RT. (Wn 8) ral » where Vj, is volume of gas (a, B are constant). The hein) @ ‘A real gas follows the equation : P= temperature above which the gas cannol be Sut at any pressure is equal (a) XeF, +H,0 —> NS [ma :) (ve o-* (b) XeF) + H,0-— () XeF,=Hj0-——> aps 2Seep (@) Powhite) + NaOH — a (©) Cl; + hot & cone. NaOH — () MnO, + Fe! +H Pvy = P¥m+4— a => PV +ANm — Pb ab = PT Vn pe kT ~ Sopne fo Reuah Wor Veo The > eww = Vet Pb-eT) +aVm-ab = O 2] Vm — Ye ( b-8E) 4 Svm- 2B = RT Vn? — Vinod HC \r wes EL) + Bim Be Tw — Tm B ea Seerhlt 3 ry OAs Gincvel ze — > PTVm—TWmBp = RT Vyr-Vmol toe, ve =ve- Wm Sy opine 20 > A (pe) oat? aa eae LO > dot 2 > Wn ve (BYE) oe AB 29 a Pha r PRES awip= nee ae fz os 7 40: “BTS pe ae rh iors BL IPR Zz Find the total number of.allotropes contain|discrete molecule held together by London forces :- Diamond , Graphite ,(Fullerene, } Whe propos) Rhombic sulphur } Black phosphorus a a ae > x uweo ® 2 Bo) —-NuC ron) etink frm) esesor + [RemJ — No, ‘Space for Bagh Work ee EGvet e fheny], frie a T 1. The following reaction is a slow reaction and hence Ruthenium (molar mass = 101 gm) is used as catalyst Cast ee NaBH,(aq) + 2H20(0) Na'(aq.) + BO» + (aq) + 4H2(g) cas Kinetic studies show that reaction is_Ist_order with respect 10 catalyst_but zero-order _with respect to substrate. The rate of hydrogen production per mole of Ruthenium is 92 mole H, (mol Ru) ' min | at 27°C. Identify CORRECT option(s) {R = 0.08 atm - ¢/ mol - K} 8) {R= 0.08 atm - ¢/mol-K) (A) Approximately 0.045 mg Ru, must be added to 0.1 dm? , 1 mol dm? NaBH, to supply H, gas atrate of 0.1 dm? min Tat 27°C and 1 atm (B) Approximately 4.574 mg of Ru, must be added to 0.1 dm} , | mol dm™ NaBH, to supply Hy gas at rate of 0.1 dm’ min” at 27°C and | atm (C) 1f0.1 dm’, | mol dm NaBH, is used to supply H, at at rate of 0.1 dm*min™ at 27°C, | atm, then upto 96 min hydrogen can be supplied in this way (D) If 0.1 dm’, 1 mol dm-* NaBH, is used to supply Hz at at rate of 0.1 dm'min | at 27°C, 1 atm, then upto 48 min hydrogen can be supplied in this way Imole Ry —> 42, — Space for Rough Work Ba me poe ortdm'/onin T2 200K, P= lnbon Oil T2300k fs tabu vener > py, _ [xo1O = "="er ~poaxzo0 *%37 OOICJAIOZI21108 4. 2mdLe Hy tmole 4 ky £-13/28 MASS sz Flint \ Qky =x Xl0lxi000 mg —— #6 a “ato Rexig ndTo 0.35 litre of 0.1 M NH3@.1S litre of 0.1 M MgCl; 3) added. What minimum mass of (NH,)> SO, should be added to cause Mg(OH)) 10 re-TSSONG OSL FO ISL ae The value of K,, of Mg(OH)3 = 1.2 * 10"! Ky(NH3)=2 * 10° Fost yy (A) 2.31 gm (B) 1.555 gm (©) 9.24 gm (D) 4.62 gm ws Space for Rough Work oe ciao ges on —> Mons | De at eae ge + sa! — 2+ 4 ong _ Kep(eslomla, toe ee. we om . P+] [lng vax" Meese = > (eine eee Tonal] £-12/28 ——— P1SOL ” 1 BISADL) ( SHxB2E) GS y 7. Potassium dichromate is one of the most widely used precipitating reagents, The following equilibria are established in aqueous solutions of CVI) AUC, SCOP 4H slog Ky=-6.50 ~~ HOMO = Crag Ht Ka 2HCIO, = C07 +10 Gk Te ERED greet ' is 36 “ Given Ky= 104 and 10136 = 23 one pea Select corréet options (3) benie aT. 2. AF ea, OO 1,0 HOO, + OH Cavxw Fd Kb Oy (B) Keg. for: CrO,* + H,0 = HCO, + OH 2 tani"! 1001CJA102121105 2 Gee 3 MET Keg. for : C1 +20H = 2Cr + Brive action : C1072 + 20H = 2CrO,> + 10 is strongly favored in forward direction, Space for Rough Work Ks -65 K, e ‘a 16% Hrty = oe +H ok, —O 2ALog = os tHe Ke 2 Hoo Sut row np} to = 2HoOg E14/28 2 Heyy —PAGrOe oe x Ke 100164A102121105 2ut + 200" => 2Hs0 = ka"molecular orbital ©) 03° Z2PL Which of the following is/are diamagnetic and HOMO is the Gerad Ax ®) 0. X faxa Space for Rough Work Homo, Ny 10, Find compounds given below, which produce metallic residue and paramagnetic gas on heating HK (A) POO)» BAF HO $ «© Ko; (D) BalNs)p ‘pave rr nuuyit wurK PhO), Porn +0, Hye +a Mgt OL Ba(s), So Bar M- Ina Cu-Zn alloy the molar fractions of Cu and Zn are 0.750 and 0.250, respectively. The structure type of the alloy is the same as that of pure copper, except Zn atoms substitute some Cu atoms randomly and statistically, ie. at every atomic position, the probability of the occupation of Cu and Zn is proportional to the composition of the alloy. In this sense the alloy can be considered as composed of statistical atoms Cu,Zn,_,. X-ray analysis hows that the arrangement of atoms in the alloy is of the cubic face-centred close packing type. 25.7 Density of the alloy d= (3 aa $5) gem. C Zn=65 (Ny = 6 10") Space for Rough Work Xoneo1s — Ken= 02s —~ &) culate the radius in A of the statistical atoms in the alloy. en ) > gs 4y a: 72x64 tg “G022 0? xadCH,-C=C-CH, 5 alte ©” Ag Na/liq. NH3 AIEHICCh A 8 CHytscthy Home CCl SS cp (CH,=CH-CH=CI —— reds CHC EN CH (ewe)! 2° at Qe ‘Space for Rough Work a . ‘<" Cy — CX =eor= Cm 8 Oy ety woe ony te Om,