Test Bank for Chemistry The Central Science, 10th Edition: Brown

Test Bank for Chemistry The Central Science, 10th

Edition: Brown

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Exam

Name___________________________________

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.

1) Hydrogen bonding is a special case of __________. 1)

A) ion-dipole attraction
B) London-dispersion forces
C) dipole-dipole attractions
D) none of the above
E) ion-ion interactions
Answer: C
Explanation: A)
B)
C)
D)
E)

2) Which statements about viscosity are true? 2)

(i) Viscosity increases as temperature decreases.
(ii) Viscosity increases as molecular weight increases.
(iii) Viscosity increases as intermolecular forces increase.
A) (i) only
B) (i) and (iii)
C) (ii) and (iii)
D) none
E) all
Answer: E
Explanation: A)
B)
C)
D)
E)

3) What portion of the volume of each atom or ion on the face of a unit cell is actually within the unit 3)
cell?
A) 3/4 B) 1/4 C) 1/2 D) all of it E) none of it
Answer: C
Explanation: A)
B)
C)
D)
E)

1
4) Based on the figure above, the boiling point of diethyl ether under an external pressure of 1.32 atm 4)
is ________°C.
A) 20 B) 0 C) 10 D) 30 E) 40
Answer: E
Explanation: A)
B)
C)
D)
E)

5) What fraction of the volume of each corner atom is actually within the volume of a face-centered 5)
cubic unit cell?
1 1 1 1
A) 1 B) C) D) E)
2 4 8 16
Answer: D
Explanation: A)
B)
C)
D)
E)

6) Ethanol (C2 H5 OH) melts at -114°C. The enthalpy of fusion is 5.02 kJ/mol. The specific heats of 6)
solid and liquid ethanol are 0.97 J/g-K and 2.3 J/g-K, respectively. How much heat (kJ) is needed to
convert 25.0 g of solid ethanol at -135°C to liquid ethanol at -50°C?
A) 207.3 B) 9.21 C) -12.7 D) 6.91 E) 4192
Answer: D
Explanation: A)
B)
C)
D)
E)

2
7) C12 H26 molecules are held together by __________. 7)
A) ion-ion interactions
B) dispersion forces
C) hydrogen bonding
D) ion-dipole interactions
E) dipole-dipole interactions
Answer: B
Explanation: A)
B)
C)
D)
E)

8) The predominant intermolecular force in CaBr2 is __________. 8)

A) dipole-dipole forces
B) London-dispersion forces
C) ion-dipole forces
D) hydrogen bonding
E) ionic bonding
Answer: E
Explanation: A)
B)
C)
D)
E)

9) What is the predominant intermolecular force in CBr4 ? 9)

A) hydrogen-bonding
B) ion-dipole attraction
C) ionic bonding
D) dipole-dipole attraction
E) London-dispersion forces
Answer: E
Explanation: A)
B)
C)
D)
E)

3
10) Based on the figure above, the boiling point of ethyl alcohol under an external pressure of 10)
0.0724 atm is __________°C.
A) 60 B) 80 C) 40 D) 70 E) 20
Answer: E
Explanation: A)
B)
C)
D)
E)

4
11) Which one of the following substances will not have hydrogen bonding as one of its intermolecular 11)
forces?
A)

B)

C)

D)

E)

Answer: E
Explanation: A)
B)
C)
D)
E)

12) A gas is __________ and assumes __________ of its container whereas a liquid is __________ and 12)
assumes __________ of its container.
A) compressible, the shape, not compressible, the volume and shape
B) condensed, the volume and shape, condensed, the volume and shape
C) compressible, the volume and shape, compressible, the volume
D) condensed, the shape, compressible, the volume and shape
E) compressible, the volume and shape, not compressible, the shape of a portion
Answer: E
Explanation: A)
B)
C)
D)
E)

5
13) A substance that expands to fill its container yet has a density approaching that of a liquid, and that 13)
can behave as a solvent is called a(n) __________.
A) liquid
B) supercritical fluid and gas
C) plasma
D) amorphous solid
E) gas
Answer: B
Explanation: A)
B)
C)
D)
E)

14) The phase diagram of a substance is given above. This substance is a __________ at 25°C and 1.0 14)
atm.
A) supercritical fluid
B) gas
C) liquid
D) crystal
E) solid
Answer: C
Explanation: A)
B)
C)
D)
E)

6
15) CsCl crystallizes in a unit cell that contains a Cs+ ion at the center of a cube and a Cl- ion at each 15)
corner. The unit cell of CsCl is __________.
A) amorphous
B) primitive cubic
C) close packed
D) body-centered cubic
E) face-centered cubic
Answer: B
Explanation: A)
B)
C)
D)
E)

16) Which statement is true about liquids but not true about solids? 16)
A) They flow and are compressible.
B) They are highly ordered and not compressible.
C) They flow and are highly ordered.
D) They flow and are not compressible.
E) They assume both the volume and the shape of their containers.
Answer: D
Explanation: A)
B)
C)
D)
E)

17) CsCl crystallizes in a unit cell that contains the Cs+ ion at the center of a cube that has a Cl- at each 17)
corner. Each unit cell contains __________ Cs+ ions and __________ Cl- , ions, respectively.
A) 1 and 8 B) 2 and 1 C) 1 and 1 D) 2 and 4 E) 2 and 2
Answer: C
Explanation: A)
B)
C)
D)
E)

18) The vapor pressure of a liquid __________. 18)

A) decreases linearly with increasing temperature
B) decreases nonlinearly with increasing temperature
C) increases linearly with increasing temperature
D) increases nonlinearly with increasing temperature
E) is totally unrelated to its molecular structure
Answer: D
Explanation: A)
B)
C)
D)
E)

7
19) Which one of the following exhibits dipole-dipole attraction between molecules? 19)
A) XeF4 B) BCl3 C) Cl2 D) CO2 E) AsH3
Answer: E
Explanation: A)
B)
C)
D)
E)

20) __________ is the energy required to expand the surface area of a liquid by a unit amount of area. 20)
A) Meniscus
B) Capillary action
C) Surface tension
D) Viscosity
E) Volatility
Answer: C
Explanation: A)
B)
C)
D)
E)

21) The fluorocarbon C2 Cl3 F3 has a normal boiling point of 47.6°C. The specific heats of C2 Cl3 F3 (l) 21)
and C2 Cl3 F3 (g) are 0.91 J/g-K and 0.67 J/g-K, respectively. The heat of vaporization of the
compound is 27.49 kJ/mol. The heat required to convert 50.0 g of the compound from the liquid at
5.0°C to the gas at 80.0°C is __________ kJ.
A) 1454 B) 10.36 C) 30.51 D) 3031 E) 8.19
Answer: B
Explanation: A)
B)
C)
D)
E)

22) The intermolecular force(s) responsible for the fact that CH4 has the lowest boiling point in the set 22)
CH4 , SiH4 , GeH4 , SnH4 is/are __________.
A) mainly hydrogen bonding but also dipole-dipole interactions
B) dipole-dipole interactions
C) London dispersion forces
D) mainly London-dispersion forces but also dipole-dipole interactions
E) hydrogen bonding
Answer: C
Explanation: A)
B)
C)
D)
E)

8
23) Large intermolecular forces in a substance are manifested by __________. 23)
A) high critical temperatures and pressures
B) high heats of fusion and vaporization
C) high boiling point
D) low vapor pressure
E) all of the above
Answer: E
Explanation: A)
B)
C)
D)
E)

24) The unit cell with all sides the same length and all angles equal to 90° that has lattice points only at 24)
the corners is called __________.
A) primitive cubic
B) spherical cubic
C) face-centered cubic
D) monoclinic
E) body-centered cubic
Answer: A
Explanation: A)
B)
C)
D)
E)

25) Crystalline solids __________. 25)

A) are usually very soft
B) exist only at high temperatures
C) exist only at very low temperatures
D) have their particles arranged randomly
E) have highly ordered structures
Answer: E
Explanation: A)
B)
C)
D)
E)

9
26) How high a liquid will rise up a narrow tube as a result of capillary action depends on __________. 26)
A) gravity alone
B) only the magnitude of cohesive forces in the liquid
C) the viscosity of the liquid
D) the magnitudes of cohesive forces in the liquid and adhesive forces between the liquid and
the tube, and gravity
E) only the magnitude of adhesive forces between the liquid and the tube
Answer: D
Explanation: A)
B)
C)
D)
E)

27) When NaCl dissolves in water, aqueous Na+ and Cl- ions result. The force of attraction that exists 27)
between Na+ and H2 O is called a(n) __________ interaction.
A) ion-dipole
B) hydrogen bonding
C) ion-ion
D) London dispersion force
E) dipole-dipole
Answer: A
Explanation: A)
B)
C)
D)
E)

10
28) Based on the figure above, the boiling point of water under an external pressure of 0.316 atm atm is 28)
__________°C.
A) 80 B) 90 C) 70 D) 60 E) 40
Answer: C
Explanation: A)
B)
C)
D)
E)

29) Consider the following statements about crystalline solids: 29)

(i) Molecules or atoms in molecular solids are held together via
intermolecular forces.
(ii) Metallic solids have atoms in the points of the crystal lattice.
(iii) Ionic solids have formula units in the point of the crystal lattice.
(iv) Atoms in covalent-network solids are connected via a network
of covalent bonds.
Which of the statements is false?
A) (i) B) (ii) C) (iii) D) (iv) E) none
Answer: C
Explanation: A)
B)
C)
D)
E)

11
30) What intermolecular force is responsible for the fact that ice is less dense than liquid water? 30)
A) ion-dipole forces
B) hydrogen bonding
C) London dispersion forces
D) dipole-dipole forces
E) ionic bonding
Answer: B
Explanation: A)
B)
C)
D)
E)

31) Heat of sublimation can be approximated by adding together __________ and __________. 31)
A) heat of freezing (solidification), heat of condensation
B) heat of fusion, heat of condensation
C) heat of freezing (solidification), heat of vaporization
D) heat of fusion, heat of vaporization
E) heat of deposition, heat of vaporization
Answer: D
Explanation: A)
B)
C)
D)
E)

32) On a phase diagram, the melting point is the same as __________. 32)
A) the triple point
B) the freezing point
C) the vapor-pressure curve
D) the boiling point
E) the critical point
Answer: B
Explanation: A)
B)
C)
D)
E)

33) The strongest interparticle attractions exist between particles of a __________ and the weakest 33)
interparticle attractions exist between particles of a __________.
A) solid, gas
B) solid, liquid
C) gas, solid
D) liquid, gas
E) liquid, solid
Answer: A
Explanation: A)
B)
C)
D)
E)

12
34) Elemental iodine (I2 ) is a solid at room temperature. What is the major attractive force that exists 34)
among different I2 molecules in the solid?
A) dipole-dipole attractions
B) covalent-ionic interactions
C) London dispersion forces
D) dipole-dipole rejections
E) ionic-dipole interactions
Answer: C
Explanation: A)
B)
C)
D)
E)

35) Metallic solids do not exhibit __________. 35)

A) extreme brittleness
B) variable hardness
C) excellent thermal conductivity
D) variable melting point
E) excellent electrical conductivity
Answer: A
Explanation: A)
B)
C)
D)
E)

36) A volatile liquid is one that __________. 36)

A) is highly viscous
B) readily evaporates
C) is highly flammable
D) is highly cohesive
E) is highly hydrogen-bonded
Answer: B
Explanation: A)
B)
C)
D)
E)

13
37) Volatility and vapor pressure are __________. 37)
A) both independent of temperature
B) not related
C) the same thing
D) inversely proportional to one another
E) directly proportional to one another
Answer: E
Explanation: A)
B)
C)
D)
E)

38) On a phase diagram, the critical pressure is __________. 38)

A) the pressure above which a substance is a liquid at all temperatures
B) the pressure at which a liquid changes to a gas
C) the pressure required to melt a solid
D) the pressure required to liquefy a gas at its critical temperature
E) the pressure below which a substance is a solid at all temperatures
Answer: D
Explanation: A)
B)
C)
D)
E)

39) Some things take longer to cook at high altitudes than at low altitudes because __________. 39)
A) water boils at a higher temperature at high altitude than at low altitude
B) water boils at a lower temperature at high altitude than at low altitude
C) there is a higher moisture content in the air at high altitude
D) heat isn't conducted as well in low density air
E) natural gas flames don't burn as hot at high altitudes
Answer: B
Explanation: A)
B)
C)
D)
E)

40) An ionic solid, NaCl (s), dissolves in water because of the __________. 40)
A) relatively low melting point
B) strong coulombic interactions between oppositely charged ions
C) 1:1 ratio of ions in the unit cell
D) simple face-centered cubic unit cell type it forms
E) relatively low lattice energy due to small charges of Na+ and Cl- ions
Answer: E
Explanation: A)
B)
C)
D)
E)

14
41) A solid has a very high melting point, great hardness, and poor electrical conduction. This is a(n) 41)
__________ solid.
A) metallic and covalent network
B) covalent network
C) molecular
D) metallic
E) ionic
Answer: B
Explanation: A)
B)
C)
D)
E)

42) The property responsible for the "beading up" of water is __________. 42)
A) surface tension
B) hydrogen bonding
C) vapor pressure
D) density
E) viscosity
Answer: A
Explanation: A)
B)
C)
D)
E)

43) Which of the following molecules has hydrogen bonding as its only intermolecular force? 43)
A) HF
B) H2 O
C) C5 H11OH
D) C6 H13NH2
E) None, all of the above exhibit dispersion forces.
Answer: E
Explanation: A)
B)
C)
D)
E)

15
44) Crystalline solids differ from amorphous solids in that crystalline solids have __________. 44)
A) atoms, molecules, or ions that are close together
B) much larger atoms, molecules, or ions
C) no orderly structure
D) a long-range repeating pattern of atoms, molecules, or ions
E) appreciable intermolecular attractive forces
Answer: D
Explanation: A)
B)
C)
D)
E)

45) The phase changes B C and D E are not associated with temperature increases because the heat 45)
energy is used up to __________.
A) rearrange atoms within molecules
B) break intramolecular bonds
C) increase distances between molecules
D) increase the density of the sample
E) increase the velocity of molecules
Answer: C
Explanation: A)
B)
C)
D)
E)

16
46) The enthalpy change for converting 10.0 g of ice at -25.0°C to water at 80.0°C is __________ kJ. The 46)
specific heats of ice, water, and steam are 2.09 J/g-K, 4.18 J/g-K, and 1.84 J/g-K, respectively. For
H2 O, Hfus = 6.01 kJ/mol, and Hvap = 40.67 kJ/mol
A) 6.16 B) 9.88 C) 3870 D) 7.21 E) 12.28
Answer: D
Explanation: A)
B)
C)
D)
E)

47) Together, liquids and solids constitute __________ phases of matter. 47)
A) the disordered
B) the fluid
C) all of the
D) the compressible
E) the condensed
Answer: E
Explanation: A)
B)
C)
D)
E)

48) In general, the vapor pressure of a substance increases as __________ increases. 48)
A) hydrogen bonding
B) temperature
C) molecular weight
D) viscosity
E) surface tension
Answer: B
Explanation: A)
B)
C)
D)
E)

49) The ease with which the charge distribution in a molecule can be distorted by an external electrical 49)
field is called the __________.
A) polarizability
B) viscosity
C) hydrogen bonding
D) electronegativity
E) volatility
Answer: A
Explanation: A)
B)
C)
D)
E)

17
50) When the phase diagram for a substance has a solid-liquid phase boundary line that has a negative 50)
slope (leans to the left), the substance __________.
A) can go from solid to liquid, within a small temperature range, via the application of pressure
B) cannot be liquefied above its triple point
C) sublimes rather than melts under ordinary conditions
D) cannot go from solid to liquid by application of pressure at any temperature
E) melts rather than sublimes under ordinary conditions
Answer: A
Explanation: A)
B)
C)
D)
E)

51) NaCl crystallizes in a face-centered cubic cell. What is the total number of ions (Na+ ions and Cl- 51)
ions) that lie within a unit cell of NaCl?
A) 6 B) 2 C) 4 D) 8 E) 5
Answer: D
Explanation: A)
B)
C)
D)
E)

52) Which of the following is not an existing or a potential application of the supercritical carbon 52)
dioxide?
A) isolation of the flavor components of herbs and spices
B) extraction of essential flavor elements from hops for use in brewing
C) extraction of caffeine from coffee beans
D) use as a solvent in dry cleaning
E) use as a coolant in refrigeration
Answer: E
Explanation: A)
B)
C)
D)
E)

53) As a solid element melts, the atoms become __________ and they have __________ attraction for 53)
one another.
A) larger, greater
B) closer together, less
C) closer together, more
D) more separated, less
E) more separated, more
Answer: D
Explanation: A)
B)
C)
D)
E)

18
54) In liquids, the attractive intermolecular forces are __________. 54)
A) strong enough to hold molecules relatively close together
B) not strong enough to keep molecules from moving past each other
C) strong enough to keep the molecules confined to vibrating about their fixed lattice points
D) very weak compared with kinetic energies of the molecules
E) strong enough to hold molecules relatively close together but not strong enough to keep
molecules from moving past each other
Answer: E
Explanation: A)
B)
C)
D)
E)

55) __________ are particularly polarizable. 55)

A) Large polar molecules
B) Large nonpolar molecules
C) Small nonpolar molecules
D) Small polar molecules
E) Large molecules, regardless of their polarity,
Answer: E
Explanation: A)
B)
C)
D)
E)

56) Viscosity is __________. 56)

A) the same as density
B) unaffected by temperature
C) the resistance to flow
D) the "skin" on a liquid surface caused by intermolecular attraction
E) inversely proportional to molar mass
Answer: C
Explanation: A)
B)
C)
D)
E)

19
57) The shape of a liquid's meniscus is determined by __________. 57)
A) the type of material the container is made of
B) the amount of hydrogen bonding in the liquid
C) the relative magnitudes of cohesive forces in the liquid and adhesive forces between the
liquid and its container
D) the volume of the liquid
E) the viscosity of the liquid
Answer: C
Explanation: A)
B)
C)
D)
E)

58) The enthalpy change for converting 1.00 mol of ice at -50.0°C to water at 70.0°C is __________ kJ. 58)
The specific heats of ice, water, and steam are 2.09 J/g-K, 4.18 J/g-K, and 1.84 J/g-K, respectively.
For H2 O, Hfus = 6.01 kJ/mol, and Hvap = 40.67 kJ/mol
A) 12.28 B) 13.16 C) 6.41 D) 9.40 E) 7154
Answer: B
Explanation: A)
B)
C)
D)
E)

59) The critical temperature and pressure of CS2 are 279°C and 78 atm, respectively. At temperatures 59)
above 279°C, CS2 can only occur as a __________.
A) liquid and gas
B) solid
C) liquid
D) gas
E) supercritical fluid
Answer: E
Explanation: A)
B)
C)
D)
E)

60) The vapor pressure of any substance at its normal boiling point is 60)
A) 1 atm
B) 1 torr
C) equal to atmospheric pressure
D) equal to the vapor pressure of water
E) 1 Pa
Answer: A
Explanation: A)
B)
C)
D)
E)

20
61) The slope of a plot of the natural log of the vapor pressure of a substance versus 1/T is __________. 61)
1 -1 Hvap
A) B) Hvap C) D) - Hvap E) -
Hvap Hvap R

Answer: E
Explanation: A)
B)
C)
D)
E)

62) The predominant intermolecular force in (CH3 )2 NH is __________. 62)

A) hydrogen bonding
B) ion-dipole forces
C) ionic bonding
D) London dispersion forces
E) dipole-dipole forces
Answer: A
Explanation: A)
B)
C)
D)
E)

63) Which one of the following derivatives of ethane has the highest boiling point? 63)
A) C2 F6 B) C2 Cl6 C) C2 Br6 D) C2 H6 E) C2 I6
Answer: E
Explanation: A)
B)
C)
D)
E)

64) On a phase diagram, the critical temperature is __________. 64)

A) the temperature below which a gas cannot be liquefied
B) the temperature required to melt a solid
C) the temperature above which a gas cannot be liquefied
D) the temperature at which all three states are in equilibrium
E) the temperature required to cause sublimation of a solid
Answer: C
Explanation: A)
B)
C)
D)
E)

21
65) Which one of the following substances will have hydrogen bonding as one of its intermolecular 65)
forces?

A)

B)

C)

D)

E)

Answer: B
Explanation: A)
B)
C)
D)
E)

66) The scattering of light waves upon passing through a narrow slit is called __________. 66)
A) grating B) diffusion C) incidence D) adhesion E) diffraction
Answer: E
Explanation: A)
B)
C)
D)
E)

22
SHORT ANSWER. Write the word or phrase that best completes each statement or answers the question.

67) In general, intramolecular forces determine the __________ properties of a substance and 67)
intermolecular forces determine its __________ properties.
Answer: chemical, physical
Explanation:

68) The direct conversion of a solid to a gas is called __________. 68)

Answer: sublimation
Explanation:

69) London Dispersion Forces tend to __________ in strength with increasing molecular 69)
weight.
Answer: increase
Explanation:

70) How many atoms are contained in a face-centered cubic unit cell? 70)
Answer: 4
Explanation:

71) Chromium crystallizes in a body-centered cubic unit cell. There are __________ chromium 71)
atoms per unit cell.
Answer: 2
Explanation:

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.

72) Of the following substances, only __________ has London dispersion forces as the only 72)
intermolecular force.

CH3 OH
NH3
H2 S
Kr
HCl
A) Kr B) HCl C) CH3 OH D) H2 S E) NH3
Answer: A
Explanation: A)
B)
C)
D)
E)

23
73) Of the following substances, __________ has the highest boiling point. 73)

H2 O
CO2
CH4
Kr
NH3
A) H2 O B) Kr C) CH4 D) CO2 E) NH3
Answer: A
Explanation: A)
B)
C)
D)
E)

74) The heat of fusion of water is 6.01 kJ/mol. The heat capacity of liquid water is 75.3 J/mol · K. The 74)
conversion of 50.0 g of ice at 0.00°C to liquid water at 22.0°C requires __________ kJ of heat.
A) 17.2
B) 3.8 × 102
C) 0.469
D) 21.3
E) Insufficient data are given.
Answer: D
Explanation: A)
B)
C)
D)
E)

24
75) On the phase diagram below, segment __________ corresponds to the conditions of temperature 75)
and pressure under which the solid and the gas of the substance are in equilibrium.
A) AB B) BC C) AC D) CD E) AD
Answer: C
Explanation: A)
B)
C)
D)
E)

76) On the phase diagram shown, the coordinates of point __________ correspond to the critical 76)
temperature and pressure.
A) A B) B C) C D) D E) E
Answer: B
Explanation: A)
B)
C)
D)
E)

25
77) The phase diagram of a substance is given above. The region that corresponds to the solid phase is 77)
__________.
A) w B) x C) y D) z E) x and y
Answer: A
Explanation: A)
B)
C)
D)
E)

78) The heating curve shown was generated by measuring the heat flow and temperature of a solid as 78)
it was heated. The heat flow into the sample in the segment __________ will yield the value of the
Hvap of this substance.
A) AB B) BC C) CD D) DE E) EF
Answer: D
Explanation: A)
B)
C)
D)
E)

26
79) The substance with the largest heat of vaporization is __________. 79)

I2
Br2
Cl2
F2
O2
A) O2 B) Cl2 C) I2 D) F2 E) Br2
Answer: C
Explanation: A)
B)
C)
D)
E)

80) Of the following, __________ should have the highest critical temperature. 80)

CBr4
CCl4
CF4
CH4
H2
A) CCl4 B) CF4 C) H2 D) CBr4 E) CH4
Answer: D
Explanation: A)
B)
C)
D)
E)

27
81) Based on molecular mass and dipole moment of the five compounds in the table below, which 81)
should have the highest boiling point?

Molecular Dipole
Substance Mass (amu) Moment (D)
Propane, CH3 CH2 CH3 44 0.1
Dimethylether, CH3 OCH3 46 1.3
Methylchloride, CH3 Cl 50 1.9
Acetaldehyde, CH3 CHO 44 2.7
Acetonitrile, CH3 CN 41 3.9

A) CH3 OCH3
B) CH3 CHO
C) CH3 CN
D) CH3 CH2 CH3
E) CH3 Cl
Answer: C
Explanation: A)
B)
C)
D)
E)

82) Of the following, __________ is the most volatile. 82)

CBr4
CCl4
CF4
CH4
C6 H14
A) CCl4 B) CF4 C) CBr4 D) CH4 E) C6 H14
Answer: D
Explanation: A)
B)
C)
D)
E)

28
83) Of the following substances, only __________ has London dispersion forces as its only 83)
intermolecular force.

CH3 OH
NH3
H2 S
CH4
HCl
A) CH3 OH B) CH4 C) NH3 D) HCl E) H2 S
Answer: B
Explanation: A)
B)
C)
D)
E)

84) __________ solids consist of atoms or molecules held together by dipole-dipole forces, London 84)
disperson forces, and/or hydrogen bonds.
A) Metallic and covalent-network
B) Covalent-network
C) Metallic
D) Molecular
E) Ionic
Answer: D
Explanation: A)
B)
C)
D)
E)

85) Which of the following is not a type of solid? 85)

ionic
molecular
supercritical
metallic
covalent-network
A) molecular
B) metallic
C) supercritical
D) covalent-network
E) ionic
Answer: C
Explanation: A)
B)
C)
D)
E)

29
86) Which of the following has dispersion forces as its only intermolecular force? 86)

CH4
HCl
C6 H13NH2
NaCl
CH3 Cl
A) C6 H13NH2
B) CH4
C) CH3 Cl
D) HCl
E) NaCl
Answer: B
Explanation: A)
B)
C)
D)
E)

87) The phase diagram of a substance is shown above. The area labeled __________ indicates the gas 87)
phase for the substance.
A) w B) x C) y D) z E) y and z
Answer: C
Explanation: A)
B)
C)
D)
E)

30
88) Gallium crystallizes in a primitive cubic unit cell. The length of the unit cell edge is 3.70Å. The 88)
radius of a Ga atom is __________ Å.
A) Insufficient data is given.
B) 7.40
C) 0.930
D) 3.70
E) 1.85
Answer: E
Explanation: A)
B)
C)
D)
E)

89) Which one of the following cannot form a solid with a lattice based on the sodium chloride 89)
structure?

NaBr
LiF
RbI
CuO
CuCl2
A) CuO B) CuCl2 C) RbI D) LiF E) NaBr
Answer: B
Explanation: A)
B)
C)
D)
E)

90) According to the phase diagram shown above, the normal boiling point of this substance is 90)
__________ °C.
A) 38 B) 29 C) -3 D) 10 E) 0
Answer: B
Explanation: A)
B)
C)
D)
E)

31
91) The heating curve shown was generated by measuring the heat flow and temperature for a solid as 91)
it was heated. The slope of the __________ segment corresponds to the heat capacity of the solid.
A) AB B) BC C) CD D) DE E) EF
Answer: A
Explanation: A)
B)
C)
D)
E)

92) Potassium metal crystallizes in a body-centered cubic structure with a unit cell edge length of 5.31 92)
Å. The radius of a potassium atom is __________ Å.
A) 5.31 B) 1.33 C) 2.30 D) 2.66 E) 1.88
Answer: C
Explanation: A)
B)
C)
D)
E)

93) Which one of the following should have the lowest boiling point? 93)

PH3
H2 S
HCl
SiH4
H2 O
A) SiH4 B) PH3 C) H2 S D) H2 O E) HCl
Answer: A
Explanation: A)
B)
C)
D)
E)

32
94) Of the following, __________ is an exothermic process. 94)

melting
subliming
freezing
boiling
A) freezing
B) boiling
C) subliming
D) melting
E) All of the above are exothermic.
Answer: A
Explanation: A)
B)
C)
D)
E)

95) The heating curve shown was generated by measuring the heat flow and temperature for a solid as 95)
it was heated. The slope of the __________ segment corresponds to the heat capacity of the liquid of
the substance.
A) AB B) BC C) CD D) DE E) EF
Answer: C
Explanation: A)
B)
C)
D)
E)

33
96) In which of the following molecules is hydrogen bonding likely to be the most significant 96)
component of the total intermolecular forces?

CH4
C5 H11OH
C6 H13NH2
CH3 OH
CO2
A) C5 H11OH
B) CO2
C) CH3 OH
D) CH4
E) C6 H13NH2
Answer: C
Explanation: A)
B)
C)
D)
E)

97) Of the following, __________ has the highest boiling point. 97)

N2
Br2
H2
Cl2
O2
A) Br2 B) O2 C) Cl2 D) N2 E) H2
Answer: A
Explanation: A)
B)
C)
D)
E)

34
 98) The normal boiling point of the substance with the phase diagram shown above is __________ °C. 98)
A) 10 B) 20 C) 30 D) 40 E) 50
Answer: D
Explanation: A)
B)
C)
D)
E)

TRUE/FALSE. Write 'T' if the statement is true and 'F' if the statement is false.

99) The principal source of the difference in the normal boiling points of ICl (97°C; molecular mass 99)
162 amu) and Br2 (59°C; molecular mass 160 amu) is both dipole-dipole interactions and London
dispersion forces.
Answer: True False
Explanation:

100) Under ordinary conditions, a substance will sublime rather than melt if its triple point occurs at a 100)
pressure above atmospheric pressure.
Answer: True False
Explanation:

101) Heats of vaporization are greater than heats of fusion. 101)

Answer: True False
Explanation:

102) The boiling points of normal hydrocarbons are higher than those of branched hydrocarbons of 102)
similar molecular weight because the London-dispersion forces between normal hydrocarbons are
greater than those between branched hydrocarbons.
Answer: True False
Explanation:

103) The type of solid that is characterized by low melting point, softness, and low electrical conduction 103)
is a covalent-network solid.
Answer: True False
Explanation:

35
Answer Key
Testname: C11

1) C
2) E
3) C
4) E
5) D
6) D
7) B
8) E
9) E
10) E
11) E
12) E
13) B
14) C
15) B
16) D
17) C
18) D
19) E
20) C
21) B
22) C
23) E
24) A
25) E
26) D
27) A
28) C
29) C
30) B
31) D
32) B
33) A
34) C
35) A
36) B
37) E
38) D
39) B
40) E
41) B
42) A
43) E
44) D
45) C
46) D
47) E
48) B
49) A
50) A
36
Answer Key
Testname: C11

51) D
52) E
53) D
54) E
55) E
56) C
57) C
58) B
59) E
60) A
61) E
62) A
63) E
64) C
65) B
66) E
67) chemical, physical
68) sublimation
69) increase
70) 4
71) 2
72) A
73) A
74) D
75) C
76) B
77) A
78) D
79) C
80) D
81) C
82) D
83) B
84) D
85) C
86) B
87) C
88) E
89) B
90) B
91) A
92) C
93) A
94) A
95) C
96) C
97) A
98) D
99) FALSE
100) TRUE
37
Test Bank for Chemistry The Central Science, 10th Edition: Brown

Answer Key
Testname: C11

101) TRUE
102) TRUE
103) FALSE

38

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