Quaticative We can divebe the sai anya wt fe art (1) Anaten of acute reais aK | | (2) Anahyes of basic raaicals .@ cabOF | Anatraia of Ackdhc Reims: ute ov tue wmrencaton cf arora in gen aaa, fat we ichve the sft satte wo! (AR VE OS, {SsOe cone HiSO.) each case a chwractersar gas tm Moeraind Thess DTS SG rmation of | sees hua which conf tho aneon Le cic radicals by the colour chackze oioured compound ne precaptales Se Peer ar oncormponed by ie HC, 1 aan M50," cone Hi SO, mmm we aes pertorm ceria ssvtctic tests) see can clase tne anions in fies gro | Sega. 1(0) catonate (2) sche (c sprade (3) nara, (2) sexta The radicals af group 1 are decomposed by dit HC, or die HySO. / Cese.h a conde (a bromide Ke Hote} ate {0} cui | ‘The racicas of group 2 are decomposed By cane: MSO. / Mesa 8) were (b) phosphate .(c ) Dorms . (dl) fhaartie. {ihe radicals of group 3:40 nal gre any charactensi gas wath chute conc. aif HE! of MSO ‘Tests with reactions and explanations “outs of sche cada of Grou 1 | (a) Caronete(CO)*): tne carbonains are decomposed with diikie HC! of éhute WSO. with the evciution of errr pan. Wen bes gas 8 pan! Bw hme wate Doe we water ens cilky with the ormanon of caicrum carbonate | Na.CO, +H SO, -» Na.SO, + H0+CO. Ca\OW), «CO, + 4.0 + Ca'D, & | However. the CO, gas s passed in excess the mhy solution becomes cxiourless due to the formation of ohio catcum bicarbonate } CaCO, 4 9.04.00. + CaCO), Note. This test also given by SO? a | (>) Suiphae(80,") - A suiptite with diute H;SO. gres cul sulphur chante gas which possesses suffocating ‘eal of burn ssh ‘When aciditod potussum dichromate paper & exposed to the gas it atlas geen ‘solou! due to he Formation of chromic sulphate. NaS = SO,» Na 80+ 104 80 KO WSU, AMD + B80, C180) HO : “ () Bulphida(8?) - Date 1,50, decomposes 4 sulphicke sal form HAS gas which senels ike roten egos. NaS +H SO, Na SOs HST On enponure lo the gas, the lead acetate paper wns Mack deur lo the formation of mad sulphicie LS 1CHCOO) Po» PAS CH. COONQuaitistrre Ansiysis — Or on reaction with sodium nitro prusiide, Ma$ germs pure colons NaS) Nu[RACNE,NO] © NeLAAON MOL (d) Nie (MO) - Wher a nti a Wealed wih ie HO. yen »extuatons nic onde gaat} {contact wth oxygen of the at Becomes brswn dun to tee fowmation NaNO © H.SO, + No.8, 2HNO. VHNO, + NO 22N HO (Dkypmpertinmacn) INO 0, 9 2NOAg)T “a |. On passing he gas in diule FeSO, wchston, brow calpyred comes sa torment Fest), 71.0.6 80-4 [Fett 0,80], +2110 a decanposed gpre eciet vapours of 1 When a muniure of dice and nara a reactec wits HS. ve ede i gdne 2NaNO. 411,80,» Na,SO, © 2HNO- 2+ 1.80, + SO, «HE IWNO NEOs 1 Tot J. + starch + bbe colemar Suvch edge paper is ume blue due tothe iberaton of xine fam sodide bry nitrous acid whech eves blun colo win stares je) Acetate lon (CH,C00 }: -Acatates when heated wih dixie H,S0, decompose to ge acetic ack wapows which pussess characteroc prneil of vie@aat, 2CH,COONa + Ht SO, -» 2CH COOH + Na.SO, 1 On additon of neutral FeCh soliton to the sokdion of an acetate, Bieed med eoteuration dnveiops due to | the formation of fer: acetate. Foti» ACH COONa 94 CH C00), Fe + NACT 2. Actes are gis decomposed wilh oxakt acad and grre off acetic ac CH COON ECO, 9 ROH CDOH 4 Na O0, ‘Tete of acidic radicals of Growp 2 | Tone small amount cf fre substance and add low drops of concendrated HSC, wait gantly. observe Ie changes | ‘Vesta with reactions and enpienatons | ey a emt te tt ee NaF HS, + Nuff, « HEL | Yetoe wh -grepn gas of cone (Cl) eh Miocaing oduu © evoked. when Chonda = mexed manganete donde mri healed with cane HS, ~ . = AuCP< TSO,» NaHS, + CD Moth ANCL + Mac hae OTThe gas evaived by heating chiorde with sulphune acd forms wivie Rurnes of ammonsue ciiorise wah NHLOM NAOH + HEL + NE Ho w "The gas evolved by heating chionde wah HO. lorena a curdy whale procsiain of sivet chlance wy srver firate solution The preciptates af ACI nolubse in exonss of Ammann hydronde sokiion AgNO, HOD 9 ae hd OHNO, a fig Te NAOH + | dg NAL JOE UL \wow Cchromy! ehtoride twat whan sok chloride Naatnd with conc HSO.in presence of KC GeD Fest \ ‘ROUEN of Cuomyt chionde are evolved | Vols H SO, 9 Nati, + WET KO 2 SO, + IKNSO, 10 HO | CrO, HEE OC) HO | |Wnen these vapours are passed fhrough NaC sakuon the solution becomes yellow duc to the formaton of | ‘soma roma | CrO.C1 + 4NQOM -» Na,CrO, + 2NaCT + 2H ‘he yetow schiton 1 neutaised wh scm acd and on ada of tad aca ores a Yodo Dinette of | | ead chromate | Na, CrO, (CH COO), Pb 9 POCO, b+ 20H. COON | | (o) Riromidie(Bir}: Redcesh-brown fumes ol bromne are fared whan he sobd bromade is healed with Cone: H:80x | Null HLSO, + NaltSO, «tthe | 2B 6 SO, 9 He «2+ SO, More reddinh-brawn furnes of Brame Can be obtained on aditon of MeO> | Mit SO, Abas, HOO Die + FIO Be at raection is Nar + Min, «MSO, -+ 2 NaPESO, + MnSQ, + 24,0 + Be, | The aqueotss solution of bromide given, id inves trarnicte h pase volo pimcspdat (city wile precaotate | Sasa enue fH, arm eke compton Presets Agr party wohabe in Recnsary power of halogens acts Ce ee alle 6 4g 8 tate Ls Saved fire OME 6 Ltt SAE), le HOHi Chhorotorm wayer_teet Wher the frost sa or manture is treated with citer S04 CHE (ar CCL OF replaces the hromce aa brottine aid the liberated tirorrerwe diseases in) CHC: fwown apiour (CS )) ana chionne water chiesme foe CClaoe C5) bnver wove IAM UT 8 REDS Be ie + chaararme Hore aver | (chhodidde (1) Vioket vaso adie are evolved on heating sore with concaearatecd HiGO+ fbi RIND, = 2H Mi WE eh ee More woln! vapours can be obtained on axkstor of Mrs IRE eH SO, 0 ND TE Moe 6 WS, 8 Mast 9 10 | dhe atta Met reaction /s a + Mit, © SOD on SAHIN « Md» eh 1 Yiaiet wapours win starch produce Bie coms Tete + Mls cine in exces of NKLOW sh + dO tat + NaN, | | | | | wl Chloroform tweet leet nen a gran wtstance ms rwatec wth tule HBO CHG (oF GO| and chiens see chigrme repiace the dite we ocine which dasoeven m CHC (or CCl. | layer giog # wea cols dai te tweed | FOE one he Nigh? © ANG, NahiSO, «INO: ane, IH OAND 0 These fumes internsty when copper haningys are ached Cy ANNO 6 NO) INO 20 substance m (rented with Feahiy prepared mokilion of ferrous Ring test when the aqueous sutton of the fing 10 formed due to the formabon of a comples at le sUiphate nd cone iSO. a brown Jue of tr as Na, 18,90, 9 abd, + TENE), fheSO, DUNG MESO, 9 Me (NO), «FLO INO) [Petit On I, AO) NO oben, NOW 20.0 —— Page 40) Oxstate{Cr0,") wher oxatate os hemled wth cone 1,550. a merhae of CO ane CO, reen oft The CO | buena frit tue flere | Nw C0) ITSO, 9 Ne.80, ICO, N00, e000 LO CO” untae atic ot Gone | Some anions are Kentfied by they charaxtenak: cherscal reactor phosphate and tuonde: These rachonis are sulphate borate, (a) Suiphata($0.!),dissotve itie amount of he subatanicr (sai ot ren) ‘A wie pessighlale rmokube iv conc HNO: eer Reaction with explanation while precistate of baum sdhte i obkeined! treated wiih barium chianate rokulion: Na S02, + at? 9 DNael'D + aS, + {Thee wetute precipitate a insciitte # cone: HNO Wine” Conan chionde e.g NaCl and Bah when present tage carmen may form a white precipdate ‘which dissolve on cthubon wit wile Hote, Sliver ang Imad (or Hay" of Car by the sadiéon of banum ction ‘To avced i baru eae ry be sent plac of num HOTS | 3 To email quantty off substance (sat cf anture), ack! Sew a of et alco ane | (gi OSE 9 et 2 glam Fr Hale at be ane rng a meu of te est hbo meat | | | | 1 pemnant nay be precited a vive core and mod cherie | | | Aesction with explanation: Wien orate 16 Heated wih hy skal and HSC ett Dae. YAR oath ul whee!) ‘burn wath sree edged fheere, \ 2h BO, + SO), 9 Na 50, + 2B, ew ast 11,80..3CH,.0H ACH), BOO | mers, 1 ote: in place of eftyt alaahol. metty! aleahol car also be (sed | TNote: This tes! should be performed in a Nest lube and pot in a porcolase ban because copper oF barki sums, # present wall come in cottact with tie flame wtuch aio gres. gree Haas | {c) Prosphete(PO.'): Take stra! amount of the subslance in 2 lead lube and add 2 mt cone HNO, Heat | and add 2 mi ammonum molybdate solution Agen heat A canary yeiow precioitain indicates the presence id phosphate | Reaction with explanation: The canary yatow precpiaie is. due to the formation of ammonum af PO) RANE 6 Cat 901, 2H PO, JED AUNT) Mot THIN ONE) PO, LRG. QUNIE NOLO Wow: Anenic a4 As0,)(Arvanate) under serdar concition min yeeuia a yelow precistnie of "Aa, T2M, jammonnanarsano mesyania So ' Heid at occu earnest ns ent meres 902". Gnome MO the CAG} Page 5(6) Faveriae(F i; Take a small amount of the substance ina dry tee! kdbe and add an equal amount of sand Mi fhe contents and add conc 150. Heal the contents and plane a metal rod over the movth of the test ‘Wibe. A wary white epos on the rod is formed, Resctons with explenstion: the fuorde with conc H;SOs forms Hf (Iyrdroftuonc: acid) which attacks thca forrreng silicon letra fuorde. Sis “The vapours of SF, are hydechysed by HO ao gelatingys siicoc ad SHOM ) which 19 Oepoeted on the tod. Dhak + HSO, + Ne SO, + HF SHO, 2 F 9 SU + AMO ASIF, 441 O40,» 2H SR, eote: The teat shouk! be pertormed in parlecty dry test tube; ctheratee wamy mite: Gepost walt not be formed ote: oCk and NH,C} alse produces a depost under theve condiiors, tall thes doposs.\ crrstalins \9 nature