Safety Data Sheet

Hempel's Curing Agent 95370

Conforms to Regulation (EC) No. 1907/2006 (REACH), Annex II, as amended by Regulation (EU) No. 2020/878 - Europe

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Product name : Hempel's Curing Agent 95370
Product identity : 9537000000
Product type : Curing agent

1.2 Relevant identified uses of the substance or mixture and uses advised against
Field of application : used only as part of two- or multi component products.
Ready-for-use mixture : (see base component)
Identified uses : Industrial applications, Professional applications, Used by spraying.

1.3 Details of the supplier of the safety data sheet 1.4 Emergency telephone number
Company details : HEMPEL A/S Emergency telephone number (with hours of operation)
Lundtoftegårdsvej 91
DK-2800 Kgs. Lyngby +45 45 93 38 00 (08.00 - 17.00)
Denmark See section 4 First aid measures.
Tel.: + 45 45 93 38 00
hempel@hempel.com
Date of issue : 16 November 2021
Date of previous issue : 14 June 2021.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Product definition : Mixture
Classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]
Flam. Liq. 3, H226 FLAMMABLE LIQUIDS
Skin Irrit. 2, H315 SKIN CORROSION/IRRITATION
Skin Sens. 1, H317 SKIN SENSITIZATION
STOT SE 3, H335 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation)
See Section 11 for more detailed information on health effects and symptoms.

2.2 Label elements

Hazard pictograms :

Signal word : Warning

Hazard statements :
Precautionary statements :
Prevention :
Hazardous ingredients :
Supplemental label elements :
Special packaging requirements
Containers to be fitted with child-
resistant fastenings :
Tactile warning of danger :
H226 - Flammable liquid and vapor.
H315 - Causes skin irritation.
H317 - May cause an allergic skin reaction.
H335 - May cause respiratory irritation.
Wear protective gloves. Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking.
hexamethylene diisocyanate, oligomerisation product (biuret type)
hexamethylene-di-isocyanate
Contains isocyanates. May produce an allergic reaction.
Not applicable.
Not applicable.

2.3 Other hazards

This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

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SECTION 2: Hazards identification

Other hazards which do not result None known.
in classification :

SECTION 3: Composition/information on ingredients

3.2 Mixtures
.

Product/ingredient name Identifiers % Regulation (EC) No. 1272/2008 [CLP] Type

hexamethylene diisocyanate,
oligomerisation product (biuret
type)
2-methoxy-1-methylethyl
acetate
xylene
ethylbenzene
hexamethylene-di-isocyanate
REACH #: 01-2119970543-34 ≥50 - ≤75 Acute Tox. 4, H332 - [1]
EC: 500-060-2 Skin Sens. 1, H317
CAS: 28182-81-2 STOT SE 3, H335
REACH #: 01-2119475791-29 ≥10 - <20 Flam. Liq. 3, H226 - [1] [2]
EC: 203-603-9 STOT SE 3, H336
CAS: 108-65-6
REACH #: 01-2119488216-32 ≥10 - ≤25 Flam. Liq. 3, H226 C [1] [2]
EC: 215-535-7 Acute Tox. 4, H312
CAS: 1330-20-7 Acute Tox. 4, H332
Index: 601-022-00-9 Skin Irrit. 2, H315
REACH #: 01-2119489370-35 ≥1 - ≤3 Flam. Liq. 2, H225 - [1] [2]
EC: 202-849-4 Acute Tox. 4, H332
CAS: 100-41-4 STOT RE 2, H373 (hearing organs)
Index: 601-023-00-4 Asp. Tox. 1, H304
REACH #: 01-2119457571-37 <0.5 Acute Tox. 4, H302 2 [1] [2]
EC: 212-485-8 Acute Tox. 1, H330
CAS: 822-06-0 Skin Irrit. 2, H315
Index: 615-011-00-1 Eye Irrit. 2, H319
Resp. Sens. 1, H334
Skin Sens. 1, H317
STOT SE 3, H335
See Section 16 for the full text of the H statements declared .
above.

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are
classified as hazardous to health or the environment and hence require reporting in this section.
Type
[1] Substance classified with a health or environmental hazard
[2] Substance with a workplace exposure limit, see section 8.
[3] Substance meets the criteria for PBT according to Regulation (EC) No. 1907/2006, Annex XIII
[4] Substance meets the criteria for vPvB according to Regulation (EC) No. 1907/2006, Annex XIII
[5] Substance of equivalent concern
[6] Additional disclosure due to company policy

SECTION 4: First aid measures

4.1 Description of first aid measures

General : In all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth
to an unconscious person.
If breathing is irregular, drowsiness, loss of consciousness or cramps: Call 112 and give immediate
treatment (first aid).
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15
minutes, occasionally lifting the upper and lower eyelids. In all cases of doubt, or when symptoms
persist, seek medical attention.
Inhalation : Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. Give nothing by
mouth. If unconscious, place in recovery position and get medical attention immediately.
Skin contact : Remove contaminated clothing and shoes. Wash skin thoroughly with soap and water or use
recognized skin cleanser. Do NOT use solvents or thinners.
Ingestion : If swallowed, seek medical advice immediately and show this container or label. Keep person warm
and at rest. Do not induce vomiting unless directed to do so by medical personnel. Lower the head so
that vomit will not re-enter the mouth and throat.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing
apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.

4.2 Most important symptoms and effects, both acute and delayed
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : May cause respiratory irritation.

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SECTION 4: First aid measures

Skin contact : Causes skin irritation. May cause an allergic skin reaction.
Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:
pain or irritation
watering
redness
Inhalation : Adverse symptoms may include the following:
respiratory tract irritation
coughing
Skin contact : Adverse symptoms may include the following:
irritation
redness
Ingestion : No specific data.

4.3 Indication of any immediate medical attention and special treatment needed
Notes to physician : If gasses have been inhaled, from the decomposition of the product, symptoms may be delayed. Treat
symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested
or inhaled.
Specific treatments : No specific treatment.

SECTION 5: Firefighting measures

5.1 Extinguishing media

Extinguishing media : Recommended: alcohol resistant foam, CO2, powders, water spray.
Not to be used: waterjet.

5.2 Special hazards arising from the substance or mixture

Hazards from the substance or Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated,
mixture : a pressure increase will occur and the container may burst, with the risk of a subsequent explosion.
Hazardous combustion products : Decomposition products may include the following materials: carbon oxides nitrogen oxides

5.3 Advice for firefighters

Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any
personal risk or without suitable training. Fire will produce dense black smoke. Exposure to decomposition products may cause a health
hazard. Cool closed containers exposed to fire with water. Do not release runoff from fire to drains or watercourses. Fire-fighters should
wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a
basic level of protection for chemical incidents.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid all direct contact with the spilled material. Exclude sources of ignition and be aware of explosion hazard. Ventilate the area. Avoid
breathing vapor or mist. Refer to protective measures listed in sections 7 and 8. No action shall be taken involving any personal risk or
without suitable training. If the product contaminates lakes, rivers, or sewers, inform the appropriate authorities in accordance with local
regulations.

6.2 Environmental precautions

Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil or air).

6.3 Methods and materials for containment and cleaning up

Stop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses,
basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local
regulations (see Section 13). Use spark-proof tools and explosion-proof equipment. Contaminated absorbent material may pose the same
hazard as the spilled product.

6.4 Reference to other sections

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SECTION 6: Accidental release measures

See Section 1 for emergency contact information.
See Section 8 for information on appropriate personal protective equipment.
See Section 13 for additional waste treatment information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Vapors are heavier than air and may spread along floors. Vapors may form explosive mixtures with air. Prevent the creation of flammable or
explosive concentrations of vapors in air and avoid vapor concentrations higher than the occupational exposure limits. In addition, the
product should be used only in areas from which all naked lights and other sources of ignition have been excluded. Electrical equipment
should be protected to the appropriate standard. To dissipate static electricity during transfer, ground drum and connect to receiving
container with bonding strap. No sparking tools should be used. Contains isocyanates. Exposure to isocyanate may result in acute irritation
and/or sensitisation when breathing.
Care should be taken when re-opening partly-used containers.

Avoid inhalation of vapour, dust and spray mist. Avoid contact with skin and eyes. Eating, drinking and smoking should be prohibited in area
where this material is handled, stored and processed. Appropriate personal protective equipment: see Section 8. Always keep in containers
made from the same material as the original one.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local regulations for flammable liquids. Store in a cool, well-ventilated area away from incompatible materials and
ignition sources. Keep out of the reach of children. Keep away from: Oxidizing agents, strong alkalis, strong acids as well as of amines,
alcohols and water. No smoking. Prevent unauthorized access. Containers that are opened must be carefully resealed and kept upright to
prevent leakage.

7.3 Specific end use(s)

See separate Product Data Sheet for recommendations or industrial sector specific solutions.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Product/ingredient name Exposure limit values

2-methoxy-1-methylethyl acetate EU OEL (Europe, 10/2019). Absorbed through skin.

STEL: 550 mg/m³ 15 minutes.
STEL: 100 ppm 15 minutes.
TWA: 275 mg/m³ 8 hours.
TWA: 50 ppm 8 hours.
xylene EU OEL (Europe, 10/2019). Absorbed through skin.
TWA: 50 ppm 8 hours.
TWA: 221 mg/m³ 8 hours.
STEL: 100 ppm 15 minutes.
STEL: 442 mg/m³ 15 minutes.
ethylbenzene EU OEL (Europe, 10/2019). Absorbed through skin.
STEL: 884 mg/m³ 15 minutes.
STEL: 200 ppm 15 minutes.
TWA: 442 mg/m³ 8 hours.
TWA: 100 ppm 8 hours.
hexamethylene-di-isocyanate EU OEL (Europe, 2/2010).
(ACGIH) TWA: 0.03 mg/m³ 8 hours.
(ACGIH) TWA: 0.01 ppm 8 hours.

Recommended monitoring procedures

If this product contains ingredients with exposure limits, personal, workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control measures and/or the necessity to use respiratory protective equipment.
Reference should be made to monitoring standards, such as the following: European Standard EN 689 (Workplace atmospheres -
Guidance for the assessment of exposure by inhalation to chemical agents for comparison with limit values and measurement strategy)
European Standard EN 14042 (Workplace atmospheres - Guide for the application and use of procedures for the assessment of exposure
to chemical and biological agents) European Standard EN 482 (Workplace atmospheres - General requirements for the performance of
procedures for the measurement of chemical agents) Reference to national guidance documents for methods for the determination of
hazardous substances will also be required.
Derived effect levels

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SECTION 8: Exposure controls/personal protection

Product/ingredient name Type Exposure Value Population Effects

2-methoxy-1-methylethyl acetate DNEL Long term Dermal 796 mg/kg Workers Systemic
DNEL Long term Inhalation 275 mg/m³ Workers Systemic
xylene DNEL Long term Inhalation 77 mg/m³ Workers Systemic
DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
ethylbenzene DNEL Long term Dermal 180 mg/kg bw/day Workers Systemic
DNEL Long term Inhalation 77 mg/m³ Workers Systemic
hexamethylene-di-isocyanate DNEL Long term Inhalation 0.035 mg/m³ Workers Systemic
Predicted effect concentrations
Product/ingredient name Compartment Detail Value Method Detail
xylene Fresh water 0.327 mg/l -
Marine water 0.327 mg/l -
Fresh water sediment 12.46 mg/kg -
Marine water sediment 12.46 mg/kg -
Soil 2.31 mg/kg -
Sewage Treatment Plant 6.68 mg/l -
ethylbenzene Fresh water 0.1 mg/l -
Marine water 0.01 mg/l -
Sewage Treatment Plant 9.6 mg/l -
Fresh water sediment 13.7 mg/kg -
Soil 2.68 mg/kg -
hexamethylene-di-isocyanate Fresh water 77.4 µg/l -
Marine 7.74 µg/l -
Fresh water sediment 13.34 mg/kg -
Marine water sediment 1.33 mg/kg -
Soil 2.6 mg/kg -
Sewage Treatment Plant 8.42 mg/l -

8.2 Exposure controls

Appropriate engineering controls
Arrange sufficient ventilation by local exhaust ventilation and good general ventilation to keep the airborne concentrations of vapors or dust
lowest possible and below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-
station location.
Individual protection measures
General : Gloves must be worn for all work that may result in soiling. Apron/coveralls/protective clothing must be
worn when soiling is so great that regular work clothes do not adequately protect skin against contact
with the product. Safety eyewear should be used when there is a likelihood of exposure.

Hygiene measures : Wash hands, forearms, and face thoroughly after handling compounds and before eating, smoking,
using lavatory, and at the end of day.
Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk assessment
indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is
possible, the following protection should be worn, unless the assessment indicates a higher degree of
protection: chemical splash goggles.
Hand protection : Wear chemical-resistant gloves (tested to EN374) in combination with 'basic' employee training. The
quality of the chemical-resistant protective gloves must be chosen as a function of the specific
workplace concentrations and quantity of hazardous substances.
Since the actual work situation is unknown. Supplier of gloves should be contacted in order to find the
appropriate type. Below listed glove(s) should be regarded as generic advice:

Recommended: Silver Shield / Barrier / 4H gloves, polyvinyl alcohol (PVA), Viton®

May be used: nitrile rubber, butyl rubber
Short term exposure: neoprene rubber, natural rubber (latex), polyvinyl chloride (PVC)

Body protection :
Respiratory protection :
Personal protective equipment for the body should be selected based on the task being performed and
the risks involved handling this product.
Wear suitable protective clothing. Always wear protective clothing when spraying.
Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk
assessment indicates this is necessary. Respirator selection must be based on known or anticipated
exposure levels, the hazards of the product and the safe working limits of the selected respirator. If
working areas have insufficient ventilation: When the product is applied by means that will not generate
an aerosol such as, brush or roller wear half or totally covering mask equipped with gas filter of type A,
when grinding use particle filter of type P. Be sure to use an approved/certified respirator or equivalent.
Dry sanding, flame cutting and/or welding of the dry paint film will give rise to dust and/or hazardous
fumes. Wet sanding/flatting should be used wherever possible. If exposure cannot be avoided by the

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SECTION 8: Exposure controls/personal protection

provision of local exhaust ventilation, suitable respiratory protective equipment should be used.
Environmental exposure controls
Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental
protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to
reduce emissions to acceptable levels.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Physical state : Liquid.
Color : Transparent
Odor : Solvent-like
pH : Testing not relevant or not possible due to nature of the product.
Melting point/freezing point : -39.85°C This is based on data for the following ingredient: hexamethylene diisocyanate,
oligomerisation product (biuret type)
Boiling point/boiling range : Testing not relevant or not possible due to nature of the product.
Flash point : Closed cup: 40°C (104°F)
Evaporation rate : Testing not relevant or not possible due to nature of the product.
Flammability : Highly flammable in the presence of the following materials or conditions: open flames, sparks and
static discharge and heat.
Lower and upper explosive 0.8 - 7 vol %
(flammable) limits :
Vapor pressure : 0 kPa This is based on data for the following ingredient: hexamethylene diisocyanate, oligomerisation
product (biuret type)
Vapor density : Testing not relevant or not possible due to nature of the product.
Specific gravity : 1.07 g/cm³
Solubility(ies) : Very slightly soluble in the following materials: cold water and hot water.
Partition coefficient (LogKow) : Testing not relevant or not possible due to nature of the product.
Auto-ignition temperature : Lowest known value: 333°C (631.4°F) (2-methoxy-1-methylethyl acetate).
Decomposition temperature : Testing not relevant or not possible due to nature of the product.
Viscosity : Aspiration hazard (H304) Not classified. Testing not relevant due to nature of the product.
Explosive properties : Testing not relevant or not possible due to nature of the product.
Oxidizing properties : Testing not relevant or not possible due to nature of the product.

9.2 Other information

Solvent(s) % by weight : Weighted average: 25 %
Water % by weight : Weighted average: 0 %
VOC content : 269 g/l
TOC Content : Weighted average: 195 g/l
Solvent Gas : Weighted average: 0.055 m³/l

SECTION 10: Stability and reactivity

10.1 Reactivity
No specific test data related to reactivity available for this product or its ingredients.

10.2 Chemical stability

The product is stable.

10.3 Possibility of hazardous reactions

Under normal conditions of storage and use, hazardous reactions will not occur.

10.4 Conditions to avoid

Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat
or sources of ignition.

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SECTION 10: Stability and reactivity

10.5 Incompatible materials

Highly reactive or incompatible with the following materials: oxidizing materials.
Reactive or incompatible with the following materials: reducing materials.

10.6 Hazardous decomposition products

When exposed to high temperatures (i.e. in case of fire) harmful decomposition products may be formed:
Decomposition products may include the following materials: carbon oxides nitrogen oxides

SECTION 11: Toxicological information

11.1 Information on hazard classes as defined in Regulation (EC) No 1272/2008

Exposure to component solvent vapor concentrations may result in adverse health effects such as mucous membrane and respiratory
system irritation and adverse effects on the kidneys, liver and central nervous system. Solvents may cause some of the above effects by
absorption through the skin. Symptoms and signs include headaches, dizziness, fatigue, muscular weakness, drowsiness and, in extreme
cases, loss of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin, resulting
in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause irritation and reversible
damage. Accidental swallowing may cause stomach pain. Chemical lung inflammation may occur if the product is taken into the lungs via
vomiting.
Isocyanate containing products have characteristics that include producing acute irritation and/or sensitisation when breathing, subsequent
asthmatic problems and lung contractions. Sensitised people can, as a result from this, show asthmatic symptoms with exposure to
atmospheric concentrations far below the TLV. Repeated exposures will lead to permanent damage to the respiratory system.
Acute toxicity
Product/ingredient name Result Species Dose Exposure
hexamethylene diisocyanate, LC50 Inhalation Dusts and mists Rat 18500 mg/m³ 1 hours
oligomerisation product (biuret type)
2-methoxy-1-methylethyl acetate LD50 Dermal Rabbit >5 g/kg -
LD50 Oral Rat 8532 mg/kg -
xylene LC50 Inhalation Gas. Rat 5000 ppm 4 hours
LC50 Inhalation Vapor Rat 6350 ppm 4 hours
LD50 Dermal Rabbit >4200 mg/kg -
LD50 Oral Rat 3523 mg/kg -
ethylbenzene LD50 Dermal Rabbit >5000 mg/kg -
LD50 Oral Rat 3500 mg/kg -
hexamethylene-di-isocyanate LC50 Inhalation Dusts and mists Rat 124 mg/m³ 4 hours
LC50 Inhalation Vapor Rat 0.124 mg/l 4 hours
LD50 Dermal Rabbit >7000 mg/kg -
LD50 Oral Rat 746 mg/kg -
Acute toxicity estimates
Product/ingredient name Oral Dermal Inhalation Inhalation Inhalation
mg/kg mg/kg (gases) (vapors) (dusts and
ppm mg/l mists)
mg/l
Hempel's Curing Agent 95370 12141.8 55190.2 26.7 7
hexamethylene diisocyanate, oligomerisation product 4.625
(biuret type)
2-methoxy-1-methylethyl acetate 8532
xylene 3523 1100 5000
ethylbenzene 3500 11
hexamethylene-di-isocyanate 746 0.124
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure
hexamethylene diisocyanate, Skin - Mild irritant Rabbit - -
oligomerisation product (biuret type)
Eyes - Mild irritant Rabbit - -
Respiratory - Mild irritant Rabbit - -
2-methoxy-1-methylethyl acetate Respiratory - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
xylene Eyes - Severe irritant Rabbit - 24 hours 5 milligrams
Skin - Moderate irritant Rabbit - 24 hours 500 milligrams
Skin - Irritant Rabbit - -
ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 milligrams
Respiratory - Mild irritant Rabbit - -
Eyes - Mild irritant Rabbit - -
hexamethylene-di-isocyanate Skin - Severe irritant Rabbit - -
Eyes - Severe irritant Rabbit - -

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SECTION 11: Toxicological information

Respiratory - Severe irritant Rabbit - -
Sensitizer
Product/ingredient name Route of exposure Species Result
hexamethylene diisocyanate, skin Guinea pig Sensitizing
oligomerisation product (biuret type)
hexamethylene-di-isocyanate skin Guinea pig Sensitizing
Mutagenic effects
No known significant effects or critical hazards.

Carcinogenicity
No known significant effects or critical hazards.

Reproductive toxicity
No known significant effects or critical hazards.

Teratogenic effects
No known significant effects or critical hazards.

Specific target organ toxicity (single exposure)

Product/ingredient name Category Route of exposure Target organs
hexamethylene diisocyanate, oligomerisation product Category 3 Respiratory tract irritation
(biuret type)
2-methoxy-1-methylethyl acetate Category 3 Narcotic effects
Specific target organ toxicity (repeated exposure)
Product/ingredient name Category Route of exposure Target organs
ethylbenzene Category 2 - hearing organs

Aspiration hazard
Product/ingredient name Result
ethylbenzene ASPIRATION HAZARD - Category 1

Information on the likely routes of exposure

Routes of entry anticipated: Oral, Dermal, Inhalation.
Potential chronic health effects
Sensitization : Contains hexamethylene diisocyanate, oligomerisation product (biuret type), hexamethylene-di-
isocyanate. May produce an allergic reaction.
11.2 Information on other hazards
Endocrine disrupting properties : No known data avaliable in our database.
Other information : No additional known significant effects or critical hazards.

SECTION 12: Ecological information

12.1 Toxicity
Do not allow to enter drains or watercourses.
Product/ingredient name Result Species Exposure
hexamethylene diisocyanate, Acute EC50 >100 mg/l Algae 72 hours
oligomerisation product (biuret type)
2-methoxy-1-methylethyl acetate Acute LC50 100 - 180 mg/l Fish 96 hours
ethylbenzene Chronic NOEC <1000 µg/l Fresh water Algae - Pseudokirchneriella subcapitata 96 hours

12.2 Persistence and degradability

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SECTION 12: Ecological information

Product/ingredient name Test Result Dose Inoculum

hexamethylene diisocyanate,
oligomerisation product (biuret type)
2-methoxy-1-methylethyl acetate
xylene
ethylbenzene
hexamethylene-di-isocyanate
- 1 % - Not readily - 28 days - -
OECD 301F Ready 90 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
OECD 301F Ready 83 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
OECD 301F Ready 90 - 98 % - Readily - 28 days - -
Biodegradability - Manometric
Respirometry Test
- >60 % - Readily - 28 days - -
- >70 % - Readily - 28 days - -
- 42 % - Not readily - 28 days - -

Product/ingredient name Aquatic half-life Photolysis Biodegradability

hexamethylene diisocyanate,
oligomerisation product (biuret type)
2-methoxy-1-methylethyl acetate
xylene
ethylbenzene
hexamethylene-di-isocyanate
- - Not readily
- - Readily
- - Readily
- - Readily
- - Not readily

12.3 Bioaccumulative potential

Product/ingredient name LogPow BCF Potential
hexamethylene diisocyanate, oligomerisation product (biuret type) 5.54 - high
2-methoxy-1-methylethyl acetate 1.2 - low
xylene 3.12 8.1 - 25.9 low
ethylbenzene 3.6 - low
hexamethylene-di-isocyanate 0.02 57.63 low

12.4 Mobility in soil

Soil/water partition coefficient No known data avaliable in our database.
(KOC) :
Mobility : No known data avaliable in our database.

12.5 Results of PBT and vPvB assessment

Product/ingredient name PBT P B T vPvB vP vB
This mixture does not contain any substances that are assessed to be a PBT or a vPvB.

12.6 Endocrine disrupting properties

No known data avaliable in our database.
12.7 Other adverse effects
No known significant effects or critical hazards.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

The generation of waste should be avoided or minimized wherever possible. Residues of the product is listed as hazardous waste. Dispose
of according to all state and local applicable regulations. Waste should not be disposed of untreated to the sewer unless fully compliant with
the requirements of all authorities with jurisdiction. Spillage, remains, discarded clothes and similar should be discarded in a fireproof
container.
European waste catalogue no. (EWC) is given below.
European waste catalogue (EWC) : 08 01 11*
Packaging
The generation of waste should be avoided or minimized wherever possible. Waste packaging should be recycled. Incineration or landfill
should only be considered when recycling is not feasible.

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SECTION 14: Transport information

Transport may take place according to national regulation or ADR for transport by road, RID for transport by train, IMDG for transport by
sea, IATA for transport by air.
14.1 14.2 14.3 14.4 14.5
UN / ID no. Proper shipping name Transport hazard class(es) PG* Env* Additional information

ADR/RID UN1263 PAINT 3 III No. Tunnel code (D/E)

Class

IMDG UN1263 PAINT 3 III No. Emergency schedules

Class F-E, S-E

IATA UN1263 PAINT 3 III No. -

Class

PG* : Packing group

Env.* : Environmental hazards

14.6 Special precautions for user

Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the
product know what to do in the event of an accident or spillage.
14.7 Maritime transport in bulk according to IMO instruments
Not applicable.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
EU Regulation (EC) No. 1907/2006 (REACH) Annex XIV - List of substances subject to authorization - Substances of very high concern
Annex XIV
None of the components are listed.
Substances of very high concern
None of the components are listed.
Annex XVII - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, mixtures and articles
As from 24 August 2023 adequate training is required before industrial or professional use.
Other EU regulations
Seveso category This product is controlled under the Seveso III Directive.
Seveso category
P5c: Flammable liquids 2 and 3 not falling under P5a or P5b

15.2 Chemical Safety Assessment

Yes.

SECTION 16: Other information

Abbreviations and acronyms : ATE = Acute Toxicity Estimate
CLP = Classification, Labelling and Packaging Regulation [Regulation (EC) No. 1272/2008]
EUH statement = CLP-specific Hazard statement
RRN = REACH Registration Number
DNEL = Derived No Effect Level
PNEC = Predicted No Effect Concentration
Full text of abbreviated H statements : H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H319 Causes serious eye irritation.
H330 Fatal if inhaled.
H332 Harmful if inhaled.

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Safety Data Sheet
Hempel's Curing Agent 95370

SECTION 16: Other information

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
Full text of classifications [CLP/GHS] : Acute Tox. 1 ACUTE TOXICITY - Category 1
Acute Tox. 4 ACUTE TOXICITY - Category 4
Asp. Tox. 1 ASPIRATION HAZARD - Category 1
Eye Irrit. 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2
Flam. Liq. 2 FLAMMABLE LIQUIDS - Category 2
Flam. Liq. 3 FLAMMABLE LIQUIDS - Category 3
Resp. Sens. 1 RESPIRATORY SENSITIZATION - Category 1
Skin Irrit. 2 SKIN CORROSION/IRRITATION - Category 2
Skin Sens. 1 SKIN SENSITIZATION - Category 1
STOT RE 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2
STOT SE 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 3
Procedure used to derive the classification according to Regulation (EC) No. 1272/2008 [CLP/GHS]

Classification Justification
FLAMMABLE LIQUIDS On basis of test data
SKIN CORROSION/IRRITATION Calculation method
SKIN SENSITIZATION Calculation method
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) Calculation method

Notice to reader
Indicates information that has changed from previously issued version.
The information contained in this safety data sheet is based on the present state of knowledge and EU and national legislation. It provides
guidance on health, safety and environmental aspects for handling the product in a safe way and should not be construed as any guarantee
of the technical preformance or suitability for particular applications.
It is always the duty of the user/employer to ascertain that the work is planned and carried out in accordance with the national regulations.

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Safe Use of Mixture Information
Hempel's Curing Agent 95370

This document is intended to communicate the conditions of safe use for the product and should always be read in combination with the
product's Safety Data Sheet and labels.
General description of the process covered
Indoor or outdoor spray painting by professionals or with brush, roller, putty knife, dipping etc. with good general room ventilation
This safe use information is : Professional spray painting and/or low-energy painting, local effect - Level II
linked to Skin Sens. 1, Eye Irrit. 2 , Asp. Tox. 1 or Solvent.
Sector(s) of use : Industrial uses - Professional uses
Product category(ies) : Coatings and paints, thinners, paint removers

Operational conditions
Place of use : Indoor or outdoor use

Risk management measures (RMM)

Contributing Process Maximum Ventilation Respiratory Eye Hands
activity category duration
(ies) Type and air changes per
hour
Preparation of material for PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
application hours ventilation - Outdoors according to EN 166. tested to EN374.

Loading of application PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
equipment and handling hours ventilation - Outdoors according to EN 166. tested to EN374.
of coated parts before
curing

Professional application of PROC10 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
coatings by brush or roller hours ventilation - Outdoors according to EN 166. tested to EN374.

Professional application of PROC11 More than 4 Good general room 3-5 Wear a respirator Use eye protection Wear suitable gloves
coatings by spraying hours ventilation - Outdoors conforming to EN140 with according to EN 166. tested to EN374.
an assigned protection
factor of at least 10.

Film formation - force PROC04 More than 4 Good general room 3-5 None None None
drying, stoving and other hours ventilation - Outdoors
technologies

Cleaning PROC05 More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation - Outdoors according to EN 166. tested to EN374.

Waste management PROC08a More than 4 Good general room 3-5 None Use eye protection Wear suitable gloves
hours ventilation - Outdoors according to EN 166. tested to EN374.
See chapter 8 of this Safety Data Sheet for specifications.

The information in this Safe Use of Mixture Information (SUMI) sheet is based on the data provided by the substance supplier for the substances in the product for which a chemical safety
assessment has been carried out at the time of issue. It does not guarantee safe use of the product and does not replace any occupational risk assessment required by legislation. When developing
workplace instructions for employees, SUMI sheets should always be considered in combination with the Safety Data Sheet (SDS) and the label of the product.
No liability is accepted for any damage, no matter of what kind, which is a direct or indirect consequence of acts and/or decisions based on the contents of this document.
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