SAFETY DATA SHEET

Product Trade Name:

BaraBrine® W-1059
Revision Date: Revision Number:
03-May-2023 6

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE

COMPANY/UNDERTAKING
Product Identifier
Product Trade Name:
BaraBrine® W-1059
Synonyms
None
Chemical Family
Not determined
Internal ID Code
HM009534

Recommended use and restrictions on use

Application
Scale Inhibitor
Uses advised against
Consumer use

Manufacturer's Name and Contact Details

Manufacturer/Supplier
Halliburton Energy Services
14th Floor, CitiBank Tower, Al-Qutayat Street
Dubai, UAE
Telephone Number : +971 43036666

Additional Information

Prepared By
Chemical Stewardship
e-mail: fdunexchem@halliburton.com

Emergency Telephone Number

1-760-476-3959
Global Incident Response Access Code: 334305
Contract Number: 14012

2. HAZARDS IDENTIFICATION
Classification System This SDS was prepared in accordance with United Nations "Globally Harmonized System of
Classification and Labelling of Chemicals (GHS)" and its revisions.
Classification

Acute Oral Toxicity Category 4 - H302

Skin Corrosion / Irritation Category 2 - H315
Serious Eye Damage / Eye Irritation Category 1 - H318
Acute Aquatic Toxicity Category 3 - H402
Substances/mixtures corrosive to metal Category 1 - H290

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Hazard Pictograms

Signal Word
Danger

Hazard Statements
H290 - May be corrosive to metals
H302 - Harmful if swallowed
H315 - Causes skin irritation
H318 - Causes serious eye damage
H402 - Harmful to aquatic life

Precautionary Statements

Prevention
P234 - Keep only in original packaging.
P264 - Wash face, hands and any exposed skin thoroughly after handling
P270 - Do not eat, drink or smoke when using this product
P273 - Avoid release to the environment
P280 - Wear protective gloves/protective clothing/eye protection/face protection
Response
P390 - Absorb spillage to prevent material damage
P301 + P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
P330 - Rinse mouth
P302 + P352 - IF ON SKIN: Wash with plenty of water.
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 + P364 - Take off contaminated clothing and wash before reuse
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing
P310 - Immediately call a POISON CENTER or doctor/physician
Storage
P406 - Store in corrosive resistant container with a resistant inner liner.
Disposal
P501 - Dispose of contents/container in accordance with local/regional/national/international regulations

Contains
Substances CAS Number
Phosphonic acid Proprietary
Phosphonic acid 13598-36-2
Hydrochloric acid 7647-01-0

Additional Information
None known

3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT (w/w) GHS Classification
Phosphonic acid Proprietary 30 - 60% Eye Irrit. 2 (H319)
Aquatic Acute 3 (H402)
Phosphonic acid 13598-36-2 1 - 5% Acute Tox. 4 (H302)
Skin Irrit. 1A (H314)
Eye Irrit. 1 (H318)

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STOT SE 3 (H335)
Met. Corr. 1 (H290)
Hydrochloric acid 7647-01-0 1 - 5% Skin Corr. 1B (H314)
Eye Corr. 1 (H318)
STOT SE 3 (H335)
Met. Corr. 1 (H290)

4. FIRST AID MEASURES

First-aid Measures
Inhalation
If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult.
Skin
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. Get medical attention.
Eyes
In case of contact, immediately flush eyes with plenty of water for at least 30 minutes. Remove contact lenses after the first 5
minutes and continue washing. Seek immediate medical attention/advice. Suitable emergency eye wash facility should be
immediately available
Ingestion
Do NOT induce vomiting. Rinse mouth. Never give anything by mouth to an unconscious person. Obtain immediate medical
attention.

Most important symptoms and effects, both acute and delayed

Harmful if swallowed. Causes skin irritation. Causes severe eye irritation which may damage tissue.

Indication of any immediate medical attention and special treatment needed

Notes to Physician
Not Applicable

5. FIRE FIGHTING MEASURES

Suitable Extinguishing Media
Water fog, carbon dioxide, foam, dry chemical.
Extinguishing media which must not be used for safety reasons
Do NOT spray pool fires directly with water. A solid stream of water directed into hot burning liquid can cause splattering.

Specific hazards arising from the chemical

Decomposition in fire may produce harmful gases.

Special protective actions for fire-fighters

Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Ensure adequate ventilation. Use appropriate protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Avoid contact
with skin, eyes and clothing.

Environmental Precautions
Prevent from entering sewers, waterways, or low areas.

Methods and material for containment and cleaning up

Dike far ahead of liquid spill for later disposal. Soak up with inert absorbent material. Pick up and transfer to properly labeled
containers.

Additional Information
See Section 8 and 13 for additional information.

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7. HANDLING AND STORAGE
Precautions for safe handling
Do not breathe dust/fume/gas/mist/vapors/spray. Ensure adequate ventilation. Use appropriate protective equipment. Avoid contact
with eyes, skin, or clothing.

Conditions for safe storage, including any incompatibilities

Store in a well ventilated area. Store in original container. Store in corrosive resistant container with a resistant inner liner.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Control parameters
Exposure Limits
Substances CAS Number United Arab Bahrain Kuwait Gulf Cooperation
Emirates Council
Phosphonic acid Proprietary Not applicable Not applicable Not applicable Not applicable
Phosphonic acid 13598-36-2 Not applicable Not applicable Not applicable Not applicable
Hydrochloric acid 7647-01-0 Not applicable Not applicable Not applicable Not applicable

Appropriate engineering controls

Ensure adequate ventilation, especially in confined areas

Individual protection measures, such as personal protective equipment

If engineering controls and work practices cannot prevent excessive exposures, the selection and proper use of personal protective
equipment should be determined by an industrial hygienist or other qualified professional based on the specific application of this
product.
Respiratory Protection
If engineering controls and work practices cannot keep exposure below occupational exposure limits or if exposure is unknown,
wear a NIOSH certified, European Standard EN 149, AS/NZS 1715:2009, or equivalent respirator when using this product.
Selection of and instruction on using all personal protective equipment, including respirators, should be performed by an Industrial
Hygienist or other qualified professional.
Hand Protection
Manufacturer's directions for use should be observed because of great diversity of types. Oil-resistant gloves. Suitable materials for
longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation time as per EN 374):
Impervious gloves Neoprene gloves.
Skin Protection
Wear impervious protective clothing, including boots, gloves, lab coat, apron, rain jacket, pants or coverall, as appropriate, to
prevent skin contact.
Eye Protection
Chemical goggles; also wear a face shield if splashing hazard exists. (EN-166)
Other Precautions
Eyewash fountains and safety showers must be easily accessible.

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State:
Liquid
Color
Clear to Slightly Hazy , Colorless to Light Amber
Odor:
Mild
Odor Threshold:
No information available
pH:
1.5 - 2.5 (10% in 1:1 IPA:H2O)
Specific Gravity
1.260 - 1.320 (20 °C/68 °F)
Freezing Point/Range (°C):
No information available

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Pour Point/Range (C):
No information available
Boiling Point/Range (C):
No information available
Flash Point/Range (°C):
> 93.3 °C
Flash Point Method:
No information available
Flammability Limits in Air - Lower (%):
No information available
Flammability Limits in Air - Upper (%):
No information available
Autoignition Temperature (°C):
No information available
Evaporation Rate (Butyl Acetate=1):
No information available
Vapor Pressure
No data available
Vapor Density (Air=1):
No information available
Water Solubility
Soluble in water
Decomposition Temperature (C):
No information available
Viscosity, Dynamic:
No data available
Viscosity, Kinematic:
No information available
Partition Coefficient/n-Octanol/Water:
No information available
Molecular Weight (g/mole):
No information available

10. STABILITY AND REACTIVITY

Reactivity
Not expected to be reactive.

Chemical Stability
Stable

Possibility of hazardous reactions

Will Not Occur

Conditions to Avoid
None anticipated

Incompatible materials
Strong oxidizers. Strong acids. Strong alkalis. Contact with metals.

Hazardous decomposition products

Carbon oxides. Oxides of phosphorus. Chlorine.

Additional Guidelines
Not Applicable

11. TOXICOLOGICAL INFORMATION

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Information on Toxicological Effects
Acute Toxicity
Inhalation
May cause mild respiratory irritation.
Eye Contact
Causes serious eye damage.
Skin Contact
Causes skin irritation.
Ingestion
Harmful if swallowed.

Chronic Effects/Carcinogenicity
No data available to indicate product or components present at greater than 0.1% are chronic health hazards.

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

Phosphonic acid Proprietary No data available No data available No data available
Phosphonic acid 13598-36-2 1895 mg/kg ( Rat ) No data available No data available
Hydrochloric acid 7647-01-0 238 - 277 mg/kg ( Rat ) 5010 mg/kg ( Rabbit ) 1.68 mg/L ( Rat ) 1 h

Substances CAS Number Skin corrosion/irritation

Phosphonic acid Not irritating to skin in rabbits. (similar substances)
Phosphonic acid 13598-36-2 Corrosive to skin (Rabbit)
Hydrochloric acid 7647-01-0 Causes severe burns

Substances CAS Number Serious eye damage/irritation

Phosphonic acid Irritating to eyes (Rabbit) (similar substances)
Phosphonic acid 13598-36-2 Corrosive to eyes
Hydrochloric acid 7647-01-0 Causes severe burns

Substances CAS Number Skin Sensitization

Phosphonic acid Did not cause sensitization on laboratory animals (guinea pig) (similar substances)
Phosphonic acid 13598-36-2 Not applicable due to corrosivity of the substance.
Hydrochloric acid 7647-01-0 Did not cause sensitization on laboratory animals (guinea pig)

Substances CAS Number Respiratory Sensitization

Phosphonic acid No information available
Phosphonic acid 13598-36-2 No information available
Hydrochloric acid 7647-01-0 No information available

Substances CAS Number Mutagenic Effects

Phosphonic acid In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects. (similar
substances)
Phosphonic acid 13598-36-2 In vitro tests did not show mutagenic effects.
Hydrochloric acid 7647-01-0 In vitro tests did not show mutagenic effects.

Substances CAS Number Carcinogenic Effects

Phosphonic acid Did not show carcinogenic effects in animal experiments (similar substances)
Phosphonic acid 13598-36-2 No information available
Hydrochloric acid 7647-01-0 No data of sufficient quality are available.

Substances CAS Number Reproductive toxicity

Phosphonic acid Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
experiments. (similar substances)
Phosphonic acid 13598-36-2 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
experiments.
Hydrochloric acid 7647-01-0 Embryo and fetotoxicity has been observed in female rats exposed to maternally toxic levels of
hydrogen chloride (450 mg/m3, 1hr.). When tested at maternally toxic doses, no adverse effects on
fertility, teratogenicity, or development were observed.

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Substances CAS Number STOT - single exposure

Phosphonic acid No information available
Phosphonic acid 13598-36-2 No significant toxicity observed in animal studies at concentration requiring classification.
Hydrochloric acid 7647-01-0 May cause respiratory irritation.

Substances CAS Number STOT - repeated exposure

Phosphonic acid No significant toxicity observed in animal studies at concentration requiring classification. (similar
substances)
Phosphonic acid 13598-36-2 No significant toxicity observed in animal studies at concentration requiring classification.
Hydrochloric acid 7647-01-0 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number Aspiration hazard

Phosphonic acid Not applicable
Phosphonic acid 13598-36-2 Not applicable
Hydrochloric acid 7647-01-0 Not applicable

12. ECOLOGICAL INFORMATION

Toxicity
Ecotoxicity effects Harmful to aquatic life.
Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Phosphonic acid Proprietary EC50 (72 h) 80 mg/L LC50 (48 h) 160 mg/L EC0 (5 d)>100 mg/L EC50 (48 h) 94 mg/L
(Skeletonema costatum) (Oncorhynchus mykiss) (activated sludge) (similar (Acartia tonsa) (similar
(similar substance) (similar substance) substance) substance)
NOEC (60 d) 23 mg/L NOEC (28 h) >=25 mg/L
(Oncorhynchus mykiss) (Daphnia magna) (similar
(similar substance) substance)
Phosphonic acid 13598-36-2 EC50(72h): 153 mg/L LC50(96h): > 100 mg/L No information available EC50(48h): > 1000 mg/L
(Pseudokirchnerella (Cyprinus carpio) (Daphnia magna)
subcapitata)
Hydrochloric acid 7647-01-0 No information available LC50 282 mg/L EC50 (3h) >= 5 and <= EC50 (48 h) 4.92 mg/L
(Gambusia affinis) 5.5 (pH) (Activated (Daphnia magna)
LC50 20.5 mg/L (Lepomis sludge, domestic)
macrochirus)
LC50 (96h) 3.25 – 3.5
(pH) (Lepomis
macrochirus)

Persistence and degradability

Substances CAS Number Persistence and Degradability

Phosphonic acid Proprietary No information available
Phosphonic acid 13598-36-2 No information available
Hydrochloric acid 7647-01-0 The methods for determining biodegradability are
not applicable to inorganic substances.

Bioaccumlation potential

Substances CAS Number Bioaccumulation

Phosphonic acid Proprietary No information available
Phosphonic acid 13598-36-2 No information available
Hydrochloric acid 7647-01-0 -2.65

Mobility in soil

Substances CAS Number Mobility

Phosphonic acid Proprietary No information available
Phosphonic acid 13598-36-2 No information available
Hydrochloric acid 7647-01-0 No information available

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Other adverse effects
No information available

13. DISPOSAL CONSIDERATIONS

Waste treatment methods
Disposal methods
Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging
Follow all applicable national or local regulations.
Other Information
No information available

14. TRANSPORT INFORMATION

UN Number
UN3265

UN proper shipping name:

Corrosive Liquid, Acidic, Organic, N.O.S.
(Contains Phosphonic Acid)

Transport Hazard Class(es):

8

Packing Group:
III

Environmental Hazards:
Not applicable

Special Precautions for User

None

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable

15. REGULATORY INFORMATION

Regulatory Information:
This SDS was prepared in accordance with United Nations "Globally Harmonized System of Classification and Labelling of
Chemicals (GHS)" and its revisions.

NFPA Ratings:
Health 3, Flammability 1, Reactivity 0

16. OTHER INFORMATION

Key literature references and sources for data
www.ChemADVISOR.com/

Revision Date:
03-May-2023
Revision Note
SDS sections updated:
2
4

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14

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained
from various sources including the manufacturer and other third party sources. The information may not be valid under all
conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any
material is the sole responsibility of the user.

End of Safety Data Sheet

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