction of migrating melt with gab- may approach the pre-mixing isotopic compositions of the mag-
bros. However this scenario is not applicable here because the mas more closely and thus may more easily reveal the presence of
mantle section traversed by the rising off-axis diapir was de- pyroxenite veins.
void of gabbro. Alternatively, the pyroxenites could be of cumu- Pyroxenite veins have lower melting points than the surround-
late origin if clinopyroxene precipitates before plagioclase. During ing peridotite and will thus be the first components to melt in an
fractional crystallization, both greater pressures and higher water upwelling mantle diapir (Hirschmann and Stolper, 1996; Kogiso et
contents favor the formation of clinopyroxene (Feig et al., 2006; al., 2004a, 2004b; Lambart et al., 2012; Stracke et al., 2000). Be-
Koepke et al., 2009). As the MTZ of the on and off-axis di- neath the ridge axis, melting rates are high, leading to a greater
apirs probably formed at similar depths (i.e., crustal thickness was contribution from peridotite. In the MTZ of the on-axis diapir, the
roughly constant), a differential pressure effect seems unlikely. On early pyroxenite-derived melts are overwhelmed by melts derived
the other hand, enhanced water contents in the off-axis diapir are from the surrounding fertile peridotite, so the Nd and Sr iso-
consistent with geological constraints. As the hot diapir rose from topic ratios have MORB-like values. Off-axis, extents of melting are
the asthenosphere, it partially assimilated the intervening litho- lower, so the pyroxenite signature is more likely to be preserved.
spheric mantle, as shown by the deformed ultramafic xenoliths As the off-axis diapir ascends towards the Moho, it interacts with
in the Nidab intrusions (Fig. 2g–h). The presence of amphiboles and incorporates the harzburgitic lithosphere. This lithosphere is
in the margins of the Wasit sills surrounding the diapir implies highly depleted in incompatible elements and cannot contribute
that their parental magmas were water rich, suggesting that the much Nd and Sr to the rising melts, so the magmas reaching the
off-axis lithosphere incorporated into the rising diapir was hy- MTZ retain the Nd and Sr isotopic signature of the original pyrox-
drated. Evidence for hydrothermal processes at Moho depth in the enite veins (see the electronic appendices for an example of how
Oman ophiolite (Bosch et al., 2004; Nicolas and Mainprice, 2005; such a vein melting model might work).
Nicolas et al., 2003) provides a likely hydration mechanism, assum- Melts derived from pyroxenite veins are unlikely to be in
ing that such circulation can descend into the underlying mantle equilibrium with the surrounding peridotite (e.g. Sobolev et al.,
section. 2007). Based on both experiments and theoretical modeling,
However the presence of water, though favoring clinopyrox- Lambart et al. (2012) determined that the interaction of melts
ene crystallization while inhibiting that of plagioclase, may not derived from pyroxenite veins with peridotite leads to the crys-
suffice to explain the large volumes of clinopyroxenite found in tallization of clinopyroxene and, depending on the conditions and
the Mansah diapir MTZ. If these formed by crystallization from compositions of the melt, to the crystallization of olivine and the
a magma, they should be conjugate to large masses of resid- dissolution of orthopyroxene or vice versa. Although their experi-
ual melt. The volume of the Wasit and Nidab intrusions, which mental conditions are not the same as ours (they consider lherzo-
could in theory represent such residual melts, is much smaller lite instead of harzburgite, their modeling and experiments were
than that of the crustal section conjugate to the thinner gabbroic performed at higher pressures and under anhydrous conditions),
MTZ of the on-axis diapir. Furthermore, even at water saturation, their study shows that it is possible to produce a large amount
the temperature interval for clinopyroxene fractionation without of clinopyroxene by melt interaction in the mantle over a wide
plagioclase is limited in MORB type magmas (∼40 ◦ C in experi- range of pressure and temperature conditions. An analogous pro-
ments using hydrated tholeiitic compositions; Koepke et al., 2009; cess could explain the clinopyroxenes found in the MTZ of the
Feig et al., 2010). So if the pyroxenites were cumulates from even off-axis diapir.
a water-rich MORB-type melt, it is surprising that they contain no We suggest that in the Mansah region, magmas formed by the
trace of plagioclase. partial melting of pyroxenite veins within an ascending astheno-
Thus an additional cause besides the presence of water may be spheric diapir. In Fig. 7, it is further speculated that a random
needed to explain the very large volumes of pyroxenite observed abundance of pyroxenite veins within the root of the on-axis up-
in the off-axis diapir. One possibility, developed below, is that the welling zone may have caused enhanced melting, and triggered the
compositions of melts delivered to the off-axis MTZ differed from off-axis diapirism. In the final stage of its ascent, the off-axis melt
those delivered on-axis, being enriched in a clinopyroxene com- reacted with the hydrated lithospheric harzburgite to crystallize
ponent. This hypothesis is supported by the difference in Sr, and clinopyroxene and some olivine, while dissolving orthopyroxene. In
especially Nd, isotopic composition between the MTZ of the two the model of Lambart et al. (2012), the scarcity of orthopyroxene
M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149 145
Fig. 7. Schematic cross-section of the flow structure with a possible mechanism for
the triggering of off-axis diapirism. Black arrows show large scale mantle flow, color
shades and solid contours show melt fraction in the melting region, which in many
classic models is triangular and centered on the ridge axis (e.g. Parmentier and
Morgan, 1990). A local high abundance of pyroxenite veins would produce an un-
usual amount of melting that could create a gravitational instability and trigger an
off-axis diapiric uprise superimposed on the normal flow. Also, because of its low
melting point and of the large base of the triangular melt production zone, it may
be difficult for any such heterogeneity to reach the axis unless it rose right beneath
the axis where the flow is strictly vertical.
Fig. 9. (a) Chondrite normalized Nd/Yb ratios in the calculated melts in equilibrium
with the clinopyroxenes in our samples and in Koga et al. (2001). Partition coef-
ficients used in the calculation based on the model of Wood and Blundy (1997).
All of the analyses are included for each sample. (b) Primitive mantle normalized
La/Nb ratios versus 143 Nd/144 Nd ratios in the calculated melts in equilibrium with
the clinopyroxenes in the off-axis pyroxenites. Here the partition coefficients of Hart
Fig. 10. Bottom: evolution of the off-axis Mansah diapir and formation of the Wasit
and Dunn (1993) were used to calculate liquid Nb and La contents, as values for Nb
and Nidab intrusions. Top: schematic diagrams of the REE compositions expected
are not available from the study of Wood and Blundy (1997). Though the exact val-
in the melts, clinopyroxene and/or whole rocks produced during each step of the
ues of the calculated La/Nb ratios will depend on the choice of these coefficients,
model (blue: observed; green: inferred liquid compositions that cannot be directly
the low La/Nb values obtained are consistent with the existence of negative Nb
observed). Circled letters in bottom panel correspond to REE evolution stages shown
anomalies in the equilibrium liquids. Data for the Geotimes (V1) and Lasail (V2)
in top panel. First, melting (at unknown depth but above the stability limit of gar-
lavas from Godard et al. (2006) and for N-MORB are shown for comparison (with
net) of a pyroxenite vein-rich zone triggers the rise of a diapir; after this diapir
the 143 Nd/144 Nd ratio recalculated at 95 Ma). Primitive mantle normalization values
reaches the base of the lithospheric mantle (depleted harzburgite), it continues to
taken from Sun and McDonough (1989).
ascend, incorporating the harzburgite and imprinting steeply plunging lineations;
melt interacts with harzburgite forming pyroxenite towards the top of the diapir
In the context of our model, the low incompatible element con- (light yellow); melt from the diapir intrudes into the overlying lithosphere, forming
the earliest Wasit–Nidab sills and lenses which may contain mantle xenoliths. In
tents of the off-axis pyroxenites could result in part from effective
the second stage (center), a large part of the depleted lithospheric mantle has been
dilution caused by interaction of the original pyroxenite-derived traversed and transformed by the diapir; early Wasit–Nidab intrusions are cross-cut
melts with lithospheric, depleted harzburgite (direct evidence for by the rising diapir, and the pyroxenite-bearing zone grows thicker. Finally, the di-
harzburgite assimilation, albeit at a higher level, is provided by apir reaches and tectonises the Moho and lowermost crust, and forms, in places, the
the ultramafic xenoliths in the Nidab intrusions). Clinopyroxenes crust–pyroxenite melange; the final Nidab intrusions are injected into the crust. Wa-
sit sills represent cumulates from the liquids expelled from the diapir, while Nidab
formed during melt interaction with depleted harzburgite are ex-
intrusions are approximate mixtures of liquids conjugate to the Wasit sills and to
pected to have more depleted REE spectra than those formed by the pyroxenite rich zones in the diapir. (For interpretation of the references to color
simple crystallization from melts. This effect might be enhanced by in this figure legend, the reader is referred to the web version of this article.)
direct melting of the hydrated harzburgites as the diapir ascends,
diluting the incompatible element contents even further, while those of the pyroxenites (Fig. A.5). Using the model of Wood and
having very little effect on Nd isotopic compositions, which would Blundy (1997), we calculated REE compositions of liquids in equi-
reflect those of the original pyroxenite veins. Nevertheless, as our librium with clinopyroxene from the Wasit sills (Fig. 8b). However
modeling shows (see electronic appendices), interaction with de- these values are only approximate, as the complementary Ta–Nb
pleted harzburgite, while greatly lowering REE contents, can ex- anomalies of the clinopyroxenes and amphiboles (Fig. A.6) sug-
plain only part of the relative LREE depletion. In other words, the gest post-crystallization re-equilibration occurred between these
pyroxenite veins in the source must themselves have been some- two phases.
what LREE depleted. The Nidab intrusions, which have bulk major element composi-
tions approximating those of basaltic liquids (Fig. A.1) and nearly
5.5. Origin of the Wasit and Nidab intrusions
flat whole rock and clinopyroxene REE spectra (Figs. A.3 and 4b),
Lambart et al. (2012) show that reaction of pyroxenite-derived may represent mixtures between liquids residual to the pyroxen-
melts with peridotite generates a second melt, of quantity and ites and those residual to the Wasit sills. The Nidab intrusions
composition dependent on the conditions. If the pyroxenites of the contain abundant amphibole-rich veins and numerous ultramafic
off-axis diapir formed by an analogous process, the resultant melt and crustal xenoliths, suggesting that they have assimilated litho-
may have escaped above and on both sides of the ascending di- spheric material hydrated by hydrothermal circulation of seawater.
apir, forming melt lenses in the surrounding mantle (Fig. 10). Given This could explain why the Nidab intrusions, while having Sr and
their MgO and Ni rich compositions, the Wasit sills may represent Nd isotopic compositions broadly similar to those of the pyroxen-
cumulates from such melts, thus explaining why they share the ites and the Wasit sills, include samples with somewhat elevated
87
same Sr and Nd isotopic compositions as the pyroxenites. Clinopy- Sr/86 Sr ratios even after leaching. The full-overlap between the
roxenes from the Wasit sills display LREE depletion similar to, but εNd values of the Wasit and Nidab intrusions surrounding the
slightly less marked, than that of clinopyroxenes from the pyrox- off-axis diapir, and those of the pyroxenites within the diapir, sug-
enites (Fig. 4). However they have much higher overall REE levels, gest that all of these rocks form a magmatic suite, derived from
suggesting that their parental melts experienced extensive olivine the same initial melts. The minor heterogeneity of the Nd and Sr
and minor clinopyroxene fractionation prior to crystallization of isotopic signatures at the level of the MTZ could reflect isotopic
the sills. This is supported by the lower Fo contents of the Wa- variability among the pyroxenite veins that provided the original
sit olivines and the lower Mg# of their clinopyroxenes relative to melts.
M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149 147
The structural positions of the Wasit sills and Nidab intrusions V2 magmatism (somewhat tenuous in our view, since as noted
can be understood within the context of the off-axis diapir. The above, V2 and V1 magmas have indistinguishable ε Nd values), ar-
absence of sills within the diapir and the sheer zone separating guing that both formed in a proto-arc setting. Since the samples
the diapir from the Wasit sills of the surrounding mantle suggest analyzed by Rioux et al. (2013) were collected far from the Mansah
that as the diapir ascended towards the Moho, it progressively en- diapir and in the upper crust rather than the MTZ, their pertinence
gulfed the lithospheric mantle containing the Wasit sills and Nidab to the age of this structure is not obvious. In the shallow subduc-
dikes that were produced above and at its periphery (Fig. 10). The tion model of Boudier et al. (1988), oceanic detachment is inferred
presence of elongated and rounded mantle xenoliths in the Nidab to occur along the asthenosphere–lithosphere boundary. Since the
intrusions would not be possible if the Nidab intrusions were pro- Mansah diapir shows asthenospheric flow structures, if this model
duced only after the diapir had reached the Moho. These intrusions is correct, emplacement of the diapir must predate detachment
are only present in the last few meters of the mantle and in the and thus be roughly concomitant with magmatism at the ridge
lowermost crust. We suggest that to first order, the Nidab lenses axis. Therefore, clarification of the tectonic context of the off-axis
represent the liquid produced by melt–rock reaction in the diapir, diapirism requires precise determination of its timing.
mixed with residual liquids from the Wasit sills and modified by We conclude that there is no compelling evidence to suggest
interaction with the pre-existing crust and uppermost mantle. that development of the Mansah structure was related to fluids
rising in a supra-subduction zone setting. Nevertheless, more work,
5.6. Could the Mansah diapir result from SSZ magmatism? in particular U–Pb zircon dating (e.g. Rioux et al., 2013) of rocks
associated with the Mansah diapir, is needed to better define the
As discussed above, we think that our off-axis results are most tectonic setting in which the diapir ascended.
simply explained by interaction of pyroxenite-derived melts with
hydrated, depleted harzburgites in the lithospheric section tra- 6. Summary and conclusion
versed by an upwelling diapir. Nevertheless, we must consider the
alternate possibility that the unusual features of the Mansah diapir Our study of the Mansah diapir of the Oman ophiolite pro-
reflect late-stage magmatic processes in an SSZ setting. Though the vides new insights into off-axis magmatic processes, particularly
absence of arc volcanism or of any volcaniclastic sediments, and those occurring in the critical crust–mantle boundary region. The
the lack of arc-like trace element signatures (Godard et al., 2006) Moho Transition Zone (MTZ) of this off-axis diapir displays plung-
argue against the existence of a fully developed subduction envi- ing lineations that cut at high angle the horizontal foliation of the
ronment, evidence exists from throughout the ophiolite for higher surrounding mantle, contrasting with the continuity from vertical
fluid contents in the magmatic sources relative to those of MORB to horizontal mantle flow observed in on-axis diapirs. The MTZ
(MacLeod et al., 2013). Given the tectonic complexity that surely of the off-axis diapir is even thicker than that of the nearby on-
existed prior to obduction, such hydrous conditions could perhaps axis Maqsad diapir and contains massive clinopyroxenite lenses in
be reconciled with several different models. dunite, rather than the gabbroic lenses in dunite found in the on-
The REE spectra of clinopyroxenes from the Mansah pyroxen- axis case. Gabbroic sills intrude the mantle around the off-axis di-
ites resemble those of clinopyroxenes from lower crustal wehrlites apir and microgabbroic intrusions are found in the overlying crust.
of the Haylayn block described by Koepke et al. (2009), which they Clinopyroxenes from the off-axis pyroxenites were derived from
related to the Lasail magmas (also called V2) found in the northern melts more depleted in incompatible elements than their on-axis
part of the Oman ophiolite (Ernewein et al., 1988). These late- equivalents. However, the Nd isotopic composition of the off-axis
stage magmas are thought to result from fluid-enhanced melting melts indicates a less depleted source (ε Nd = 6.2–7.9 in 18 of 19
of previously depleted lithosphere, with the fluids derived from analyses) than that of the on-axis melts (ε Nd = 7.8–9.2, 10 analy-
dehydration of sediments and altered crust of the underlying slab ses), which are isotopically similar to Indian Ocean MORB.
during incipient (Boudier et al., 1988) or more well-developed To explain these unusual features, we suggest that in the off-
(Pearce et al., 1981) subduction. However several observations ar- axis setting, a diapir rooted in the asthenosphere ascended through
gue against a subduction related origin for the Mansah diapir. The the depleted, hydrated lithosphere. The first melts to form were
negative Nb–Ta anomalies characteristic of lavas from SSZ settings derived from pyroxenite veins at depth, as suggested by the less ra-
are lacking in Mansah, notably among the rocks with composi- diogenic ε Nd values of the off-axis samples. During its ascent, the
tions most closely resembling those of liquids (Nidab intrusions, diapir assimilated parts of the hydrated and depleted lithosphere
Fig. A.4). Moreover, although the presence of abundant clinopyrox- in its path. As the melt rose, it interacted with the lithospheric
ene is considered to be an argument in favor of SSZ settings, the harzburgite, forming clinopyroxene and olivine at the expense of
liquids in equilibrium with our off-axis pyroxenites lack the nega- the orthopyroxene, and acquiring a more depleted trace element
tive Nb anomalies that characterize lavas from SSZ (Fig. 9b; ratios signature. As harzburgite contains very little Nd, this process had
La/Nb <0.5). V2 magmas have never been found in the Sumail little effect on Nd isotopic compositions. The water derived from
block, while in the northern blocks of the ophiolite, where these this hydrothermally altered lithosphere enhanced the crystalliza-
magmas are located, no structures resembling the Mansah diapir tion of clinopyroxene and suppressed that of plagioclase. The gab-
exist. The V2 magmas have Nd isotopic compositions very similar broic sills found in the mantle around the diapir are cumulates
to those of the V1 (i.e., ridge-related) magmas (V1: ε Nd = 7.9–8.8; formed from the fractionated daughters of liquids produced by the
V2: ε Nd = 7.3–8.7; Godard et al., 2006) and of the on-axis Maqsad reaction between the harzburgite and pyroxenitic melts, while the
diapir (ε Nd = 7.8–8.8). In contrast, samples related to the off-axis microgabbroic intrusions, found essentially in the crust, represent
Mansah diapir have mostly less radiogenic values (ε Nd = 6.2–7.9). the approximate corresponding liquid compositions.
This contrast in Nd isotopic composition suggests that the Mansah The less radiogenic Nd compositions of the off-axis samples add
diapir is not genetically related to the V2 magmas, so even if the to the growing evidence for the presence of pyroxenite veins in the
latter have a subduction-related origin this does not imply a simi- MORB mantle source. This component was probably present in the
lar origin for the Mansah magmas. source of both diapirs, but in on-axis magmas its signature was
Rioux et al. (2012, 2013) found that post-ridge magmatic muted by a larger relative contribution from peridotite melts. Our
crustal intrusions from the Sumail, Wadi Tayn and Rustaq–Haylayn results show that off-axis melt delivery can have a major impact
massifs have younger U–Pb zircon ages and slightly lower ε Nd val- on the mineralogy and geochemistry of the magmatic products.
ues than ridge related magmas. They therefore drew a parallel with As most of the geophysical evidence for off-axis deep magmatic
148 M. Nicolle et al. / Earth and Planetary Science Letters 437 (2016) 138–149
activity at fast spreading centers is recent, the importance of such Godard, M., Dautria, J.-M., Perrin, M., 2003. Geochemical variability of the Oman
processes may have been underappreciated. ophiolite lavas: relationship with spatial distribution and paleomagnetic direc-
tions. Geochem. Geophys. Geosyst. 4. http://dx.doi.org/10.1029/2002GC000452 .
Godard, M., Jousselin, D., Bodinier, J.L., 2000. Relationships between geochemistry
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line at http://dx.doi.org/10.1016/j.epsl.2015.12.005 . below a paleo-spreading center in the Oman ophiolite. J. Geophys. Res. 103,
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