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Electric Circuits & Kirchhoff's Law
Electric Circuits & Kirchhoff's Law
An electric circuit is a 𝒄𝒍𝒐𝒔𝒆𝒅 path of wires and electrical components which allow a current through
it on the application of potential difference across two points with in the circuit. An electric circuit contains
mainly following three components;
1. Source of electrical Energy such as chemical cell or battery.
2. Sink (or load) of electrical energy such as resistors, capacitors, inductors, motors, lamp etc.
3. Connecting wires.
Electrical Cell: It is a source of electrical energy which maintains the potential difference across the circuit
and hence a continuous flow of charge (𝑒𝑙𝑒𝑐𝑡𝑟𝑖𝑐 𝑐𝑢𝑟𝑟𝑒𝑛𝑡)in the circuit at the cost of chemical or radiant
energy.
❖ An electric cell 𝒅𝒐𝒆𝒔 𝒏𝒐𝒕 provide charges rather it just provides
Energy to the already existing mobile charges in the circuit to
establish current.
❖ A chemical cell is prepared by placing two rods (𝑜𝑟 𝑝𝑙𝑎𝑡𝑒𝑠) of
different metals in a chemical solution which provide electric
potential difference across the two rods using chemical reaction
between the solution and the rods (𝑐𝑎𝑙𝑙𝑒𝑑 𝑒𝑙𝑒𝑐𝑡𝑟𝑜𝑑𝑒𝑠 𝑜𝑓 𝑡ℎ𝑒 𝑐𝑒𝑙𝑙)
❖ A combination of two or more electric cells is called ‘Battery’
E.M.F. (𝐞𝐥𝐞𝐜𝐭𝐫𝐨𝐦𝐨𝐭𝐢𝐯𝐞 𝐟𝐨𝐫𝐜𝐞) of a cell: It is the work done ( 𝑜𝑟 𝑒𝑛𝑒𝑟𝑔𝑦 𝑠𝑢𝑝𝑝𝑙𝑖𝑒𝑑) by the cell in moving a unit
charge in the whole (external + internal circuit)
𝑾𝒕𝒐𝒕𝒂𝒍
𝓔= V (𝑣𝑜𝑙𝑡)
𝒒
OR
It is the work done by the internal mechanism force of the cell in taking a unit positive charge from lower to
higher potential or a unit negative charge from higher potential electrode to lower potential electrode
inside the electrolyte.
OR
Mathematically, it is equal to the potential difference between the terminals of the cell when no current is drawn
from the cell or driven into the cell. 𝑽𝑷 − (−𝑽𝑵 ) = 𝑽𝑷 + 𝑽𝑵 = 𝓔
❖ Both 𝑉𝑃 & 𝑉𝑁 are with respect to the electric potential of the electrolyte of the cell which is same
throughout in when 𝒏𝒐 current is drawn from the cell.
❖ E.M.F. is not a force rather a constant potential difference for a cell.
❖ E.M.F. of a cell is originated due to non-electrical (chemical process) so remains constant for a cell as
long as nature of electrodes and electrolyte are same.
• The E.M.F. of a cell depends upon:
i. The material of electrodes.
ii. The nature of electrolyte used in the cell
iii. Decreases on increasing the concentration of the cell.
iv. Decreases on increasing the temperature of the cell.
• The E.M.F. of a cell does not depend upon:
i. Shape used size of electrode.
ii. Separation between electrodes
Internal Resistance of a cell: It is the obstruction offered to the positive and negative ions to establish
current in the electrolyte of the cell and is denote by ‘r’
❖ Its S.I units is ohm (Ω)
❖ It is 𝒏𝒐𝒕 constant for a cell rather increases slowly as the cell is used.
The internal resistance (r) of cell:
i. Decrease with increase in common surface area of electrodes (inside the electrolyte)
ii. Decreases with increase in temperature of electrolyte (as viscosity decreases).
iii. Increases with increase in concentration of electrolyte.
iv. Increases with increase in distance between the electrodes.
Terminal potential difference of a cell: It is defined as the work done per unit charge in carrying a unit
charge in the external circuit connected across the terminals of
the cell.
• EMF is the 𝒄𝒂𝒖𝒔𝒆 of terminal potential difference & terminal potential is the 𝒆𝒇𝒇𝒆𝒄𝒕 of EMF.
• The terminal potential difference is not the characteristic property of a cell and depends upon the
value of R & hence on the value of I drawn from the cell.
❖ The S.I unit of both ‘𝓔’ & ‘ V ‘ is volt (V)
⟹ 𝓔 = 𝐼𝑅 + 𝐼𝑟
⟹ 𝓔 = 𝐼(𝑅 + 𝑟)
𝓔
⟹ 𝑰= = 𝑡𝑜𝑡𝑎𝑙 𝑐𝑢𝑟𝑟𝑒𝑛𝑡 𝑖𝑛 𝑡ℎ𝑒 𝑐𝑖𝑟𝑐𝑢𝑖𝑡. This is known as 𝐶𝑖𝑟𝑐𝑢𝑖𝑡 𝐸𝑞𝑢𝑎𝑡𝑖𝑜𝑛
(𝑹 + 𝒓)
𝓔𝐑 𝓔 𝑽 = 𝓔 − 𝑰𝒓
⟹ 𝑽= 𝒓 = 𝑹( − 𝟏)
(𝑹 + 𝒓) 𝑽
❖ Also from equation 1, for different modes of operations of an electric cell we have:
From the circuit diagram given above: From the circuit diagram given above:
From the circuit diagram given above: From the circuit diagram given above:
𝓔𝟏 𝒓𝟐 + 𝓔𝟐 𝒓𝟏
𝓔𝒆𝒒 =
𝒓𝟏 + 𝒓𝟐
𝓔𝟏 𝒓𝟐 − 𝓔𝟐 𝒓𝟏
𝓔𝒆𝒒 = (𝓔𝟏 > 𝓔𝟐 )
𝒓𝟏 + 𝒓𝟐
𝓔𝒆𝒒 𝓔𝟏 𝓔𝟐
= +
𝒓𝒆𝒒 𝒓𝟏 𝒓𝟐
𝑀𝑖𝑥𝑒𝑑 𝐶𝑜𝑚𝑏𝑖𝑛𝑎𝑡𝑖𝑜𝑛 𝑜𝑓 𝐸𝑙𝑒𝑐𝑡𝑟𝑖𝑐 𝐶𝑒𝑙𝑙𝑠
When the external resistance of the circuit is of the 𝒔𝒂𝒎𝒆 𝒐𝒓𝒅𝒆𝒓 as that of internal resistance, then we
employ mixed grouping of cells to obtain maximum current.
𝑇𝑜𝑡𝑎𝑙 𝐸𝑀𝐹 = 𝒏𝓔
𝒏𝒓
𝑇𝑜𝑡𝑎𝑙 𝑖𝑛𝑡𝑒𝑟𝑛𝑎𝑙 𝑟𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒 =
𝒎
𝑛ℰ 𝒎𝒏𝓔
𝑇𝑜𝑡𝑎𝑙 𝑐𝑢𝑟𝑟𝑒𝑛𝑡, 𝐼 = 𝑛𝑟 =
𝒏𝒓 + 𝒎𝑹
𝑚 +𝑅
𝒏𝒓 𝒏𝓔
∴𝑹→ ⇒ 𝑰𝒎𝒂𝒙 =
𝒎 𝟐𝑹
𝑱𝒖𝒏𝒄𝒕𝒊𝒐𝒏 𝑹𝒖𝒍𝒆 ∶ In an electrical network, at any 𝑳𝒐𝒐𝒑 𝑹𝒖𝒍𝒆: The algebraic sum of changes in
junction the sum of currents potential around any closed loop
entering the junction is equal to the sum of currents involving resistors and cells in the loop is zero
leaving the junction.
❖ From figure: 𝑰𝟏 + 𝑰𝟐 = 𝑰𝟑 + 𝑰𝟒 ❖ This rule is based upon the fact that if after
❖ This rule is based upon the fact that in 𝑠𝑡𝑒𝑎𝑑𝑦 moving in a closed loop a charge comes back to
the same initial point there will be no change in
state, charges cannot accumulate at any
its electrical energy as electric potential will
junction or at any point in the circuit. So remain unchanged for that point. So energy is
charge is conserved. conserved.
❖ From Figure
❖ This rule is also valid if a point in a line of
𝐹𝑜𝑟 𝑙𝑜𝑜𝑝 1
circuit is considered instead of a junction of
𝓔𝟏 − 𝓔𝟐 − 𝑰𝟏 𝑹𝟏 + 𝑰𝟐 𝑹𝟐 = 𝟎 ………(1)
several lines.
𝐹𝑜𝑟 𝑙𝑜𝑜𝑝 2
𝓔𝟐 − 𝑰𝟐 𝑹𝟐 − (𝑰𝟏 + 𝑰𝟐 )𝑹𝟑 = 𝟎 ………(2)
❖ A Wheatstone bridge is most sensitive when 𝑎𝑙𝑙 𝑓𝑜𝑢𝑟 𝑟𝑒𝑠𝑖𝑠𝑡𝑎𝑛𝑐𝑒𝑠 are of 𝒔𝒂𝒎𝒆 order.
Potentiometer: It is a device used to measure the EMF of a cell or potential difference between two points
of an electric circuit to a very good extent of accuracy.
❖ A potentiometer can be regarded as an ideal voltmeter with infinite resistance as it does not draw
any current from the source of EMF at the null point.
❖ It consists of a long wire of 4 𝑡𝑜 10 𝑚 having high resistivity & low temperature coefficient of
resistance like constantan or manganin wire.
❖ When to be used it should also have a 𝑑𝑟𝑖𝑣𝑖𝑛𝑔 𝑜𝑟 𝑎𝑢𝑥𝑖𝑙𝑖𝑎𝑟𝑦 𝑐𝑖𝑟𝑐𝑢𝑖𝑡 which contains a battery, a key
and a rheostat, all connected in series with the long wire of potentiometer.
❖ On 𝒊𝒏𝒄𝒓𝒆𝒂𝒔𝒊𝒏𝒈 the length of wire, the potential gradient 𝒅𝒆𝒄𝒓𝒆𝒂𝒔𝒆𝒔 but sensitivity of the
potentiometer 𝒊𝒏𝒄𝒓𝒆𝒂𝒔𝒆𝒔.
Principle of Potentiometer: When a constant current is passed through a wire of uniform cross section
area, the p.d. across any portion of the wire is directly proportional to the
length of that portion.
𝑷𝒐𝒕𝒆𝒏𝒕𝒊𝒂𝒍 𝒅𝒊𝒇𝒇𝒆𝒓𝒆𝒏𝒄𝒆 𝒂𝒄𝒓𝒐𝒔𝒔 𝒂𝒏𝒚 𝒑𝒐𝒓𝒕𝒊𝒐𝒏 = 𝑷𝒐𝒕𝒆𝒏𝒕𝒊𝒂𝒍 𝒈𝒓𝒂𝒅𝒊𝒆𝒏𝒕 × 𝑳𝒆𝒏𝒈𝒕𝒉 𝒐𝒇 𝒕𝒉𝒂𝒕 𝒑𝒂𝒓𝒕.
𝑨𝒑𝒑𝒍𝒊𝒄𝒂𝒕𝒊𝒐𝒏 𝒐𝒇 𝑷𝒐𝒕𝒆𝒏𝒕𝒊𝒐𝒎𝒆𝒕𝒆𝒓
From the circuit diagram given above: From the circuit diagram given above:
When key 𝑎 is closed and null point is at length 𝒍𝟏 When key 𝐾1 is closed and null point is at length 𝒍𝟏
from end point A of the wire, EMF of cell 1 is; from end point A of the wire EMF of cell is;
When key 𝑏 is closed and null point is at length 𝒍𝟐 When key 𝐾2 is closed and null point is at length 𝒍𝟐
from end point A of the wire, EMF of cell 2 is; from end point A of the wire terminal P.D. is ;
………….𝑩𝒆 𝒇𝒐𝒄𝒖𝒔𝒆𝒅.