‘or Paint & Chemical Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 01.01.2016 [ECE Re Me + Product identifier ‘Trade name: PDI NC Thinner M Relevant identified uses of the substance or mixture and uses advised against ‘No further relevant information available. Application of the substance /the mixture. Details ofthe supplier of te safety datasheet Manufacturer/Supplier: PDI For Paint & Chemical Coatings + New Borg El-Arab City, third Industrial Zone EGYPT Alexandria, + info@pdipaintco.com Further information obtainable from: Product safety department Emergency telephone number: During normal opening times: +20 34623360 Page 1/8 Revision: 20.01.2016 rds: Classification of the substance ormixture + Classification according to Regulation(EQ) No 1272/2008 & GHS02 flame Flam, Lig. 3 H226 Flammable liquid and vapour. Dow cc Eye Dam. 1 H318 Causes serious eve damage. Qe STOTSE3 11336 May cause drowsiness ordi Label elements Labelling according to Regulation (EQ) No1272/2008 ‘The product is classified and labelled according to the CLP regulation. ess, (Conta on page 2)Page 2/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 ‘Trade name: PDI NC Thinner M_ {Contd of page ‘Hazard pictograms OOD GHS02 GHS0s GHS07 Signal word Danger Hacard-determining components oftabelling: butanol n-butyl acetate Hazard statements +226 Flammable liguid and vapour. BIS Causes skin irritation. 4318 Causes serious eve damage. 11336 May cause drowsiness or dizziness. Precautionary statements PIOL medical advice is needed, have produet comainer or label ai hand. PI02 Keep out of reach of children. P103 Read label before use. P20 Keep avay from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. ‘P303-+P361 +P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P305-+P351-+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. 310 Inmediately call a POISON CENTER/doctor. aos Store locked up. PSO1 Dispose of contents/container in accordance with local‘regional/national/international regulations. Other hazards Results of PBT and vPrBassessment ' Not applicable, 2 Not applicable Wn eee eae Chemical characterisation: Mixtures Description: Mixture of substances listed belowwith nonhazardous additions Dangerous components: CAS: 1330-20-7 sylone 25-50% EINECS: 215-535-7 © Flam Lig. 3, #226; D Acute Tox. 4, H3TZ; Aewe Tox. 4, 1332; Skin Imt CAs: 18 eg ocete 10-25% EINECS: 204-658-1 @ Flam. Lig. 3, H226; D STOT SE 3, H336 AS27881 bytanol 25-10% EINECS: 201-148-0, & Po. Lig 3, 1276; © Eve Dam. 1, #318; © Stn Il 2 W315; STOP | SE 3, Hi35-H336 Additional information: For the wording ofthe listed risk phrases refer to section 16. (Contd on page 3)Page 3/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 Trade name: PDLNG Thinner M (Contd ofp Pigmaee Description of frst aidmeasures General information: ‘Simptoms of poisoning may even occur after several hours; therefore medicalobservation for at least 48 ious after the accident After inhatation: ‘Supply fresh air. required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist. In case of unconsciousness place patient stably in side position for transportation. + After skin contact: Inmediately wash with water and soap and rinsethoroughiy. «After eye contact: Rinse opened eve for several minutes under running water. Then consult a doctor. + Afler swattowing: If symptoms persist consultdoctor. Information for doctor: - Most important symptoms and effects, both acute and delayed No further relevant information avatlable Indication of any immediate medical attention and special treatment needed ‘No further relevant information avatlable, ue ru bee Extinguishing media ‘Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water with full et ‘Special hazards arising from the substance or mixture No further relevant information available Advice for firefighters + Protective equipment: Mouth respiratory protectivedevice. Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away Environmental precautions: Do not allow to enter sewers! surface or ground water. ‘Methods and material for containment and cleaningup: Absorb with liquid-bindling material (sand, diatomite, acid binders, universal binders, sawdust) Dispose contaminated matertal as waste according to item 13. Ensure adequate ventilation. Do not flush with water or aqueous cleansing agents Reference to other sections ‘See Section 7 for information on safe handling. ‘See Section 8 for information on personal protection equipment. ‘See Section 13 for disposal information. — (Ere Haniling: Precautions for safe handling Ensure good venilation/exhaustion at the workplace, Prevent formation of aerosol. Information about fire - and explosionprotectior Keep ignition sources away - Do not smoke. Protect against electrostatic charges. Conditions for safe storage, including anyincompatibilities Storage: Requirememtsto be met by storerooms and receptacles: No special requirements. ‘Information about storage in one common storage facility: Not required. (Contd. on pages)Page #8 Safety Data Sheet according to 1907/2006, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 ‘Trade name: PDINC Thinner M {Contd ofpaze3) ‘Further information about storage conditions: Keep container lightly sealed. ‘Specific end use(s) No further relevant informationavailable. par ee Additional information about design of technical facitities: No further data; see item 7 Conirol parameters Ingredients with limit values that require monitoring at the workplace: 1330-20-7 aylene WEL| Short-term value: 441 mgm’, 100 ppm Long-term value: 220 mgm’, 50 ppm Sk; BMGY 123-86-4 n-butyl acetate WEL Short-term value: 965 mg/h, 200 pin Long-term value: 724 mg/m! 150ppm 78-83-1 butanol WEL| Short-term value: 231 mg/m’, 75 ppm Long-term value: 154 mgin’, SOppm Ingredients with biological limitvalues: 1320-20-7 xylene BMGV | 650 mmolimol creatinine Median: urine Sampling time: post shift Parameter: methyl hippuric acid Additional information: The lists valid during the making were used as basis. Exposure controls: Personal protective equipment: General protective and hygienic measures: Keep away from foodstuff, beverages and feed. Tnmediately remove all soiled and contaminated clothing Tash hands before breaks and at the end of work. Avoid contact with the skin, ‘Avoid contact with the eyes and skin. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product’ the preparation! the chemical méchure Selacionaf the slove maleriaton consieatin of the pencirtion Himersralerof dision anit legradation Material of gloves ‘The selection of the suitable gloves does not only clepend on the material, but also on further marks of quality ‘and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application, (Contd on page 5)Page 5/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 ‘Trade name: PDI NC Thinner M_ {Cont of page) “Penetration time of glovematerial ‘The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed, Eye protection: Tightly sealed goggles Pree ae Information on basic physical and chemicalproperties General Information Appearance: Form: Fluid Colour: According to product specification Odour: Characteristic Odour threshold: Not determined. pH-value: Not determined. ‘Change in condition ‘Melting point/Metting range: Undetermined. Boiling point/Boiting range: 108°C Flash point mec Flammability (solid, gaseous): Not applicable, Ignition temperature: 333°C Decomposition temperature: ‘Not determined. Self-igniting: Product is not seffigniting. Danger of explosion: Productis not explosive. However, formation of explosive airvapour mixtures are possible. Explosion limits: Lower Upper: Vapour pressure at 20°C: 12 hPa Density: Not determined. Relative density Not determined. Vapour density Not determined. Evaporation rate Not determined. Solubility in / Miscibitty with water: Not miscible or difficult to mi. Partition coefficient (n-octanol/water): Notdetermined. Viscosity: Dynamic: Not determined. Kinematic: Not determined. Solvent content: Organic solvents: 85.0% FOC (EQ) 85.00 % Solids content: 5.0% (Contd. on pase 6)Page 6/8 Safety Data Sheet according to 1907/2006EG, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 ‘Trade name: PDI NC Thinner M_ {Contd of ee 5) Other information ‘No further relevant information available. PR ee Reactivity No further relevant informationavailable. Chemical stabitity Thermal decomposition / conditions to be avoided: No decomposition ifused according to specifications. Possibility of hazardousreactions No dangerous reactions known. * Conditions to avotd No further relevant informationavailable. “Incompatible materiats: No further relevant information available. Hazardous decomposition products: No dangerous decomposition products known, Information on toxicological effects “Acute toxicity LDILCSO-vatues relevant for classification: 1330-207 xylene Oral LD50 4300 mgikg (rat) Dermal LD50 2000 mg/kg (rabbit) Primary irritant effect: ‘Skin corrosiowinritat Causes skin irritation. Serious eye damage/irritation Causes serious eye damage. Respiratory or skin sensitisation Based on available data, the classification criteria are not met. CMR effects (carcinogenity, mutagenicigy and toxicity forreproduction) Germ cell mutagenicity Based on available data, the classification criteria are not met Carcinogenicity Based on available data, the classificationcriteria are not met. Reproductive toxicity Based on available data, the classification criteria are not mes STOT-single exposure ‘May cause drowsiness or dizziness. STOT-repeatedexposure Based on available data, the classification criteria are not met. Aspiration hazard Based on available data, the classification criteria are not met Dried ened Toxicity Aauatie toxicity: No further relevant informationarailable. Persistence and degradabitity No further relevant informationavailable. Behaviour in environmental systems: Bioaceumulativepotential No further relevant information available ‘Mobility in soit No further relevant informationavailable, “Additional ecological information: General notes: Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground, Results of PBT and vPvBassessment PBT: Not applicable. wPvB: Not applicable. (Contd on page 7)Page 7/8 Safety Data Sheet according to 1907/2006/EC, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 ‘Trade name: PDI NC Thinner M_ etd toa I Other adverse effects No further relevant information available 73 Disposal considerations Waste treatment methods Recommendation ‘Must not be disposed together with household garbage. Do not allow product to reach sewage system. Uncteaned packagit Recommendation: isposal must be made according 10 official regulations, ii UN-Number ADR, IMDG, IATA ‘UN proper shipping name ADR (1263 PAINT RELATED MATERIAL IMDG, IATA PAINT Transport hazard elass(es) 3 Packing group MW Environmental hazards: Marine pollutant: No ‘Special precautions foruser EMS Number: FESE ‘Transport in bulk according to Annex II of Marpol ‘and the IBC Code Not applicable. UN "Model Regulation”: UN 1263 PAINT RELATED MATERIAL, 3, HI, (DIE) PER ee Safety, heaith and environmental regulationsfegislation specific for the substance or mixture Directive 2012180 “Named dangerous substances - ANNEX I None of the mgredients is listed ‘Seveso category P5c FLAMMABLE LIQUIDS Quatifying quantity (tonnes) forthe application of tower-tier requirements 5.000 ‘Qualifying quantity (tonnes) for the application of upper-tier requirements 50.000 Chemical safety assessment: A Chemical Safety Assessment has not been carried ot AO ‘This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H226 Flammable liguid and vapour. #312 Harmful in contact with skin. F315 Causes skin irritation. HIB Causes serious eve damage. ‘H1332 Harmful if inhaled. E335 Mav cause respiratory irritation. 336 May cause drowsiness or (Conta on page 8)Page 8/8 Safety Data Sheet according to 1907/2006, Article 31 Printing date 03.11.2015 Revision: 30.09.2015 Trade name: PDINC Thinner M. Department issuing MSDS: Product safety department Contact: Mr. KHALIL Abbreviations and acronyms: ADR: sccord euvapion sure ransport des marchandiesdangereuses por Route (Europea Agreement concern the Inara Ganriage of Dango Goats by oad) serene "ane * {IMDG* nernononal she Code fr Dongeros Goode AT: nernanona ar Ronsporassocianon GH: Globll Hormonised Sytem of Clesrcotion and Labelling of Chenscale EINECS: European Irony of Evang Conmrcil Chantca useemces [ELINCS:Enropeon Lt of Noe Chomcn Subcncee C48: Chena dbsnacs Senice (vision ofthe neican Ohi Soci) TOC: Tolan Organ Compounds (S420) LLCS0: Latha concentration 3Opercon ‘LDSts Lana doe 50 percent (PAT: Persitene,Boaceamilie ond Toxic vPB: ‘ey Portion and von Bionceulate Flam 9. Flammable ids, Hosnrd Category 8 “ete Tox. 4 Aide ot, Hecard Csegory 4 Shinra 2: Stn corrosion, ecard Category 2 Brean i: Sonou ee-domagetne nrtanon Hawird Ctegor 1 Cost of