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Il. FERTILIZER PRECISION
Question 1. Add 5.00 mL of solution out of
solution Y (the total concentration of existing
forms of Fe(III) in the remaining solution is
less than 106 M).
pKa(CH3COOH) = 4,7
-5,.92
Question 2. (a) Calculate the pH of solution X containing 0.01 M AICI3
and 0.02 M MgCl2 (b) Slowly add 10 mL of 0.07 M NH3 solution to 10 mL of solution
What precipitates appear?
(c) Calculate the concentration range of NH3 added to solution X to completely precipitate Al(OH)3 without
precipitating Mg(OH)2? Consider the total concentration of all forms of aluminum in the solution to be no
more than 0.1% and consider the separation process complete and maintaining NH3 does not change the volume
of the system. Know: -Ig*B(Al(OH) 2*) = 4.30; -1g*B(Mg(OH)*) = 12.80; pKa(NH4 ) = 9.24; pKs(Mg(OH)2) -
9.20; pKs(Al(OH)3) = 32.40; pKa(HALO2.H20) = 12,60.
Question 3. Solution X includes 0.02M CdCl2 and 0.04M FeCl2.
(a) Calculate the pH of solution X.
(b) Slowly add 10.00 mL of 0.1M H2S solution into 10.00 mL of X solution, shake well until
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