Xumux O. B. Murseuna, spay B. J. Teperroesa Ma Vucturyra o6uteit u KommynampHoi rurueu AMH CCCP B npakrue poguux 2aGopatopili 20 nactomutero BpeMenim ayuIUMM MeTOLOM ompe- menenHa IKECTKOCTHH BO CUNTANCA MANbMHTATHEI MeTOR, OAHAKO OH HMeCT PsA HeNO- crarkos: pactsopyi NaabMuTata He o¥eHs cTOMKH, Koen THTpoBaHHa pacnmunuar, Teneps mpenaoxen MeTO OMPexeneHi 2eCTKOCTH BORK MPH MoMOULM TpHIOHA B. ‘Tpuaon B nipectasaner coof AsyHarpuesyio comb STHIeHAHAMUHTeTpAyKcyCHOM KiKC- gor; € MOHAMH ABYXBANeHTHEIX MeTa/IJ0B, B YACTHOCTH, c HOHAMM Kansilin HM MarHH ‘puaon B oOpasyer BecbMa mpountie Kommtexce. Onpexenetve eCTKOCTH BOMB TPOHSBO- urea enocpenctsentio THrposanuem mpoGu Bom (npx pH~10) pactaopom tpHzoHa B Onpemeneiioh Kpentoctn c MpuMeveHwem B KaecThe MMAUKaTopa KPachTelA spuoxpoMuep- mu, Sfor HHANKATOP act C_MOHAMM MarHHs KOMMeKcHOe COeAHHEHHe, OKpauIuDaR AHA octs B BuHHOKpacuuit Wer. [pu TurpoBanu TpuxoHoM B pactsopa, comepacamlero Wout Kamina H Marina, peakWii Wer ckavana c MOHaMM KambuNa, a SaTem Marius, Korda bce KATHOHLE KANLIMT M MArHUs BORLYT B KOMMeKc C STHACHAKAMHNTETPAYKCYCHOR KHCTO- ‘Tol, wet pacrBopa 113 BHHHOKpacoro cranosrea roay6uM. he 'B taba. 1 Me MPHBORNM CPABHTeAbHBLe Lae ONPeLeneHNA 2KeCTKOCTH BOM MO economy MeToRy Hc TpHaoHoM B. Ta6nunal Cpannene apyx meToos ompexenenua 2KecTKOCTH BORE 2KecrKoct» , onpe- Hata Menennaa ‘BIATHA Mecto s3ataa mpo6ut mpo6st neconum | 10 tpi: meroxom | 1ony B 3o/vil_ | Oxa wume Tpy6exa .. .. . 13,2° | 13,2° 29/1X Tay mejihixtia ces] NO MP ALT AO, 1 17/X ; eather 9,13° | 9,24" 15/1X | Oxa y Pasa... 2. ~~] 12,1° 11,9° 30/X1 Maumee afew as bs fe BAS |: 616" p 1gjvitt | Boara y r.Kaanunna. ....| 52° | 5,32° 23/1X Ta ae yo se PO 30/X Sa ii he Sead a alts 28 OS th A6tdas 26/IX | Tnepua y cera Meanoe....| 4,47° | 4,34° 10/VII_ | TIpona y aepenun Buono . . | 15,8° | 15,68° 1 Kak creayer 3 mpescTastenmMix RaHHBIX, PacxOweNA MEXY PesyabTaTAMM, NOMy- MeHHBIMH STHMHE ABYMS MeTORAMH, COBCeM HesiawNTenbuts. Tipit aitasnse MpHpomtx BOA HepeaKO MpHXOANTCA uMeTh Ae10 ¢ BORAMH BHICOKOA userioctn u MytHocti, Kax oxastinawr naniBte Ta6x. 2, UBeTHOCTe 20 120° He OrpaxKa- wach Ha pesymbTATAx OnpeneneHHA XKeCTKOCTH BORE B orlenbunix mpoOaX Mu UccnenORAMH BAWSHMe B3BeMIeHNEX BeuIecTs Ha TOWHOCTS onpexenenust 2kecTKOCTH TIpH MOMOMLM TpHaOHa B. C stof wen B MOGs Boa BBOAWAH KpeMiesem B KosMecTBe NO 1 T/m; HecMOTPH Ha SHAWHTeNDHyI MyTHOCTL BOL, MOMENT OKOWaHHA THTPORAHUA He MIMeHAICH H OBI XOcTaTO¥NO YeTOK. TpiioH B Moxer Guth ¢ yerexom HcnombsonaH B SKCeANMOHHBIX YCTOBMAX, TAK KaK SHAUMTeMDHOe OXnaxKAeHNE, KoTopoe HeusGexHO Mp padoTaX B SHMHNX SKCTCAMLHONMEX YCLOBUAX, He OTPArKaNocs Ha timpe. He o6napyxisaxocs take OTKOHeNKi PK THTpOBAHMM MIpOG BORH, KOHCepSEpO- Battunix xaopotbopuom. B nacrosuee apewa Taanxnmpeaxrusom suinyntex Aan npoxarkn HaGop peaxrHnon AAA onpenerenun 2eCTKOCTH BOK; B STOM HaGope UMeeTcR TpHAOH BM TPH pasaHuNEX MIMNKaTOpa, OK 43 KOTOPHX 3pHoxpomuepHul K waGopy peaxTuBoB MpHAOKeHa ue 42‘erpyrams, 8 KoTopoit aerem onucanMe npurorosenna peaxrHBop H XOM axanutsa. OanaKo B HBMOKeHUM uMelOTeR HescHOcTH M HeTAAH, HBANIMNE TIDH MpoBeeUNN caHHTApHAX anaansoi Hike mi mpwsoaua suepxky 43 MHCTPYKUKH —MpHMeHHTeABHO K OnpenenemHO 2KCTKOCTH MPH callHTapHOM alfatuse M ae PeKOMeHAAMUT 1O NPHGAU-xKeHHOMy OmpeRe- HHO KECTKOCTH, TaGanna 2 Onpereseume 2xecTKocTH AByMs MeTORaMM B NpoGax BoAM pasaMuHOH YBeTHOCTH Kectkocth, Mara onpezezentan santa | Mecro nsatun mpo6u | Linetuoers | mpoout Becosum | no 1pHxony ‘MeTONOM: B 10/VII_| Tlpous y xepenun Buxoso| 10° 15,8° 15,68" “got | Oxa y Pasa... 70° 6,1" 6,16° 31/VIML| Boara yr. Kaanunna 100° 5,91° 59° 26/IX | Tepua y cea Meauoe 120° 4,47° 4,34° Peaxrusu. _ 1. Turponanmut pacrsop rpizoua B. ‘2. Ammuauneii Gycbepaeil pacrsop. * 3. Pacrsop nxaukatopa, : Bce peaxrusii rorossr Ha ABaKAM NeperHanHoR AecTHAAHpORAHHON BORE. Zlaa npurorosmeaus 0,1 x. pactsopa Tpiiona B orseumupaior wa avaawTiveckux ne- sax owio 18,613 r tpuzoa B, Hasecky pactnopsior B aurponof KonGe yectHamuponal- Hof wozofi (eau pactBop noxysuzes: MyTHBIf, ero OTHbissTpOBEIBAIOT), H ROBOART MO METKH. ‘Turp pactsopa yerofiuns u He MenseTcs n TeveHHe HeCKONBKHX Mecaen. Xpansr 0,1 H. pac ‘Top TpHAOHa B 8 cKMAHKe ¢ MpHTepToi npobKol. Amauaunsi Gydhepitii pacrsop rorosat nyrem cmeumeanna 100 x 20% pactsopa XuMMeCKH wHCTOrO XAOpHCTOTO aMMoHus co 100 ma 20% pactRopa XHMHYecKH sHCTOTO ammuaka, nocie vero cMec AOBOAAT NO THTpa AecTHAAMPOBAHHOA BORO! Pactsop unauxaropa noayyaior pacrsopexvem 0,5 7 spHoxpomuepHoro B 10 Ma axe Muaunoro Gycbeporo pactsopa m Aosereniem x10 100 ma stastoBKM cnuprom. Jaa yera- wopku turpa 0,1 x. pactsopa tpuzoHa B noasayiores pacrsopamu xnopuctoro Kaabii H cepyoKnenoro Marni. 0,1 #. pacrsop XHopHeroro Kaxbuna npHrorasausawr crenyiouum oGpasom. Ha ana- amrmueckux Becax OTseulMBaior TOW 5,005 r XUMUMecKH wucTOrO yraeKHeNOTO Kambitiia, RpexBapHrenbHo noxcyulenHoro 8 Tevenme vaca pu 110° w cyumaKHoM uIKaby m Oxnax. RewHoro 8 9KCHKaTOpe Han MpoKasennum XAOpucTHM Kamien. Hanecky Mepenonat 8 Jnurposyio Kon6y, KyAa noGananor 5—9 Ma KoxweHTpuposannof coniiof KucaOTH (Kena enero wenvute)’ Ww noche oKoraMin peau OcraTKH YETeRHcTOro. Kamla OCTopONNO pactsopsior, mpHOanaaa KHCTOTY NO KarinaM m KaxKARH pas OXWAA NpeKpamenus Bune: Zeit nysuipbKos AByoKucn yraepona, To okoHYaHHM Pacrsopeniin >KUAKOCTs B KONG Rowoxar NO MeTKH jecTHANpOBAHHON BOO H xOpomlo mepemeuuBai0T. Tipurorosaenue 0,1 H. pactsopa cepHOKHcoro MarHHa MpousnonsT nytem oTaeWH- Bawa Ha aviamuruueckux Becax TouHo 12,325 r XHMMMeCKH WHCTOTO CeMHBORHOTO. Cy:tb- ara MarHHs MH PACTBOPEHMR ero B AECTHATHPOBAHHOM BOTe B MepHOil wHTpORO! KOAGe. M KWAKOCTH AOBOART 0 METKH H XOPOUIO epeMemuBaioT. Comm CepHOKHeHOrO Maria HOMKHa GuITp NepexpyeTaransonana HAM MpOBepeHa na COReprKanNe KpHcTarmaanHOHHOR Bose, Tak Kak MpH Xpanienun OHa sterxo OGesboxuBaeTes. Konentpanio 0,1 H. pac- ‘TBOPA CePHOKHCIOTO MarHHs XeAATeTHO MpOHepHT BECOBLIM HIN IHRM croco6OM. Hs 0,1 i. pactsopa comm Kamut m 0,1 H. pactsopa comm MarHHm TOTOBRT cMece, ans wero Gepyt 75 Ma Kambumesoro pacrsopa H 25 Ma” MarHHeBOrO PacTaopa 1 NOBOAAT xo 1 x. Jax yerauonku turpa tpuaoHa B otGupaior 100 ma céecn pactsopa Kambunenoh HM MarnHesoh Coan B KOHHUeCKyIO KonGy Ha 250—300 Ma, TpHOanamioT 5 Ns aMMuaaHoro Gydepuoro pactsopa, 5 Kanen» muaHKaTopa H MexeHHO NpHABaioT us GroperKH pactBop tpuHaoHa B npw uiTeHcHaHoM NOMeMIMBaHH Xo HBMeHeHHA BMHHOKPacHoro WBeTa, B TOAy- Goh. Tax Buncnenna nonpasowHoro KOsibuINeHTa NMcTO MHAZIHANTPOR CMeCH yMeHBILaIOT 8 10 pas (cmecs 0,01 u.) u meas Ha uNcHO © MAnHAKTpoB TpHnONa B, noweauux wa ‘Tiirponaune. Tlepea tavaom aazisa xexateabio HMeTS OpHeHTHpOBOWHEE CBENeHHsA O 2KECTKO- ‘TH HcHLITYeMO!t BORH, AA Nero MO:HO PeKOMEHROBATS MpoCToe H cKOpOe KavecTReHHOe conpererenne 2KectkocTi mpm noMoU TponeomMia 00. B sapHcHMoctm OT cremeuH aKecT- KOCTH BOAM At aHlasiHsa GepyT pasaNyHoe KOsMYeCTHO HeMATYeMOR Bom (TaGA. 3) H AO- soust 20 o6zema 8 100 ma ecruaauponaHHolt Bons. 43K 100 ma turpyemof Boas npHGasanior 5 ma aMMnayncro 6ytbepnoro pactsope, 5 Kaneas | MHANKaTOpa H MenTeHHO Mpuausalor 13 Gloperku 0,1 #, pactsop Tpxzona B HO MOYNeHHA ToGo! OKpacki. ‘Yeo muxaaiteTpos TpHaoHa B, MowexuMx Ha THTpORAHWe HemEITYeMOf BOA, YMHO- 2aloT Ha TonpasowNDA KOSbuNMeHT H Ha PasRexeHMe, ecaM OHO HMesIO MecTO; TaK Kak karan MustauTp To¥KOTO 0,1 H. pacTBopa TpHzoHa B pasex 0,1 or, nonyNenioe aHcTe TaGaunua3 PasGanaeune pu pasawuuoli xectxocra KoamyeciBo Bo- 2Kecrxocrs | abt aaa anaausa (5 Ma) 5 14-14" 100 14-30" 50 30— 56° 25 56—140° 10 MuAAMAUTPOB, MOMERUIe Ha THTPoBaHHe 100 sa xucmITyeMOM ORK (nocre BHECeHKs NlonpaBoK), slaer ®ECTKOCT BOAKL B MI/9KB; YMHOAKeHHeM Ha 28 nomywaem 2%ecTKOCTS B rpaaycax. pee Onpeenente KeCTKOCTH npit MOMOM Tprona B TpeGyer cero HecKombKN MHEyT, Mpocro H AOCTYMHo ManOOMUTHLIM paGoTHHKaM, TAX KaK MepeXOR KPACOK OTAHYaeTcA "eT- KOCTBIO. TIpuMeneHve onveaHHoro MeroRa pH caHHTapHMX aNaaHsax BoM mpencrananeT HeCOMHEHHBe MPeHMYMLeCTBa HM MOKET c¢ YCTeXOM SaMeHHTS BCe ApyrHe MeroRB. BoabIOTO. BHNMANHA sacmyAHBAeT BOTPOC O NpHMeHeHHM TpuAOHA B ams pasmenHoro KomHNecTReH- noro onpenenenua Kanbina H MarHHA. Takum O6pasom, onperterene %ecTKOCTH Mm KPONOTAMBOe ONpeRenenne cone Kaab- nus H Markus MoryT OLITS BbINOMHENB Ges yuLepOa Ana TOUHOCTH allamusa B TeYeHMe caMo- FO KoporKoro cpoxa. JIMTEPATYPA ‘Meroms xuMuveckoro_H GaktepHomorHyeckoro aHamHsa Bons, on pea, C. M. Jipa- sesa, M., Mearus, 1963— Criouxer» TB. SixuwenE. M. Canunonexat iA. DKypuasx anaxutuveckohi xumun, 1953, T. VIII, 8. 3—Schwarzenbach G, Riede mann E, Helv. Chim. Acta, 1948, 31, 56—58— Schwarzenbach G, Willi . Acta, 1947, 39, 1303. Bach R, Helv. Cl Tocrynnaa 16/1V 1964 3S y K BONPOCY OB OFPAHHYEHHH COJEPKAHHA APOMATHUYECKHX YIJIEBOLOPOAOB B YAHT-CNMPHTE Acnupaur B. M. Pernes Ws xaepu ruruems tpyaa a mpodeccuonansunx Sonesieh Jlennurpazexoro opzena Jleunna uncruryra Yeoseptiencrsonania spaveli umenu C. M. Kupona Yaiit-cnupur umpoko/ npunenseres 8 AaHHOe BPE B MPOMEINIeHHOCTH Kak pacTBo- puTeIb daKoKpacoumtix Matepyasos. Toxcuyeckoe eficraie. yaiir-cnuputa Ha opraxiaM NpaGaNsNTeTbHO. uAeHTHTHO RelicTEUNO GeHsHHa. C rarHeHHNecKoi TONKH apeuna yaiiT-cnu- pit B Kauectne pacrsopHresin Gonee Mpwentem, vem GeH30M, KcHAON, XAOPGEHSO.1, OANAKO MpUNeHeHHe ETO TAKKe HNOTAA BELsIBAeT %aTOGH Co CTOpoHs: paGoux. To HaMIHM HAGmO- AeHUsIM, BO BPEMA OKPACKH 2KeeSHOAOPORMLX TaccaKMPCKHX BATOHOB, OCOGEHKO MPH AaKH- Powke suyrpexuux noMenienuil Baroua, y MaaspoB HacTynano MuorAa YyBeTBO onbseHuA Onn xaroBaauch na ToAODHYIO Gons, Yale B OGAACTH BUCKOB H BaTLIIKa, THKECTh B TOO Be, roaoBoKpyxenne. HexoToprte Mamsipsl, TOMHMO 9TOro, YyBcTAOBAMH Cibo xOKEHIE nognoxesxofl. Hitoraa nMea Mecto ToumoTa u psora. Bce yKasatnie seein mpoxomnaN