CD1: Ancol D2: Phenol CD3: Tong 6n ancol - phenol CHUYEN DE 1: ANCOL KIEN THUC CAN NHO I, Khai nigm, cng thite, tén goi, ddng phan, = Nhém OH duge goi la nhém hidroxyl 2. Céng thie: R(OH), hodc CyHsq.2240s (a la s6 nhém OH, n 8R nj Ancol no, dom chife, mach h6: CyHaqs1OH hoge CyHap:20 3. Tén goitTén thong thong = Ancol + tén géc hidzocacla+ ic TTén thay thé (IUPAC) = Tén hidrocacbon tuong ting THUQNG GAP (sé dbng phn) | __ Pte phan ancol r ee Ten TUPAC — | Bae ancol CHO 0) ‘ancol metylie | metanol T CHO.) ancl etylie etanol T ancol propylis | propan =I al T CoHLO @) ancol isopropylie | propan—2— ol z | ancol butylie | butan—1—ol 1 ancol see-buiylie_| butan =2— ol 2 ancol isobutylie —_| 2-metylpropan—I-ol 2] ancol tert-butylic | 2-metylpropan—2—ol 3] ancolanlylic | propenol 1] ancol benzylic | phenylmetanol T (CHOW), etylen glivol etan = 1,2 —diol Tl SHOW) alixerol [propan = 12,3 -wiol [1.2.1 lign két hidro liga phan ti Lim ting nbiét dé s6i nén ancol c6 mhiét d6 soi cao hon % véi hidrocacbon, dn xuat halogen, ete c6 cling s6 nguyén tir cacbon. ~ Ce ancol ti C; dén Cs tan v6 han trong nucée do tao lign ket hidro véi nude. TIT. Tinh chat héa hoe 1, Phan img thé véi KL kiém Na, K: R(OH),+aNa_ > R(ONa)s* 3H Chi y: Phan img nay ding 48 nhjn biét ancol do ¢6 hign tugng sii bot khi 12. Phin img riéng ciia ancol da ehite ancol da chite c6 it nhét 2 nh6m OH canh nhau 6 kha ndng héa tan Cu(OH)2 & nbigt 46 thutémg tgo phite chat ma xanh lam thém. 2CsH(OH)s + Cu(OH)z—+ — [CsH(OH),O;Cu + 2420 glixerol _(két tia xanh lam) (phife tan, xanh lam tham) Phan img nay dimg dé nhan biét ancol da chite cé it nhat 20H canh nhau, 3. Phan ting véi axit vo co: R(OH), + aHX —“> RX, + alo 4. Phan img tach nude (@) Tach nude tao ete (dk: H_SO, dic, 140° C): ROH + R'OH Es > Re we nin+ 1) Chit §: Cho m ancol dom chitetich nutes tg0 18% da ete (b) Téch nude tao anken (dk: H28O4 de, 170°C): Hane Quy tie tach Zaixep: Khi tach HO tit ancol thi OH sé téch wu f ao hon. 5. Phin img oxi hoa khdng hoan toan = Cac ancolbj oxi héa khdng hoan toan bai CuO khi dun + Ancol bac 1 bj oxi héa thanh andehit: | R-CH CHO + Cu+ Hz0 + Ancol bée 2 bj oxi héa thank xeton: R = CH > R-CO-R’ +Cu+H,0 + Ancol bac 3 khdng bj oxi héa bai CuO, t°. 6. Phan img chay (oxi héa hoan toan| canh c6 bic ~ Dbi v6i ancol no, don chite, mach 20+ SSA C02 + (0+ 1)H0 con 7 > CHsOH 5 CoHi205 ~ Lén men tinh bot: (LH Cel g05—=** 2C3Hs 2. Diéu ché metant cong nghiép 2c & 0 > CO + 2H,—“25 CH;-OH V. Mat Saphan ting @cbict: KN vin va goi tén (TUPAC va thong thurémg néu ¢6) cdc ancol e6 eéng thite sau: CyH4O CaOCsH20 (Cau 2: Hoan thinh bang sau Tén goi Cong thire ‘Ancol metyl ‘Ancol efylic ‘Ancol anlylie ‘Ancol benzylic Giu 3: Hoin thanh chudi phan img sau: CoH3Cl PE (C2HsONa CH; He Gls 2 Cory $$ can 2%. CH.COOH om AM, an CH,CHO ‘Phap héa hoe hdy nhgn biét cdc chat ling trong cée trug hp sau: &, ancol etylic, glixerol Cals CeHsCH=Ci | Hs01 CHS(OH)s PTH: (1)@ @), (b) Ancol etylic, etilen glicol, made, stiren. (C2HsOH ee CoHSCH=CH, | @ @. @ BAL TAP TRAC NGHIEM Cu L. Ancol la nhiing hop chat hitu eo ma phan t én két trac tiép voi A. nguyén tir eacbon, khong no. C. nguyén tir eacbon no. A. Cla=CH-OH. Cu 3. Hop chit nao sau day khony C. CsHsCHOH. A. CH.CHOH. B. (CHs).C) D. CH=CH-CH,OH. C4u 4. Hop chit nao sau day 1a yc A. CHsCH(OH). Be -O fou. D. (CHs):CH-OH, Cau 5. Hop chat nao say A. HOCH,-CH,OH. C. CHs-CH-CH-OH. D, HC(OH), Cu 6. Céng thite ting quan fom chite, mach hala A. CyHoy 1H (2 3 B. C,Hpy.20H (n2 1). C. Coogi 10 (02 D. CHo10H (n= 1), Cau 7. Cong thitg@ig quff ciaMffeol khong no, mot ndi ddi, don chire, mach he la n D. CyHae20H (n > 3). B. C,Ho,OH (n> 3). ng quit ctia ancol no, hai chite, mach hé 1 B. CyHo4(OH): (n> 1). D. CyHze:202 (n> 2), fao sau day 1a ancol da chite? LOH. —_B, CH;CH(OH) C. CH=CH-CH(OH);.D. HO-CH-CH-OH. 3-18 = 202): Chat nao sau day thuge logi ancol no, don chite, mach hé? B.C;H,(OH); ©. CH,-CHCH,OH. D.C,H,OH Cau 11. Hp chat nao sau day 1a ancol khéng no? A. CHz=CH-OH. B. CsHsOH. C.CiHs-CHOH, —_D, CH:>CH-CH,OH. Cu 12. Céng thite nao sau day lé anol no, hai chife, mach hé? A. CL(OID>. B. ClL(OH) C. C10, D. Call (OIDs. CAu 13. Hop chit ndo sau day li ancol bie mét, no, don chite, mach hé? 4A, CH:-CH-CH,OH, —_B. (CHs);CH-( Cu 14. Hop chat nao sau day 1a ancol bic hai, no, don chite, ma A. CHs-CHOH-CHs, —B. CH>-CH-CH.OH. C. HOCH,-CH,OH. —_D. CHs-CH,OH. D, (CHs),CHOH. ‘Cau 15. Hop chat nao sau day la ancol no, hai chit, mach ho? A. CHy=CH-CH,OH, B. CH;CH(OH) C. CH;-CHOH-CH,OH. D. CoHs-CHOH-CH,OH. Cu 16 (QG.18 - 201): Cong thite phan tir etanol la ‘A. CoHO2 B. Coll. C. CoH, D. CoH Cau 17 (MH.15). Tén thay thé iu tao CHsCH,CH,OH If incol e6 c6ng thite A. propan-1-ol B. propan-2-ol pentan-1-ol. D. p Au 18 (QG.16): Etanol 1a chit c6 ta kinh tr \ Pine mau tng cao sé c6 hign tuong ndn, mat tinh téo va ¢6 thé dn dén ti von; lla A. phenol. B. ancol etylic. . etanal Cau 19 (B.14): Ancol nao sau day cé sO nguyén tit cacbon bing s6, ‘A. Propan-I,2-tiol_—_B. Glixerol C. Ancol ber: Cu 20. Cong thite edu tgo cia butan-I-ol 1d A. (CHls):CH-CHOH, B. (CH C. CHsCHz-CHOH-CH3. D.C Cau 21. Cong thite edu tgo cia 2-metylbutan-1-ol A. CHsCHCH(CHs)-CH01. . (CHs):CHCH-CHOH. Cau 22. Céng thite cdu tao cua ancol anlylic 1a ‘A. CH=CH-OH. B. Cols-CHOH. gCM-CHLOH. D. Cu 23. Cong thite edu tgo cha ancol A. CHsCH;CH,OH. . (CHs).CH-CH2OH. Cau 24, Cong thite cu tao cba A. CoHlsOH. BS Cu 25. Danh phap TU A. etatr-l,2-01. Cu 26. Danh php IUPAC A, propane1,2,3etri Cau 27. Trong ede B. SWACHOH-CH,. D. CHsCH:CH,CH2OH. c he CH-CHLOH. D. CsHs(OH), C. etan-I,1-diol D, ctan-1,2-diol. C. propan-l,3ediol. —D. propan-1,2,3-0l. . CANE. C. CoH D. CHBF. cde GS ay, chat nio e nhigt d6 si lon nhét? B. CHCl. C. CoHs. _ __D.CHjOH. CoB.OH vai HySO, dae & 140 °C, thu duge sin phim li B. CH3-O-CHs. C. CpHs-0-CoHs. D. CH;-CH=0. 1g ha hge sau: 11904 (CH3CH2CH2CH2OH po-mre ‘SBMpham cia phan img c6 tén goi la A. bMQ-cn, B. 2-metylprop-2-en. _C. but-I-en. D. prop-2-en, Cu 31. Ancol nao sau day bi oxi héa béi CuO/t® tao ra andehit? A. CH;-CHOH-CHs. B. (CH3);C-OH. C. CHsCH;-CHOH-CH5. D. (CH:);CH-CHOH. ‘Cfiu 32. Ancol nao sau day bj oxi héa béi CuO/t*khéng tao ra andehit? A. CH;OH, B. CH;CH,OH. C. (CH;),CH-OH. D. (CH3);C-CH,OH.‘Cu 33. Cho phan img héa hoe sau: (CH;),CH-CH,OH + CuO —"> San phim cia phin img c6 eéng thite edu tgo 1a A. (CHs):C=0. B.(CHs),CH-COOH. €. (CHy),CH-CHO. DD. (CHs);C=CH). Cau 34, Khi dot chay mét ancol thu duge hén hop sin pham c6 nyo >Moo, thi c6 thé két ludn ancol dé 1a no, don chite, mach hé. B. no, mach hé. no, don chite D. khéng no. (Cu 35. Khi dét chay m6t ancol mach hé thu duge hén hop sin phim 6 ny, Iugin ancol 46 1a A.no, don chit. B. khéng no, don chit CC. khéng no, mot lign két dai. D. no, mot ving, 2. Mite d6 thong hieu (trung binh) Cau 36. Cho cdc hop chat sau: CH;CH:OH (X); (CHs);C-OFQY). CHNCHS@@H;),0H (Z); (CH=CH-CH(OH)-CH; (1). Ci ie ancol bac ba Ta: A.X va T. B.Y vaZ C.Zya Dy vit. Cfu 37 (A.13): Ung véi cong thite phan tir C,HjoO 6% go col ng phan cdu tao cia hau? AA. B.3. a) D.S. Ciiu 38 (C.12): $6 ancol bj Ta dng phn ci thise phan tr CsH30 1 4. BI D.3 Cau 39 (C.11): Sé ancol ding phan cau tao cia Sea thitc phan tis CsH).0, tac dung vai CuO dun néng sinh ra xeton li Ad . B.2 cs D.3 Cu 40. Phat biéu nao sau day A. Ancol c6 tinh axit yéu. Ag@l hong lim Adi miu quy tim. B. C. Ancol phan img dugcyéi D. Mfcol phan img duge véi dung dich NaOH. Cau 2. Phan img nio B. CH;CH,OH + Ni c CCHS B.2. C1. D.3. og |hgp ancol prop-2-en-1-ol va metanol v6i ISOs die & 140 °C thi sé ete t6i B.2. C3 D.4. fio sau day khong thé duge tgo thanh khi dun néng hén hop CH;OH va CHsOH? s-O-CHs, B. C3H-0-CH CCH O-GHs, — D. CHs-O-GoHs }. Cho phan img héa hge sau: oe H:804 Hs—GH—CICHahs neo . OH San phim cia phan img c6 tén goi li A. L,l-dimetylbut-3-en. B. 3,3-dimetylbut-2-en. 6C. 1, I-dimetylbut-2-en, D. 3,3-dimetylbutel-en. Cu 45. Ancol nao sau day khi tich nude tao thanh hai anken? A. CHsCHLOH. B. CH;-CHOH-CHs, C. CHs-CHOH-CH.CHs, D. CH.OH. Cu 46. Ancol nao sau day khi tich muée chi tao ra mét anken? A. CHs-CHOH-CH,CHb. B. CHs-CHOH-CH(CH:), C. CHs-CHOH-CHs, D. CHsCH;-CHOH-CH(CHs). Cu 47. Sin phim chinh thu duge khi dun néng ancol 3-metylbutan-2-ol vé 6 tén goi a A. 3-metylbut-| 6 tén goi la A. 4-metylpent-2-en, —B. metylpent-2-en. — C, 2-metylpent-I-ef Cu 48 (A.08): Khi tich made tir ancol 3-metylbutan- A.3metylbut2en, — B,3-metylbut-loen (CHi)sCHCH OHI v6 dung dich H,8Oy de la A.3-metylbut-2-en, _B, 2-metylbut-I-en Cau 50 (B.12): Hidrat héa 2-metylbut-2-en (digu kign phim chinh la A.2-metybutan-2-ol. B. 3-metybutan-2-o A. Zetylpent-3-en, —B. 2-etylpent-2-en, Cau 52 (A.07): Khi téch made tir mi dng phan cia nhau (tinh cd ddng phi A. CHsCH(CHs)CH;OH, C. CH;OCH,CH,CHy Cau 53 (QG.19 - 201). Ch thém timg giot dung dj mau dung dich KMn‘ ‘A. ancol metylic. C. ancol etylic. D. andehit axetic. (Cau 54 (A.14): Chodainbay? M9 t8 Dynghigm digu ché khi Y tir dung dich X: \ dung dich X. B. CH;CH(OH)CH,CHs, D. (ClgsCOH. Sng@fthigm kno c6 sin vai vién da bot, sau d5 hgp, sinh ra hidrocacbon lim nhat ANI B. NaCl(rin) + HySO.(d3c) —“>NaHSO, + HCL. C.C:HsOH 5 C:Hy + 140. Cl + NaOH —>NaCl + NHs + H20. D. CH;COONa(rin) + NaOH(rin) —> NayCO3+ CH,. 7Cu 55, Phat bigu ndo sau day khong ding? A, Dun néng etanol vi H2SO. dc 6 140°C tao ra dietyl ete. B. Dun néng etanol véi H280, dc 6 170 °C thi tgo ra etn. C. Phan img tach nude cia ancol tudn theo quy tic Mac-c6p-nhi-cép. D. Trong phan tmg tich nude cia ancol, nhém OH wu tign téch ra cling véi H & nguyén tir cacbon bbe cao hon bén canh dé tao thanh lign két doi C=C. Cau 56. Phat biéu ndo sau day khong ding? A. Nhigt d@ néng chay, nhiét d6 s6i, d6 tan trong nue eda ancol lin hon so véi hid xudt halogen cé kh6i Itong mol tuong dong. B. Phan tir ancol 6 edu tao kha gidng HO nén nén c6 nhiéu tinh chat twomg ty C. Cac ancol c6 nhigt 46 s6i kha cao, ti C; dén C2 1a chit Jong, > Ci la chat ran, D. Ancol khéng cé kha nang tao lign két hidro giéng HO. C4u 7 (A.08): Khi phan tich thanh phin mét ancol don chtte X thi Iuong ciia cacbon va hidro gip 3,625 lin kh6i long oxi. S6 dé: phan tir ea X 1a AL B.4, Cu 58 (C.07): C6 bao nhiéu ancol bac 2, no, don chiic, ma phan ti eta ching e6 phan tram khdi lurgng cacbon A.2. B.4. C3. Cu $9. Hén hop X g6m rugu etylic va made. Con; A.DO nagu = YE 109 t ql ye khéi vai cong thite du tgo cia nhau 100. HOH nguyén chit? D.0,23 D, 140 ml, én chit la 0,8 gamvml. Khdi long cia C;Hs0H A. 60 ml Cau 62. Khéi hrong nguyén chat trong 2 lit rugu A. 1120 gam Cau 63. C6 5 lit c. 750 gam. D. 480 gam OH nguyén chat 18 0,8 gam/ml Polgard@t ngu¥en chat (CHsOH 100°) dé duge rugu etylic 50°? - 800 ml C. 2000 mi D. 1200 mL hg, e6 Khong qué 3 nguyén tir eacbon trong phin we Biét X ign thuémg. $6 céng thire cdu tgo bén phit hgp v6i X la C D.S. }: Cho cée chét 6 céng thite edu tgo hue sau: HOCH:-CH;OH (X); HOCH;-CH)- JH (Y); HOCHs-CHOH-CH,OH (Z); CHs-CH2-O-CH2-CH; (R); CHs-CHOH-CH,OH (T). Nhimchat tic dung duge véi Cu(OH)2 tg0 thanh dung dich mau xanh lam la A.Z.R,T. B.X.Y,RT. CXZT. D.X,Y,Z,T. Cu 66 (B.09): Cho cdc hop chit sau: (a) HOCH,-CH,0H (b) HOCH,-CH,-CH,0H (c) HOCH;-CH(OH)-CH,0H (a) CHs-CH(OH)-CH,0# (c) CHs-CH2OH () CH:-O-CH,CH;Cac cht déu tée dung duge véi Na, Cu(OH)2 a: A.(), @), , B@, 6) © C. (@), (©), (@) D. (©), (@), (©) Cu 67(C.09): Day gdm cae chit déu tic dung véi ancol etylic fi: ‘A. NaOH, K, MgO, HCOOH (xiic tac). B. NaxCOs, CuO (1°), CHsCOOH (xtie tie), (CHsCO),0. €.Ca, CuO (1°), CelHsOH (phenol), HOCH;CHOH. D. HBr (1°), Na, CuO (t®), CHsCOOH (xtc téc). Sir dung dir kign sau dé tra loi cdc eau hii 68, 69, 70, 71, 72, 73, 74 XX Cho so dé phan tng sau: NN CHsCOONa Ld ) 15009 |g Ha PAGO, EC py NOM, HCI, ata o Fae \e Alc, 12 . wsoenoe | \\ 2 a \ea 6 an 4 Cau 68, Tén goi cla A 1a wn, A. metan. B. etilen, a D. etan Cau 69. Tén goi eta Bi A. metan. B. butan, Na hen D. etilen, Cu 70. Tén goi cia D 1a A. ctilen, B. ctyprom C. axetifen Dz ctan Cu 71. Cong thite héa hoc gga ONG 2 A. CHa. ©. (GH)20. D.(CH),0. Cu 72. H thuge loai A.ancol . C. andehit. D. ankan. 4} trén 1a din xudt halogen? ACE. CDF D.D,E,G. Cau 74. Trong c: (7), (8), (9), (10), Cée phan ting thé li (6). (8), (10). _€.(5), (Dy (8). D.(5), (6), (9). A. (6), ( q chay hon toan m gam hén hgp hai ancol no, don chite, mach he thu durge tc) yi'a gam H,0. Bigu thifc lién hé gitta m, a va V 1a Bat chay hodn toan hén hgp X gdm hai ancol no, hai chire, mach hé can vira dit Vi ‘Guge V2 lit khi CO» va a mol HO. Cac khi déu do & digu kign tiéu chudn, Bigu thite B.V,=V2+224a CV; =V2-224a DLV, =2V2 + 11,22. HET.CHUYEN DE 2: PHENOL KIEN THUC CAN NHO 1. Khai nigm . . - Phenol 1a nhimg hgp chat hitu co ma phan tir e6 chira nhém hidroxyl (OH) lign két true tiép véri nguyén tir C ca ving benzen, - Néu OH gn vao mach nhénh ciia véng thom thi hgp chat dé 1a ancol thom khéng pha phguol. oH on OH Cth - OH o oOo” a, O CF phenol o-crezol —m-rezal ancal benzylic Lt Phenol ancol thom 2. Tinh chat vat li * Phenol (CsHsOH) la chat rn khéng mau, it tan trong nuéedanh, t ng Ngnoky ete, = Phenol de, nhigt d6 s6i cao do e6 lién két hidro. 3. Tinh chat héa hi Phenol c6 tinh axit yéu va tinh chit eva vang thom ~ Khong Lim di mau qui tim. - Tae dung véi kim logi nhur Na, K: CsHsOH + - Tae dung véi bazo kiém nh NaOH, KOH: Cel Phan tmg trén chimg minh phenol c6 Ie axit. (b) Tinh chat cita yong thom: Bhan v - Do e6 nhém OH diy e vao yom hi nang lam mit mau dung’ (I +H “sHsONa + HzO OF do c6 vong benzen hiit e lam ting cila vong benzen nén phenol c6 thura@®, tao két ta tring: “oH2Br3(OH)| sing + 3HBr 4. Diéu ché = Phuong phép efi: Bi tr clo *| > CxHsONa —> CoHsOH - Phuomg phap hid # BATTAP TC BAN Cau 1: Vig pine vA Nefa0H, Br, ‘an tmg xay ra (néu c6) khi cho: ancol etylic, ancol anlylic, phenol Lin @ ® © 2: Neale chit: (1) ancol metylic, (2) ancol etylic, (3) etilenglicol, (4) glixerol, (5) benzen, (6) . (7) stiren, (8) phenol, (9) 6 —erezol. = NhimMg chit tée dung véi Na Ba ~ Nhitng chat tée dung véi NaOH la Nhiing chét lim mat mau dung dich brom la - Ning chét hda tan Cu(OH)» 6 ditu kign thuémg la 10Céiu 3: Chi dig | thude thir hay nhan biét dung dich cic chét sau: benzen, stiren, phenol Colle GiHsCH=CH; | _ CeHsOH PTH: (1) tir eacbon no. CC. nguyén tir cacbon cia vong benzen. Cau 2. Hop chat CoHsOH c6 tén 1a A.benzen, B. ancol etylic. Cau 3. Hop chit CeHs-CH:OH 06 tén 1a A. ancol benzylic. B. ancol metylic. Cu 4. Trong céc hop chit sau: oH Loh a Q Phat biéu nao sau day khong ding? ‘A. (1), (3) la ancol thom, B. (1), (2), (3) déu 6 céng thite Pagn tir €. (2), (4) 14 ancol thom. D. (1), (3) la phenol Cau 5, Hop chat nao Tén goi cua X la A. m-etylphenol B. o-etylphenol. D. nguyén tir cac . ancol ben: . phen aXe cH 8 @ on ach w Ho bien pono CH.CHy CC. m-crezol. D. p-etylphenol. itu co Xi, X2, Xs ld dng phin céu tao ciia nhau, e6 cOng thite phan tir la tu tao cla X1, Xa, Xs Hin lot la cta Tén thong thurémg cita X; va Xs ln hugt li: A. o-crezol va m-crez0l. B. m-crezol va p-crezol. C. o-erezol va p-crezol. D. p-etezol vi m-crezol, Cu 9. Phan img nao sau day khdng xy ra? A. CH\OH + Na > CHsONa+ $1. B. C6HsOH + NaOH —> Cob . C. CHsOH + NaOH —> CHsONa + H,0. D. CsHsOH + Na -> Na Cu 10. Phin img no sau day khong xiy ra? A, CISOH + NaOH —> CHsONa + 0. B. ClIsONa 4 C. CHsONa + H,0 —> CHsOH + NaOH. D.C CHs Cau 11 (A.13): Phenol phan img durge véi dung dich na A. NaCl. B.HCL C. Nall KO Cau 12 (MH.18). Cho vai giot madcbrom vao dungdich’ a Sag thicn A. két tatrang, B. két tiadé nau. boi ‘dungdich mau xanh. Cu 13 (C.13): Dung dich phenol (C.HsOH) khdn| hit nao sau day? ‘A. NaOH, B. NaCl. D.Na Cu 14 (A.14): Phenol (CsHsOH) khong phan’ ALNa, B. NaHCOs. MUTA a Nala AB. Cau 17 (B.07); S6 chai ee v A.2. Cau 18 Q 10: Pi D.2. . xuat ciia benzen) déu tée dung cl D4. mg thitc phn tir CsHioO, chita ving benzen, téc dung hg i dung dich NaOH 18 C6. D.4. chi ding phin cu tgo et nau c6e6ng the phn te Cia, ong, pin ‘dung duege véi Na, khdng téc dung duge voi NaOH 1a B.6, C7. DS. : Anh husg cia nhém -OH dén géc CéHls- trong phan tir phenol thé hign qua phan gitta ORL vai lung dich NaOH. —_B. Na kim Logi C. nude Br. D. H(Ni, nung nong), Cau %. Khi cho phenol phan img véi brom (ti 1 mol 1:1) thu duge sin phim chinh 18 A. m-bromtoluen, B. o- vi p-bromphenol. C. m-bromphenol. D. o- va p-bromtoluen, ‘Cau 22. Khi cho phenol phan img véi brom du thu duge sn phim la A.2,4,6-tribromtoluen. B. o- va p-bromphenol. CC. m-bromphenol. D. 2,4,6-tribromphenol. 2Cu 23 (B.07): Day gdm céc chat déu phan img véi phenol 1: ‘A. dung dich NaCl, dung djch NaOH, kim loai Na. B. nude brom, axit axetic, dung dich NaOH. C. nude brom, anhidrit axetic, dung dich NaOH. D. nude brom, andehit axetic, dung dich NaOH. . Cu 24 (C.09): Trong thy t8, phenol duge ding dé sin xudt A. poli(phenol-fomandehit), chat diét c6 2,4-D va axit picric B. nhya rezol, nhya rezit va thude tri s 666 . nha poti(vinyl clorua), nhyta novolac va chat digt e6 2,4-D D. nhya rezit, chat diét c& 2,4-D va thuée né TNT (Cau 25 (C.14): Phat bigu nao sau day la sai khi néi vé phenol (C ancol > axit cacbonic. D. axit eacbonic > ancol > phenol. C. axit cacbonie > ph : i 5 (X); CoHsOH (¥) vi CHSOH (Z) bin ddi theo tht tr Cau 29. Tinh axit nado dudi day? C.Z>Y>X. D.X>Z>Y. B.3, C4, D1 i: C,H, Se x, ys 7, Ha chit hit co Y, Z B. CelHs(OMe, CHCl D. CsHsONa, CcHsOH. XE MOH Go. y HHO, 7 Trong dé X, Y, Z déu 1a hén hop cua eée chat hitu eo. Z c6 thinh phan chinh gdm A. m-metylphenol va o-metylphenol B. benzyl bromua va o-bromtoluen. C. o-bromtoluen va p-bromtoluen, D. o-metylphenol va p-metylphenol. (Cu 33 (A.10): Trong s6 cdc phat biéu sau vé phenol (CeHsOH): (1) Phenol tan it trong nude nhung tan nhiéu trong dung dich HCl 1B(2) Phenol c6 tinh axit, dung dich phenol khéng Lim di mau quy tim, (3) Phenol ding dé san xuat keo din, chat di (4) Phenol tham gia phan img thé brom va thé nitro dé hon benzen, Cac phat bigu ding la: A. (1), (2), (4). B. (2), (3), (4). C.(), 2), @). D.(1), GB), 4). Cu 34 (A.12): Cho cée phat biéu sau vé phenol (CeHsOH): (a) Phenol tan nhigu trong nude lanh, (b) Phenol c6 tinh axit nhung dung dich phenol trong nude khOng lam Adi mau q (©) Phenol duge ding dé sin xuat pham nhudm, ct (@) Nguyén ta H cia ving benzen trong phenol dé _ (6) Cho nuée brom vao dung dich phenol thay xuat hign két tia, S6 phat bigu ding 1a Ad B.2 Gs. HET. uaCHUYEN DE ING ON ANCOL — PHENOL 10 DIEU THAY BINH DAY VE ANCOL - PHENOL. 1. Diéu kign t6n tai ancol: (1) nhém OH phai gin vio nguyén ti Cy, (2) mdi C chi gin tdi da 1OH, 2. Ancol no, dan chife, mach ho: CyHan-1OH hoe CyHan.20 (2 = 1). 3.Bac ca ancol bing bic cla nguyén tir C lién két true tiép voi nhom OH (Bac cua nguyén tir C = sé nguyén tir C lién két truce tiép vei C 6) 4, Dg nugula s6 ml ancol etylic nguyén chat c6 trong 100 ml dung dich rugu va H:0 Veanyoringoescst Dora = SHEEN 100% 5. Lin két hidro la luc hit tinh dign gitta H linh dng (mang dign duomg) F, 0, N (mang dign am), Céc cht chita lién két HF, H—O, H—N, 6. Ancol cd it nhat 2 nhom OH canh nhau e6 kha nang haa tan Cu(O) 7.Quy te tach Zaixep: Khi tach HO tit ancol thi OH sé tach cao hon. 8. Phenol la hgp chat hitu co trong phan tir 6 nhém OH lig 9. Trong phan tit phenol, nhém OH diy e vao vang beyzeN(a% ting kha Mpg thé = phenol c6 kha ning thé brom ngay diéu kin thudng tao két tha tring wen hat e Lim ting 46 phan eye cia lign k&t © — H = ting d6 Linh én, inh axit yéu, 06 kha ning te dung véi dung dich kiém. 10.M6t sé phan (ing die biét:(1)CHs0H + Of (2) 2C2H.0H. [CsHs(OH)20],Cu + 2H20 s-OH + 2CO; 1, Ancol la hche trong 2. Phenol ld hehe trong pha 3. Bac ancol bing bag gi ngt 4.D6 rugula.. 5. Quy ti lién két true tiép véi nguyén tir - +. Vi nh6m OH. ogy od. a Pylic nguyen chit 6 trong 100 ml dung dich rugu va HO. ich ay téch H10 tir ancol thi OH sé téch wu tign véi H cia C bén canh 6 bée Cong thire Tén goi Cong thite © Glixerol © Ancol benzylic (@) Phenol @o- Crezol @ Etienglicol - Nhiing chat tée dung véi Na la - Nhiing chit tée dung véi NaOH la ~ Nhiing chat lam mit mau dung dich brom 1a- Nhiing cl 7. Nha biét céc chat sau: ancol etylic, glixerol, phenol, nuée, stiren, ft hoa tan Cu(OH): & digu kign thardng la GHSOH GHS(OH)s CHO #0 (CeHsCH=CHe PTHE: (1) @ @) @).. 8. Ti khi thién nhiéngue nga (1 °98P "OS*HD *ONH 14 3un weg (a) apa Zag pp 198 Bun ueyg (©) wazuoq 3ugA OFS 9H dz (99 oy jo2u2) HORN 19 Sun weya (@) MeN 198 Fun wey (2) gd xe GULL“ FOND 19q BOY xo Sun uvyd “Ss 2 =9 engo wy diy oft s9nu yoy, (@) ‘219 of 99nu Y>RL, (8) apnu ype Bun utd “y 69 QA sXe Yoa Bun ued “E (919 uequ)anyD ep fooue eNO BugH WyYD YUN "Z wy ON wa gu Bun ueug * a6u wou ypUD HU “QUT “ony Wop “OU fOOU jour 1m DLL + anu Bug wgT eq TONTHA TONY, "IONGHd - TOONY ONAL NID LIM ONOL AGIDE LUYEN ANCOL - PHENOL 20 cu - 30 phiit 1 2 3 4 s 6 7 8 9 10 11 12 B 14 5 16 17 18 9 20 CAu 1(QG.18 - 202): Chat nao sau day thuge logi ancol no, don chite, mach hé? AHICHO. B.C,H,(OH)9. €. CH;=CHCH;OH. D.C)H,OH. Céu 2 (QG.16): Etanol la chat c6 téc d6ng dén than kinh trung wong. Khi him lugng etanol trong mdu ting cao sé c6 hign tugng nén, mat tinh tao va e6 thé dan dén tir vong. Tén goi khéc cia etanol A. phenol B. ancol etylic. . etanal D. axit fomic. Cau 3 (A.13): Ung véi cng thiic phan tir CeHgO 6 bao nhiéu ancol 1a ding phan edu tao ciia hau? A. B.3, G2 D.S. Cau 4 (C.08): Khi dun néng hén hop ancol gim CHOH vi C)HsOH (xiie te H2SO, dae, 6 140°C) thi s6 ete thu duge toi da la 4. B.2. cl D3. Cu 5 (MH.18). Cho vai giot nudicbrom vdo dungdich phenol, Kéenhethdyxuathign A. két tiatrang, B. két tiadd nu, C. bot kl D. dungdich mau xanh. Cu 6 (B.12): C6 bao mhiéu chit chira vong benzen ed eiimg cng thire phan tit CsH40? ALS. B.S. C6. D.4, Cau 7 (4.08): Khi tach nude tir ancol 3-metylbutan-2-ol, sin phdm chinh thu duge la A.3-metylbut-2-en. _B. 3-metylbut-I-en, —C, 2-metylbut-2-en. _D, 2-metylbut-3-en. Cu 8 (C.14): Phat bigu ndo sau day 1d sai khi néi vé phenol (C6HsOH)? ‘A. Dung dich phenol khéng lam déi mau quy tim B. Phenol téc dung véi mude brom tao két tia C. Phenol thugec logi ancol thom, don chite D, Phenol it tan trong nude Janh nhung tan nhiéu trong mede nong Cau 9 (A.14): Cho hinh vé m6 ta thi nghigm digu ché khi ¥ wr dung dich X: dung dich X. ae mic Hinh vé trén minh hoa phan img nao sau day? A.NHACl + NaOH —“>NaCl + NHs + H20. in) + HySOc(die) —-»NaHSO, + HCL C.C:H;OH —2>C.H, + H20, D. CH;COONa(rin) + NaOH(ran): Cu 10 (B.09): Cho cae hop chat sau: (a) HOCH,-CH.OH (b) HOCH,-CH.-CH.OH (c) HOCH;-CH(OH)-CH,OH (d) CHs-CH(OH)-CH,OH >NagCOy+ CHa.I-CHOH () CH0-CH,CH; tie dung durge véi Na, Cu(OH), li f) B. (a), (b), (€) C. (a), (©), (@) D. (©), (4), (©) (Cu 11 (B.12): Cho day chuyén héa sau; CaC, —Y° 4X > YZ Ten goi cia X va Z lin lugt la: A. axetilen va ancol etylic. B. axetilen va etylen glicol. C. ctan va etanal D. etilen va ancol etylic CAu 12 (MHL15). Cho day cée dung dich sau: NaOH, NaHCOs, HCl, NaNOs, Bi trong diy phan tmg duge véi phenol la ALD. B.3, C4. D1 Cau 13 (A.14): Ancol X no, mach hé, c6 khéng qua 3 nguyén tir cack Khdng tac dung véi Cu(OH), 6 digu kign thurémg. Sé cng thie cu tao, A. B.2. . C3. Cu 14 (C.11): Cho m gam hin hgp X gdm phenol va etanol thu duge 2,24 lit khi Hz (dkte). Mat khéc, dé phan ing hoan toa dich NaOH 1M. Gié tricia m la A.70 B14 Cu 15 (A.07): Cho 15,6 gam hén hop hai ancol don dung hét véi 9,2 gam Na, thu durge 24,5 gam cl A. GHSOH va C3H0H. C. CHOH vi GHSOH. Céu 16(B.08): Dun néng m@t ancol dom chite thich hgp sinh ra chat hitu co Y, ti Kl A. C3HIgO. B. C2H60) Cau 17 (A.12): Cho cae phat biéu sau’ (a) Phenol tan nhiéu trong mi (b) Phenol c6 tinh axit nl (6) Phenol duge ding (@) Nguyén tir H ct _(@) Cho mide brom vio 6 phat biéu ding 1 And. C5 D.3. 2 . Cau 18(4,10): as xin Mf m gam hdn hgp 3 ancol don chitc, thude cing day ding ding, thu duge S08 1 ng tc) va 54 gam H,0. Gia tr cia m la SS B. 5,72. 4,72. D. 7,42 12804 dc trong didu kign nhigt d6 428. Cong thite phan tir cia Y 1a ‘D. C4HR0, 19