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@JEEAdvanced_2024

(Academic Session: 2022 - 2023)


ONLINE TEST SERIES CONTACT PROGRAMME

JEE (MAIN + ADVANCE)

MAJOR TEST
DATE : 04-04-2023
(PAPER : 2)

PATTERN : ADVANCED COURSE : NURTURE

READ THE INSTRUCTIONS CAREFULLY


Important Instructions:
1. This paper contains a total number of 54 questions.
2. The Questions appearing in the paper are based on Physics, Chemistry and Mathematics.
4. Duration of the test is 3 hours.

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Online Test Series/Nurture Course/04-04-2023/Paper-2

PART -1 : PHYSICS
SECTION–I : (Maximum Marks : 12)
• This section contains FOUR Questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
the correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme :
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
Negative Marks : –1 In all other cases.

1. Position & velocity of two particles moving along x-axis is shown in diagram at t = 0. What
is the displacement of centre of mass of the given system of two particles in 5 sec ?

(A) 2m (B) 5m (C) 4m (D) Zero

2. In the figure, the block B of mass m starts from at rest top of a wedge W of mass M. All
surfaces are without friction. W can slide on the ground. B slides down onto the ground,
move along it with a speed v, has an elastic collision with the wall, and climbs back onto W.

(A) B will reach the top of W again

(B) From the beginning, till the collision with the wall, the centre of mas of 'B' plus W' is
stationary.

(C) After the collision, centre of mas of 'B plus W' moves with the horizontal component of
2mv
velocity
m+ M

mv
(D) When B reaches its highest position on W, the speed of W is
m+ M

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1
3. A cart with a mass M = kg is connected by a string to a weight of mass m = 200 g. At the
2
initial moment the cart is moving to the left along a horizontal plane at a speed v0 = 7
ms–1, as shown in figure. The magnitude of the velocity of M at t = 5 sec is:-

(A) 7 ms–1 (B) 14 ms–1 (C) 21 ms–1 (D) 5 ms–1

4. A sample of an ideal gas expanded to twice its original, initial volume of 1 m3 in a process
for which P = KV2 where K is a constant whose value is 5 atm/m6. The work done by the
expanding gas is :

(A) 11.78 J (B) 1178 J (C) 11.78 × 105 J (D) 11.78 × 103 J

SECTION–II : (Maximum Marks : 24)


• This section contains SIX multiple choice questions.
• Each question has four choices (A), (B), (C) and (D) out of which ONE or More Than One are
correct.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 For incorrect answer

5. A long uniform beam of square cross section floats on surface of water with fraction f out
of water. The stable position of beam for small rotation is :-

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Online Test Series/Nurture Course/04-04-2023/Paper-2

(A) if f << 1 (B) if

1 1
(C) if f = (D) If f << 1 f =
2 2

6. An insulated container is filled with ice at 0°C, and another container is filled with water
that is continuously boiling at 100°C. In series of experiments, the container is connected
by various, thick metal rods that pass through the walls of the container as shown in the
figure.

In experiment I : A copper rod is used and all ice melts in 20 minutes.


In experiment II : A steel rod of identical dimensions is used and all ice melts in 80 minutes.
In experiment III : Both rods are used in series and all ice melts in t1 minutes.
In experiment III : Both rods are used in parallel and all ice melts in t2 minutes.

(A) t1 = 100 (B) t1 = 50 (C) t2 = 16 (D) t2 = 8

7. Two surfaces of same nature and area but of different material are heated to same
temperature. They are allowed to cool down in same surroundings. If dQ/dt represents rate of
loss of heat and dθ/dt represents rate of fall of temperature, then initially for both :-

(A) dQ/dt is same (B) dQ/dt is different (C) dθ/dt is same (D) dθ/dt is different.

8. Three coherent source kept along the same line produce intensity I0 each at point P on this
line. When S1 & S2 are switched on simultaneously, intensity at point P is 2I0. When S2 and
S3 are switched on simultaneously, intensity at point P is 2I0. Then :-

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(A) When S1 and S3 are switched on simultaneously, intensity at point P can be 2I0
(B) When S1 and S3 are switched on simultaneously, intensity at point P can be 0
(C) When all 3 sources are switched on simultaneously, intensity at point P can be I0
(D) When all 3 sources are switched on simultaneously, intensity at point P can be 3I0

9. A solid cylinder of mass M and radius R, rolling without sliding on a rough horizontal plane,
is pulled at its axis with a horizontal velocity of V0. By means of a string of length 2R
attached to its axis, the cylinder is dragging a thin plate of mass m = 2M lying on the plane.
If the system is released then, choose the correct option. (μ = 0.4, V0 = 2 m/sec, R = 0.5m, g
= 10 m/sec2)

(A) Distance covered before stopping is 0.96 m.


(B) Distance covered before stopping is 0.49 m
(C) Time taken to stop is 0.96 see
(D) Average speed during the motion is 1 m/sec

10. There are two circular tracks of same radius as shown are touching at point A. From
positions as shown in the figure two insects 1 and 2 starts moving on the circumference of
their respective circular track with same speed 1 m/s. Then :-

 π 
(A) Their separation increases for time  0, sec  .
 2 

π 
(B) Their separation decreases for time  , π sec  .
2 
(C) Their maximum separation is 2 m.
(D) Their maximum separation is 4 m.

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SECTION–III : (Maximum Marks : 24)
• This section contains EIGHT questions. The answer to each question is a NUMERICAL
VALUE.
• For each question, enter the correct numerical value of the answer in the place designated
to enter the answer. If the numerical value has more than two decimal places,
truncate/round-off the value to Two decimal places; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –
127.30, if answer is 11.36777..... then both 11.36 and 11.37 will be correct)
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered.
Zero Marks : 0 In all other cases.

11. Two persons of equal height are carrying a long uniform wooden beam of length ℓ. They
are at distance ℓ/4 and ℓ/6 from nearest end of the rod. The ratio of normal reaction at
their heads is p : q. Find (p + q).

12. A comet is in elliptical orbit around the sun. In this orbit the comet’s smallest distance from
the sun is 72 × 106m and its largest distance from the sun is 144 × 106m. The ratio of
comet’s maximum speed to the minimum speed in the orbit is :- (Neglect the presence of
all bodies other than the sun and comet).

13. The centre of mass of a solid object which is formed by rotating a parabola x = ky2 about x-
axis having height of object as 6m is given by (αm, βm). Find (α + β)

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14. One mole of an ideal gas undergoes a thermodynamic cyclic process as shown in the figure.
The cyclic process consists of an isochoric, an isothermal and an adiabatic process.
n2α
Adiabatic exponent of gas is . Here α is an integer. Find α.
nα

15. An impulse of I = 30N-sec is given at t = 0 to 3 kg block attached with 2 block with the help
of spring in natural length. Initially the system is at rest and all surfaces are smooth. Find
velocity of centre of mass at t = 5 sec ?

16. In the given figure : k1 = k2; mA = mB = mC = mD = m. Consider all pulley, strings and springs
to be ideal. The arrangement is in equilibrium in a vertical plane. At any instant the string

d 2 x2
between C and D is cut. The value of is found to be x times 10 (m/s2). The value of
dt 2

x is _____. (x2 = length of spring of constant k2)

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17. A rod of mass M and length L is placed on a rough surface as shown in figure. Friction co-
efficient on right side of point P is 2µ and on left side is µ. Linear mass density of rod is λ0x
where λ0 is constant and x is distance from left end. The rod is moved along the surface
completely to the other side where friction co-efficient is 2µ. Work done during this
nMgLµ
process is . Find n.
3

18. A projectile is projected with speed v m/s such that magnitude of displacement of
projectile in 2nd and 7th sec is same and equals to 5 × 217 . Find value of v/10. (Take : g =
10 m/s2)

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PART-2 : CHEMISTRY
SECTION–I : (Maximum Marks : 12)
• This section contains FOUR Questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
the correct Answer.
• For each question, choose the option corresponding to the correct Answer.
• Answer to each question will be evaluated according to the following marking scheme :
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unAnswered)
Negative Marks : –1 In all other cases.
1. At constant pressure what would be the percentage decrease in density of an ideal gas for
a 10% increase in temperature :
(A) 10
100
(B)
11
(C) 11
(D) None of these

2. Select the reaction indicating correct products (ignore balancing) :


(A) Mg + NaOH → Mg(OH)2 + Na2O
(B) Na2CO3 + HCl → NaCl + CO2 + H2O

(C) Li2CO3 → Li2O + CO2 + O2

(D) NaHCO3(s) → Na2O + CO2 + O2 + H2O

3. Pick the incorrect statement for s - block metals :


(A) All form basic oxides.
(B) Except Be and Mg all the metals respond to flame test.
(C) Except Be and Mg all the metals dissolve in liquid ammonia.
(D) Fr and Ra are radioactive element

4. Which of the following compound can not show tautomerism :

(A) (B)

(C) (D)

SECTION–II : (Maximum Marks : 24)


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Online Test Series/Nurture Course/04-04-2023/Paper-2
• This section contains SIX multiple choice questions.
• Each question has four choices (A), (B), (C) and (D) out of which ONE or More Than One are
correct.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 For incorrect Answer

5. Gas A & B are founed in atmosphere in quantities of 200 and 500 per trilion (1012) by
volume.
(R = .08 atm lit/mole.K)
(A) In mid -lattitude troposhere (27°C and 1atm) molarity of A is 8.33 × 10–12
(B) In antarctic stratosphere (27°C & 0.5 atm) molarity of B will 1.04 × 10–11
(C) In antarctic stratosphere (27°C & 0.5 atm) molarity of A will 7.05 × 10–11
(D) In mid -lattitude troposhere (27°C and 1atm) molarity of B is 4.39 × 10–12

6. Which is/are correct relationship for vander waal's gas


8a
(A) Boyle's temperature =
27Rb
a
(B) Critical pressure =
27b2
a
(C) Pressure for 1 mol gas at Boyle's temperature =
bVm
(D) Critical volume = 3b

7. In which of the following reaction t-butylbenzene is formed :


AlCl3
(A) Benzene + iso-butyl chloride  →
BF3 .THF
(B) Benzene + (CH3)2C = CH2  →
(C) Benzene + t-butyl alcohol 
H2SO4

AlCl3
(D) Benzene + (CH3)2 C= CH2  →

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8. Which of the following elimination reactions will occur to give but-1-ene as the major
product ?
(A) CH3.CHCl.CH2.CH3 + KOH  
EtOH

EtOH
(B) CH3.CH.CH2.CH3 + NaOEt
| ∆
NMe3
+

(C) CH3.CH2.CHCl.CH3 + Me3COK+ →
(D) CH3.CH2.CH(OH).CH3 + conc. H2SO4 

9. Which of the following compound is/are produced during heating borax (Na2B4O7·
10H2O)
(A) Na2B4O7(Anhydrous)
(B) NaBO3
(C) NaBO2
(D) B2O3

10. Which of the following specie(s) has same value of "maximum atoms in one plane" as that
of SF6.
(A) XeO2F4
(B) PCl3F2
(C) XeO6−4
(D) IF7
SECTION–III : (Maximum Marks : 24)
• This section contains EIGHT questions. The Answer to each question is a NUMERICAL
VALUE.
• For each question, enter the correct numerical value of the Answer in the place designated
to enter the Answer. If the numerical value has more than two decimal places,
truncate/round-off the value to Two decimal places; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –
127.30, if Answer is 11.36777..... then both 11.36 and 11.37 will be correct)
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered.
Zero Marks : 0 In all other cases.

11. If a solution is 0.1M with respect to H2S and 0.5M with respect to HCl then the
concentration of [S2–] in the solution is x × 10–22 M. Find the value of x.
K a1 = 10−7 
Given :  H2S
K a2 = 10−14 

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12. Given that
1
P4(s) + 3Cl2(g) → 2PCl3(ℓ) ΔH = –600 kJ
2
PCl3(ℓ) + Cl2(g) → PCl5(s) ΔH = –200 kJ
Heat of formation of PCl5(s) is (–x × 102 kJ), value of x is :

13. Calculate the magnitude of work done by 2mole ideal gas in kJ, when expansion is taking
place from 2 litre to 22 litre against constant external pressure of 1 atm.
[Given :1 litre-atm = 100 J]

14. For how many carbonyl (aldehyde / ketones) compound hydration equilibrium constant
(Keq) > 1
(a) HCH = O (b) CH3CH = O (c) Me3C – CH = O
(d) Cl3C – CH = O
(e) F3C – CH = O
(f) Ph – C – C – C - Ph
|| || ||
O O O

15. Number of compounds in which white ppt is obtained on reaction with ammonical AgNO3

(a) (b) CH2 = C − C ≡ CH


|
Cl
(c) CH2=CH–Cl (d) CH3–C≡C–CH2–Cl

16. How many H-atom can be replaced by D. When the following molecule kept in excess
Θ
of OD / D2O solution

17. Find the number of s-block elements which can produce ammoniated cation and
ammoniated electron with liquid ammonia.
Li, Na, K, Rb, Cs, Ca, Sr, Ba

18. The species / compounds containing uninegative ion of its anionic part is :
KO3, CaOCl2, Na2O2, KO2, O3

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PART -1 : MATHEMATICS
SECTION–I : (Maximum Marks : 12)
• This section contains FOUR Questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is
the correct Answer.
• For each question, choose the option corresponding to the correct Answer.
• Answer to each question will be evaluated according to the following marking scheme :
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unAnswered)
Negative Marks : –1 In all other cases.

1. If x > 1, y > 1, z > 1 and x2 = yz, then the value of logzx(xy4z)⋅logxy(xyz4), is


(A) 9
(B) 10
(C) 11
(D) 12

1 − cos(sin3x)
2. lim is equal to -
x →0 n(1 + 4x)(e2x − 1)

9
(A)
8
4
(B)
9
8
(C)
9
9
(D)
16

3. ABCD is a convex quadrilateral and 3, 4, 5 and 6 points are marked [excluding the vertices]
on the sides AB, BC, CD and DA, respectively. The number of triangles with vertices on
different sides is:
(A) 270
(B) 220
(C) 282
(D) 342

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4. The number of integers in the range of m for which point (m,1) lies in the smaller region
enclosed by x2 + y2 – 3x + 1 = 0 and 2x – y = 2 is -
(A) 0
(B) 1
(C) 2
(D) 3

SECTION–II : (Maximum Marks : 24)


• This section contains SIX multiple choice questions.
• Each question has four choices (A), (B), (C) and (D) out of which ONE or More Than One are
correct.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks : +2 If three or more options are correct but ONLY two options are
chosen, both of which are correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen
and it is a correct option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks : –2 For incorrect Answer

(7 + 4 3 ) , where n is a natural number, then -


n
5. Let =
x

(A) [x] is an even integer (where [.] denotes greatest integer function)
(B) [x] is an odd integer (where [.] denotes greatest integer function)
(C) (1 – {x})(x) = 1 (where {.} denotes fractional part function)
(D) x{x} = 1 (where {.} denotes fractional part function)

6. If the circle x2 + y2 + 2gx + 2fy + c = 0 bisects the circumference of the circles x2 + y2 = 6,


x2+y2–6x –4y + 10 = 0 and x2 + y2 + 2x – 2y – 2 = 0, then
(A) c = –6
(B) g +f – c = 4
(C) gf = 1
(D) g2 +f2 – c = 8

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7. If nth term of an arithmetic progression is Tn = (k – 3)n2 + (k + 1)n – 3, then -
(A) k = 3
(B) common difference = 8
(C) common difference = 4

(D) first term = 1

8. Which of the following can be the possible value(s) of expression 1 + 4sin2xcos2x

(A) 1
3
(B)
2

3
(C)
4

5
(D)
2

9. If a, b , c, d and p are distinct real numbers such that

(a 2
) ( )
+ b2 + c2 p2 − 2 ( ab + bc + cd ) p + b2 + c2 + d2 „ 0 , then

(A) b2 = ac

(B) c2 = bd

(C) ap = b

(D) bp = c

10. Three lines px + qy + r = 0, qx + ry + p = 0 and rx + py + q = 0 are concurrent if


(A) p + q + r = 0

(B) p2 + q2 + r2 = pr + rp + pq

(C) p + q + r =
3 3 3
3pqr
(D) None of these

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SECTION–III : (Maximum Marks : 24)
• This section contains EIGHT questions. The Answer to each question is a NUMERICAL
VALUE.
• For each question, enter the correct numerical value of the Answer in the place designated
to enter the Answer. If the numerical value has more than two decimal places,
truncate/round-off the value to Two decimal places; e.g. 6.25, 7.00, –0.33, –.30, 30.27, –
127.30, if Answer is 11.36777..... then both 11.36 and 11.37 will be correct)
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered.
Zero Marks :0 In all other cases.

11. The line through the points (h, 3) and (4, 1) intersects the line 7x – 9y – 19 = 0 at right
9h
angle, then the value of is
22

3a + 6b
12. If 3a2 – 4a – 4 = 0 and 3b2 – 4b – 4 = 0, where a, b ∈ R and a < b then value of can
2
be

13. The number of solution of equation


3
sin x − 1 + 3 sin x + 3 sin x + 1 =
0 , lying in [0, 2π], is

14. Let a, b, c, d be four distinct real numbers which are in AP and 2(a – b) + x(b – c)2
+ (c – a)3 = 2(a – d) + (b – d)2 + (c – d)3. If range of x ∈( −∞ , p] ∪ [q, ∞ ) , then the value of
p + q is

15. There are 11 players including DHONI and VIRAT in a cricket team. In how many ways all
11 players are arranged in a row to bat so that exactly 3 players bat between DHONI and
N
VIRAT, if any player can bat at any place, are N, then value of is
29

16. Let from a point P(–3, –4) pair of tangents are drawn to parabola y2 = 4(x – 1). The sum of
slopes of these tangents is

17. The normal chord at a point 't' on the parabola y2 = 4x subtends a right angle at the
vertex, then t2 is equal to

1
18. If a,b,c are positive numbers such that abc = , then minimum value of a2 + 9b2 + 6ab + 2c2
3
is

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PART-1 : PHYSICS
ANSWER KEY
Que. 1 2 3 4
Section-I
Ans. B C A C

Que. 5 6 7 8 9 10
Section-II
Ans. ABC AC AD BC ACD D

Que. 11 12 13 14 15 16 17 18
Section-III
Ans. 7 2 4 3 6 2 5 8

SOLUTIONS

1. Ans. (B)

2 × 2 + 1( −1) 4 − 1
Vcm
= = = 1m/ s
2+1 3

S = Vt

S=1×5

S = 5m

2. Ans. (C)

Before collision

m
vB = v & vW =   v
M

Impulse by wall = 2 mv

 2mv 
velocity of com =  
 M +m

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5. Ans. (A,B,C)

a a2 a a 2a
× θ × < 1× × θ ×
4 2 2 2 2

a2 a 1
× × θ
2 2 3
a a a a
2× × θ× ×
2 2 2 3
a3 2a3
θ < θ
6 2 3 2

a
−2 fa ×
xc = 2= − fa
a
Not in equilibrium.

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6. Ans. (A,C)

When the rods are connected alone use

dq ∆T
=
dt 
KA

For series combination use :


dq ∆T
=
dt 1 
+ 2
K 1 A1 K 2 A2
For parallel use :

dq K A K A 
∆T  1 1 + 2 2 
=
dt  1 2 

7. Ans. (A,D)

dQ
=eAσ(T 4 − T04 ) =same
dt

dθ eAσ 4
= (T − T=
0 ) different
4

dt ms

8. Ans. (B,C)

For S1 & S2
I = I0 + I0 + 2I0cosθ1
For S2 & S3,
I = I0 + I0 + 2I0cosθ2
Thus,

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9. Ans. (A,C,D)
1 a
F2 – F1 = (m + M)a, F1R = MR 2
2 R
1
F1 = Ma
2
F2 = μ(mg – T sin α) ; T cos α – F1 = Ma
Solving these equation

=a = 2.08m / sec2
3(1 + µ tan α ) + 4
V02 4
S
= = = 0.96m
2a 2 × 2.08
u
t= = 0.96
a

10. Ans. (D)

Separation increases (0, π] and maximum separation when particles are at A, B point
respectively.

11. Ans. (7)


 2
N1 × = N2 ×
4 6

N1 4
=
N2 3

12. Ans. (2)


By conservation of angular momentum
mv1r1 = mv2r2
v1 r2 144 × 106
= = = 2
v2 r1 72 × 106

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13. Ans. (4)

∫=
x·dm ∫ x πy dxρ
2

xcm
=
∫ dm ∫ πy dxρ
2

6
x
∫ x·πρ · k dx 2 63
= 0
6
= × 2 =4m
x 3 6
∫ πρ k dx
0

14. Ans. (3)


CA is adiabatic, BC is isothermal as per slope.
P0V0 V0
Hence= V1 =
3P0 3
n6
Using PVγ = const ⇒ γ =
n3

15. Ans. (6)


I = ΔP
30 = 3(vf – 0) ⇒ vf = 10 m/s
3 × 10 + 2 × 0
⇒ vcm = 6m / s
=
5
Velocity of centre of mass remains constant because there is no external force on the
system.

16. Ans. (2)


Initially :
K2x02 = mg
K1x01 = 3 mg

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Just after the string is cut.

aC= g ↑
This tension will not change spontaneously due to spring K2

aA + B = 0
Tension between A and B will not change.
TAB = 2mg

18. Ans. (8)

0 = vy – 10 × 4 ⇒ vy = 40 m/s

snth = u + ( v x2 + 625)
1/2
5( 217 )
1/2
=

sy = 40 – 5(C) = 25
sx = vx × 1 = vx
v 2x =25 × 217 − 625

v 2x =25 × 217 − 625 = 25 (217 – 25) = 25 × 192

v x = 40 3

Speed = v x2 + v 2y =
80m / s

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PART-2 : CHEMISTRY
ANS.WER KEY
Que. 1 2 3 4
Section-I
Ans.. B B A C
Que. 5 6 7 8 9 10
Section-II
Ans.. AB BCD ABCD BC ACD AC
Que. 11 12 13 14 15 16 17 18
Section-III
Ans.. 4 5 2 4 3 7 8 3
SOLUTIONS
SECTION–I
1. Ans. (B)

Intial − finaldensity
% decrease in density × 100
Initialdensity
PM PM

RT R(1.1T)
= × 100
PM
RT

2. Ans. (B)

Stronger acids replace CO2 from metal carbonates.

3. Ans. (A)
• BeO is amphoteric
• In group II, only Ca, Sr, Ba form blue solution in liquid NH3.

4. Ans. (C)
Theoretical

SECTION–II
5. Ans. (AB)

6. Ans. (BCD)

7. Ans. (ABCD)

8. Ans. (BC)

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9. Ans. (ACD)

10. Ans. (AC)


SECTION–III
11. Ans. (4)

[H+ ]2[S2− ]
Ka1 Ka2 =
[H2S]
(0.5)2 2−
10–21 = [S ]
0.1
1
× 10–20 = [S2–]
25
[S2–] = 4 × 10–22 M

12. Ans. (5)


1 5
P4 (s) + Cl2(g) → PCl5(s) ....(1)
4 2
1
P4 (s) + 3Cl2 → 2PCl3(ℓ) ....(2)
2
PCl3(ℓ) + Cl2(g) PCl5(s) ....(3)
1
On applying thermodynamic operation (1) = (3) + (2)
2
1
= –200 + (– 600)
2
= – 500 kJ = – 5 × 102 kJ

13. Ans. (2)

w = –pext.ΔV = –1atm × (22 – 2) litre = –20


lit-atm = –2000 J = –2 kJ.

14. Ans. (4)

15. Ans. (3)

16. Ans. (7)

17. Ans. (8)

18. Ans. (3)

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PART-3 : MATHEMATICS
ANS.WER KEY
Que. 1 2 3 4
Section-I
Ans.. A D D A
Que. 5 6 7 8 9 10
Section-II
Ans.. B,C A,B,C,D A,C,D A,B A,B,C,D A,B,C
Que. 11 12 13 14 15 16 17 18
Section-III
Ans.. 1 5 3 8 7 1 2 6
SOLUTIONS
1. Ans. (A)
x z
= = t x = yt
y x
z = xt ⇒ z = yt2

( ) ( )
log y2t3 yt·y 4 ·yt 2 ·log y2t yt·y·y 4 t 8

log ( y t )·log ( y t )
y 2t3
6 3
y 2t
6 9

9 × log y t × log ( y t ) =
y 2t 3
2
9 y 2t
2 3

2. Ans. (D)
9 1 − cos(sin3x) sin2 3x 4x 2x
lim × × × 2x
8 x →0 2
sin 3x 9x 2
n(1 + 4x) e − 1
9 1 9
= × =
8 2 16

3. Ans. (D)

The number of triangles with vertices on sides AB, BC, CD is 3C1 × 4C1 × 5C1.
Similarly, for other cases, the total number of triangles is :
3C1 × 4C1 × 5C1 + 3C1 × 4C1 × 6C1 + 3C1 × 5C1 × 6C1 + 4C1 × 5C1× 6C1 = 342.

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4. Ans. (A)
S1 < 0 ⇒ m2 – 3m + 2 < 0 ⇒ m ∈ (1,2)
3 3
(2m − 1 − 2)  2 × 
− 0 − 2 < 0 ⇒ m <
 2  2

 3
hence, m ∈  1, 
 2

5. Ans. (B,C)

( )
n
x= 7+4 3 = I + ƒ where 0 < ƒ < 1

( )
n
Let F =      
7−4 3    0 < F < 1

I + F + ƒ = even integer
0< F + f < 2⇒ F + f =
1
⇒ I → odd integer
ƒ = {x} = 1 – F
So (1 – {x}) (x) = 1

6. Ans. (A,B,C,D)
If the circle x2 + y2 + 2gx + 2fy + c = 0 bisects the circumference of a given circle, then the
common chord will pass through the centre of given circle.
⇒ 2gx + 2fy + c + 6 = 0 passes through (0,0)
⇒ c = –6
Also 2gx + 2fy + c + 6x + 4y – 10 = 0 passes through (3,2)
⇒ 6g + 4f + 10 = 0 ...(i)
and 2gx + 2fy + c – 2x + 2y + 2 = 0 passes through (–1,1)
⇒ –2g + 2f = 0 ...(ii)
From (i) & (ii), g = f = –1

7. Ans. (A,C,D)
Tn = (k – 3)n2 + (k + 1)n – 3
as Tn must be linear in n ⇒ k = 3
⇒ Tn = 4n – 3

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8. Ans. (A,B)
ƒ(x) = 1 + (sin2x)2
0 ⩽ (sin 2x)2 ⩽ 1
1 ⩽ 1 + (sin2x)2 ⩽ 2
3
possible values are 1 and
2

9. Ans. (A,B,C,D)

(a 2
) ( )
+ b2 + c2 p2 − 2 ( ab + bc + cd ) p + b2 + c2 + d2 „ 0

⇒ (ap – b)2 + (bp – c)2 + (cp – d)2 = 0


b c d
⇒ p= = =
a b c
⇒ a, b, c, d are in G.P.
Ans.wer A,B,C,D.

10. Ans. (A,B,C)


For concurrency, of three lines px + qy + r = 0,
qx + ry + p = 0, rx + py + q = 0, we must have,
⇒ 3pqr − p3 − q3 − r3 =
0

(
⇒ ( p + q + r ) p2 + q2 + r2 − pq − pr − rq =
0 )

11. Ans. (1)


Slope of line through (h,3) and (4,1)
3−1 2
is =
h−4 h−4
7
slope of 7x – 9y – 19 = 0 is
9
2 7
× =−1
h−4 9
14 = 36 – 9h
9h
9h = 22 ∴ =1
22

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12. Ans. (5)
a,b are roots of 3x2 – 4x – 4 = 0
2
x= 2, −
3
2
a=
− , b=
2
3

13. Ans. (3)


Given α + β + γ = 0
⇒ α3 + β3 + γ3 = 3αβγ

=
⇒ 3sin x 3 3 (sin2 x − 1)sin x

⇒ sinx = 0 or sin2x = sin2x – 1


⇒ sinx = 0

14. Ans. (8)


Let k be common difference of AP.
⇒ given equation is
–2k + x.k2 + (2k)3 = 2(–3k) + (–2k)2 + (–k)3
⇒ 9k2 + k(x – 4) + 4 = 0
D>0
(x – 4)2 > 144
x ∈ ( −∞ , −8] ∪ [16, ∞ )

p = –8, q = 16
p+q=8

15. Ans. (7)

9
N= ( C ) ( 7 )( 3 )( 2) =
9
3
6 3
( ) ( )( 2 )
× 7 × 3

N
=7
29

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16. Ans. (1)
a 1
⇒ y = m(x – 1) + ⇒ –4 = –4m +
m m
1
4m2 – 4m – 1 = 0; m1 + m2 = 1, m1m2 = −
4
|m1 + m2| = 1

17. Ans. (2)


2
Use tt1 = – 4 and t1 = – t – 𝑡𝑡
⇒ tt1 = –t2 – 2 ⇒ –4 = –t2 – 2
⇒ t2 = 2

18. Ans. (6)


1
a2 + 9b2 + 3ab + 3ab + c2 + c2
6
(
≥ 34 a 4 b4c4 ) 6

⇒ a2 + 9b2 + 6ab + 2c2 ≥ 1 × 6


∴ min value = 6

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