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IO United States 83529AL 12301 as) 2, Patent Application Publication co pub. No.: US 2023/0183529 Al Rowitsch et al. (43) Pub. Date: Jun. 15, 2023 (1) SPRAYABLE WATER-BASED ADHESIVE Publication Classification (1). Applicants HENKEL AG & CO, KGaA, G1) Ime Duesselort DE) Coes 1108 (2006.01) Coss S00 (2006.01) (72) Toventors: Robert W. Rowitsch, Springville, NY Coss i110 (Gin601) (US) deffrey Cash, Travers Rest, SC 09 14770 (2006001) S); Michael Maue, Butlalo, NY (US Dani JcLevalle isn NY Sn.) 2 US.Ch Deel ee shee CPC. 094 11/08 2013.01). CO9s $00 2013.01, (US); Michael Kasprzak, Lackawanna, Co LE net rede tibe Ney ey iceea pr rateeae Omer 201301), Cost. 3/00 2013.01); YrOT 42825 aay (2015.01); Y107 438/281 (2015.01): Y0T 428/254 (2015.01), YIOT 428/2438 (20150, 21) Appl Nos 181169.484 Y10T 428/24372 (2015 01); Y1OT 428/24405 (2015.01); Yi07 4287249072 (2015.08, (22) Filed: Feb. 18,2023 YIO1 442/699 2015.08) Related US. Application Dats 6 ABSTRACT (63) Continuation of application No. 16/387,248, fled on Water-based adhesive compositions are improved by the ‘apr 17,2019, wow Pat No. 11608456, which iva iMcorporatio of hollow polymeric microspheres having continuation of application No. 14/138,366, filed on ober surfaces enated with one or more barrier materials Dev. 23, 2013 now. abandoned, ‘which isa Sich as calcium carbonate particles, The adhesive composi continuation of application No. 1/650,497, filed on tons exhibit enfanced theology, sprayabiity. drying tine Mar. 23,2007, now abandoned tack and storage stability as compared to analogous adke sives that are not modied with coated hollow polymeric (60) Provisional application No, 60/785,589 filed on Mar. microspheres, Such compositions are use as both contact 24, 2006, adhesives as well as Wet bonding one-way adhesives. US 2023/0183529 Al SPRAYABLE WATER-BASED ADHESIVE (CROSS-REFERENCE TO RELATED "APPLICATIONS 10001] This application isa continuation of United States Application No, 16/387,248 which isa divisional of Uaited States Application No” 14/138,366, filed Dee. 23, 2013, Which isa continuation of United States Application No 11/690,497, filed Mar. 23, 2007, now abandoned, which

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