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4 5886482142090757881
4 5886482142090757881
PART I I
1- STATE OF MATTER 1
2-ATOMIC STRUCTURE 13
3- ISOTOPES 31
4- BONDING 43
5- CHEMICAL FORMULA 49
cover slips
A chemical reaction
B condensation
C diffusion
D evaporation
2- The diagram shows the result of dropping a purple crystal into water.
water purple
after five hours solution
purple
crystal
chemical
diffusing
iffusing d
reaction
A
B
C
D
3
3- The diagram shows a sugar lump in a cup of tea.
Which two processes must happen to spread the sugar evenly in the tea?
A diffusion dissolving
B dissolving diffusion
C dissolving melting
D melting diffusion
5- The particles of a substance gain energy and change from a regular ordered structure to a
disordered structure with large distances between the particles.
A boiling
B evaporation
C melting
D sublimation
4
6- The diagram shows an experiment to demonstrate diffusion.
Which statement explains why the ring of ammonium chloride appears as shown?
A Ammonia solution only produces a gas which moves until it meets the hydrochloric acid.
B Both solutions produce a gas, but ammonia moves quicker than hydrogen chloride because
it is lighter.
C Hydrochloric acid produces hydrogen chloride which stays at one end of the tube until the
ammonia reaches it.
D The two solutions run along the tube until they meet.
7- Small crystals of purple KMnO4 (Mr = 158) and orange K2Cr2O7 (Mr = 294) were placed at the
centres of separate petri dishes filled with agar jelly. They were left to stand under the same
physical conditions.
After some time, the colour of each substance had spread out as shown.
dish 1 dish 2
KMnO4 K2Cr2O7
The lengths of the arrows indicate the relative distances travelled by particles of each substance.
5
8- Small crystals of purple KMnO4 (Mr = 158) and orange K2Cr2O7 (Mr = 294) were placed at the
centres of separate petri dishes filled with agar jelly. They were left to stand under the same
physical conditions.
After some time, the colour of each substance had spread out as shown.
dish 1 dish 2
KMnO4 K2Cr2O7
The lengths of the arrows indicate the relative distances travelled by particles of each substance.
6
9- In which changes do the particles move further apart?
W X
gas liquid solid
Y Z
X Y Z
A X to Y B Y to Z C Z to X D Z to Y
11- ‘Particles moving very slowly from an area of higher concentration to an area of lower
concentration.’
7
12- ‘Particles moving very slowly from an area of higher concentration to an area of lower
concentration.’
8
13- Which process causes the greatest increase in the distance between particles?
A condensation
B freezing
C melting
D sublimation
A Particles moving slowly past each other speed up and move further apart.
B Particles vibrating next to each other become mobile and move slowly past each other.
C Particles vibrating next to each other start to move rapidly and move further apart.
D Rapidly moving particles slow down and move closer together.
9
16- Compound X is a colourless liquid at room temperature.
(a) A sample of pure X was slowly heated from –5.0 °C, which is below its melting point, to 90 °C,
which is above its boiling point. Its temperature is measured every minute and the results are
represented on the graph.
F
90 °C
D
E
temperature
B
t °C C
A
–5 °C
time
(i) Complete the equation for the equilibrium present in the region BC.
X(s) ....................
.......................................................................................................................................
.......................................................................................................................................
(iv) What would be the difference in the region BC if an impure sample of X had been used?
.......................................................................................................................................
10
17- Matter can exist as solid, liquid or gas. The arrows show some changes of state.
solid
A B
liquid gas
(i) A ....................................................................................................................................
(ii) B ....................................................................................................................................
(iii) C ....................................................................................................................................
(b) Explain why energy has to be supplied to turn a liquid into a gas.
....................................................................................................................................................
..............................................................................................................................................
11
18- The graph shows how the temperature of a substance changes as it is cooled over a period of
30 minutes. The substance is a gas at the start.
300 S
250 T
V W
200
X
temperature Y
150
/ °C
Z
100
50
0
0 10 20 30
time / minutes
Each letter on the graph may be used once, more than once or not at all.
(i) the particles in the substance have the most kinetic energy,
. ......................................................................................................................................
. ......................................................................................................................................
. ......................................................................................................................................
(b) Use the graph to estimate the freezing point of the substance.
.............................. °C
..............................................................................................................................................
(d) W
hen smoke is viewed through a microscope, the smoke particles in the air appear to jump
around.
. ......................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ......................................................................................................................................
12
13
14
1- Which statements about a phosphorus atom, 31
15 P , are correct?
2- Element X is a non-metal.
15
3- The diagram shows the structure of an atom of element X.
e
key
e e e = electron
n = neutron
5p p = proton
6n
= nucleus
e e
What is X?
A boron
B carbon
C sodium
D sulfur
4- Element X is in Group I of the Periodic Table. X reacts with element Y to form an ionic compound.
Which equation shows the process that takes place when X forms ions?
A X + e – → X+
B X – e – → X–
C X + e – → X–
D X – e – → X+
16
5- Two atoms, X and Y, can be represented as shown.
41 45
20 X 20 Y
6- Two atoms have the same relative atomic mass but different chemical properties.
Which row about the proton and neutron numbers of these atoms is correct?
A different different
B different same
C same different
D same same
7- Which statements comparing the properties of electrons, neutrons and protons are correct?
A
B
C
D
17
8- Q+ is an ion of element Q.
9- Which statements comparing the properties of electrons, neutrons and protons are correct?
A
B
C
D
18
10- Two atoms have the same relative atomic mass but different chemical properties.
Which row about the proton and neutron numbers of these atoms is correct?
A different different
B different same
C same different
D same same
11- Which statements comparing the properties of electrons, neutrons and protons are correct?
A
B
C
D
19
12- Element X has a nucleon (mass) number of 19 and a proton (atomic) number of 9.
A I B III C VII D 0
13- The table shows the structure of different atoms and ions.
Mg 12 24 12 W 12
Mg2+ X 24 12 12 10
F 9 19 9 Y 9
F– 9 19 9 10 Z
W X Y Z
A 10 10 9 9
B 10 12 10 9
C 12 10 9 10
D 12 12 10 10
20
14 Which statement is an example of diffusion?
e e
e e
key
e e e electron
e e n neutron
e 16n e
e e nucleus
e e
A Al B P C S D Si
21
17-
Which statement about a neutron is not correct?
e e
e e
key
e e e electron
e e n neutron
e 16n e
e e nucleus
e e
A Al B P C S D Si
22
19- An element, X, can be represented as ba X .
20- Which information about an element can be used to predict its chemical properties?
A boiling point
B density
C melting point
D position in the Periodic Table
21- The table shows information about atoms of three different elements.
chlorine 17 35 17 W 17
chlorine 17 X 17 19 17
argon Y 40 18 22 18
potassium 19 39 19 20 Z
W X Y Z
A 18 35 18 19
B 18 36 18 19
C 19 35 19 18
D 19 36 19 18
23
23- ‘Particles moving very slowly from an area of higher concentration to an area of lower
concentration.’
24- An atom has three electron shells. There are three electrons in the outer shell.
How many protons and how many neutrons are in this atom?
protons neutrons
A 13 14
B 13 27
C 14 13
D 21 24
24
25- Complete the following table which gives the number of protons, electrons and neutrons in each
of the five particles.
19 19 20
..............
56
26 Fe
.............. .............. ..............
3 2 4
..............
70 3+
31 Ga
.............. .............. ..............
34 36 45
..............
.......................................................................................................................................
.............................................................................................................................................
.......................................................................................................................................
(b) The table shows the number of protons, neutrons and electrons in some atoms or ions.
B 12 12 12
C 8 16 2-
8O
D 11 10 13
25
27-
Concentrated ammonia solution gives off ammonia gas. Concentrated hydrochloric acid gives off
hydrogen chloride gas. Ammonia, NH3, and hydrogen chloride, HCl, are both colourless gases.
Ammonia reacts with hydrogen chloride to make the white solid ammonium chloride.
glass tube
After ten minutes a white solid forms in the tube where the gases meet.
(a) (i) Write the chemical equation for the reaction of ammonia with hydrogen chloride.
. ......................................................................................................................................
(ii) Name the process by which the ammonia and hydrogen chloride gases move in the tube.
. ......................................................................................................................................
(iii) At which point, A, B, C or D, does the white solid form? Explain why the white solid forms
at that point.
explanation ..........................................................................................................................
. .....................................................................................................................................
Predict how the results of the experiment would be different. Explain your answer.
. ............................................................................................................................................
. ............................................................................................................................................
. ......................................................................................................................................
26
28- (b) State what is meant by the terms
(i)
element,
..............................................................................................................................................
........................................................................................................................................
(ii)
compound,
..............................................................................................................................................
........................................................................................................................................
(iii)
ion.
..............................................................................................................................................
........................................................................................................................................
proton +1
neutron 1
electron
27
30- Rubidium and strontium are very reactive metals at the top of the reactivity series. Because their
ions have different charges, their compounds behave differently when heated.
(a) The formulae of the ions of these two elements are Rb+ and Sr2+.
Explain why these metals, which are in different groups, form ions which have different charges.
....................................................................................................................................................
..............................................................................................................................................
(b) (i) How many protons, neutrons and electrons are there in one copper(II) ion 64
29 Cu 2+ ?
45
(ii) 21 Sc represents an atom of scandium.
How many nucleons and how many charged particles are there in one atom of scandium?
28
31- (a) (i) Define the term molecule.
. ............................................................................................................................................
. ......................................................................................................................................
. ............................................................................................................................................
. ......................................................................................................................................
(b) The table shows the composition of four atoms or ions, A, B, C and D.
. ......................................................................................................................................
. ......................................................................................................................................
. ......................................................................................................................................
. ......................................................................................................................................
. ......................................................................................................................................
(c)
Complete the table.
number of number of
protons electrons
Na
S2–
Cl 2
29
3030
31
32
1- The diagrams show four particles.
1 2
e e
e e
2p 3p key
2n 3n e = an electron
n = a neutron
e e
p = a proton
= nucleus
3 4
e e
e e
3p 3p
3n 4n
e e
e
Which two diagrams show atoms that are isotopes of each other?
A 15 B 23 C 30 D 46
33
3- The diagrams show four particles.
1 2
e e
e e
2p 3p key
2n 3n e = an electron
n = a neutron
e e
p = a proton
= nucleus
3 4
e e
e e
3p 3p
3n 4n
e e
e
Which two diagrams show atoms that are isotopes of each other?
particle
p article el neutrons protons
W 8 9
X 7 9
Y 8 1
Z 9 1
34
5- Two atoms, X and Y, can be represented as shown.
41 45
20 X 20 Y
1 They are atoms which have the same chemical properties because they have the
same number of electrons in their outer shell.
2 They are atoms which have the same number of electrons and neutrons but
different numbers of protons.
3 They are atoms which have the same number of electrons and protons but different
numbers of neutrons.
used as
compound A an energy
source
C
B D
radioactive
35
8- Which statements about isotopes of the same element are correct?
1 They are atoms which have the same chemical properties because they have the
same number of electrons in their outer shell.
2 They are atoms which have the same number of electrons and neutrons but
different numbers of protons.
3 They are atoms which have the same number of electrons and protons but different
numbers of neutrons.
used as
compound A an energy
source
C
B D
radioactive
36
10 Two isotopes of hydrogen are H
1 2
1H 1H
e e key
e = an electron
A n p
p = a proton
e n = a neutron
e e = a nucleus
p
B p
n
e e
p
C p
p
e
p p
D
n n
37
11- Which diagram does not show the outer shell electrons in the molecule correctly?
A B C D
H H H Cl H C H Cl Cl
A nucleon number
B number of electron shells
C number of electrons in the outer shell
D proton number
38
13- What do the nuclei of 11H hydrogen atoms contain?
14- Which statement explains why isotopes of the same element have the same chemical properties?
15- Carbon has three naturally occurring isotopes, 12C, 13C and 14C.
Which statement explains why the isotopes have the same chemical properties?
39
16-
23 24
(c) Two different atoms of sodium are 11 Na and 11 Na .
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(ii) 24
11 Na is radioactive. It changes into an atom of a different element which has one more
proton.
. ...................................................................................................................................... [1]
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(i) In terms of numbers of protons, neutrons and electrons, how are these three isotopes the
same and how are they different?
.............................................................................................................................................
.............................................................................................................................................
[3]
(ii) Why do all isotopes of carbon have the same chemical properties?
....................................................................................................................................... [1]
40
18- Carbon and silicon are elements in Group IV of the Periodic Table. Both carbon and silicon exist as
more than one isotope.
.....................................................................................................................................................
............................................................................................................................................... [2]
(b) Complete the following table which gives information about carbon atoms and silicon atoms.
carbon silicon
proton number
electronic structure
nucleon number 12 28
41
19- .Six different atoms can be represented as follows
3 3 12 13 14 19
1A 2D 6E 6G 7J 9L
(b) Two of the six atoms shown are isotopes of each other.
..............................................................................................................................................
........................................................................................................................................ [2]
(ii) Which two of the six atoms shown are isotopes of each other?
........................................................................................................................................ [1]
..............................................................................................................................................
........................................................................................................................................ [1]
42
43
44
1- The electronic structures of two atoms, X and Y, are shown.
X Y
What is the type of bonding in the compound and what is the formula of the compound?
A covalent X2Y
B covalent XY2
C ionic XY2
D ionic X2Y
1 methane
2 lead bromide
3 sodium chloride
C
A D
B
45
4- In which compounds are pairs of electrons shared between atoms?
1 methane
2 lead bromide
3 sodium chloride
W 2,8,1
X 2,8,4
Y 2,8,7
Z 2,8,8
6- Which statement describes the attractive forces between molecules (intermolecular forces)?
46
7- Part of the Periodic Table is shown.
Which element is a gas that does not form a compound with potassium?
A B
C D
19 39
Element X, 9 X , forms a compound with element Y, 19 Y .
1 methane
2 lead bromide
3 sodium chloride
47
9- Part of the Periodic Table is shown.
Which element is a gas that does not form a compound with potassium?
A B
C D
W 2,8,1
X 2,8,4
Y 2,8,7
Z 2,8,8
10- Which statement describes the attractive forces between molecules (intermolecular forces)?
48
11- Caesium chloride and rubidium bromide are halide compounds of Group I elements.
Caesium chloride has the formula ……1……, a relative formula mass ……2…… that of rubidium
bromide and bonds that are ……3…… .
1 2 3
12- Which dot-and-cross diagram shows the outer shell electron arrangement in a molecule of
nitrogen?
A B C D
N N N N N N N N
49
13- Metal P reacts with non-metal Q to form a compound.
H O
H C C
H O H
Which diagram shows the arrangement of outer shell electrons in a molecule of ethanoic acid?
A B
H H
O O
H C C H C C
O H O H
H H
C D
H H
O O
H C C H C C
O H O H
H H
50
15- Ethanol is a liquid at room temperature and boils at 78 °C.
Which statement about the bonding in ethanol and sodium chloride is not correct?
16- The molecules N2, C2H4, CO2 and CH3OH all have covalent bonds.
These bonds consist of shared pairs of electrons.
Which row gives the total number of shared pairs of electrons in the molecules shown?
A N2 2
B C2H4 6
C CO2 2
D CH3OH 4
51
17- Which dot-and-cross diagram shows the outer shell electron arrangement in a molecule of
carbon dioxide?
A B C D
O C O O C O O C O O C O
gro
group II III IV V VI VII VIII
element R S T V W Y Z
52
19- c) The structural formula of carbonyl chloride is given)
.below Cl
C O
Cl
Draw a diagram showing the arrangement of the valency electrons around the atoms in one
molecule of this covalent compound.
20- (b) Scandium fluoride is an ionic compound. The valency of scandium in scandium fluoride is
three.
Draw a diagram which shows the formula of this compound, the charges on the ions and the
arrangement of the valency electrons around the negative ions.
21- Calcium reacts with nitrogen to form the ionic compound calcium nitride, Ca3N2.
(a) Draw a diagram, based on the correct formula, which shows the charges on the ions and the
arrangement of the electrons around the negative ion.
53
54
22- (c) The diagram shows the electron arrangement in a molecule of ammonia, showing only outer
shell electrons.
N H
.......................................................................................................................................
H H
N N
H H
55
(d) Magnesium reacts with sulfur to form the ionic compound magnesium sulfide, MgS.
The diagrams show the electronic structures of atoms of magnesium and sulfur.
Mg S
56
23- Nitrogen can form ionic compounds with reactive metals and covalent compounds with non-metals.
(a) Nitrogen reacts with lithium to form the ionic compound lithium nitride, Li3N.
(i) Write the equation for the reaction between lithium and nitrogen.
....................................................................................................................................... [2]
(ii) Lithium nitride is an ionic compound. Draw a diagram which shows its formula, the charges
on the ions and the arrangement of the valency electrons around the negative ion.
(i) Draw a diagram showing the arrangement of the valency electrons in one molecule of the
covalent compound nitrogen trifluoride, NF3.
[2]
(ii) Lithium nitride has a high melting point, 813 °C. Nitrogen trifluoride has a low melting point,
–207 °C.
Explain why the melting points are different.
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
57
(c) Name two forms of the element carbon which have giant covalent structures.
(d) Complete the diagram to show the electron arrangement in a carbon dioxide molecule.
Show the outer shell electrons only.
O C O
24- Silicon(IV) oxide and sodium chloride have different types of bonding and structure.
.............................................................................................................................................. [1]
58
(c) (i) Silicon(IV) oxide has a high melting point. Explain why.
.............................................................................................................................................
....................................................................................................................................... [2]
....................................................................................................................................... [1]
(d) Solid sodium chloride does not conduct electricity. However, it conducts electricity when molten.
Explain why solid sodium chloride does not conduct electricity, whereas molten sodium chloride
does conduct electricity.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
[2]
25- (b) Ethanol can also be made by the catalytic hydration of ethene. The equation for the reaction is
shown.
....................................................................................................................................... [1]
(ii) Calculate the maximum mass of ethanol that can be made from 56 g of ethene.
59
60
61
62
1- The structure of an organic compound, X, is shown.
H H
H H
C C
H C
H
C C
H H
C C
H H
H H
What is the molecular formula of X?
2- A compound contains one atom of calcium, two atoms of hydrogen and two atoms of oxygen.
3- A molecule, Z, contains two atoms of oxygen, six atoms of hydrogen and three atoms of carbon.
A CH3CH2CHO
B CH3COCH3
C C2H5CO2H
D C3H6CO2H
63
4- Which element does not form a stable ion with the same electronic structure as argon?
A aluminium
B chlorine
C phosphorus
D potassium
Q R
64
7- The electronic structures of atoms X and Y are shown.
X Y
W Na(Al Si3)O8
X Ca(Al 2Si2)O8
9-
How many atoms of hydrogen are there in a molecule of ethanol, C2H5OH?
A 1 B 2 C 5 D 6
65
10- Which diagram correctly shows the ions present in the compound potassium fluoride?
–
+ e e
e e e e
e e
e e e e e e
A K+ e e e e e e F–
key
e e
e e e e = nucleus
e e
e = electron
+
– e e
e e e e
e e
e e e e e e
B K– e e e e e e F+
e e
e e e e
e e
e e + –
e e e e
e e
e e e e e e
C K+ e e e e e e F–
e e
e e e e
e e
–
e e +
e e e e
e e
e e e e e e
D K– e e e e e e F+
e e
e e e e
e e
66
11- The electronic structures of atoms X and Y are shown.
X Y
12- Two atoms of magnesium, Mg, react with one molecule of oxygen, O2.
13- The table shows the numbers of atoms present in the formula of some compounds.
67
14- Use your copy of the Periodic Table to help you answer these questions.
68
16- (a) For each of the following, give the name of an element from Period 2 (lithium to neon), which
matches the description.
Elements may be used once, more than once or not at all.
[Total: 10]
17- Gallium is a metallic element in Group III. It has similar properties to aluminium.
18- Thallium is a metal in Group III. It has oxidation states of +1 and +3.
69
19- (a) The symbols of six particles are shown below.
Select from the list of particles to answer the following questions. A particle may be selected
once, more than once or not at all.
(i) Which two ions have the same electronic structure? . .................................................. [1]
(ii) Which ion has the same electronic structure as an atom of argon? . ............................ [1]
(iii) Which atom can form an ion of the type X3–? ................................................................ [1]
(iv) Which atom can form a hydride which has a formula of the type XH4? . ....................... [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
70
21- The table gives information about five particles. The particles are all atoms or ions.
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
(b)
D is an ion of an element.
.............................................................................................................................................. [2]
71
72
72
73
74
1- The diagrams show the structure of two substances used to make electrical conductors.
X Y
2- Which statement about the uses of aluminium, mild steel and stainless steel is correct?
75
3-
Electrical cables are made from either ……1……, because it is a very good conductor of
electricity, or from……2……, because it has a low density.
Overhead cables have a ……3…… core in order to give the cable strength.
1 2 3
A B
C D
76
5- Why is argon gas used to fill electric lamps?
A It conducts electricity.
B It glows when heated.
C It is less dense than air.
D It is not reactive.
6- An element melts at 1455 °C, has a density of 8.90 g / cm3 and forms a green chloride.
7- he diagrams show two items that may be found in the home. Each item contains zinc.
bucket door-knocker
A
B
C
D
77
8- Which substance will not conduct electricity?
A aluminium
B copper
C plastic
D steel
9- The diagrams show two items that may be found in the home. Each item contains zinc.
bucket door-knocker
A
B
C
D
78
10- An element melts at 1455 °C, has a density of 8.90 g / cm3 and forms a green chloride.
A It conducts electricity.
B It glows when heated.
C It is less dense than air.
D It is not reactive.
A Elements in the same period have the same number of outer electrons.
B The elements on the left are usually gases.
C The most metallic elements are on the left.
D The relative atomic mass of the elements increases from right to left.
resistance to
density strength
corrosion
A high
igh low
B high
igh low
C low
ow h high
D low
ow high
79
Which properties of the element titanium, Ti, can be predicted from its position in the Periodic
14- Table?
A
B
C
D
When X reacts with Y a salt is formed. A solution of this salt reacts with Z to form a different salt.
X Y Z
A K Cl 2 I2
B Li Cl 2 Br2
C Mg Br2 Cl 2
D Na I2 Cl 2
16- In the outline of the Periodic Table below, some elements are shown as numbers.
1 2
3 4
5 6
7
80
Which properties of the element titanium, Ti, can be predicted from its position in the Periodic
17- Table?
A
B
C
D
81
18- The table shows some properties of the Group I metals.
metal melting point / °C hardness reaction with water
C melts above 181 °C, very soft, reacts explosively with water
D melts above 181 °C, very soft, reacts slowly with water
19- In the outline of the Periodic Table below, some elements are shown as numbers.
1 2
3 4
5 6
7
82
20- Which diagram represents an alloy?
A B
C D
83
22- The noble gases, which are in Group 0 of the Periodic Table, are all very ....... 1....... .
....... 2......., one of these gases, is used to provide an inert atmosphere in lamps.
Another, ....... 3......., is used for filling balloons because it is less dense than air.
1 2 3
23- The diagrams show the structure of two substances used to make electrical conductors.
X Y
24-
Which statement about the uses of aluminium, mild steel and stainless steel is correct?
84
25- Which properties of the element titanium, Ti, can be predicted from its position in the Periodic
Table?
A
B
C
D
When X reacts with Y a salt is formed. A solution of this salt reacts with Z to form a different salt.
X Y Z
A K Cl 2 I2
B Li Cl 2 Br2
C Mg Br2 Cl 2
D Na I2 Cl 2
27- In the outline of the Periodic Table below, some elements are shown as numbers.
1 2
3 4
5 6
7
85
28- Where in the Periodic Table is the metallic character of the elements greatest?
A left bottom
B left top
C right bottom
D right top
86
31- Where in the Periodic Table is the metallic character of the elements greatest?
A left bottom
B left top
C right bottom
D right top
compounds
melting point density
formed
A high
igh coloured
B high
igh white
C high
igh white
D low
ow h coloured
87
34- Some properties of substance X are listed.
A a covalent compound
B a macromolecule
C a metal
D an ionic compound
88
37- Which element is less reactive than the other members of its group in the Periodic Table?
A astatine
B caesium
C fluorine
D rubidium
38- The elements oxygen and sulfur are in the same group of the Periodic Table.
Stainless steel is an alloy of iron and other metals. It is strong and does not rust but it costs much
39- more than normal steel.
A cutlery
B pipes in a chemical factory
C railway lines
D saucepans
89
40- Which element is less reactive than the other members of its group in the Periodic Table?
A astatine
B caesium
C fluorine
D rubidium
Ununseptium (atomic number 117) is a man-made element that is below astatine in Group VII of
41- the Periodic Table.
A a diatomic gas
B a liquid
C a monatomic gas
D a solid
Stainless steel is an alloy of iron and other metals. It is strong and does not rust but it costs much
42- more than normal steel.
A cutlery
B pipes in a chemical factory
C railway lines
D saucepans
90
43- Element X is shiny and can be formed into a sheet by hammering.
A
B
C
D
44- The table compares the properties of Group I elements with those of transition elements.
45-
Which compound is likely to be coloured?
91
46- The diagram shows the positions of elements P, Q, R, S and T in the Periodic Table.
These letters are not the chemical symbols for the elements.
S T
Q R
A B
– + – +
+ – + –
– + – +
92
48- Which diagram shows a common use of stainless steel?
A B C D
1 It acts as a catalyst.
A
B
C
D
A low density
B resistance to corrosion
C good conductor of electricity
D poor conductor of heat
93
51-
Which object is least likely to contain aluminium?
A a bicycle frame
B a hammer
C a saucepan
D an aeroplane body
steel
ceramic
aluminium
52-
Which statement explains why a particular substance is used?
94
53- Which statement about the elements of Group I is correct?
A Lithium is more dense than sodium.
B Potassium has a higher density than lithium.
C Potassium is less reactive than sodium.
D Sodium has a higher melting point than lithium.
1 It acts as a catalyst.
2 It forms colourless ions.
property 1 property 2
A
B
C
D
1 It conducts heat.
2 It has a low density.
3 It is resistant to corrosion.
Which properties make aluminium useful for making food storage containers?
95
56- Which metal is commonly used to form alloys with a non-metallic element?
A copper
B iron
C magnesium
D zinc
A a bicycle frame
B a hammer
C a saucepan
D an aeroplane body
96
58- Which statements about Group I and Group VII elements are correct?
statement 1 statement 2
A
B
C
D
The melting points of Group I elements ....... 2 ....... down the group.
The melting points of Group VII elements ....... 3 ....... down the group.
1 2 3
A good 0.97 98
B good 7.86 1535
C poor 2.33 1410
D poor 3.12 –7
97
61- Which diagram shows the structure of an alloy?
A B
– + –
+ – +
– + –
+ – +
– + –
+ – +
– + –
+ – +
– + –
C D
62- Which metal would be suitable for all of the following uses?
A aluminium
B brass
C mild steel
D pure iron
98
63- What is not a property of Group I metals?
64- Which statement about transition elements and their compounds is correct?
99
65- What is not a property of Group I metals?
A They are soft and can be cut with a knife.
B They react when exposed to oxygen in the air.
C They produce an acidic solution when they react with water.
D They react rapidly with water producing hydrogen gas.
A chromium
B nickel
C vanadium
D zinc
100
69- Which statements about the trends across a period of the Periodic Table are correct?
The melting point of astatine is ......2...... than the melting point of iodine.
1 2 3
A high no no
B high yes yes
C low no yes
D low yes no
101
72- What is a property of all metals?
A conduct electricity
B hard
C low melting points
D react with water
A aluminium tin
B aluminium zinc
C copper tin
D copper zinc
102
74- For each of the following unfamiliar elements predict one physical and one chemical
property.
..................................................................................................................................... [2]
..................................................................................................................................... [2]
..................................................................................................................................... [2]
[Total: 6]
103
75- The table below gives the electron distributions of atoms of different elements.
For each of the following, select an element or elements from the table that matches the description.
Each element may be selected once, more than once or not at all.
.............................................................................................................................................. [1]
(b) This element forms a fluoride with a formula of the type XF3.
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
.............................................................................................................................................. [1]
[Total: 7]
104
76- Scandium, proton number 21, is not a typical transition element.
(a) Scandium is a low density metal which has only one oxidation state in its compounds. Scandium
compounds are white solids which form colourless solutions. Titanium, the next metal in the
period, is a far more typical transition element. How would the properties of titanium differ from
those of scandium?
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
105
78- Iron from a blast furnace contains about 5% of the impurities – carbon, silicon, phosphorus and sulfur.
Most of this impure iron is used to make steels, such as mild steel, and a very small percentage is
used to make pure iron.
[2]
.............................................................................................................................................
....................................................................................................................................... [2]
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [2]
[Total: 14]
106
79- Gallium is a metallic element in Group III. It has similar properties to aluminium.
(d) Alloys of gallium and other elements are often more useful than the metallic element itself.
Suggest two reasons why alloys of gallium are more useful than the metallic element.
....................................................................................................................................................
.............................................................................................................................................. [2]
80- Nickel, copper and zinc are three consecutive elements in the Periodic Table.
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
107
81- For each of the following elements give one physical property and one chemical property.
(b) carbongraphite(C)
108
82- Substances can be classified as elements, compounds or mixtures.
109
110
111
112
1- A student carried out an experiment to find the order of reactivity of five metals.
They were tested with cold water, hot water and steam and the results recorded in a table.
A V W Y X Z
B W X Z V Y
C Z X V W Y
D Z X Y W V
2- In an experiment, three test-tubes labelled X, Y and Z were half-filled with dilute hydrochloric
acid. A different metal was added to each test-tube. After a few minutes the following
observations were made.
A copper
oppe iron
B magnesium
agne copper
C zinc
inc magne copper
D zinc
inc magne iron
113
3- Samples of five different metals, E, F, G, H and J were reacted with dilute sulfuric acid using the
apparatus shown.
gas syringe
bung
The volume of hydrogen gas collected after one minute was measured.
25
20
15
volume of gas
collected / cm3
10
0
E F G H J
metal
4-
What is the order of reactivity of the metals (most reactive first)?
A E, F, G, H, J
B G, E, H, F, J
C J, F, H, E, G
D J, H, G, F, E
114
5- The statements describe how different metals react with cold water.
Using the information, where should hydrogen be placed in the reactivity series?
A below copper
B between sodium and calcium
C between calcium and zinc
D between zinc and copper
6- Four metals P, Q, R and S are added to separate aqueous solutions of their ions.
2+
me
metal Q2+ R2+ S2+
P key
Q = reaction occurs
R = reaction does not occur
S
A Q→P→S→R
B Q→S→P→R
C R→P→S→Q
D R→S→P→Q
115
A list of metals is shown.
aluminium
copper
iron
magnesium
silver
zinc
Which metal will displace all of the other metals from aqueous solutions of their salts?
A aluminium
7- B iron
C magnesium
D zinc
116
8- A list of metals is shown.
aluminium
copper
iron
magnesium
silver
zinc
Which metal will displace all of the other metals from aqueous solutions of their salts?
A aluminium
B iron
C magnesium
D zinc
9- The section of the reactivity series shown includes a newly discovered element, symbol X.
Ca
Mg
Fe
X
H
Cu
117
10- The ionic equations represent the reactions between four metals, P, Q, R and S, and solutions of
the salts of the same metals.
P + Q2+ → no reaction
R + P2+ → R2+ + P
Q + S2+ → Q2+ + S
S + P2+ → S2+ + P
S + R2+ → S2+ + R
S + Q2+ → no reaction
most least
A P R S Q
B Q R S P
C Q S R P
D S Q P R
11- Zinc oxide can be reacted with carbon to produce zinc metal.
A 2ZnO + C → 2Zn + CO
C ZnO + C → Zn + CO
D ZnO + 2C → Zn + 2CO2
118
12- Some metals react readily with dilute hydrochloric acid.
A calcium
B copper
C iron
D magnesium
119
How many different salts could be made from a supply of dilute sulfuric acid, dilute hydrochloric
13- acid, copper, magnesium oxide and zinc carbonate?
A 3 B 4 C 5 D 6
Which row describes the products made in the reaction and the trend in reactivity of the
elements?
products trend in reactivity
14- The table shows the reactions of four different metals with water.
metal
etal rea
What is the correct order of reactivity, from most reactive to least reactive?
A W→X→Y→Z
B W→Z→Y→X
C Z→W→X→Y
D Z→W→Y→X
120
15- The oxide of element X is reduced by heating with carbon.
Element X does not react with cold water, steam or dilute hydrochloric acid.
What is X?
A copper
B iron
C magnesium
D zinc
16- The diagrams show what happens when three different metals are added to water.
bubbles flame
of gas
X Y Z
X Z
A calcium
alcium potassium
B copper
opper ca potassium
C potassium
otassiu copper
D potassium
otassi calcium
121
17- The metal beryllium does not react with cold water.
It reacts with hydrochloric acid but cannot be extracted from its ore by using carbon.
magnesium
A
zinc
B
iron
C
copper
D
18- The statements describe how different metals react with cold water.
Using the information, where should hydrogen be placed in the reactivity series?
A below copper
B between sodium and calcium
C between calcium and zinc
D between zinc and copper
122
19- Part of the Periodic Table is shown.
W X Y
Z
has four
has variable reacts with very
outer shell
oxidation states cold water unreactive
electrons
A W Y Z X
B X W Y Z
C Z W Y X
D Z Y X W
123
20- Some properties of element X are shown.
melting point in °C 98
boiling point in °C 883
reaction with cold water gives off H2 gas
reaction when heated with oxygen burns to give a white solid
A Group I
B Group VII
C Group VIII
D transition elements
124
21- Aluminium is extracted from aluminium oxide by electrolysis.
(a) Why is aluminium not extracted by heating aluminium oxide with carbon?
....................................................................................................................................................
.............................................................................................................................................. [1]
125
22-(d) hen a piece of aluminium is placed in dilute hydrochloric acid, there is no immediate visible
W
reaction.
If the aluminium is left in the dilute hydrochloric acid for several hours, bubbles start to form.
Explain why aluminium does not react immediately with dilute hydrochloric acid.
....................................................................................................................................................
.............................................................................................................................................. [1]
126
127
128
1- Solid F is an element.
Solid G is a compound.
Neither solid conducts electricity but G conducts electricity when dissolved in water.
These properties suggest that F is ……1…… and that G is ……2…… with ……3…… bonds.
1 2 3
129
4- Metals consist of a lattice of positive ions in a ‘sea of electrons’.
5-
Which property is not considered a typical metallic property?
130
7- Graphite and diamond are both forms of the element carbon.
Which row shows the number of other carbon atoms that each carbon atom is covalently bonded
to in graphite and diamond?
graphite diamond
A 3 3
B 3 4
C 4 3
D 4 4
A ammonia
B carbon dioxide
C diamond
D water
X Y
131
10- The ‘lead’ in a pencil is made of a mixture of graphite and clay.
‘lead’
When the percentage of graphite is increased, the pencil slides across the paper more easily.
‘lead’
When the percentage of graphite is increased, the pencil slides across the paper more easily.
132
Two macromolecular forms of carbon are graphite and diamond. The structures of graphite and
12- diamond are given below.
graphite diamond
(a) Explain in terms of its structure why graphite is soft and is a good conductor of electricity.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
(b) State two uses of graphite which depend on the above properties.
It is soft ......................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
[2]
.............................................................................................................................................
....................................................................................................................................... [1]
(ii) Predict two physical properties which diamond and silicon(IV) oxide have in common.
.............................................................................................................................................
....................................................................................................................................... [2]
133
13- In 1985 the fullerenes were discovered. They are solid forms of the element carbon. The structure
of the C60 fullerene is given below.
....................................................................................................................................... [1]
(ii) Explain why metals, such as potassium, are good conductors of electricity.
.............................................................................................................................................
....................................................................................................................................... [2]
134
14- Carbon and silicon are elements in Group IV. They both form oxides of the type XO2.
. ............................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [3]
(ii) State three properties which silicon(IV) oxide and diamond have in common.
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [3]
(iii) How could you show that silicon(IV) oxide is acidic and not basic or amphoteric?
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(b) Explain why the physical properties of carbon dioxide are different from those of diamond and
silicon(IV) oxide.
....................................................................................................................................................
.............................................................................................................................................. [1]
[Total: 9]
135
15- Beryllium is a metallic element in Group II.
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [3]
(ii) Explain why metallic elements, such as beryllium, are good conductors of electricity.
. ............................................................................................................................................
. ...................................................................................................................................... [1]
136
16- (c) (i) Describe the bonding in iron. Include a diagram in your answer.
. ............................................................................................................................................
. ...................................................................................................................................... [3]
. ............................................................................................................................................
. ...................................................................................................................................... [2]
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(d) (i) hen iron is added to dilute sulfuric acid, an aqueous solution of iron(II) sulfate is formed
W
as one of the products.
. ...................................................................................................................................... [1]
(ii) hen iron(III) oxide is added to dilute sulfuric acid, an aqueous solution of iron(III) sulfate
W
is formed as one of the products.
. ...................................................................................................................................... [3]
137
16-
138
139
140
1- Which reaction is not characteristic of an acid?
The acid reacts with the oxide layer on the surface of the metal, forming a salt and water.
A alloy
B base
C element
D indicator
141
3- Different plants grow best under different pH conditions.
A cabbage 6-8
B potato 4-7
C strawberry 5-7
D wheat 6-7
5- Which acid reacts with ammonia to produce the salt ammonium sulfate?
A hydrochloric
B nitric
C phosphoric
D sulfuric
142
6- Which statement is not correct?
A
B
C
D
9- Which row describes whether an amphoteric oxide reacts with acids and bases?
A no
o
B no
o y
C yes
es
D yes
es
143
10- Which statements are properties of an acid?
1 2
A
B
C
D
11- Which row describes whether an amphoteric oxide reacts with acids and bases?
A no no
B no yes
C yes no
D yes yes
12- Which statements about a weak acid, such as ethanoic acid, are correct?
13- Chloric(I) acid, HCl O, is formed when chlorine dissolves in water. It is a weak acid.
144
14- Which reaction will result in a decrease in pH?
15- The oxide of element X was added to an acid. It reacted to form a salt and water.
oxide of
element X
acid
What is the pH of the acid before the reaction and what type of element is X?
pH type of element X
145
16- A colourless solution is tested by the following reactions.
A A piece of magnesium ribbon is added. Bubbles are seen and the magnesium disappears.
B A pungent smelling gas is produced when ammonium carbonate is added.
C Copper oxide powder is added and the mixed is warmed. The solution turns blue.
D The solution turns blue litmus red.
17- The graph shows how the pH of soil in a field changes over time.
11 A
pH of 7 B
soil D
5 C
time
3 Fe2+(aq) → Fe3+(aq) + e–
146
19- Which substance is the most acidic?
substance pH
A calcium hydroxide 12
B lemon juice 4
C milk 6
D washing up liquid 8
20- The graph shows how the pH of soil in a field changes over time.
11 A
pH of 7 B
soil D
5 C
time
22- Which method can be used to obtain ammonia from ammonium sulfate?
147
23- Hydrogen chloride gas reacts with water to produce an acidic solution. The equation for the
reaction is shown.
148
Hydrogen chloride gas reacts with water to produce an acidic solution. The equation for the
25- reaction is shown.
from to
A 6 7
B 7 8
C 8 7
D 8 6
149
28- (a) Match the following pH values to the solutions given below.
1 3 7 10 13
solution pH
(b) Explain why solutions of hydrochloric acid and ethanoic acid with the same concentration, in
mol / dm3, have a different pH.
....................................................................................................................................................
....................................................................................................................................................
..............................................................................................................................................
(c) Measuring pH is one way of distinguishing between a strong acid and a weak acid.
Describe another method.
method .......................................................................................................................................
....................................................................................................................................................
results ........................................................................................................................................
....................................................................................................................................................
150
Butane is oxidised to a mixture of carboxylic acids by oxygen in the presence of a catalyst.
29- The acids formed are methanoic acid, ethanoic acid and propanoic acid – the first three members
of the carboxylic acid homologous series.
(a)
.............................................................................................................................................
.............................................................................................................................................
.......................................................................................................................................
151
Butane is oxidised to a mixture of carboxylic acids by oxygen in the presence of a catalyst.
30- The acids formed are methanoic acid, ethanoic acid and propanoic acid – the first three members
of the carboxylic acid homologous series.
.............................................................................................................................................
.............................................................................................................................................
.......................................................................................................................................
.............................................................................................................................................
.......................................................................................................................................
(ii) Describe how you could show that ethanoic acid is a weaker acid than hydrochloric acid.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
......................................................................................................................................
152
153
154
1- Element X forms an oxide, XO, that neutralises sulfuric acid.
A metal acidic
B metal basic
C non-metal acidic
D non-metal basic
2- Only two elements are liquid at 20 °C. One of these elements is shiny and conducts electricity.
This suggests that this element is a ......1...... and therefore its oxide is ......2...... .
1 2
A metal
etal a
B metal
etal
C non-metal
on-met
D non-metal
on-me
155
3- Hydrochloric acid is used to clean metals.
The acid reacts with the oxide layer on the surface of the metal, forming a salt and water.
A alloy
B base
C element
D indicator
The acid reacts with the oxide layer on the surface of the metal, forming a salt and water.
A alloy
B base
C element
D indicator
156
5- Which type of oxide is aluminium oxide?
A acidic
B amphoteric
C basic
D neutral
6- Element E:
• forms an alloy
What is E?
A carbon
B copper
C sulfur
D zinc
157
7- Which oxide is amphoteric?
8- Element E:
• forms an alloy
What is E?
A carbon
B copper
C sulfur
D zinc
Y
X Z
158
10- The diagram shows a simplified form of the Periodic Table:
W X
Y
A acidic
B amphoteric
C basic
D neutral
159
12- Some properties of four oxides are listed.
Oxide 2 reacts with acids to form salts but does not react with alkalis.
Oxide 3 reacts with alkalis to form salts but does not react with acids.
13-
Which statement about oxides is correct?
A acidic
B amphoteric
C basic
D neutral
160
15- Some properties of four oxides are listed.
Oxide 2 reacts with acids to form salts but does not react with alkalis.
Oxide 3 reacts with alkalis to form salts but does not react with acids.
17- Which other property would you expect this element to have?
A acts as a catalyst
B brittle
C forms an acidic oxide
D highly reactive with water
161
18- Scandium, proton number 21, is not a typical transition element. [3]
(c) Scandium oxide is insoluble in water. Describe how you could show that it is an amphoteric
oxide.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
162
19- This question is concerned with the following oxides.
aluminium oxide
carbon monoxide
copper(II) oxide
silicon(IV) oxide
sodium oxide
sulfur dioxide
zinc oxide
Choose one oxide from the above list to match each of the following descriptions. An oxide may be
used once, more than once or not at all.
(a) This oxide does not react with acid or alkali. ....................................................................... [1]
(b) This oxide reacts with water to give a strong alkali solution. ............................................... [1]
[Total: 6]
163
20- Beryllium is a metallic element in Group II.
. ...................................................................................................................................... [1]
(ii) Write a chemical equation for the reaction between beryllium hydroxide and
hydrochloric acid.
. ...................................................................................................................................... [2]
(iii) Beryllium hydroxide also reacts with alkalis. The salts formed contain beryllate ions,
BeO22–.
Suggest a chemical equation for the reaction between beryllium hydroxide and
sodium hydroxide solution.
. ...................................................................................................................................... [2]
164
165
166
1- Which equation shows an oxidation reaction?
A C + O2 → CO2
D N2O4 → 2NO2
A C + O2 → CO2
D N2O4 → 2NO2
A 2CuO + C → CO2 + Cu
B Fe2O3 + 3CO → 2Fe + 3CO2
C 2Mg + O2 → 2MgO
D MnO2 + 4HCl → MnCl 2 + 2H2O + Cl 2
N2
B
A
N2O4 N2O3 N 2O
C
D
NO
167
3- In which change is N2O3 oxidised?
N2
B
A
N2O4 N2O3 N 2O
C
D
NO
168
5- Which equation represents a reduction reaction?
A Fe2+ + e– → Fe3+
B Fe2+ → Fe3+ + e–
C Fe3+ + e– → Fe2+
D Fe3+ → Fe2+ + e–
A Fe2+ + e– → Fe3+
B Fe2+ → Fe3+ + e–
C Fe3+ + e– → Fe2+
D Fe3+ → Fe2+ + e–
Zn + Cu2+ → Zn2+ + Cu
Zn + Cu2+ → Zn2+ + Cu
169
9- Which process is involved in the extraction of zinc from zinc blende?
170
10- The red colour in some pottery glazes may be formed as a result of the reactions shown.
heat
CuCO3 CuO + CO2
1 2
A CO2 SnO2
B CuCO3 CuO
C CuO SnO
D SnO CuO
P 2NaNO2 + O2 → 2NaNO3
Q 2HgO → 2Hg + O2
P Q
A
B
C
D
171
13- The equations for two reactions P and Q are given.
P 2NaNO2 + O2 → 2NaNO3
Q 2HgO → 2Hg + O2
P Q
A
B
C
D
14-
Which process does not involve oxidation?
172
15- The element vanadium, V, forms several oxides.
A VO2 → V2O3
B V2O5 → VO2
C V2O3 → VO
D V2O3 → V2O5
3 Fe2+(aq) → Fe3+(aq) + e–
CuO + H2 → Cu + H2O
A H2 CuO
B CuO H2
C H2O Cu
D Cu H2O
173
18- .The following are examples of redox reactions
(i) Describe what you would observe when this reaction occurs.
....................................................................................................................................
.............................................................................................................................. [2]
.............................................................................................................................. [1]
(iii) Explain, in terms of electron transfer, why bromine is the oxidant (oxidising agent) in
this reaction.
....................................................................................................................................
.............................................................................................................................. [2]
(b) Iron and steel in the presence of water and oxygen form rust.
colourless
gas forms
oxygen dissolved
in water
electrons
Fe2+ goes
move
into solution
in metal
reaction 1
Fe → Fe2+ + 2e–
The electrons move through the iron on to the surface where a colourless gas forms.
reaction 2
Fe2+ + 2OH– → Fe(OH)2
from water
reaction 3
..........Fe(OH)2 + O2 + ..........H2O → ..........Fe(OH)3
174
19- (i) What type of reaction is reaction 1? .................................................................... [1]
..............................................................................................................................
..............................................................................................................................
....................................................................................................................................
..............................................................................................................................
175
20- The rate of a photochemical reaction is affected by light.
(a) The decomposition of silver bromide is the basis of film photography. This is a redox reaction.
step 2 Ag+ + e– → Ag
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
176
4
Mg + Cu2+ Mg2+ + Cu
(i) Give one change you would observe during this reaction.
. ...................................................................................................................................... [1]
. ............................................................................................................................................
. ...................................................................................................................................... [1]
(iii) Identify the oxidising agent in this reaction. Give a reason for your answer.
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(iv) A redox reaction occurs when magnesium is heated with iron(III) oxide.
Write a chemical equation for the reaction between magnesium and iron(III) oxide.
. ...................................................................................................................................... [2]
177
178
179
180
1- Copper and hydrogen can each be formed by electrolysis.
copper hydrogen
A anode anode
B anode cathode
C cathode anode
D cathode cathode
+ –
181
3- What will be produced at the anode and at the cathode, if molten potassium chloride is
electrolysed?
A chlorine hydrogen
B chlorine potassium
C hydrogen chlorine
D potassium chlorine
4- Which products are formed at the anode and cathode when electricity is passed through molten
lead(II) bromide?
182
5- Copper and hydrogen can each be formed by electrolysis.
copper hydrogen
A anode anode
B anode cathode
C cathode anode
D cathode cathode
6- An object is electroplated with silver using an aqueous silver salt as the electrolyte.
A anode carbon
B anode silver
C cathode carbon
D cathode silver
183
7- Copper and hydrogen can each be formed by electrolysis.
copper hydrogen
A anode anode
B anode cathode
C cathode anode
D cathode cathode
8- An object is electroplated with silver using an aqueous silver salt as the electrolyte.
A anode carbon
B anode silver
C cathode carbon
D cathode silver
184
9- The diagram shows the electrolysis of molten zinc chloride, ZnCl 2.
electrode X + – electrode Y
molten zinc
chloride
B Oxidation occurs at electrode Y and the equation is: Zn2+ + 2e– → Zn.
C Reduction occurs at electrode X and the equation is: Zn2+ + 2e– → Zn.
+ –
copper pan
copper(II) sulfate
solution
A Cu2+ + 2e– → Cu
B 2H+ + 2e– → H2
D 2O2– → O2 + 4e–
185
12- Which statement about electrolysis is correct?
A Electrons move through the electrolyte from the cathode to the anode.
B Electrons move towards the cathode in the external circuit.
C Negative ions move towards the anode in the external circuit.
D Positive ions move through the electrolyte towards the anode during electrolysis.
A Electrons move through the electrolyte from the cathode to the anode.
B Electrons move towards the cathode in the external circuit.
C Negative ions move towards the anode in the external circuit.
D Positive ions move through the electrolyte towards the anode during electrolysis.
186
15- The diagram shows apparatus used in an attempt to electroplate a metal ring with copper.
+ –
bulb
aqueous copper(II)
sulfate (electrolyte)
187
16- When concentrated sodium chloride solution is electrolysed, elements X and Y are formed.
X Y
concentrated
sodium chloride
solution
– +
X Y
A chlorine hydrogen
B hydrogen chlorine
C hydrogen oxygen
D oxygen hydrogen
A coloured gas was formed at the anode and a metal was formed at the cathode.
power supply
anode cathode
substance X
What is substance X?
188
18- Which metal could not be used for electroplating by using an aqueous solution?
A chromium
B copper
C silver
D sodium
19- Which products are formed at the electrodes when a concentrated solution of sodium chloride is
electrolysed?
A hydrogen chlorine
B hydrogen oxygen
C sodium chlorine
D sodium oxygen
A bromine
romine h
B bromine
romine po
C hydrogen
ydrogen
D potassium
otassiu
189
21- A student wishes to electroplate an object with copper.
A anode CuO(s)
B anode CuSO4(aq)
C cathode CuO(s)
D cathode CuSO4(aq)
+ –
W X
W X Y
190
23- Which apparatus could be used to electroplate an iron nail with copper?
A B key
+ – + – = copper sheet
= iron nail
C D
+ – + –
24- Which statements about the electrolysis of concentrated copper(II) chloride are correct?
2 Electrons move round the external circuit from the cathode to the anode.
3 Chloride ions are attracted to the anode.
4 Hydroxide ions transfer electrons to the cathode.
191
25- Which apparatus could be used to electroplate an iron nail with copper?
A B key
+ – + – = copper sheet
= iron nail
C D
+ – + –
26- Which statements about the electrolysis of concentrated copper(II) chloride are correct?
2 Electrons move round the external circuit from the cathode to the anode.
3 Chloride ions are attracted to the anode.
4 Hydroxide ions transfer electrons to the cathode.
192
27- Fuel cells are used in spacecraft to produce electrical energy.
hydrogen
anode
electrolyte
oxygen
cathode
2H2 + O2 → 2H2O
.............................................................................................................................. [1]
.............................................................................................................................. [1]
.............................................................................................................................. [1]
(c) (i) Give two reasons why hydrogen may be considered to be the ideal fuel for the
future.
....................................................................................................................................
....................................................................................................................................
.............................................................................................................................. [2]
(ii) Suggest a reason why hydrogen is not widely used at the moment.
....................................................................................................................................
.............................................................................................................................. [1]
[Total: 8]
193
28- Aluminium was first isolated in 1827 using sodium.
(c) The electrolysis of a molten electrolyte is one method of extracting a metal from its ore.
Other methods are the electrolysis of an aqueous solution and the reduction of the oxide
by carbon. Explain why these last two methods cannot be used to extract aluminium.
...........................................................................................................................................
..................................................................................................................................... [2]
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [5]
194
30- Hydrogen can be manufactured from methane by steam reforming.
The reaction is carried out using a nickel catalyst at temperatures between 700 °C and 1100 °C and
using a pressure of one atmosphere.
(e) Hydrogen can also be manufactured by electrolysis. The electrolyte is concentrated aqueous
sodium chloride. The electrodes are inert.
. ............................................................................................................................................
. ...................................................................................................................................... [2]
. ...................................................................................................................................... [1]
(iii) Write an ionic half-equation for the reaction in which hydrogen is produced.
. ...................................................................................................................................... [1]
. ...................................................................................................................................... [1]
chlorine, .....................................................................................................................................
hydrogen. ...................................................................................................................................
[3]
195
31- (b) The ions present in aqueous sodium chloride are Na+(aq), Cl –(aq), H+(aq) and OH–(aq).
The electrolysis of concentrated aqueous sodium chloride forms three products. They are
hydrogen, chlorine and sodium hydroxide.
(i) Explain how these three products are formed. Give ionic equations for the reactions at the
electrodes.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [4]
(ii) If the solution of the electrolyte is stirred, chlorine reacts with sodium hydroxide to form
sodium chlorate(I), sodium chloride and water.
Write an equation for this reaction.
196
32- Copper(II) sulfate solution was electrolysed using the apparatus shown.
copper wire
Identify this gas and give the test for this gas.
gas . ............................................................................................................................................
test . ............................................................................................................................................
(b) During electrolysis, electricity passes through the copper(II) sulfate solution.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [3]
197
33- c) )
The electrolysis was repeated using copper electrodes in place of carbon electrodes. The
half-equations for the reactions at the two electrodes are shown.
ionic
anode Cu(s) → Cu2+(aq) + 2e–
(i) Which species is reduced during the electrolysis? Explain your answer.
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [2]
(ii) The masses of the copper electrodes changed during the electrolysis.
State how and explain why the masses of the two copper electrodes changed.
Use the ionic half-equations to help you.
. ............................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [3]
(iii) Explain why, during the electrolysis, the colour of the copper(II) sulfate solution does not
change.
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [1]
198
When lead(II) nitrate is heated, two gases are given off and solid lead(II) oxide remains.
34- The equation for the reaction is shown.
test . ............................................................................................................................................
result . .........................................................................................................................................
[2]
199
35- Silicon(IV) oxide and sodium chloride have different types of bonding and structure.
(e) A concentrated aqueous solution of sodium chloride is electrolysed using carbon electrodes.
(ii) Write an ionic half-equation for the reaction occurring at the negative electrode.
. ...................................................................................................................................... [1]
(f) A dilute aqueous solution of sodium chloride is electrolysed using carbon electrodes.
.............................................................................................................................................. [1]
....................................................................................................................................... [1]
(ii) Write an ionic half-equation for the reaction occurring at the negative electrode.
....................................................................................................................................... [1]
test ......................................................................................................................................
result ...................................................................................................................................
[2]
200
201
202
1- Four reactions that take place in the blast furnace to produce iron are shown.
A C + O2 → CO2
B CO2 + C → 2CO
C
D
203
3- The diagram shows a blast furnace.
C
D
Which row describes the conditions used to make steel from the iron produced by a blast
4- furnace?
calcium oxide
oxygen
xyge
(lime)
A
B
C
D
Which row describes the conditions used to make steel from the iron produced by a blast
5- furnace?
calcium oxide
oxygen heat
(lime)
A
B
C
D
204
Which row describes the conditions used to make steel from the iron produced by a blast
6- furnace?
calcium oxide
oxygen heat
(lime)
A
B
C
D
205
Iron from a blast furnace is treated with oxygen and with calcium oxide to make steel.
7-
Which substances in the iron are removed?
calcium oxide
oxygen removes
removes
8-
Why is cryolite used during the extraction of aluminium by electrolysis?
9-
Aluminium is extracted by electrolysis of a mixture of aluminium oxide and cryolite.
10- Which process is involved in the extraction of zinc from zinc blende?
206
11- Iron is extracted from the ore hematite in the Blast Furnace.
waste gases
raw materials:
coke, C
firebrick lining iron ore, Fe2O3
limestone, CaCO3
CO forms
CO2 forms
air
slag
molten iron
(a) The coke reacts with the oxygen in the air to form carbon dioxide.
C + O2 → CO2
(i) Explain why carbon monoxide is formed higher in the Blast Furnace.
.............................................................................................................................................
....................................................................................................................................... [2]
(ii) Write an equation for the reduction of hematite, Fe2O3, by carbon monoxide.
....................................................................................................................................... [2]
(b) (i) Limestone decomposes to form two products, one of which is calcium oxide.
Name the other product.
....................................................................................................................................... [1]
(ii) Calcium oxide reacts with silicon(IV) oxide, an acidic impurity in the iron ore, to form slag.
Write an equation for this reaction.
....................................................................................................................................... [2]
(iii) Explain why the molten iron and the molten slag form two layers and why molten iron is
the lower layer.
.............................................................................................................................................
....................................................................................................................................... [2]
(iv) Suggest why the molten iron does not react with the air.
....................................................................................................................................... [1]
207
12- (c) Aluminium can be extracted by electrolysis using the apparatus shown.
+ power –
supply
anodes wires
cathode
+ +
aluminium oxide
and cryolite
molten aluminium
(i) Name the type of particle responsible for the transfer of charge in
1 . .........................................................................................................................................
2 . .........................................................................................................................................
[2]
(iii) Write the ionic half-equation for the formation of aluminium during the electrolysis.
. ...................................................................................................................................... [1]
. ............................................................................................................................................
. ............................................................................................................................................
. ...................................................................................................................................... [3]
208
13- Iron is extracted from its ore using coke in a blast furnace.
waste gases
raw materials:
coke,
iron ore,
limestone
air air
slag
molten iron
.............................................................................................................................................. [1]
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [6]
209
210
211
212
1- The diagram shows a simple cell.
flow of electrons
wire
metal X metal Y
dilute
sulfuric acid
For which pair of metals would electrons flow from metal X to metal Y?
X Y
A copper iron
B copper zinc
C iron zinc
D zinc iron
wire
metal P metal Q
dilute
sulfuric acid
metal P metal Q
A iron
ron co
B magnesium
agnesi
C magnesium
agne
D zinc
inc co
213
3- The reactivity series for a number of different metals is shown.
electrolyte
214
4- The reactivity series for a number of different metals is shown.
electrolyte
215
5- The diagram shows a simple cell.
voltmeter
V
metal X metal Y
electrolyte
X Y
A magnesium copper
B magnesium iron
C zinc copper
D zinc iron
216
6- The diagram shows two different metal strips dipped into an electrolyte.
metal strips
electrolyte
217
7- Which metal combination produces the highest voltage reading in the cells shown?
A B
V V
Fe Cu Zn Cu
C D
V V
Cu Cu Mg Cu
218
8- Which metal combination produces the highest voltage reading in the cells shown?
A B
V V
Fe Cu Zn Cu
C D
V V
Cu Cu Mg Cu
219
9- Chemical reactions are always accompanied by an energy change.
(b) The cell shown below can be used to determine the order of reactivity of metals.
magnesium copper
electrode electrode
MgSO4(aq) CuSO4(aq)
porous barrier
(i) Is the reaction in the cell exothermic or endothermic? Explain your answer.
.............................................................................................................................................
....................................................................................................................................... [1]
(ii) Explain why the mass of the magnesium electrode decreases and the mass of the copper
electrode increases.
.............................................................................................................................................
....................................................................................................................................... [2]
(iii) How could you use this cell to determine which is the more reactive metal, magnesium or
manganese?
.............................................................................................................................................
....................................................................................................................................... [2]
220
10- Nickel, copper and zinc are three consecutive elements in the Periodic Table.
(i) Write the ionic half-equation for the reaction occurring at the zinc electrode in cell 1.
........................................................................................................................................ [2]
(ii) Putthe three metals, copper, nickel and zinc, in order of reactivity.
........................................
(iii) Complete the labelling in cell 3 by writing the polarity (+/–) of each electrode in the circles
and calculating the reading on the voltmeter. [2]
[Total: 11]
221
11- The diagram shows a simple cell.
voltmeter
V
metal 1 metal 2
electrolyte
The simple cell was used with different metals as electrodes. The voltages were recorded in the
table.
● If the voltage measured is positive then metal 2 is more reactive than metal 1.
● If the voltage measured is negative then metal 1 is more reactive than metal 2.
metal 2
beryllium cobalt nickel silver vanadium
beryllium 0.0 V –1.6 V –1.6 V not measured –0.7 V
cobalt 0.0 V 0.0 V –1.1 V 0.9 V
metal 1
(a) In a simple cell using nickel and silver, the nickel is oxidised.
........................................................................................................................................ [1]
........................................................................................................................................ [1]
(iii) What will happen to the mass of the nickel electrode when the nickel is oxidised?
..............................................................................................................................................
........................................................................................................................................ [1]
222
12- (b) Use the data in the table to answer the following questions.
..............................................................................................................................................
........................................................................................................................................ [2]
(ii) State which two different metals have the same reactivity.
........................................................................................................................................ [1]
(iii) Predict the voltage produced by a simple cell with beryllium as metal 1 and silver as
metal 2.
..............................................................................................................................................
........................................................................................................................................ [2]
(c) Describe how the simple cell in the diagram can be used to show that magnesium is more
reactive than beryllium. Explain your answer.
.....................................................................................................................................................
.....................................................................................................................................................
.....................................................................................................................................................
............................................................................................................................................... [2]
[Total: 10]
223
A fuel cell produces electrical energy by the oxidation of a fuel by oxygen.
13- The fuel is usually hydrogen but methane and methanol are two other fuels which may be used.
A diagram of a hydrogen fuel cell is given below.
H2
e–
anode
V
cathode
e–
H2O O2
.............................................................................................................................................. [1]
(b) Write the equation for the chemical reaction that takes place in a hydrogen fuel cell.
.............................................................................................................................................. [1]
(c) (i) At which electrode does oxidation occur? Explain your choice.
....................................................................................................................................... [1]
....................................................................................................................................... [2]
....................................................................................................................................................
.............................................................................................................................................. [2]
224
14-
Hydrogen and oxygen react together in a hydrogen fuel cell. A hydrogen fuel cell is shown in the
diagram.
hydrogen oxygen
H2 O2
electrolyte
water
membrane
.............................................................................................................................................. [1]
(b) (i) In a hydrogen fuel cell, the hydrogen molecules are converted into hydrogen ions, H+,
according to the ionic half-equation shown.
H2 2H+ + 2e–
....................................................................................................................................... [1]
....................................................................................................................................... [1]
(c) Write a chemical equation for the overall reaction that occurs in a hydrogen fuel cell.
.............................................................................................................................................. [1]
(d) Hydrogen fuel cells are being developed as alternatives to petrol engines in cars.
(i) Give one advantage of hydrogen fuel cells compared to petrol engines.
....................................................................................................................................... [1]
(ii) Give one disadvantage of hydrogen fuel cells compared to petrol engines.
....................................................................................................................................... [1]
225
(e) S
ome fuel cells use ethanol, C2H5OH, instead of hydrogen. Carbon dioxide and water are
products of the reaction in an ethanol fuel cell.
(i) Write a chemical equation for the overall reaction occurring in an ethanol fuel cell.
. ...................................................................................................................................... [2]
(ii) tate an environmental problem caused by the release of carbon dioxide into the
S
atmosphere.
. ...................................................................................................................................... [1]
(iii) Name the process by which ethanol can be manufactured from a renewable resource.
. ...................................................................................................................................... [1]
(f) Name the process occurring when electrical energy is used to break down an ionic compound.
.............................................................................................................................................. [1]
226
227
228
1- A metal, X, is used to make oil pipelines.
2- A piece of zinc is attached to the hull of a steel boat. Steel is an alloy of iron.
Which statement explains why the zinc prevents the iron from rusting?
A Zinc is less reactive than iron, and iron is less likely to lose electrons than zinc.
B Zinc is less reactive than iron, and iron is more likely to lose electrons than zinc.
C Zinc is more reactive than iron, and iron is less likely to lose electrons than zinc.
D Zinc is more reactive than iron, and iron is more likely to lose electrons than zinc.
3-
Which method is not used for rust prevention?
229
A test-tube containing damp iron wool is inverted in water.
4-
After three days, the water level inside the test-tube has risen.
water
air
water
Which diagram shows the level of the water at the end of the week?
A B C D
230
6- Underwater steel pipes can be protected from corrosion by attaching magnesium blocks to them.
A Fe → Fe2+ + 2e–
B Fe2+ → Fe3+ + e–
C Mg → Mg2+ + 2e–
D Mg2+ + 2e– → Mg
The nails were placed in an open dish filled with water and left for a week.
A B
wrapped wrapped
in aluminium in copper
D C
wrapped wrapped
in zinc in magnesium
8-
Which method is not used for rust prevention?
231
9- The following are examples of redox reactions.
(b) Iron and steel in the presence of water and oxygen form rust.
colourless
gas forms
oxygen dissolved
in water
electrons
Fe2+ goes
move
into solution
in metal
reaction 1
Fe → Fe2+ + 2e–
The electrons move through the iron on to the surface where a colourless gas forms.
reaction 2
Fe2+ + 2OH– → Fe(OH)2
from water
reaction 3
..........Fe(OH)2 + O2 + ..........H2O → ..........Fe(OH)3
(vi) Explain why iron in electrical contact with a piece of zinc does not rust.
....................................................................................................................................
....................................................................................................................................
.............................................................................................................................. [3]
232
(c) Rusting of steel can be prevented by coating the steel with a layer of zinc.
Explain, in terms of electron transfer, why steel does not rust even if the layer of zinc is
scratched so that the steel is exposed to air and water.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
..............................................................................................................................................
233
234
235
236
1- Some magnesium compounds undergo thermal decomposition.
What are the products of thermal decomposition of magnesium nitrate, Mg(NO3)2, and
magnesium hydroxide, Mg(OH)2?
Mg(NO3)2 Mg(OH)2
237
2- Which equations are balanced?
A chemical
B exothermic
C physical
D separation
238
Aqueous iron(III) sulfate and aqueous sodium hydroxide react to give a precipitate of
4-
iron(III) hydroxide and a solution of sodium sulfate.
reaction 1 reaction 2
A reduction hydration
B reduction hydrolysis
C thermal decomposition hydration
D thermal decomposition hydrolysis
239
Some metal nitrates and carbonates decompose when heated strongly.
7-
Metal Q has a nitrate that decomposes to give a salt and a colourless gas only.
The carbonate of metal Q does not decompose when heated with a Bunsen burner.
What is metal Q?
A calcium
B copper
C sodium
D zinc
Some marble chips (calcium carbonate) are heated strongly and substances X and Y are formed.
Substance X is a white solid that reacts with water, giving out heat. Substance Y is a colourless
gas.
240
8- Rubidium and strontium are very reactive metals at the top of the reactivity series. Because their
ions have different charges, their compounds behave differently when heated.
(b) Strontium carbonate is similar to calcium carbonate. It is insoluble in water and it decomposes
when heated. Rubidium carbonate is soluble in water and does not decompose when heated.
2RbNO3 → 2RbNO2 + O2
....................................................................................................................................... [1]
241
9-
thermal decomposition is copper(II) oxide.
(i) State the colour change of the solid seen during the reaction.
(ii) Write a chemical equation for the thermal decomposition of copper(II) carbonate.
. ...................................................................................................................................... [1]
(b) Copper(II) carbonate reacts with dilute nitric acid. One of the products of the reaction is a
Balance the chemical equation for the thermal decomposition of copper(II) nitrate.
242
10- Iron is extracted from its ore using coke in a blast furnace.
waste gases
raw materials:
coke,
iron ore,
limestone
air air
slag
molten iron
(d) (i) When iron is added to dilute sulfuric acid, an aqueous solution of iron(II) sulfate is formed
as one of the products.
....................................................................................................................................... [1]
(ii) When iron(III) oxide is added to dilute sulfuric acid, an aqueous solution of iron(III) sulfate
is formed as one of the products.
....................................................................................................................................... [3]
11- (a) (i) Name the products formed when sodium nitrate is heated.
....................................................................................................................................... [2]
(ii) When copper(II) nitrate, Cu(NO3)2, undergoes thermal decomposition, three products are
formed. One of the products is nitrogen dioxide, NO2.
....................................................................................................................................... [2]
243
244
245
246
1- A student was investigating the reaction between marble chips and dilute hydrochloric acid.
gas syringe
bung
In separate experiments, a catalyst is added to a reaction mixture and the temperature of the
2- mixture is decreased.
What are the effects of these changes on the rate of the reaction?
catalyst temperature
added decreased
A faster
aster
B faster
aster
C slower
lower
D slower
lower
247
In separate experiments, a catalyst is added to a reaction mixture and the temperature of the
3- mixture is decreased.
What are the effects of these changes on the rate of the reaction?
catalyst temperature
added decreased
A faster faster
B faster slower
C slower faster
D slower slower
1 Mixing flour with a small amount of yeast and some water to make a ‘dough’.
2 Leaving the dough in a warm place for the yeast to act on the dough to form carbon
dioxide which increases the volume of the dough.
A
B
C
D
248
5- The diagram shows an experiment to measure the rate of a chemical reaction.
dilute
hydrochloric acid
measuring cylinder
metal
water
249
6- A liquid X reacts with solid Y to form a gas.
Which two diagrams show suitable methods for investigating the rate (speed) of the reaction?
1 2
cotton wool cotton wool
X X
Y Y
balance
3 4
stopper stopper
X X
Y Y
balance
Which row describes how the energy of collision between particles changes when concentration
7- and temperature are increased?
concentration temperature
A increases increases
B increases no change
C no change increases
D no change no change
250
A liquid X reacts with solid Y to form a gas.
8-
Which two diagrams show suitable methods for investigating the rate (speed) of the reaction?
1 2
cotton wool cotton wool
X X
Y Y
balance
3 4
stopper stopper
X X
Y Y
balance
9- Which row explains why increasing temperature increases the rate of reaction?
A
B
C
D
251
10- A student was investigating the reaction between marble chips and dilute hydrochloric acid.
gas syringe
bung
marble
chips 25 cm3 of dilute
hydrochloric acid
11- A student was investigating the reaction between marble chips and dilute hydrochloric acid.
gas syringe
bung
marble
chips 25 cm3 of dilute
hydrochloric acid
252
12- (a) Sodium chlorate(I) decomposes to form sodium chloride and oxygen. The rate of this reaction
is very slow at room temperature provided the sodium chlorate(I) is stored in a dark bottle to
prevent exposure to light.
2NaCl O → 2NaCl + O2
The rate of this decomposition can be studied using the following experiment.
20 40 60 80 100
oxygen collects
in syringe
Sodium chlorate(I) is placed in the flask and 0.2 g of copper(II) oxide is added. This catalyses
the decomposition of the sodium chlorate(I) and the volume of oxygen collected is measured
every minute. The results are plotted to give a graph of the type shown below.
volume
of oxygen
0
0 time
(i) Explain why the gradient (slope) of this graph decreases with time.
.............................................................................................................................................
....................................................................................................................................... [2]
(ii) Cobalt(II) oxide is a more efficient catalyst for this reaction than copper(II) oxide.
Sketch, on the grid, the graph for the reaction catalysed by cobalt(II) oxide.
All other conditions were kept constant. [2]
253
(iii)What can you deduce from the comment that sodium chlorate(I) has to be shielded from
light?
.............................................................................................................................................
....................................................................................................................................... [1]
(iv) Explain, in terms of collisions between particles, why the initial gradient would be steeper
if the experiment was repeated at a higher temperature.
.............................................................................................................................................
.............................................................................................................................................
.............................................................................................................................................
....................................................................................................................................... [3]
254
13- The rate of a photochemical reaction is affected by light.
(b) A piece of white paper was coated with silver bromide and exposed to the light. Sections of the
paper were covered as shown in the diagram.
not covered
covered with
thin paper
covered with
thick card
Predict the appearance of the different sections of the paper after exposure to the light and the
removal of the card. Explain your predictions.
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [4]
(c) Photosynthesis is another example of a photochemical reaction. Green plants can make simple
carbohydrates, such as glucose. These can polymerise to make more complex carbohydrates,
such as starch.
....................................................................................................................................... [2]
(ii) Name the substance which is responsible for the colour in green plants and is essential for
photosynthesis.
....................................................................................................................................... [1]
255
14- Matter can exist as solid, liquid or gas. The arrows show some changes of state.
solid
A B
liquid gas
15- (c) The diagrams represent the same number of particles of a gas in two containers, D and E,
which have different volumes. The two containers are at the same temperature.
D E
In which container will the pressure be higher? Explain your answer.
....................................................................................................................................................
....................................................................................................................................................
.............................................................................................................................................. [1]
256
16- Magnesium carbonate reacts with dilute hydrochloric acid.
excess of magnesium carbonate pieces was added to dilute hydrochloric acid. The apparatus in
An
the diagram was used to measure the volume of gas produced. The total volume of gas collected
was recorded every 20 seconds.
bung
inverted
measuring cylinder
conical flask
dilute
hydrochloric water
magnesium carbonate
pieces acid trough
120
100
80
total volume of
gas collected 60
/ cm3
40
20
0
0 100 200 300 400 500
time / s
(i) Describe how the rate of this reaction changed during the reaction. Explain why the rate
changed in this way.
. ............................................................................................................................................
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(ii) The experiment was repeated using the same mass of powdered magnesium carbonate
with the same volume and concentration of dilute hydrochloric acid.
Explain how the initial rate of reaction and total volume of gas collected would compare to
the first experiment.
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[4]
(b) A piece of magnesium ribbon was cleaned. The experiment was repeated using this clean
magnesium ribbon instead of magnesium carbonate.
This reaction is exothermic.
The rate of the reaction gradually increased over the first 2 minutes.
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258
17- Copper(II) oxide reacts with dilute hydrochloric acid.
.00 g of copper(II) oxide were added to 50.0 cm3 of 1.00 mol / dm3 hydrochloric acid. This was an
6
excess of copper(II) oxide.
(a) T
he rate of the reaction can be increased by increasing the concentration of the hydrochloric acid
or by heating it.
(i) In terms of collisions, explain why increasing the concentration of the hydrochloric acid
increases the rate of the reaction.
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(ii) In terms of collisions, explain why heating the hydrochloric acid increases the rate of the
reaction.
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260