Assignment 01

[CHC-6911]
DESIGN AND SIMULATION LAB
“PROPERTY ANALYSIS USING ASPEN PLUS”
ASSIGNMENT-01
Date of Assignment: 19-10-2022
Date of Submission: 02-12-2022
Submitted By:
RUSHDA MASHKOOR
22CHPM102
GI0752
S.No. 02
M.Tech(Chemical Engineering)
1st Year, 1st Semester
DEPARTMENT OF CHEMICAL ENGINEERING
Zakir Hussain College of Engineering & Technology
Aligarh Muslim University
Aligarh
ASSIGNMENT NO.1
Title: Property analysis using Aspen Plus

Objective: To perform the following property analyses using Aspen Plus Simulator
a) To estimate the thermodynamic/transport properties of pure component and compare

it with experimental value.
b) To generate the vapor liquid equilibrium data (T-x-y/P-x-y) for binary mixture and
compare them with experimental data
c) To generate the liquid-liquid equilibrium data for ternary mixture at given temperature
and pressure and compare them with experimental data.Procedure:
PROCEDURE
Input:
1. Open the aspen plus GUI.
2. Select appropriate input and output units and run type.
3. Select components for which the property analysis is to be performed.
Fig-1: component selection
4. Select at least three property methods(using ideal model, peng rob model, unifac model
and if 97 model)
Fig-2: base method selection
5. ON the ribbon tabs of Home menu, select Analysis on the Run mode tab.
Fig-3: selection of analysis mode from Run tab
6. Select Pure on the Analysis tab
Fig-4: Selection of pure from analysis tab

7. On the Pure analysis form:
• Select the property type as Thermodynamics, Trasport or all.
Fig-5: selection of property type
• Select the desired property from the list:
Fig-6: selection of type of thermodynamic property
• Select the output unit of the selected property:
Fig-7: selection of type of units of selected thermodynamic property

• Check the boxes for the phase of the component
Fig-8: selection of type of phases

• Select the components from the available components by pointing the componentin
the list and press >. For selecting all components press >>
Fig-9: selection of component for doing analysis(selected component)

• Select the temperature unit
Fig-10: units of temperature and iteration times
Check the radio button list of values if property is to be obtained at different

temperature and enter the temperature at which property is to be obtained else check
the radio button Overall range and choose the lower and upper limits and no of points.
• Select the pressure and its unit
Fig-11: selection of pressure units

• Select the property method one at a time from the available property list and thenclick
on Run analysis for each property method.
Fig-12: final selection of property package
Select the property method one at a time from available property list and then click on
Run Analysis for each property method.
RESULTS:
After the Analysis run successfully, a window will open automatically showing the plot of
the selected property vs temperature. You can customised the plot by selecting the custom on
the Plot tab on the ribbon.
PENG-ROB MODEL
Rho
NRTL MODEL
Rho
IDEAL MODEL
Rho
EXPERIMENTAL DATA
TEMPERATURE (°C) PRESSURE (bar) DENSITY kg/m3
0 1.01325 1276.03
10 1.01325 1270.11
20 1.01325 1264.02
30 1.01325 1258.09
40 1.01325 1252.01
50 1.01325 1244.96
SOURCE: Fluid Flow For The Practicing Chemical Engineer. By J.Patrick Abulencia and Louis Theodone
ASPEN DATA
RESULT FOR NRTL MODEL

RESULT FOR PENG-ROB MODEL
RESULT FOR IDEAL MODEL

ASPEN DATA (IN EXCEL)
PENG-ROB NRTL IDEAL

TEMPERATURE PRESSURE
°C bar LIQUID RHO GLYCE-01 LIQUID RHO GLYCE-01(kg/cum) LIQUID RHO GLYCE-01(kg/cum
kg/cum
0 1.01325 1274.07 1274.07 1274.07
10 1.01325 1267.71 1267.71 1267.71
20 1.01325 1261.3 1261.3 1261.3
30 1.01325 1254.84 1254.84 1254.84
40 1.01325 1248.31 1248.31 1248.31
50 1.01325 1241.73 1241.73 1241.73
CALCULATION:
ERROR CALCULATIONS IN DIFFERENT METHODS
ERROR1- ERROR IN DENSITY FOR MODEL 1

PENG-ROB NRTL IDEAL ERROR1 ERROR2 ERROR3 (ERROR1)^2 (ERROR2)^2 (ERROR3)^2
TEMP PRESSURE LIQUID RHO LIQUID RHO LIQUID RHO
°C bar GLYCE-01 GLYCE-01 GLYCE-01
kg/cum kg/cum kg/cum
0 1.01325 1274.07 1274.07 1274.07 0.001536 0.001536 0.001536 2.35934E-06 2.35934E-06 2.35934E-06
10 1.01325 1267.71 1267.71 1267.71 0.00189 0.00189 0.00189 3.57059E-06 3.57059E-06 3.57059E-06
20 1.01325 1261.3 1261.3 1261.3 0.002152 0.002152 0.002152 4.63052E-06 4.63052E-06 4.63052E-06
30 1.01325 1254.84 1254.84 1254.84 0.002583 0.002583 0.002583 6.67334E-06 6.67334E-06 6.67334E-06
40 1.01325 1248.31 1248.31 1248.31 0.002955 0.002955 0.002955 8.73349E-06 8.73349E-06 8.73349E-06
50 1.01325 1241.73 1241.73 1241.73 0.002594 0.002594 0.002594 6.73123E-06 6.73123E-06 6.73123E-06
3.26985E-05 3.26985E-05 3.26985E-05
RESULT
The sum of errors in case of PENG-ROB Model is 3.26985E-05.
The sum of errors in case of NRTL Model is 3.26985E-05.
The sum of errors in case of IDEAL Model is 3.26985E-05.
The sum of error is same in all the three cases. Hence any of the above mentioned model(PENG-ROB, NRTL, IDEAL) will be suitable method for the analysis.
RHO V/S TEMPERATURE
Experiment PENG-ROB NRTL IDEAL
1280
1275
1270
1265
RHO(KG/CUM)
1260
1255
1250
1245
1240
0 10 20 30 40 50 60
TEMPERATURE (C)
ERROR V/S TEMPERATURE
Error1 Error2 Error3
0.0035
0.003
0.0025
0.002
ERROR
0.0015
0.001
0.0005
0
0 10 20 30 40 50 60
TEMPERATURE
PURE CPMPONENT PROPERTY REPORT
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + +
+ + ASPEN PLUS CALCULATION REPORT + +
+ + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
ASPEN PLUS IS A TRADEMARK OF HOTLINE:

ASPEN TECHNOLOGY, INC. U.S.A. 888/996-7100
781/221-6400 EUROPE (44) 1189-226555
PLATFORM: WINDOWS DECEMBER 1, 2022

VERSION: 36.0 Build 249 THURSDAY
INSTALLATION: 8:39:12 P.M.
ASPEN PLUS PLAT: WINDOWS VER: 36.0 12/01/2022 PAGE I
PROPERTY ANALYSIS FOR PURE COMPONENT
ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.

(ASPENTECH), AND MAY BE USED ONLY UNDER AGREEMENT WITH ASPENTECH.
RESTRICTED RIGHTS LEGEND: USE, REPRODUCTION, OR DISCLOSURE BY THE
U.S. GOVERNMENT IS SUBJECT TO RESTRICTIONS SET FORTH IN
(i) FAR 52.227-14, Alt. III, (ii) FAR 52.227-19, (iii) DFARS
252.227-7013(c)(1)(ii), or (iv) THE ACCOMPANYING LICENSE AGREEMENT,
AS APPLICABLE. FOR PURPOSES OF THE FAR, THIS SOFTWARE SHALL BE DEEMED
TO BE "UNPUBLISHED" AND LICENSED WITH DISCLOSURE PROHIBITIONS.
CONTRACTOR/SUBCONTRACTOR: ASPEN TECHNOLOGY, INC. 20 CROSBY DRIVE,
BEDFORD, MA 01730.
TABLE OF CONTENTS
RUN CONTROL SECTION.................................... 1

RUN CONTROL INFORMATION........................... 1
PHYSICAL PROPERTIES SECTION............................ 2
COMPONENTS........................................ 2
PHYSICAL PROPERTY TABLES SECTION....................... 3

PROPERTIES TABLE: PURE-1........................ 3
PROBLEM STATUS SECTION................................. 5

BLOCK STATUS...................................... 5
ASPEN PLUS PLAT: WINDOWS VER: 36.0 12/01/2022 PAGE 1

RUN CONTROL SECTION
RUN CONTROL INFORMATION

-----------------------
THIS COPY OF ASPEN PLUS LICENSED TO
TYPE OF RUN: NEW
INPUT FILE NAME: _3015yhb.inm
OUTPUT PROBLEM DATA FILE NAME: _3015yhb

LOCATED IN:
PDF SIZE USED FOR INPUT TRANSLATION:

NUMBER OF FILE RECORDS (PSIZE) = 0
NUMBER OF IN-CORE RECORDS = 256
PSIZE NEEDED FOR SIMULATION = 256
CALLING PROGRAM NAME: apmain

LOCATED IN: C:\Program Files (x86)\AspenTech\Aspen Plus V10.0\Engine\\xeq
TGS ONLY RUN

PHYSICAL PROPERTIES SECTION
COMPONENTS
----------
ID TYPE ALIAS NAME

GLYCE-01 C C3H8O3 GLYCEROL
PHYSICAL PROPERTY TABLES SECTION
PROPERTIES TABLE: PURE-1

--------------------------
SINGLE-PHASE PROPERTIES FOR THE MIXTURE: (KMOL/HR )

GLYCE-01 1.000 ,
VARIED VARIABLE(S): TEMP PRES
PROPERTY SET(S): $PS-PURE
PROPERTY OPTION SET: NRTL RENON (NRTL) / IDEAL GAS

PROPERTIES TABLE: PURE-1 (CONTINUED)
----------------------------------------
! TEMP ! PRES ! RHO !
! ! ! LIQUID !
! ! ! GLYCE-01 !
! ! ! !
! C ! BAR ! KG/CUM !
! ! ! !
!============!============!============!
! 0.0 ! 1.0133 ! 1274.0662 !
! 10.0000 ! 1.0133 ! 1267.7128 !
! 20.0000 ! 1.0133 ! 1261.3038 !
! 30.0000 ! 1.0133 ! 1254.8376 !
! 40.0000 ! 1.0133 ! 1248.3124 !
!------------+------------+------------!
! 50.0000 ! 1.0133 ! 1241.7267 !
----------------------------------------
PROBLEM STATUS SECTION
BLOCK STATUS
------------
****************************************************************************
* *
* Calculations were completed normally *
* *
* All Property Tables were completed normally *
* *
****************************************************************************
BINARY REPORT
OBJECTIVE: To generate the vapor-liquid equilibrium data (T-x-y/P-x-y) forbinary

mixture and compare them with experimental data.
PROCEDURE:
EXPERIMENTAL DATA:
Search for the experimental vapor-liquid equilibrium (VLE) data (T-x-y or P-x-y) for
thebinary system for which you intend to run the property analysis. Report it in the tabular
form and its source.
INPUT:
1. Open the aspen plus GUI.
2. Select appropriate input and output units and run type.
FIG 2- COMPONENT SELECTION

4. Click NEXT
FIG 3- CLICKING NEXT BUTTON
5. Select at least three property methods (using PENG-ROB MODEL, UNIFAC

MODEL and IDEAL MODEL)
FIG 4- BASE METHODS SELECTION

6. Select Binary on the Analysis tab
FIG 5- SELECTION OF BINARY FROM ANALYSIS TAB
8. On the Binary analysis form.
(a) Select analysis type, Txy or Pxy.
FIG 6- SELECTING T-x-y ANALYSIS
(b) Select component 1 and component 2 from the list
FIG 7- SELECTING COMPONENTS

(c) Select the basis for composition (mole fraction/mass fraction) and component
(usually more volatile component) whose composition is desired.
FIG 8- SELECTING THE BASIS AND COMPONENT
(d) Select the composition at which the VLE data are required as list of values (liquid
composition at which experimental VLE data are available) or overall range.
FIG 9- SELECTING RANGE OF MOLE FRACTION
(e) Select the pressure unit and its value as list of value or overall range.
FIG 10- ENTERING THE VALUE OF PRESSUTRE WITH ITS

RESPECTIVE UNIT
(f) On the Calculation Options tab, select the desired valid phases from the list as
vaporliquid orvapor-liquid-liquid.
FIG 11- SELECTING DESIRED VALID PHASE
(g) Select the property method from the available list on the same tab one at a time.
FIG 12- SELECTING PROPERTY METHOD

(h) Back on the Binary Analysis from, click on Run Analysis for each property method.
FIG 13- CLICK ON RUN ANALYSIS

RESULTS:
After the Analysis run successfully, a window will open automatically showing the plot of
the desired VLE (T-x-y or P-x-y) data. To plots x-y data or others, select the desired plot
from the Plot tab on ribbon. You can customised the plot by selecting the Custom on the Plot
tab on the ribbon.
UNIFAC
WILSON
NRTL
EXPERIMENT DATA
COMPONENT A- METHANOL
COMPONENT B- WATER
MOLE FRACTION OF A IN
TEMPERATURE(°C) LIQUID VAPOR
SOURCE- C. Geankoplis, “Transport-Processes-and-Unit-Operations-Geankoplis.”, 1993

NRTL MODEL
WILSON MODEL
UNIFAC MODEL
WILSON
MODEL
PRES MOLEFR TOT TOTAL TOTA LIQUID LIQUID VAPOR VAPOR LIQUID LIQUID
kPa AC AL KVL L GAMMA GAMMA MOLEFR MOLEF MOLEFR MOLEF
METHAN TEM METHAN KVL METHAN WATER AC RAC AC RAC
OL P OL WAT OL METHAN WATER METHAN WATER
(°C) ER OL OL
101.3 0 100.011 8.04247 1 2.31097 1 0 1 0 1
101.3 0.02 96.5169 6.77709 0.8821 2.17574 1.0005 0.135542 0.864458 0.02 0.98
101.3 0.04 93.7261 5.86636 0.79723 2.06127 1.00191 0.234654 0.765346 0.04 0.96
5
101.3 0.06 91.4265 5.17877 0.73327 1.96246 1.00416 0.310726 0.689274 0.06 0.94
101.3 0.08 89.4862 4.64093 0.68339 1.87597 1.00716 0.371275 0.628725 0.08 0.92
7
101.3 0.1 87.8181 4.20858 0.64349 1.79943 1.01087 0.420858 0.579142 0.1 0.9
1
101.3 0.15 84.4835 3.42539 0.57199 1.6414 1.02296 0.513809 0.486191 0.15 0.85
101.3 0.2 81.9386 2.89971 0.52507 1.51826 1.03871 0.579941 0.420059 0.2 0.8
4
101.3 0.3 78.1775 2.23935 0.46885 1.34014 1.07987 0.671805 0.328195 0.3 0.7
1
101.3 0.4 75.3845 1.84272 0.43818 1.22039 1.1327 0.737087 0.262913 0.4 0.6
9
101.3 0.5 73.1048 1.57942 0.42057 1.13779 1.19645 0.789712 0.210288 0.5 0.5
7
101.3 0.6 71.1232 1.39295 0.41057 1.08067 1.27091 0.835769 0.164231 0.6 0.4
7
101.3 0.7 69.3268 1.2548 0.40545 1.04204 1.35621 0.878363 0.121637 0.7 0.3
6
101.3 0.8 67.6517 1.14908 0.40369 1.01749 1.45277 0.91926 0.080739 0.8 0.2
8 6
101.3 0.9 66.0601 1.06618 0.40440 1.00413 1.56123 0.95956 0.040440 0.9 0.1
5 4
101.3 0.95 65.2881 1.0313 0.40550 1.00101 1.62017 0.979725 0.020275 0.95 0.05
3 2
101.3 1 64.5285 1 0.40701 1 1.68241 1 0 1 0
7
UNIFAC MODEL
PRE MOLEFR TOT TOTAL TOTA LIQUID LIQUI VAPOR VAPO LIQUID LIQUID
S AC AL KVL L KVL GAMMA D MOLEFRAC R MOLEF MOLEFR
kPa METHAN TEM METHAN WATE METHA GAMM METHANOL MOLE RAC AC
OL P OL R NOL A FRAC METHA WATER
(°C) WATE WATE NOL
R R
101.3 0 100.011 7.74968 1 2.29526 1 0 1 0 1
101.3 0.02 96.5911 6.61914 0.885324 2.17673 1.00053 0.132383 0.867617 0.02 0.98
101.3 0.04 93.8121 5.77143 0.80119 2.07024 1.00207 0.230857 0.769143 0.04 0.96
101.3 0.06 91.5059 5.11506 0.737337 1.97449 1.00455 0.306904 0.693097 0.06 0.94
101.3 0.08 89.5572 4.59338 0.687532 1.88826 1.0079 0.36747 0.63253 0.08 0.92
101.3 0.1 87.8843 4.16972 0.647809 1.81047 1.01207 0.416972 0.583028 0.1 0.9
101.3 0.15 84.5575 3.39538 0.577286 1.64678 1.02569 0.509307 0.490693 0.15 0.85
101.3 0.2 82.0381 2.87308 0.53173 1.51789 1.04336 0.574616 0.425384 0.2 0.8
101.3 0.3 78.3325 2.21783 0.478074 1.33246 1.08887 0.665348 0.334652 0.3 0.7
101.3 0.4 75.5673 1.82651 0.448992 1.2105 1.14571 0.730605 0.269395 0.4 0.6
101.3 0.5 73.2837 1.56821 0.43179 1.12867 1.21216 0.784105 0.215895 0.5 0.5
101.3 0.6 71.2759 1.38594 0.421088 1.07371 1.28718 0.831565 0.168435 0.6 0.4
101.3 0.7 69.441 1.25104 0.41424 1.03761 1.3701 0.875728 0.124272 0.7 0.3
101.3 0.8 67.7239 1.14755 0.409804 1.01533 1.46051 0.918039 0.0819608 0.8 0.2
101.3 0.9 66.0927 1.0659 0.406932 1.00355 1.55814 0.959307 0.0406932 0.9 0.1
101.3 0.95 65.3035 1.03128 0.405915 1.00086 1.60961 0.979704 0.0202958 0.95 0.05
101.3 1 64.5285 1 0.405094 1 1.66284 1 0 1 0
NRTL
MODEL
PRE MOLEFR TOT TOTAL TOTA LIQUID LIQUI VAPOR VAPOR LIQUID LIQUID
S AC AL KVL L GAMMA D MOLEFR MOLEF MOLEFR MOLEF
kPa METHAN TEM METHAN KVL METHA GAM AC RAC AC RAC
OL P OL WAT NOL MA METHA WATER METHA WATER
(°C) ER WATE NOL NOL
R
101.3 0 100 7.99914 1 2.29851 1 0 1 0 1
101.3 0.02 96.53 6.7609 0.88243 2.16979 1.0004 0.13521 0.864782 0.02 0.98
1 7 8
101.3 0.04 93.73 5.86265 0.79739 2.05947 1.0018 0.23450 0.765494 0.04 0.96
3 6
101.3 0.06 91.43 5.18084 0.73313 1.96331 1.0040 0.31085 0.68915 0.06 0.94
8 1 1
101.3 0.08 89.48 4.64551 0.68299 1.87843 1.0069 0.37164 0.628359 0.08 0.92
9 5 1
101.3 0.1 87.8 4.21399 0.64289 1.80281 1.0106 0.42139 0.578601 0.1 0.9
9
101.3 0.15 84.46 3.42998 0.57118 1.64518 1.0226 0.51449 0.485503 0.15 0.85
3 7
101.3 0.2 81.91 2.90244 0.52439 1.52113 1.0384 0.58048 0.419512 0.2 0.8
6 8
101.3 0.3 78.17 2.23919 0.46892 1.34031 1.0802 0.67175 0.328244 0.3 0.7
8 6
101.3 0.4 75.41 1.84129 0.43913 1.21854 1.1341 0.73651 0.263482 0.4 0.6
7 8 8
101.3 0.5 73.14 1.57785 0.42214 1.13504 1.1989 0.78892 0.211074 0.5 0.5
8 7 6
101.3 0.6 71.17 1.3918 0.41229 1.07797 1.2737 0.83508 0.164919 0.6 0.4
7 9 1
101.3 0.7 69.37 1.25427 0.40670 1.04001 1.3580 0.87798 0.122013 0.7 0.3
8 3 8
101.3 0.8 67.68 1.14906 0.40377 1.01637 1.4512 0.91924 0.080754 0.8 0.2
3 3 6 5
101.3 0.9 66.07 1.06639 0.40252 1.0038 1.5530 0.95974 0.040252 0.9 0.1
2 2 8 1
101.3 0.95 65.29 1.03147 0.40233 1.00092 1.6070 0.97988 0.020116 0.95 0.05
3 3 3 7
101.3 1 64.53 1 0.40234 1 1.6630 1 0 1 0
3 9
CALCULATION- FOR TEMPERATURE
MODEL1- WILSON MODEL, MODEL2- NRTL MODEL, MODEL3- UNIFAC MODEL
CALCULATION OF ERROR BY DIFFERENT METHODS
ERROR1- ERROR IN TEMPERATURE FOR MODEL 1
WILSON NRTL UNIFAC

TOTAL TOTAL TOTAL TEMP
TEMP TEMP (°C) EXPERIME ERROR1 ERROR2 ERROR3
(°C) (°C) NT
100.011 100.011 100.011 100 1.21E-08 1.21E-08 1.21E-08
96.5169 96.5278 96.5911 96.4 1.47053E-06 1.75755E-06 3.93E-06
93.7261 93.7335 93.8121 93.5 5.8476E-06 6.23664E-06 1.11E-05
91.4265 91.4255 91.5059 91.2 6.16803E-06 6.11369E-06 1.13E-05
89.4862 89.4764 89.5572 89.3 4.34767E-06 3.90206E-06 8.3E-06
87.8181 87.8007 87.8843 87.7 1.81343E-06 1.31844E-06 4.42E-06
84.4835 84.4557 84.5575 84.4 9.78787E-07 4.35537E-07 3.48E-06
81.9386 81.9118 82.0381 81.7 8.52897E-06 6.7206E-06 1.71E-05
78.1775 78.1718 78.3325 78 5.17854E-06 4.85129E-06 1.82E-05
75.3845 75.405 75.5673 75.3 1.25928E-06 1.94441E-06 1.26E-05
73.1048 73.1433 73.2837 73.1 4.31169E-09 3.50866E-07 6.32E-06
71.1232 71.1678 71.2759 71.2 1.16349E-06 2.04528E-07 1.14E-06
69.3268 69.3669 69.441 69.3 1.49556E-07 9.31935E-07 4.14E-06
67.6517 67.68 67.7239 67.5 5.05084E-06 7.11111E-06 1.1E-05
66.0601 66.0737 66.0927 66 8.29203E-07 1.24694E-06 1.97E-06
65.2881 65.2946 65.3035 65 1.96454E-05 2.05418E-05 2.18E-05
64.5285 64.5285 64.5285 64.5 1.95241E-07 1.95241E-07 1.95E-07
6.26429E-05 6.38748E-05 0.000137
RESULT
▪ The sum of errors in case of WILSON Model is 6.26429E-05. The sum of errors in case of NRTL Model is 6.38748E-05.
▪ The sum of errors in case of UNIFAC Model is 0.000137.
▪ The sum of error in WILSON Model is less. Hence WILSON Model will be suitable method for the analysis.
CALCULATION- FOR VAPOUR MOLE FRACTION OF METHANOL
ERROR BY DIFFERENT METHODS
ERROR1- ERROR IN VAPOUR MOLE FRACTION OF METHANOL FOR WILSON MODEL.
ERROR2- ERROR IN VAPOUR MOLE FRACTION OF METHANOL FOR NRTL MODEL.
ERROR3- ERROR IN VAPOUR MOLE FRACTION OF METHANOL FOR UNIFAC MODEL.
WILSON NRTL UNIFAC

VAPOR VAPOR VAPOR EXPERIME ERROR1 ERROR2 ERROR3
MOLEFRAC MOLEFRAC MOLEFRAC NT
METHANOL METHANOL METHANOL
(YA1) (YA2) (YA3)
0 0 0 0 0 0 0
0.135542 0.135218 0.132383 0.134 0.000132 8.26E-05 0.000146
0.234654 0.234506 0.230857 0.23 0.000409 0.000384 1.39E-05
0.310726 0.310851 0.306904 0.304 0.00049 0.000508 9.13E-05
0.371275 0.371641 0.36747 0.365 0.000296 0.000331 4.58E-05
0.420858 0.421399 0.416972 0.418 4.67E-05 6.61E-05 6.05E-06
0.513809 0.514497 0.509307 0.517 3.81E-05 2.34E-05 0.000221
0.579941 0.580488 0.574616 0.579 2.64E-06 6.6E-06 5.73E-05
0.671805 0.671756 0.665348 0.665 0.000105 0.000103 2.74E-07
0.737087 0.736518 0.730605 0.729 0.000123 0.000106 4.85E-06
0.789712 0.788926 0.784105 0.779 0.000189 0.000162 4.29E-05
0.835769 0.835081 0.831565 0.825 0.00017 0.000149 6.33E-05
0.878363 0.877988 0.875728 0.87 9.24E-05 8.43E-05 4.33E-05
0.91926 0.919246 0.918039 0.915 2.17E-05 2.15E-05 1.1E-05
0.95956 0.959748 0.959307 0.958 2.65E-06 3.33E-06 1.86E-06
0.979725 0.979883 0.979704 0.979 5.48E-07 8.13E-07 5.17E-07
1 1 1 1 0 0 0
0.002119 0.002033 0.000749

RESULT
▪ The sum of errors in case of WILSON Model is 0.002119.
▪ The sum of errors in case of NRTL Model is 0.002033.
▪ The sum of errors in case of UNIFAC Model is 0.000749.
▪ The sum of error in UNIFAC Model is less. Hence UNIFAC Model will be suitable method for the analysis.
BINARY COMPONENT REPORT
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + +
+ + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

781/221-6400 EUROPE (44) 1189-226555


BEDFORD, MA 01730.
TABLE OF CONTENTS


COMPONENTS........................................ 2
FLASH CURVE TABLE: BINRY-1....................... 3

BLOCK STATUS...................................... 6
RUN CONTROL SECTION

-----------------------
TYPE OF RUN: NEW
INPUT FILE NAME: _0134yhb.inm
OUTPUT PROBLEM DATA FILE NAME: _0134yhb

LOCATED IN:


TGS ONLY RUN

COMPONENTS
----------
ID TYPE ALIAS NAME

METHANOL C CH4O METHANOL
WATER C H2O WATER
FLASH CURVE TABLE: BINRY-1

---------------------------
PROPERTIES ALONG A FLASH CURVE FOR THE MIXTURE: (KMOL/HR )

METHANOL 1.000 , WATER 1.000 ,
STATE SPECIFICATIONS:
VAPOR FRACTION: 0.000
VARIED VARIABLE(S): PRES MOLEFRAC
PROPERTY SET(S): $PS-TXY
2 PHASE PV FLASHES WERE PERFORMED.
PROPERTY OPTION SET: WILSON WILSON / IDEAL GAS

FLASH CURVE TABLE: BINRY-1 (CONTINUED)
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! TEMP ! KVL ! KVL ! GAMMA !
! ! ! TOTAL ! TOTAL ! TOTAL ! LIQUID !
! ! METHANOL ! ! METHANOL ! WATER ! METHANOL !
! ! ! ! ! ! !
! BAR ! ! C ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0130 ! 0.0 ! 100.0109 ! 8.0425 ! 1.0000 ! 2.3110 !
! 1.0130 ! 2.0000-02 ! 96.5169 ! 6.7771 ! 0.8821 ! 2.1757 !
! 1.0130 ! 4.0000-02 ! 93.7261 ! 5.8664 ! 0.7972 ! 2.0613 !
! 1.0130 ! 6.0000-02 ! 91.4265 ! 5.1788 ! 0.7333 ! 1.9625 !
! 1.0130 ! 8.0000-02 ! 89.4862 ! 4.6409 ! 0.6834 ! 1.8760 !
!------------+------------+------------+------------+------------+------------!
! 1.0130 ! 0.1000 ! 87.8181 ! 4.2086 ! 0.6435 ! 1.7994 !
! 1.0130 ! 0.1500 ! 84.4835 ! 3.4254 ! 0.5720 ! 1.6414 !
! 1.0130 ! 0.2000 ! 81.9386 ! 2.8997 ! 0.5251 ! 1.5183 !
! 1.0130 ! 0.3000 ! 78.1775 ! 2.2393 ! 0.4689 ! 1.3401 !
! 1.0130 ! 0.4000 ! 75.3845 ! 1.8427 ! 0.4382 ! 1.2204 !
!------------+------------+------------+------------+------------+------------!
! 1.0130 ! 0.5000 ! 73.1048 ! 1.5794 ! 0.4206 ! 1.1378 !
! 1.0130 ! 0.6000 ! 71.1232 ! 1.3929 ! 0.4106 ! 1.0807 !
! 1.0130 ! 0.7000 ! 69.3268 ! 1.2548 ! 0.4055 ! 1.0420 !
! 1.0130 ! 0.8000 ! 67.6517 ! 1.1491 ! 0.4037 ! 1.0175 !
! 1.0130 ! 0.9000 ! 66.0601 ! 1.0662 ! 0.4044 ! 1.0041 !
!------------+------------+------------+------------+------------+------------!
! 1.0130 ! 0.9500 ! 65.2881 ! 1.0313 ! 0.4055 ! 1.0010 !
! 1.0130 ! 1.0000 ! 64.5285 ! 1.0000 ! 0.4070 ! 1.0000 !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! GAMMA ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC !
! ! ! LIQUID ! VAPOR ! VAPOR ! LIQUID !
! ! METHANOL ! WATER ! METHANOL ! WATER ! METHANOL !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0130 ! 0.0 ! 1.0000 ! 0.0 ! 1.0000 ! 0.0 !
! 1.0130 ! 2.0000-02 ! 1.0005 ! 0.1355 ! 0.8645 ! 2.0000-02 !
! 1.0130 ! 4.0000-02 ! 1.0019 ! 0.2347 ! 0.7653 ! 4.0000-02 !
! 1.0130 ! 6.0000-02 ! 1.0042 ! 0.3107 ! 0.6893 ! 6.0000-02 !
! 1.0130 ! 8.0000-02 ! 1.0072 ! 0.3713 ! 0.6287 ! 8.0000-02 !
!------------+------------+------------+------------+------------+------------!
! 1.0130 ! 0.1000 ! 1.0109 ! 0.4209 ! 0.5791 ! 0.1000 !
! 1.0130 ! 0.1500 ! 1.0230 ! 0.5138 ! 0.4862 ! 0.1500 !
! 1.0130 ! 0.2000 ! 1.0387 ! 0.5799 ! 0.4201 ! 0.2000 !
! 1.0130 ! 0.3000 ! 1.0799 ! 0.6718 ! 0.3282 ! 0.3000 !
! 1.0130 ! 0.4000 ! 1.1327 ! 0.7371 ! 0.2629 ! 0.4000 !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! GAMMA ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC !
! ! ! LIQUID ! VAPOR ! VAPOR ! LIQUID !
! ! METHANOL ! WATER ! METHANOL ! WATER ! METHANOL !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0130 ! 0.5000 ! 1.1964 ! 0.7897 ! 0.2103 ! 0.5000 !
! 1.0130 ! 0.6000 ! 1.2709 ! 0.8358 ! 0.1642 ! 0.6000 !
! 1.0130 ! 0.7000 ! 1.3562 ! 0.8784 ! 0.1216 ! 0.7000 !
! 1.0130 ! 0.8000 ! 1.4528 ! 0.9193 ! 8.0740-02 ! 0.8000 !
! 1.0130 ! 0.9000 ! 1.5612 ! 0.9596 ! 4.0440-02 ! 0.9000 !
!------------+------------+------------+------------+------------+------------!
! 1.0130 ! 0.9500 ! 1.6202 ! 0.9797 ! 2.0275-02 ! 0.9500 !
! 1.0130 ! 1.0000 ! 1.6824 ! 1.0000 ! 0.0 ! 1.0000 !
-------------------------------------------------------------------------------
----------------------------------------
! PRES ! MOLEFRAC ! MOLEFRAC !
! ! ! LIQUID !
! ! METHANOL ! WATER !
! ! ! !
! BAR ! ! !
! ! ! !
!============!============!============!
! 1.0130 ! 0.0 ! 1.0000 !
! 1.0130 ! 2.0000-02 ! 0.9800 !
! 1.0130 ! 4.0000-02 ! 0.9600 !
! 1.0130 ! 6.0000-02 ! 0.9400 !
! 1.0130 ! 8.0000-02 ! 0.9200 !
!------------+------------+------------!
! 1.0130 ! 0.1000 ! 0.9000 !
! 1.0130 ! 0.1500 ! 0.8500 !
! 1.0130 ! 0.2000 ! 0.8000 !
! 1.0130 ! 0.3000 ! 0.7000 !
! 1.0130 ! 0.4000 ! 0.6000 !
!------------+------------+------------!
! 1.0130 ! 0.5000 ! 0.5000 !
! 1.0130 ! 0.6000 ! 0.4000 !
! 1.0130 ! 0.7000 ! 0.3000 !
! 1.0130 ! 0.8000 ! 0.2000 !
! 1.0130 ! 0.9000 ! 0.1000 !
!------------+------------+------------!
! 1.0130 ! 0.9500 ! 5.0000-02 !
! 1.0130 ! 1.0000 ! 0.0 !
----------------------------------------
BLOCK STATUS
------------
****************************************************************************
* *
* *
* *
****************************************************************************
TERNARY COMPONENTS
Objective: To generate the liquid-liquid equilibrium data for ter nary mixtureand compare
them with experimental data.
Procedure:
EXPERIMENTAL DATA: Search for the experimental liquid-liquid equilibrium (LLE)

data for the ternary system for which you intend to run theproperty analysis. Report it in the
tabular form and its source.
INPUT
1. Open Aspen Plus GUI
2. Select appropriate input and output units and run type
Fig-1: component selection
4. Select at least three property methods (using peng rob, unifac and nrtlmodels).
Fig-2: base method selection
5. On the ribbon tabs of Home menu, select Analysis on the Run mode tab.
Fig-3: selection of analysis mode from Run tab
6. Select Ternary on the Analysis tab

Fig-4: Selection of ternary from analysis tab
7. Select Continue to Aspen Plus Ternary Diag on Distillation Synthesiswindow

that appears
8. On the ternary analysis form:
a. select component1, component2, and component3 from the list
Fig-5: selection of components as primary and secondary and

ternary
b. select the Property Method from the available list
Fig-6: selection of base method
c. select the Valid Phases from the list as Liquid-Liquid
Fig-7: selection of valid phases
d. Input the value of Pressure and Temperature in the desired unit

Fig-8: selection of pressure and temperature unit
e. Give the Number of tie lines
Fig-9: selection of number of tie lines
f. Click on Run Analysis.

RESULT NRTL
MODEL
ASPEN DATA
NRTL MODEL
AZEOTROPE COMPOSITION
PHASE ENVELOPE
EQUILIBRIUM COMPOSITION
UNIFAC MODEL
ASPEN DATA
UNIFAC MODEL
AZEOTROPE
PHASE ENVELOPE
EQUILIBRIUM DATA
PENG-ROB MODEL
ASPEN DATA
PENG-ROB MODEL
AZEOTROPE
PHASE ENVELOPE
EQUILIBRIUM COMPOSITION
EXPERIMENT DATA
Experimental LLE Data of Ethanol (1) + Water (2) + Hexane (3) Ternary Mixtures under
atmospheric pressure.
Temperature
Organic Phase Aqueous Phase

X1 X2 X3 X1 X2 X3
Source: C. Huang, P. Chung, I.-M. Tseng, and L. Lee, “Measurements and Correlations of
Liquid- liquid-Equilibria of the Mixtures Consisting of Ethanol, Water, Pentane, Hexane,
and Cyclohexane~!2009-08-31~!2009-11-02~!2010-06-24~!,” Open Thermodyn. J., vol. 4,
no. 4, pp. 102– 118, 2010, doi: 10.2174/1874396x01004040102.
CALCULATION
ERROR BY DIFFERENT METHODS
ERROR1- ERROR IN MOLE FRACTION OF HEXANE (SOLUTE) FOR NRTL MODEL
ERROR2- ERROR IN MOLE FRACTION OF HEXANE (SOLUTE) FOR UNIFAC MODEL
ERROR3- ERROR IN MOLE FRACTION OF HEXANE (SOLUTE) FOR PENG-ROB MODEL
ORGANIC AQUEOUS NRTL MODEL UNIFAC PENG-ROB AQUEOUS PHASE

PHASE PHASE MODEL MODEL
MOLEFRAC MOLEFRAC MOLEFRA ERROR ERROR2 ERROR
HEXANE HEXANE C HEXANE 1 3
0.9845 0 0.9981387 0.8567569 0.9804417 0 0 0
0.9757 0 0.9749593 0.911985 0.8142807 0 0 0
0.9657 0.0015 0.9630487 0.9238025 0.6839523 410922.6 378063.1 206996.1
0.9553 0.0024 0.9541089 0.9374313 0.5589001 157248.2 151785.3 53766.03
0.9402 0.0097 0.9452385 0.9479637 0.4364057 9302.076 9356.348 1935.145
0.8869 0.0394 0.93438 0.9560307 0.3138279 515.9816 541.2481 48.51366
0.8721 0.0501 0.9188109 0.9622561 0.188531 300.6596 331.4842 7.634687
0.8478 0.079 0.8941865 0.967343 0.0583025 106.478 126.4466 0.068641
0.7871 0.1132 0.8911767 0.9723949 0 47.23243 57.60903 1
0.7248 0.1484 0.8900683 0.981356 0 24.97765 31.50477 1
0.6696 0.1935 0.8832467 0.9991508 2.18E-12 12.70625 17.33532 1
578481 540310.4 262756.5

CONCLUSIONS
The sum of error in case of NRTL MODEL is 578481
The sum of error in case of UNIFAC MODEL is 540310.4
The sum of error in case of PENG-ROB MODEL is 262756.5
The sum of error is minimum in case of PENG-ROB MODEL. Hence it will be a suitable method for analysis
TERNARY REPORT
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + +
+ + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

781/221-6400 EUROPE (44) 1189-226555


BEDFORD, MA 01730.
TABLE OF CONTENTS

COMPONENTS........................................ 2

FLASH CURVE TABLE: BINRY-1....................... 3
TERDIAGRAM CURVE TABLE:TERDI-3................... 11

BLOCK STATUS...................................... 12
RUN CONTROL SECTION

-----------------------
TYPE OF RUN: NEW
INPUT FILE NAME: _1523hyx.inm
OUTPUT PROBLEM DATA FILE NAME: _1523hyx

LOCATED IN:


TGS ONLY RUN

COMPONENTS
----------
ID TYPE ALIAS NAME

ETHANOL C C2H6O-2 ETHANOL
WATER C H2O WATER
HEXANE C C6H14-1 N-HEXANE
FLASH CURVE TABLE: BINRY-1

---------------------------

ETHANOL 1.000 , WATER 1.000 ,
STATE SPECIFICATIONS:
VAPOR FRACTION: 0.000
VARIED VARIABLE(S): PRES MOLEFRAC
PROPERTY SET(S): $PS-TXY
3 PHASE PV FLASHES WERE PERFORMED.

-------------------------------------------------------------------------------
! ! ! TOTAL ! TOTAL ! TOTAL ! LIQUID 1 !
! ! ETHANOL ! ! ETHANOL ! WATER ! ETHANOL !
! ! ! ! ! ! !
! BAR ! ! C ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.0 ! 100.0178 ! 12.6303 ! 1.0000 ! 5.6970 !
! 1.0133 ! 2.0000-02 ! 94.8907 ! 9.2569 ! 0.8315 ! 4.9891 !
! 1.0133 ! 4.0000-02 ! 91.5687 ! 7.3027 ! 0.7374 ! 4.4311 !
! 1.0133 ! 6.0000-02 ! 89.2537 ! 6.0258 ! 0.6792 ! 3.9772 !
! 1.0133 ! 8.0000-02 ! 87.5634 ! 5.1260 ! 0.6412 ! 3.6005 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.1000 ! 86.2872 ! 4.4580 ! 0.6158 ! 3.2835 !
! 1.0133 ! 0.1200 ! 85.2979 ! 3.9431 ! 0.5987 ! 3.0139 !
! 1.0133 ! 0.1400 ! 84.5139 ! 3.5344 ! 0.5874 ! 2.7825 !
! 1.0133 ! 0.1600 ! 83.8801 ! 3.2027 ! 0.5804 ! 2.5825 !
! 1.0133 ! 0.1800 ! 83.3582 ! 2.9285 ! 0.5767 ! 2.4087 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.2000 ! 82.9208 ! 2.6983 ! 0.5754 ! 2.2567 !
! 1.0133 ! 0.2200 ! 82.5477 ! 2.5027 ! 0.5762 ! 2.1232 !
! 1.0133 ! 0.2400 ! 82.2241 ! 2.3347 ! 0.5785 ! 2.0054 !
! 1.0133 ! 0.2600 ! 81.9388 ! 2.1892 ! 0.5822 ! 1.9011 !
! 1.0133 ! 0.2800 ! 81.6834 ! 2.0621 ! 0.5870 ! 1.8084 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.3000 ! 81.4513 ! 1.9503 ! 0.5927 ! 1.7257 !
! 1.0133 ! 0.3200 ! 81.2376 ! 1.8515 ! 0.5993 ! 1.6518 !
! 1.0133 ! 0.3400 ! 81.0387 ! 1.7637 ! 0.6066 ! 1.5856 !
! 1.0133 ! 0.3600 ! 80.8515 ! 1.6853 ! 0.6145 ! 1.5261 !
! 1.0133 ! 0.3800 ! 80.6740 ! 1.6150 ! 0.6231 ! 1.4726 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.4000 ! 80.5046 ! 1.5518 ! 0.6321 ! 1.4243 !
! 1.0133 ! 0.4200 ! 80.3419 ! 1.4948 ! 0.6417 ! 1.3807 !
! 1.0133 ! 0.4400 ! 80.1851 ! 1.4433 ! 0.6517 ! 1.3412 !
! 1.0133 ! 0.4600 ! 80.0337 ! 1.3966 ! 0.6622 ! 1.3055 !
! 1.0133 ! 0.4800 ! 79.8872 ! 1.3541 ! 0.6731 ! 1.2731 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.5000 ! 79.7453 ! 1.3156 ! 0.6844 ! 1.2437 !
! 1.0133 ! 0.5200 ! 79.6080 ! 1.2805 ! 0.6961 ! 1.2170 !
! 1.0133 ! 0.5400 ! 79.4753 ! 1.2485 ! 0.7083 ! 1.1928 !
! 1.0133 ! 0.5600 ! 79.3473 ! 1.2194 ! 0.7208 ! 1.1708 !
! 1.0133 ! 0.5800 ! 79.2241 ! 1.1928 ! 0.7337 ! 1.1508 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.6000 ! 79.1059 ! 1.1686 ! 0.7471 ! 1.1327 !
! 1.0133 ! 0.6200 ! 78.9930 ! 1.1466 ! 0.7608 ! 1.1163 !
! 1.0133 ! 0.6400 ! 78.8855 ! 1.1266 ! 0.7750 ! 1.1014 !
! 1.0133 ! 0.6600 ! 78.7840 ! 1.1084 ! 0.7896 ! 1.0879 !
! 1.0133 ! 0.6800 ! 78.6886 ! 1.0919 ! 0.8047 ! 1.0758 !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! ! ! TOTAL ! TOTAL ! TOTAL ! LIQUID 1 !
! ! ETHANOL ! ! ETHANOL ! WATER ! ETHANOL !
! ! ! ! ! ! !
! BAR ! ! C ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.7000 ! 78.5997 ! 1.0771 ! 0.8202 ! 1.0649 !
! 1.0133 ! 0.7200 ! 78.5177 ! 1.0637 ! 0.8362 ! 1.0551 !
! 1.0133 ! 0.7400 ! 78.4428 ! 1.0518 ! 0.8527 ! 1.0463 !
! 1.0133 ! 0.7600 ! 78.3757 ! 1.0412 ! 0.8697 ! 1.0385 !
! 1.0133 ! 0.7800 ! 78.3165 ! 1.0318 ! 0.8872 ! 1.0316 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.8000 ! 78.2656 ! 1.0237 ! 0.9053 ! 1.0255 !
! 1.0133 ! 0.8200 ! 78.2236 ! 1.0167 ! 0.9240 ! 1.0202 !
! 1.0133 ! 0.8400 ! 78.1907 ! 1.0108 ! 0.9433 ! 1.0156 !
! 1.0133 ! 0.8600 ! 78.1675 ! 1.0060 ! 0.9633 ! 1.0117 !
! 1.0133 ! 0.8800 ! 78.1542 ! 1.0022 ! 0.9839 ! 1.0084 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.9000 ! 78.1515 ! 0.9994 ! 1.0052 ! 1.0057 !
! 1.0133 ! 0.9200 ! 78.1596 ! 0.9976 ! 1.0273 ! 1.0036 !
! 1.0133 ! 0.9400 ! 78.1791 ! 0.9968 ! 1.0501 ! 1.0020 !
! 1.0133 ! 0.9600 ! 78.2104 ! 0.9969 ! 1.0738 ! 1.0009 !
! 1.0133 ! 0.9800 ! 78.2540 ! 0.9980 ! 1.0984 ! 1.0002 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 1.0000 ! 78.3103 ! 1.0000 ! 1.1238 ! 1.0000 !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! GAMMA ! GAMMA ! GAMMA ! KVL2 !
! ! ! LIQUID 1 ! LIQUID 2 ! LIQUID 2 ! TOTAL !
! ! ETHANOL ! WATER ! ETHANOL ! WATER ! ETHANOL !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.0 ! 1.0000 ! MISSING ! MISSING ! MISSING !
! 1.0133 ! 2.0000-02 ! 1.0012 ! MISSING ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
!------------+------------+------------+------------+------------+------------!
!------------+------------+------------+------------+------------+------------!
!------------+------------+------------+------------+------------+------------!
!------------+------------+------------+------------+------------+------------!
!------------+------------+------------+------------+------------+------------!
!------------+------------+------------+------------+------------+------------!
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
!------------+------------+------------+------------+------------+------------!
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! KVL2 ! BETA ! MOLEFRAC ! MOLEFRAC !
! ! ! TOTAL ! TOTAL ! VAPOR ! VAPOR !
! ! ETHANOL ! WATER ! ! ETHANOL ! WATER !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.0 ! MISSING ! 1.0000 ! 0.0 ! 1.0000 !
! 1.0133 ! 2.0000-02 ! MISSING ! 1.0000 ! 0.1851 ! 0.8149 !
! 1.0133 ! 4.0000-02 ! MISSING ! 1.0000 ! 0.2921 ! 0.7079 !
! 1.0133 ! 6.0000-02 ! MISSING ! 1.0000 ! 0.3615 ! 0.6385 !
! 1.0133 ! 8.0000-02 ! MISSING ! 1.0000 ! 0.4101 ! 0.5899 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.1000 ! MISSING ! 1.0000 ! 0.4458 ! 0.5542 !
! 1.0133 ! 0.1200 ! MISSING ! 1.0000 ! 0.4732 ! 0.5268 !
! 1.0133 ! 0.1400 ! MISSING ! 1.0000 ! 0.4948 ! 0.5052 !
! 1.0133 ! 0.1600 ! MISSING ! 1.0000 ! 0.5124 ! 0.4876 !
! 1.0133 ! 0.1800 ! MISSING ! 1.0000 ! 0.5271 ! 0.4729 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.2000 ! MISSING ! 1.0000 ! 0.5397 ! 0.4603 !
! 1.0133 ! 0.2200 ! MISSING ! 1.0000 ! 0.5506 ! 0.4494 !
! 1.0133 ! 0.2400 ! MISSING ! 1.0000 ! 0.5603 ! 0.4397 !
! 1.0133 ! 0.2600 ! MISSING ! 1.0000 ! 0.5692 ! 0.4308 !
! 1.0133 ! 0.2800 ! MISSING ! 1.0000 ! 0.5774 ! 0.4226 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.3000 ! MISSING ! 1.0000 ! 0.5851 ! 0.4149 !
! 1.0133 ! 0.3200 ! MISSING ! 1.0000 ! 0.5925 ! 0.4075 !
! 1.0133 ! 0.3400 ! MISSING ! 1.0000 ! 0.5997 ! 0.4003 !
! 1.0133 ! 0.3600 ! MISSING ! 1.0000 ! 0.6067 ! 0.3933 !
! 1.0133 ! 0.3800 ! MISSING ! 1.0000 ! 0.6137 ! 0.3863 !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! KVL2 ! BETA ! MOLEFRAC ! MOLEFRAC !
! ! ! TOTAL ! TOTAL ! VAPOR ! VAPOR !
! ! ETHANOL ! WATER ! ! ETHANOL ! WATER !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.4000 ! MISSING ! 1.0000 ! 0.6207 ! 0.3793 !
! 1.0133 ! 0.4200 ! MISSING ! 1.0000 ! 0.6278 ! 0.3722 !
! 1.0133 ! 0.4400 ! MISSING ! 1.0000 ! 0.6350 ! 0.3650 !
! 1.0133 ! 0.4600 ! MISSING ! 1.0000 ! 0.6424 ! 0.3576 !
! 1.0133 ! 0.4800 ! MISSING ! 1.0000 ! 0.6500 ! 0.3500 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.5000 ! MISSING ! 1.0000 ! 0.6578 ! 0.3422 !
! 1.0133 ! 0.5200 ! MISSING ! 1.0000 ! 0.6659 ! 0.3341 !
! 1.0133 ! 0.5400 ! MISSING ! 1.0000 ! 0.6742 ! 0.3258 !
! 1.0133 ! 0.5600 ! MISSING ! 1.0000 ! 0.6828 ! 0.3172 !
! 1.0133 ! 0.5800 ! MISSING ! 1.0000 ! 0.6918 ! 0.3082 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.6000 ! MISSING ! 1.0000 ! 0.7012 ! 0.2988 !
! 1.0133 ! 0.6200 ! MISSING ! 1.0000 ! 0.7109 ! 0.2891 !
! 1.0133 ! 0.6400 ! MISSING ! 1.0000 ! 0.7210 ! 0.2790 !
! 1.0133 ! 0.6600 ! MISSING ! 1.0000 ! 0.7315 ! 0.2685 !
! 1.0133 ! 0.6800 ! MISSING ! 1.0000 ! 0.7425 ! 0.2575 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.7000 ! MISSING ! 1.0000 ! 0.7539 ! 0.2461 !
! 1.0133 ! 0.7200 ! MISSING ! 1.0000 ! 0.7659 ! 0.2341 !
! 1.0133 ! 0.7400 ! MISSING ! 1.0000 ! 0.7783 ! 0.2217 !
! 1.0133 ! 0.7600 ! MISSING ! 1.0000 ! 0.7913 ! 0.2087 !
! 1.0133 ! 0.7800 ! MISSING ! 1.0000 ! 0.8048 ! 0.1952 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.8000 ! MISSING ! 1.0000 ! 0.8189 ! 0.1811 !
! 1.0133 ! 0.8200 ! MISSING ! 1.0000 ! 0.8337 ! 0.1663 !
! 1.0133 ! 0.8400 ! MISSING ! 1.0000 ! 0.8491 ! 0.1509 !
! 1.0133 ! 0.8600 ! MISSING ! 1.0000 ! 0.8651 ! 0.1349 !
! 1.0133 ! 0.8800 ! MISSING ! 1.0000 ! 0.8819 ! 0.1181 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.9000 ! MISSING ! 1.0000 ! 0.8995 ! 0.1005 !
! 1.0133 ! 0.9200 ! MISSING ! 1.0000 ! 0.9178 ! 8.2182-02 !
! 1.0133 ! 0.9400 ! MISSING ! 1.0000 ! 0.9370 ! 6.3008-02 !
! 1.0133 ! 0.9600 ! MISSING ! 1.0000 ! 0.9570 ! 4.2952-02 !
! 1.0133 ! 0.9800 ! MISSING ! 1.0000 ! 0.9780 ! 2.1967-02 !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 1.0000 ! MISSING ! 1.0000 ! 1.0000 ! 0.0 !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC !
! ! ! LIQUID 1 ! LIQUID 1 ! LIQUID 2 ! LIQUID 2 !
! ! ETHANOL ! ETHANOL ! WATER ! ETHANOL ! WATER !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.0 ! 0.0 ! 1.0000 ! MISSING ! MISSING !
! 1.0133 ! 2.0000-02 ! 2.0000-02 ! 0.9800 ! MISSING ! MISSING !
! 1.0133 ! 4.0000-02 ! 4.0000-02 ! 0.9600 ! MISSING ! MISSING !
! 1.0133 ! 6.0000-02 ! 6.0000-02 ! 0.9400 ! MISSING ! MISSING !
! 1.0133 ! 8.0000-02 ! 8.0000-02 ! 0.9200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.1000 ! 0.1000 ! 0.9000 ! MISSING ! MISSING !
! 1.0133 ! 0.1200 ! 0.1200 ! 0.8800 ! MISSING ! MISSING !
! 1.0133 ! 0.1400 ! 0.1400 ! 0.8600 ! MISSING ! MISSING !
! 1.0133 ! 0.1600 ! 0.1600 ! 0.8400 ! MISSING ! MISSING !
! 1.0133 ! 0.1800 ! 0.1800 ! 0.8200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.2000 ! 0.2000 ! 0.8000 ! MISSING ! MISSING !
! 1.0133 ! 0.2200 ! 0.2200 ! 0.7800 ! MISSING ! MISSING !
! 1.0133 ! 0.2400 ! 0.2400 ! 0.7600 ! MISSING ! MISSING !
! 1.0133 ! 0.2600 ! 0.2600 ! 0.7400 ! MISSING ! MISSING !
! 1.0133 ! 0.2800 ! 0.2800 ! 0.7200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.3000 ! 0.3000 ! 0.7000 ! MISSING ! MISSING !
! 1.0133 ! 0.3200 ! 0.3200 ! 0.6800 ! MISSING ! MISSING !
! 1.0133 ! 0.3400 ! 0.3400 ! 0.6600 ! MISSING ! MISSING !
! 1.0133 ! 0.3600 ! 0.3600 ! 0.6400 ! MISSING ! MISSING !
! 1.0133 ! 0.3800 ! 0.3800 ! 0.6200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.4000 ! 0.4000 ! 0.6000 ! MISSING ! MISSING !
! 1.0133 ! 0.4200 ! 0.4200 ! 0.5800 ! MISSING ! MISSING !
! 1.0133 ! 0.4400 ! 0.4400 ! 0.5600 ! MISSING ! MISSING !
! 1.0133 ! 0.4600 ! 0.4600 ! 0.5400 ! MISSING ! MISSING !
! 1.0133 ! 0.4800 ! 0.4800 ! 0.5200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.5000 ! 0.5000 ! 0.5000 ! MISSING ! MISSING !
! 1.0133 ! 0.5200 ! 0.5200 ! 0.4800 ! MISSING ! MISSING !
! 1.0133 ! 0.5400 ! 0.5400 ! 0.4600 ! MISSING ! MISSING !
! 1.0133 ! 0.5600 ! 0.5600 ! 0.4400 ! MISSING ! MISSING !
! 1.0133 ! 0.5800 ! 0.5800 ! 0.4200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.6000 ! 0.6000 ! 0.4000 ! MISSING ! MISSING !
! 1.0133 ! 0.6200 ! 0.6200 ! 0.3800 ! MISSING ! MISSING !
! 1.0133 ! 0.6400 ! 0.6400 ! 0.3600 ! MISSING ! MISSING !
! 1.0133 ! 0.6600 ! 0.6600 ! 0.3400 ! MISSING ! MISSING !
! 1.0133 ! 0.6800 ! 0.6800 ! 0.3200 ! MISSING ! MISSING !
-------------------------------------------------------------------------------
-------------------------------------------------------------------------------
! PRES ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC ! MOLEFRAC !
! ! ! LIQUID 1 ! LIQUID 1 ! LIQUID 2 ! LIQUID 2 !
! ! ETHANOL ! ETHANOL ! WATER ! ETHANOL ! WATER !
! ! ! ! ! ! !
! BAR ! ! ! ! ! !
! ! ! ! ! ! !
!============!============!============!============!============!============!
! 1.0133 ! 0.7000 ! 0.7000 ! 0.3000 ! MISSING ! MISSING !
! 1.0133 ! 0.7200 ! 0.7200 ! 0.2800 ! MISSING ! MISSING !
! 1.0133 ! 0.7400 ! 0.7400 ! 0.2600 ! MISSING ! MISSING !
! 1.0133 ! 0.7600 ! 0.7600 ! 0.2400 ! MISSING ! MISSING !
! 1.0133 ! 0.7800 ! 0.7800 ! 0.2200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.8000 ! 0.8000 ! 0.2000 ! MISSING ! MISSING !
! 1.0133 ! 0.8200 ! 0.8200 ! 0.1800 ! MISSING ! MISSING !
! 1.0133 ! 0.8400 ! 0.8400 ! 0.1600 ! MISSING ! MISSING !
! 1.0133 ! 0.8600 ! 0.8600 ! 0.1400 ! MISSING ! MISSING !
! 1.0133 ! 0.8800 ! 0.8800 ! 0.1200 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 0.9000 ! 0.9000 ! 0.1000 ! MISSING ! MISSING !
! 1.0133 ! 0.9200 ! 0.9200 ! 8.0000-02 ! MISSING ! MISSING !
! 1.0133 ! 0.9400 ! 0.9400 ! 6.0000-02 ! MISSING ! MISSING !
! 1.0133 ! 0.9600 ! 0.9600 ! 4.0000-02 ! MISSING ! MISSING !
! 1.0133 ! 0.9800 ! 0.9800 ! 2.0000-02 ! MISSING ! MISSING !
!------------+------------+------------+------------+------------+------------!
! 1.0133 ! 1.0000 ! 1.0000 ! 0.0 ! MISSING ! MISSING !
-------------------------------------------------------------------------------
TERDIAGRAM CURVE TABLE:TERDI-3

-------------------------------
*** PHASE ENVELOPE RESULTS ***
LIQUID MOLE FRACTION
WATER ETHANOL HEXANE
1 0.18613E-02 0.0000 0.99814

2 0.23528E-02 0.22688E-01 0.97496
3 0.25961E-02 0.34355E-01 0.96305
4 0.27531E-02 0.43138E-01 0.95411
5 0.28767E-02 0.51885E-01 0.94524
6 0.29893E-02 0.62631E-01 0.93438
7 0.31082E-02 0.78081E-01 0.91881
8 0.32691E-02 0.10254 0.89419
9 0.32790E-02 0.10554 0.89118
10 0.32846E-02 0.10665 0.89007
11 0.31149E-02 0.11364 0.88325
12 0.30629E-01 0.46786 0.50151
13 0.71387E-01 0.61758 0.31103
14 0.10565 0.69083 0.20352
15 0.12807 0.71264 0.15929
16 0.25460 0.68929 0.56106E-01
17 0.37211 0.60340 0.24494E-01
18 0.48778 0.50174 0.10484E-01
19 0.60443 0.39162 0.39525E-02
20 0.72438 0.27447 0.11474E-02
21 0.84981 0.14999 0.19967E-03
22 0.99999 0.0000 0.70099E-05
*** TIELINE RESULTS ***
LIQUID 1 MOLE FRACTION LIQUID 2 MOLE FRACTION
WATER ETHANOL HEXANE WATER ETHANOL HEXANE
1 0.1861E-02 0.000 0.9981 | 1.000 0.000 0.7010E-05

2 0.2431E-02 0.2632E-01 0.9712 | 0.8156 0.1840 0.3429E-03
3 0.2750E-02 0.4297E-01 0.9543 | 0.6069 0.3893 0.3866E-02
4 0.2982E-02 0.6184E-01 0.9352 | 0.3795 0.5972 0.2324E-01
5 0.3269E-02 0.1025 0.8942 | 0.1281 0.7126 0.1593
*** AZEOTROPE RESULTS ***
AZEOTROPE MOLE FRACTION | TEMPERATURE PHASE
WATER ETHANOL HEXANE | C
1 0.000 0.3383 0.6617 | 58.35 1 SADDLE

2 0.1099 0.2572 0.6329 | 56.32 2 UNSTABLE
3 0.1048 0.8952 0.000 | 78.15 1 SADDLE
4 0.2102 0.000 0.7898 | 61.43 2 SADDLE
BLOCK STATUS
------------
****************************************************************************
* *
* Calculations were completed with errors *
* *
* The following Property Tables were *
* completed with warnings: *
* TERDI-1 TERDI-2 *
* *
* The following Property Tables were *
* completed with errors: *
* TERDI-3 *
* *
****************************************************************************
MIXTURE PROPERTY ANALYSIS
Input
1. Open Aspen Plus GUI.
Fig 1: Select Components

3. Select a property model
Fig 2: Select Method
4. Click on the mixture analysis
Fig 3: Analysis Tab

5. On the mixture analysis form:
a) Select composition for the component and their flow rates.
b) Select temperature values on manipulated variable form.
c) On properties to report form, select New and select the properties that you
wish to estimate from the list on Find Properties window and then click OK
d) After selecting the property method click on Run Analysis
Fig 4: Selection of composition manipulated variable and properties to report

RESULT FOR MIXTURE PROPERTY ANALYSIS
PRES TEMP TOTAL CPMX TOTAL RHOMX

bar C kJ/kmol-K mol/cc
1.01325 0 79.3636 6.68E-05
1.01325 5 79.4455 6.37E-05
1.01325 10 78.4573 6.08E-05
1.01325 15 78.363 5.81E-05
1.01325 20 78.2019 5.55E-05
1.01325 25 77.9084 5.29E-05
1.01325 30 77.5613 5.01E-05
1.01325 35 75.7035 4.72E-05
1.01325 40 73.8974 4.40E-05
1.01325 45 70.9769 4.04E-05
1.01325 50 68.6773 3.77E-05
1.01325 55 69.4718 3.71E-05
1.01325 60 70.2719 3.66E-05
1.01325 65 71.0767 3.60E-05
1.01325 70 71.8855 3.55E-05
1.01325 75 72.6973 3.50E-05
1.01325 80 73.5115 3.45E-05
1.01325 85 74.3273 3.40E-05
1.01325 90 75.1441 3.36E-05
1.01325 95 75.9612 3.31E-05
1.01325 100 76.7781 3.27E-05
MIXTURE PLOT
RESULT FOR MIXTURE PROPERTY ANALYSIS
PRES TEMP TOTAL CPMX TOTAL RHOMX

bar C kJ/kmol-K mol/cc
1.01325 0 79.3636 6.68E-05
1.01325 5 79.4455 6.37E-05
1.01325 10 78.4573 6.08E-05
1.01325 15 78.363 5.81E-05
1.01325 20 78.2019 5.55E-05
1.01325 25 77.9084 5.29E-05
1.01325 30 77.5613 5.01E-05
1.01325 35 75.7035 4.72E-05
1.01325 40 73.8974 4.40E-05
1.01325 45 70.9769 4.04E-05
1.01325 50 68.6773 3.77E-05
1.01325 55 69.4718 3.71E-05
1.01325 60 70.2719 3.66E-05
1.01325 65 71.0767 3.60E-05
1.01325 70 71.8855 3.55E-05
1.01325 75 72.6973 3.50E-05
1.01325 80 73.5115 3.45E-05
1.01325 85 74.3273 3.40E-05
1.01325 90 75.1441 3.36E-05
1.01325 95 75.9612 3.31E-05
1.01325 100 76.7781 3.27E-05
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + +
+ + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +
+ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +

781/221-6400 EUROPE (44) 1189-226555


MIXTURE

BEDFORD, MA 01730.
TABLE OF CONTENTS

COMPONENTS........................................ 2

FLASH CURVE TABLE: MIX-4......................... 3

BLOCK STATUS...................................... 5

MIXTURE
RUN CONTROL SECTION

-----------------------
TYPE OF RUN: NEW
INPUT FILE NAME: _4444wvx.inm
OUTPUT PROBLEM DATA FILE NAME: _4444wvx

LOCATED IN:


TGS ONLY RUN

MIXTURE
COMPONENTS
----------
ID TYPE ALIAS NAME

BUTANE C C4H10-1 N-BUTANE
ETHANE C C2H6 ETHANE
ETHANOL C C2H6O-2 ETHANOL
ETHYLENE C C2H4 ETHYLENE
MIXTURE
FLASH CURVE TABLE: MIX-4

-------------------------

BUTANE 1.000 , ETHANE 1.000 , ETHANOL 1.000
ETHYLENE 1.000 ,
VARIED VARIABLE(S): PRES TEMP
PROPERTY SET(S): CP RHOMX HMX
2 PHASE TP FLASHES WERE PERFORMED.

MIXTURE
FLASH CURVE TABLE: MIX-4 (CONTINUED)
------------------------------------------------------------------
! PRES ! TEMP ! CPMX ! RHOMX ! RHOMX !
! ! ! TOTAL ! TOTAL ! TOTAL !
! ! ! ! ! !
! ! ! ! ! !
! BAR ! C ! CAL/MOL- ! MOL/CC ! MOL/CC !
! ! ! K ! ! !
!============!============!============!============!============!
! 1.0133 ! 0.0 ! 18.9557 ! 6.6752-05 ! 6.6752-05 !
! 1.0133 ! 5.0000 ! 18.9752 ! 6.3652-05 ! 6.3652-05 !
! 1.0133 ! 10.0000 ! 18.7392 ! 6.0816-05 ! 6.0816-05 !
! 1.0133 ! 15.0000 ! 18.7167 ! 5.8141-05 ! 5.8141-05 !
! 1.0133 ! 20.0000 ! 18.6782 ! 5.5529-05 ! 5.5529-05 !
!------------+------------+------------+------------+------------!
! 1.0133 ! 25.0000 ! 18.6081 ! 5.2890-05 ! 5.2890-05 !
! 1.0133 ! 30.0000 ! 18.5252 ! 5.0136-05 ! 5.0136-05 !
! 1.0133 ! 35.0000 ! 18.0815 ! 4.7186-05 ! 4.7186-05 !
! 1.0133 ! 40.0000 ! 17.6501 ! 4.3954-05 ! 4.3954-05 !
! 1.0133 ! 45.0000 ! 16.9525 ! 4.0358-05 ! 4.0358-05 !
!------------+------------+------------+------------+------------!
! 1.0133 ! 50.0000 ! 16.4033 ! 3.7712-05 ! 3.7712-05 !
! 1.0133 ! 55.0000 ! 16.5931 ! 3.7138-05 ! 3.7138-05 !
! 1.0133 ! 60.0000 ! 16.7842 ! 3.6580-05 ! 3.6580-05 !
! 1.0133 ! 65.0000 ! 16.9764 ! 3.6040-05 ! 3.6040-05 !
! 1.0133 ! 70.0000 ! 17.1696 ! 3.5514-05 ! 3.5514-05 !
!------------+------------+------------+------------+------------!
! 1.0133 ! 75.0000 ! 17.3635 ! 3.5004-05 ! 3.5004-05 !
! 1.0133 ! 80.0000 ! 17.5579 ! 3.4509-05 ! 3.4509-05 !
! 1.0133 ! 85.0000 ! 17.7528 ! 3.4027-05 ! 3.4027-05 !
! 1.0133 ! 90.0000 ! 17.9479 ! 3.3559-05 ! 3.3559-05 !
! 1.0133 ! 95.0000 ! 18.1430 ! 3.3103-05 ! 3.3103-05 !
!------------+------------+------------+------------+------------!
! 1.0133 ! 100.0000 ! 18.3381 ! 3.2659-05 ! 3.2659-05 !
------------------------------------------------------------------
MIXTURE
BLOCK STATUS
------------
****************************************************************************
* *
* *
* *
****************************************************************************

Assignment 01

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Assignment 01

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[CHC-6911]

DESIGN AND SIMULATION LAB

“PROPERTY ANALYSIS USING ASPEN PLUS”

Title: Property analysis using Aspen Plus

a) To estimate the thermodynamic/transport properties of pure component and compare

1. Open the aspen plus GUI.

2. Select appropriate input and output units and run type.

3. Select components for which the property analysis is to be performed.

Fig-1: component selection

Fig-3: selection of analysis mode from Run tab

6. Select Pure on the Analysis tab

Fig-4: Selection of pure from analysis tab

• Select the property type as Thermodynamics, Trasport or all.

Fig-5: selection of property type

• Select the desired property from the list:

Fig-6: selection of type of thermodynamic property

• Select the output unit of the selected property:

Fig-7: selection of type of units of selected thermodynamic property

Fig-8: selection of type of phases

Fig-9: selection of component for doing analysis(selected component)

Fig-10: units of temperature and iteration times

Check the radio button list of values if property is to be obtained at different

• Select the pressure and its unit

Fig-11: selection of pressure units

Fig-12: final selection of property package

TEMPERATURE (°C) PRESSURE (bar) DENSITY kg/m3

RESULT FOR NRTL MODEL

RESULT FOR IDEAL MODEL

PENG-ROB NRTL IDEAL

ERROR CALCULATIONS IN DIFFERENT METHODS

ERROR1- ERROR IN DENSITY FOR MODEL 1

ERROR2- ERROR IN DENSITY FOR MODEL 2

ERROR3- ERROR IN DENSITY FOR MODEL 3

3.26985E-05 3.26985E-05 3.26985E-05

The sum of errors in case of PENG-ROB Model is 3.26985E-05.

The sum of errors in case of NRTL Model is 3.26985E-05.

The sum of errors in case of IDEAL Model is 3.26985E-05.

ASPEN PLUS IS A TRADEMARK OF HOTLINE:

PLATFORM: WINDOWS DECEMBER 1, 2022

ASPEN PLUS (R) IS A PROPRIETARY PRODUCT OF ASPEN TECHNOLOGY, INC.

RUN CONTROL SECTION.................................... 1

PHYSICAL PROPERTY TABLES SECTION....................... 3

PROBLEM STATUS SECTION................................. 5

ASPEN PLUS PLAT: WINDOWS VER: 36.0 12/01/2022 PAGE 1

RUN CONTROL INFORMATION

THIS COPY OF ASPEN PLUS LICENSED TO

TYPE OF RUN: NEW

INPUT FILE NAME: _3015yhb.inm

OUTPUT PROBLEM DATA FILE NAME: _3015yhb

PDF SIZE USED FOR INPUT TRANSLATION:

CALLING PROGRAM NAME: apmain

TGS ONLY RUN

ID TYPE ALIAS NAME

PROPERTIES TABLE: PURE-1

SINGLE-PHASE PROPERTIES FOR THE MIXTURE: (KMOL/HR )

VARIED VARIABLE(S): TEMP PRES

PROPERTY SET(S): $PS-PURE

PROPERTY OPTION SET: NRTL RENON (NRTL) / IDEAL GAS

PROPERTIES TABLE: PURE-1 (CONTINUED)

OBJECTIVE: To generate the vapor-liquid equilibrium data (T-x-y/P-x-y) forbinary

1. Open the aspen plus GUI.

2. Select appropriate input and output units and run type.

3. Select components for which the property analysis is to be performed.