Toe os AMITY INTERNATIONAL SCHOOL SECTOR-46,GURGAON Session 2023-24 SYNCHRO TERM ASSESSMENT CLASS-XIL CHEMISTRY ‘Yop HRS MM-70 CP ORAL INSTRUCTIONS: Roo tie following instructions carefully. | wore are 33 questions in this question paper with internal choice. >< citon A having Q. No. 1 to 16 are very short answer questions carrying Imarks each. {ction B havingQ. No. 17 to 21 are short answer questions carrying 2 marks each. 4 Scotion C having Q. No. 22 to 28 are,short answer questions carrying 3 marks cach. 5 soccion D having.Q. No. 29-30are case based question carrying 4 marks. 6. © tion E- having Q. No. 31 to 33 are long answer questions carrying 5 marks each. of log tables and calculators is not allowed SECTION A ©). ‘onsidering the formation, breaking and strength of hydrogen bond, predict which of the following mixture w: show positive deviation from Raoult? s law? J ‘scthanol and acetone (b) Chloroform and acetone (c) Jute acid and water (d) Phenol and aniline @ Aa upc mage pled in Goncalves ee on (4. « cains water due to osmosis. (b) it loses: aad (© 4 cains water due to reverse osmosis {¢) it loses water due to osmosis: 7 ©) correct statement about colligative properties (‘sey are independent of nature of solute (0) (oversely proportional to molecular mass of solute (© ?oportional to concentration of solute endent of amount of solvent (@) indy \: a given temperature, osmotic pressure of a concentrated solution of a substance is higher than that at a dilute solution, is lower than that of a dilute solution. is same as that of a dilute solution. » cannot be compared with osmotic pressure of dilute solution. @ n solvation of ions present in solution. ‘with temperature,Q8. Which'one of the following has the highest dipole moment? (a)CH:Ck (6) CHCh (6) CCh (a) CH Q9. CHsCH20H can be converted into CHsCHO by {a) catalytic hydrogenation (b) treatment yrith LiAIHs (©) treatineht with pyridinium chlorochromate (d) treatment with KMnO« Q10. The process of converting alkyl halides into alcohols involves (a) addition reaction (b) substitution reaction (c) dehydrohalogenation reaction (d) rearrangement reaction Q11. In Clemmensen reduetion carbonyl compound is treated with (a) zinc amalgam + HCI (b) sodium amalgam + HCI (©) zine amalgam + nitric acid (d) sodium amalgam + HNOs Q12, The gas evolved when methylamine reacts with nitrous acid is . <4NH3 (b)N2 ()H2 — (d) GH Assertion and Reason Type Questions In the following questions, a statement of Assertion (A) followed by a statement of Reason (R) is given. Choose tt correct answer out of the following choices: (a) Assertion and Reason both are correct and Reason is the correct explanation of Assertion. (b) Both Assertion and Reason are correct but Reason is not the correct explanation of Assertion. (c) Assertion is correct but Reason is wrong, (@ Assertion is wrong but Reason is correct. Q13. Assertion (A): p-Nitrophenol is more acidic than phenol. ‘Reason (R): Nitro group helps in the stabilization of the phenoxide ion by dispersal of negative charge due resonance, ——— (A): The a -hydrogen atom in carbonyl compounds is less acidic. 7 Reason (R): The anion formed after the loss of a -hydrogen atom in carbonyl compounds is resonance stabilised QI5. Assertion (A): Aldehydes and ketones, both react with Tollen’s reagent toform silver mirror Reason (R): Both, aldehydes and ketones contain a carbonyl group. — Q16. Assertion (A): Hofmann’s bromamide reaction is given by amides. Reason (R): Primary amines are more basic than secondary amines. SECTION B (Q17. What happens when: @ N-ethylethanamine reacts with benzene sulphonyl chloride. b, Benzylchloride is treated with ammonia followed by the reaction with Chloromethane. QI8.Concentrated nitric acid used in the laboratory work is 68% nitric acid by mass in aqueous solution. What sho be the molarity of such a sample of acid if the density of the solution is 1504 g mL"! ? R= 0,083 L bar mol" K* : OR 200 cm’ of an aqueous solution of a protein contains 1.26 g of the protein. The osmotic pressure of such a solution : 300 K is found to be 2.57 x 10° bar. Calculate the molar mass of the protein. uit cats seesQ27. Predict the Products of the following reactions; ¥ WOH, “CH, ~ CH, -0-CH + HBr > OCH, is wy + HBr —> OCH, “* Cone. 1.80, Cone. HNO” 0 CNH, * CHG, + ale.KoH , 1) CoHSNSCl+Hi,Po, 104 (0) CHLCH Br i, tp Roe Q29. It is an el imical cell that uses spontan Connects to the half cells The reading of the Vo ir Ren 4s positive, the reaction is SPontaneous and if, it is negative, to as electrolytic cell. Electrolysis Tefers to the decomposition Of substanc electric charge when passed through « cell will discharge half, The net Fey interme is, arate acid catalyst model syere, system have been c| i thoroughly of their electrical conductivity. Thus Specific and molar conductivities have been obtained Systems combining alkali Pyrosulfates, alkali Pyrosulfates and V20s, alkali Pyrosulfares in addition to alkali hydrogen sulfates, @ ich gi @w it olga electricity. A sat edge also tage or cell Potential or electromotive ‘fore and alkali* Zn cH,coCc © cere X 2Cr°* + 7H20 What is the quantity of electricity in coulombs needed to reduce 1 mol of CO? OR (i) How much charge is required for the following reductions: (a) 1 mol of AP* to Al? (b) 1 mol of Cu** to Cu? (¢) 1 mol of MnO« to Mn"? (iiPredict the produets of electrolysis in each of the (a) An aqueous solution of “NO: with silver (b) An aqueous solution of “®S°: with plat b) Propanone to propene c) Benzene to m-Nit op