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Cross Study

Transesterification of Waste Cooking Oil


using Alkali Catalyst for Biodiesel
Production

BY FATIMA ALMARANI & XIAOHAN YU


Reviewed by Andrea Monsalve
Introduction

1 2 3
CONCERN SOLUTION METHOD

Environmental Biodiesel as WCO Recycling


Threats alternative fuel (Pre-treatment
by petroleum-based process)
diesel
Body
What am I expecting to read?

WCO Pre-treatment process


Biodiesel production process
Use of Alkali Catalyst
Biodiesel chemical properties
If WCO is an effective feedstock to produce biodiesel
What is the research question?

To evaluate if recycling WCO using Alkali Catalyst is


an effective way to produce biodiesel
How is this project done?

Transesterefication
Waste cooking oil Waste cooking oil
of WCO to
(WCO) pre-treatment
Biodiesel
Reflective Study
What have I learned?

Waste cooking oil limitations (impurities)

Acid value: Method to determine the amount of free fatty acids

FFA content allowed to carry out the transesterification without


pre-treatment: 2%

Optimal conditions for a higher yield: 60 °C | 60 min | 1:6 oil

Acid catalyst necessitates a greater ratio than base (1:15, 1:16)


How is this project done?

Theoretical Result
How is this project done?

Chemical properties values of produced biodiesel


What is unclear for you in the text?

Waste Cooking Oil pre-treatment process:

More information about the acid value (range)

High FFA and water disadvantages

Solution: Acid esterification with methanol and sulfuric acid


and evaporate the water

Diagram of the process to understand the order of the steps


What would you like to know more about
when you study other's project?

Emphasize
Who How

Why

The method used to test a hypothesis


Improvements and Changes
Explicit research question

Methodology explained with diagrams

WCO pre-treatment process

Biodiesel production flowchart ( L. Ionel., 2011)


Conclusion
WCO Pre-treatment process

Biodiesel production process


Use of Alkali Catalyst
Biodiesel chemical properties
If WCO is an effective feedstock to produce biodiesel

Good analysis and comparison with


comercial biofuel

Anything that might benefit my individual project?


Anything that might
benefit my individual
project?

Comparison table of fuel properties or


best quality standards :

Fuel proposed vs Comercial fuel


References

CVENGROS, J. & CVENGROSOVA, Z. 2004. Used frying oils and fats and their utilization in the production of methyl
esters of higher fatty acids. Biomass & bioenergy, 27(2), pp. 173-181. doi:10.1016/j.biombioe.2003.11.006

Demirbas, A. 2009. Biodiesel from waste cooking oil via base-catalytic and supercritical methanol transesterification.
Energy conversion and management, 50(4), pp. 923-927. doi:10.1016/j.enconman. 2008.12.023

Eldiehy, K. S., Daimary, N., Borah, D., Sarmah, D., Bora, U., Mandal, M. & Deka, D. 2022. Towards biodiesel
sustainability: Waste sweet potato leaves as a green heterogeneous catalyst for biodiesel production using microalgal oil
and waste cooking oil. Industrial crops and products, 187, . doi:10.1016/j.indcrop.2022.115467

F Ma, M Hanna. Biodiesel production: a review. Bioresource Technology, 70 (1999), pp. 1-15

Grönman, K., Pajula, T., Sillman, J., Leino, M., Vatanen, S., Kasurinen, H., . . . Soukka, R. 2019. Carbon handprint – An
approach to assess the positive climate impacts of products demonstrated via renewable diesel case. Journal of cleaner
production, 206, pp. 1059-1072. doi:10.1016/j.jclepro.2018.09.233
Journal of the American Oil Chemists Society, 76 (1999), pp. 545-550

Korkut, I. & Bayramoglu, M. 2018. Selection of catalyst and reaction conditions for ultrasound assisted biodiesel
production from canola oil. Renewable energy, 116, pp. 543-551. doi:10.1016/j.renene.2017.10.010

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