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Atomic Structure Re
Atomic Structure Re
Nucleus -A small, dense, positively charged centre of the atom is called nucleus. This nucleus contains protons and
neutrons.
Protons - Protons are positively charged particles reside in the nucleus of the atom.
Electrons - Electrons are negatively charged particles. They move outside and around the nucleus in circular or near
circular orbits.
Isotopes
Atoms of the same element that have the same number of protons but different numbers of neutrons are
called isotopes. (In other words)
Isotopes are the atoms of the same element with different masses.
35 37
- The atomic number of Cl is 17. The two isotopes chlorine are represented as 17Cl and 17Cl.
35 37
- In 17Cl , one atom of chlorine contains 17 protons and 35 – 17 = 18 neutrons whereas one atom of 17Cl contains 17
electrons, 17 protons and 20 neutrons.
- Note that both isotopes of chlorine contain the same number of protons (17) and electrons (also 17).
3
𝐀𝐀
𝐗𝐗
𝐙𝐙
Electronic Structure
The distribution of electrons in an atom of an element is known as the electronic structure of that element.
Sub-shells
- Each shell is again divided into a number of sub-shells, which are known as s, p, d and f.
- The letters used for sub-shells notations are the initial letters of the names given to certain spectral lines,
s stands for sharp
p for principal
d for diffuse
f for fundamental
- maximum number of electrons in s sub-shell - 2 electrons
p sub-shell - 6 electrons
d sub-shell - 10 electrons
f sub-shell - 14 electrons
- Thus, in a shell which have 8 electrons, 2 would be in sub-shell s and 6 in the sub-shell p.
- The shell which has 32 electrons will have 2 in s sub-shell (written as s2), 6 in the p sub-shell (written as p6), 10 in
the d sub-shell (written as d10) and 14 in the f sub-shell (written as f14)
- The energy increase from s to f.
- 4s has lower energy than 3d.
-
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1s 2s 2p 3s 3p 4s 3d 4p
K L M N
increasing in energy level
H 1
He 2
Li 3
Be 4
B 5
C 6
N 7
O 8
F 9
Ne 10
Na 11
Mg 12
7
Al 13
Si 14
P 15
S 16
Cl 17
Ar 18
K 19
Ca 20
Valence electrons
The number of valence electrons of an atom of a given element is equal to the group number of that element
in the periodic table (number of outermost electrons).
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Noble gases or inert gases (Helium, Neon, Argon, Krypton, Xenon) He, Ne, Ar, Kr, Xe
The elements in the Group 0 of the periodic table are known as the noble gases or inert gases.
Non-Metals
The elements to the right of the dark line are non-metals. The elements above the dark line (broken line) in p
block are non-metals.
Metalloids
For along each side of the dark line are elements that have properties of both metals and non-metals. These
elements except Aluminium (Al) are called metalloids.
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1 1
0 valence
IA VII B
0 Group
1 1 2
H H He
1 1 2
1
2 3 4 5 1
1st period
1s 1s 1s2
6
II A III B IV B VB
VI B 2nd period
3 4 5 6 7 8 9 10
Li Be B C N O F Ne
2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8
2 1 2 2 2 2 2 2 2 2 3 2 2 4 2 2 5
1s 2s 1s 2s 1s 2s 1s 2s 1s 2s 2p 1s 2s 2p 1s 2s 2p 1s2 2s2
3rd period
2p1 2p2 2p6
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
2.8.1 2.8.2 2.8.3 2.8.4 2.8.5 2.8.6 2.8.7 2.8.8
2 2 2 2 2 2 2 2 2 2 6 2 2 6 2 2 6
1s 2s 1s 2s 1s 2s 1s 2s 1s 2s 2p 1s 2s 2p 1s 2s 2p 1s2 2s2
2p6 3s1 2p6 3s2 2p6 3s2 2p6 3s2 3s2 3p3 3s2 3p4 3s2 3p5 2p6 3s2 4th period
19 20
K Ca
2.8.8.1 2.8.8.2 Metalloid (B, Si ) halogens
2 2 2 2
1s 2s 1s 2s Highest
6 2 6 2
2p 3s 2p 3s EA
6 1 6 2
3p 4s 3p 4s
Noble gas ေရေအးနဲ႔
( Exept ဓာတ္ျပဳ
မူရင္◌း atom > ဖု◌ိ ion alkali
H) Inert gas
အမ ion > မူရင္◌း atom metals
(except H
Highest IE
)
Alkaline
lowest IE earth metals
lowest EA
electronic structure ၏
ေနာက္ဆံုးဂဏန္း (1) = alkali metal IA , IIA = metals
ေနာက္ဆံုးဂဏန္း (2) = alkaline earth metal IIIB (B, Si) = metalloids
ေနာက္ဆံုးဂဏန္း (7) = halogens IV,V,VI,VII,0 = non-metals
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The element in same group have - same number of valence electrons and similar properties.
The element in same period have - same number of electron shells.
P.N
Metalloid
(shell
E.S C.E.S E.E.S အေရ G.N C.V Metal Kind of element
အတြက္
Non-metal
)
IA and
1H =1 1s1 1s1 1 1 Non-metal
VIIB
Inert gas or noble gas
2He =2 1s2 1s2 1 0 0 Non-metal
( ∵ it is in group 0)
3Li = 2.1 Alkali metal
1s2 2s1 2s1 2 IA 1 Metal
( ∵ it is in group IA )
4Be=
5B=
6C=
7N=
8O=
9F=
10Ne=
11Na=
12Mg=
13Al=
11
14Si=
15P=
16S=
17Cl=
18Ar=
19K=
20Ca=
Electronegative Elements
In general, non-metals are electronegative elements which tend to gain electrons and form negative ions.
Electropositivity
The electropositivity of the elements decreases on going from left to right across a period,
(because the greater the number of electrons that has to be lost, the more difficult it becomes for the element to
lose electrons)
Electronegativity
The electronegativity of the elements increases on going from left to right across period.
(because the elements have an increasing tendency to gain electrons.)
- When the electropositive elements combine with the electronegative elements, i.e., when metals combine with non-
metals, ionic compounds are usually formed.
- When electronegative elements, or non-metals, combine with one another, covalent compounds are formed.
Atomic Sizes
- The size of an individual atom is difficult to determine.
- However, one can estimate the approximate radii of atoms by knowing the distances between atoms in molecules.
- Atomic size is generally described by the radius of an atom.
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2. Atomic radii increase from top to bottom in a group in the periodic table.
- Down a group in the periodic table, atomic radii increase because of two reasons.
- First, the number of electrons increases.
- These additional electrons are in the larger electron shells farther and farther from the nucleus.
- Second, there is the repulsion between individual electrons.
- Hence the shell expands, resulting in large atoms.
Although the nuclear charge increases down a group, its effect will be little compared to the effect of the
change in distance between the electrons and the nucleus.
Ion
Ion is an atom (or group of atoms) that is electrically charged as the result of the loss or gain of electrons.
Ionic Sizes
Positive Ion (Cation)
- A positive ion is formed by removing one or more electrons from a metal atom.
- A positive ion is always smaller than its parent atom. Because they both have same nuclear charge but there is a
lesser number of electrons in the positive ion. The repulsion between electrons is reduced in the positive ion.
- The larger the positive charges on the cation, the smaller the size is.
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- Successive removal of other electrons give the second, third and subsequent ionization energies.
- The ionization energies become progressively higher.
- Ionization energies measure how tightly electrons are bound to atoms.
- Low ionization energies indicate ease of removal of electrons, and hence ease of positive ion (cation) formation.
A plot of first ionization energy versus atomic number for several elements
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- Another approach to this trend is to look at the relative sizes of the atoms.
- The size of the atoms decreases from left to right cross a period.
- The nuclear attractive force is greater in the smaller atoms.
- More energy is required to remove an electron from the element across the period.
Group
- Ionization energy decreases from top to bottom in the periodic table.
- The atomic size increases and the outermost electron is farther from the nucleus making it easier to remove it.
- The required energy to remove a second electron from the atom is known as Second ionization energy.
- Second ionization energy is greater than first ionization energy.
- This means that it is more difficult to remove a second electron.
- E.g., First ionization energy of sodium (Na) is 495 kJmol- but second ionization energy of sodium (Na) is
4600 kJmol-.
- Since the elements which have half-filled (ns2 np3) or fully-filled (ns2 np6) sub-shells are more stable, the ionization
energies of these elements are higher than others.
- E.g., Since Be atom has fully-filled sub-shell, Be atom is more stable than B.
Since N atom has half-filled sub-shell, N atom is more stable than O.
- Electron in higher shells are easier to remove.
3 Li 520
11 Na 495
19 K 418
37 Rb 403
55 Cs 374
Electron affinity
The electron affinity of an element is the energy released when an electron is added to a gaseous atom to
form a gaseous ion.
e.g., element(g) + electron ⟶ ion-(g) + energy
-
Cl(g) + e ⟶ Cl (g) + energy
- The halogens have the highest electron affinities because, they form stable anions with noble gas electronic
structures, ns2 np6, by gaining one electron.
- The alkali metals have very low electron affinities since they do not bind their outermost electron very strongly.
- For many reasons, the variations in electron affinities are not regular across a period.
- The electron affinities generally increase from left to right across a period.
- Non-metals generally have higher electron affinities than metals.
- Metals have lower ionization energies.
- Since non-metals gain electrons to become negative ions, the word electronegative is used to describe them.
- Similarly, since metals lose electrons to become positive ions, the word electropositive is used to describe them.
Trends in Periodic Table ( Top to Bottom ) Trends in Periodic Table( Left to Right)
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Atomic size (Radius) increase From top to Atomic size (Radius) decrease From left to
Electropositivity increase bottom Electropositivity decrease right
Electronegativity decrease of the periodic Electronegativity increase of the periodic
Ionization energy decrease table. Ionization energy increase table
Electron affinity decrease Electron affinity increase
CHEMICAL BONDS
Types of Bonds
- There are three main types of chemical bonds, (1) ionic bond (2) covalent bond and (3) metallic bond.
- The coordinate bond which is a special type of covalent bond is another common chemical bond.
- Both Na+ and Cl- ions now possess stable electronic structures of the noble gases.
- The sodium and chloride ions are held together by the strong electrostatic force of attraction which is known as the
ionic bond.
Covalent Bond
Covalent compounds are formed when non-metals react with one another. In covalent bonding actual
molecules are produced, not ions. Each electron of the "shared pair" passes from an orbit controlled by the nucleus of
one atom into an orbit controlled by the nuclei of both atoms.
- In a covalent bond between two atoms, the electrons are not actually gained or lost by the atoms concerned.
- The two electrons forming a covalent bond are shared between the two atoms.
- Simple covalent compounds are gases or volatile liquids (e.g., ammonia, carbon dioxide, ethanol) because their
molecules are electrically neutral and the forces of attraction between them are very small.
- As the molecules come closer together, the atomic nuclei of one molecule and the electrons of another molecule
attract each other while at the same time there is repulsion between their electrons.
- The forces of attraction and repulsion are balanced in the formation of crystal.
- These van der Waals forces are rather weak and the crystals have low melting points. (e.g., naphthalene has
melting point of 81 ℃ compared to that of the ionic crystal such as sodium chloride of melting point, 804℃ )j.
- Covalent compounds are usually soluble in covalent organic solvents, such as benzene or carbon disulphide.
Exception to the Octet Rule BeCl2 , BCl3 , BF3 , PCl5 , PF5 , SCl6 , SF6 , ClF3
Deviation from the Octet Rule
- There are some exceptions to the octet rule.
- Such exceptions are found with elements of the second period of the periodic table, e.g., BeCl2 and BCl3.
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- Also there are exceptions in the third period of the periodic table, e.g., PF5 , ClF3 and SF6.
Metallic Bond
Most of the metals are solids at room temperature and , therefore, there must be some sort of bonding
between these metal atoms. These metal atoms are held together in solid crystalline form by what is known as
metallic bonding.
- A metallic bond is observed in metals.
- In metallic solids, atoms of metals are present.
- They form metallic bonds.
- In a metallic bond, valence electrons of the atoms are very loosely held, forming a common electron cloud.
- Electrons move freely within this electron cloudn.
- These electrons are often described as sea of electrons.
- The positively charged metallic ions resulting by loss of valence electrons, repel each other, but they are
surrounded by free-moving electrons.
- Hence, they are held together by the attractive force of the electron cloud.
- Each metal atom is bonded to all the atoms around it by a surrounding sea of electrons.
- The sea of mobile electrons in a metallic crystal accounts for many of the properties of metals.
- Metals are malleable and ductile.
- The flexibility of metals results from the fact that the metal ion can slide by each other and the electrons are free to
flow.
- The ability of the electrons to flow freely also accounts for the high electric conductiivity of metals.
- Electricity flows easily through metals.
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(3) Volatility
- Ionic compounds are solid and do not vapourize easily.
- Covalent compounds are gases or volatile liquids.
(5) Solubility
- Ionic compounds are soluble in water but insoluble in organic solvents. (such as benzene, toluene, ether, etc)
- Covalent compounds are insoluble in water but soluble in organic solvents. (such as benzene, carbon
disulphide)
(7) Structures
- Ionic compounds have giant structures.
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(8) Forces
- In ionic compounds, the forces between cations and anions are strong electrostatic attraction.
- In covalent compounds, the forces between molecules are weak van der Waals forces.
…အေျခခံအမႈနတ
္ ႕ို ရဲ႕ ဂုဏသ
္ တၱိဆင
ို ္ (2) မွတတ
္ န္ ေမးခြနး္ တိမ
ု ်ား…
1. What is the charge and mass of a neutron?
2. In a neutral atom of an element, the number of a certain particle or particles is equal to the atomic number.
Name the particle or particles.
3. What are the charges and masses of neutron and electron?
4. Give the maximum number of electrons in number 2 shell and number 4 shells.
5. Give the maximum number of electrons in L shell and M shell.
…Isotopes ဆိင
ု ရ
္ ာ ဥာဏ္စမ္းေမးခြနး္ တိမ
ု ်ား…
8. Select the isotopes from the following and give reasons for yoru answer.
35 40 40 37
17Cl , 18Ar , 20Ca , 17Cl
35
17Cl , 235
92U ,
27
12Mg ,
238
92U
40
18Ar , 21
10Ne , 40
20Ca , 20
10Ne
41
19K , 40
18Ar ,
35
17Cl ,
40 37
20Ca , 17Cl
9. An element X has the following particles 9 protons, 10 neutrons, 9 electrons. Write down the atomic number and
mass number of element X. Suggest a possible isotope of element.
10. Determine the number of protons, electrons and neutrons in the atom of the element "E" which has the atomic
number 14 and mass number 28. Give the possible isotopes.
11. Determine the number of protons, electrons and neutrons in the atom of the element "E" which ahs atomic
number 18 and mass number 40. Give the posssible isotopes.
12. Find the number of protons, electrons and neutrons in 36
17Cl and give a possible isotope of it.
13. What are the number of protons, neutrons and electrons in the atom of 37
17Cl ? Write down the possible isotopes.
14. Write down the notation of isotope for an element "X". Express the cooresponding terms.
17. Write down the essential electronic structure, group number, period number and the chidf valence of 16S.
18. Classify the following elements as alkalimetal, alkaline earth metal, halogen and noble gas.
11Na , 17Cl , 18Ne, 12Mg.
20. Write down the essential electronic structure, position in the periodic table and chidf valence of 15P.
21. Which arrangement of elements have similar properties in the periodic table? Why?
22. Explain why the noble gases are neither electropositive nor electronegative.
23. (a) Write down
(i) the compete electronic structure
23
29. Define "Electronegative element". Arrange the following in order of their increasing electronegativity.
Oxygen, carbon, fluorine, nitrogen
30. Arrange the following elements in order of their increaisng electronegativity. Explain your arrangement.
8O , 6C , 9F , 7N
Electron affinity
24
4. Atom "A" has an atomic number 20 and atom "B" has atomic number of 10.
(i) Write down the essential electronic structure.
(ii) Give their positions in the periodic table.
(iii) What is the chief valence of each atom?
(iv) What is the type of each of the atom?
5. (i) Describe the arrangement of the following elements in order of their increasing electronegativity. N, F, O, C.
(ii) Element Y contains 2 electrons in K shell, 8 electrons in L shell and 8 electrons in M shell. Give the name of
that element Y.
(iii) From the following elements.
A(2.1) , B(2.5) , C(2.7) , D(2.8) . Which elements have a valence of 1?
(iv) Write down the electron dot-cross structure of NH4+.
6. (i) In a neutral atom of an element, the number of a certain particle or particles is equal to the atomic number.
Name the particle or particles.
(ii) How do you understand by the term electronegative element?
(iii) Name the type of bond that exists in solid metals.
(iv) How are the elements arranged in the modern periodic table?
8. (i) Determine the number of protons, neutrons and electrons in the atom of 64
30Zn .
(ii) Which has the larger radius, B or N?
(iii) What do we call bonding which involves electron sharing?
(iv) Which particle contains 16 neutrons, 15 protons and 15 electrons.
14. An element "A" contains 2 electrons in K shell, 8 electrons in L shell and one electron in M shell.
(i) Write down the complete electronic structure of element A.
(ii) What is the chief valence of element A?
(iii) Is it metal or non-metal?
(iv) What is the name of element A?
15. You are provided with three element. A = 2.8.8, C = 2.8.8.1 , D = 2.7
(i) Which element has the highest electron affinity?
(ii) Give the group numbers and period numbers of the given elements.
(iii) Which element has the lowest ionization energy?
(iv) Which element is a noble gas?
19. (i) Write down the essential electronic structures of 12Mg and 9F.
(ii) Name the type of bonding exists between above the two elements.
(iii) Write down the electron dot-cross structure of the compound.
(iv) Give the chemical formula of the compound formed.
25. The elements A, B and C are given with the following electron structures.
A(2.3) , B(2.8.2) , C(2.8.7)
(i) What type of bond can be formed between A and C?
28
28. (i) Write down the essential electronic structure of 13Al and 17Cl.
29. (i) A compound is formed between 13X and 17Y . Name the type of bonding which exists between X and Y. Write
down the electron dot-cross formula of the compound.
(ii) What type of bond is formed between the above compound and :NH3? Draw the electron dot-cross structure
of the compound formed.
30. (i) A compound is formed between 5A and 17B. Name the type of bonding that exists between A and B. Write
down the electron dot-cross formula of the compound formed.
(ii) What type of bond is formed between the above compound and :NH3? Draw the electron dot-cross structure.
31. An element X has an atomic number of 5 whereas an element Y has the atomic number of 9.
(i) Write the complete electronic structures of X and Y.
(ii) Give the valences of the elements.
(iii) Classify the type of bond formed between X and Y.
Write the electron dot-cross formula of the compound formed.
(iv) What type of bond is formed between above compound and :NH3?
Write the electron dot-cross formula of the compound formed.
34. An atom X has an atomic number 6 , whereas an atom Y has an atomic number 9.
(i) Write down their complete electronic structures.
(ii) Give their position in the periodic table.
(iii) What type of bond can be formed between X and Y?
(iv) Write down the formula of the compound formed between X and Y.
35. An atom X has an atomic number 6 , whereas an atom Y has an atomic number 9.
(i) Write down their complete electronic structures.
(ii) Give their position in the periodic table.
(iii) What type of bond can be formed between X and Y?
(iv) Write down the electron dot-cross structure of the compound formed between X and Y.
36. An atom X has an atomic number 9 , whereas an atom Y has an atomic number 14.
(i) Write down their complete electronic structures.
(ii) Give their position in the periodic table.
(iii) What type of bond can be formed between X and Y?
(iv) Write down the formula of the compound formed between X and Y.
37. An atom A has an atomic number of 6 whereas atom B has an atomic number of 17.
(i) Write down the electronic structures of A and B.
(ii) Give the group numbers and period number of A and B.
(iii) What type of bond can be formed between A and B?
(iv) Draw the electron dot-cross structure of that compound formed.
38. An element X has an atomic number of 4 whereas an element Y has an atomic number of 17.
(i) Write down the electronic structure of X and Y.
(ii) Give the group number and period number of X and Y.
(iii) What type of bond can be formed between X and Y?
(iv) Suggest the formula of the compound formed.