‘Huéng din giai Bai Tip Hoa Phin Tich . Khoa Cong nghe Hoa Hye CHUONG 7: PHUONG PHAP KHOI LUQNG. 7.1. Néu cée yeu cau déi voi phan img két tia ding trong phan tich khdi luong. 7.2. Néu cac yéu cau d6i voi dang két ta va dang can. a/ Dang két tia: — Phai la chat kh6 tan. Tich sé tan phai dii nho dé cho phan ing ket tiia xay ra mot céeh dink hrong, ~— Két tia tao thanh phai dé loc, dé rita. Sau khi rita thi tro nén tinh khiet. — Dang két tia phai chuyén thanh dang can dé dang va hoan toan khi say hod nung. — Dang két tia cé thé chita nhitng chat khac ma ching bay hoi khi xi ly nhiet. b/ Dang can — Cé thanh phan héa hoe thye té ding véi céng thite héa hoe. Diéu nay dam bao 6 dimg cia phuong phap khéi hrong. ~ Tinh khiét. — Dang can phai bén vé vé mit héa hoc (tong khong khi khéng bi hit am, khong tae dung véi oxy va khi CO2, khong bj phan hiiy do tée dung eta anh sang trong qua trinh lam ngudi va can) ~Phan tir rong dang can cang Ién cang tot — Him lrgng cia nguyén t6 xéc dinh trong dang can cang nhé cang tot (diéu nay him lam gidm dén mite thap nhat anh Insong eta cde sai s6 thure nghiém dén ket qua cudi cing. Ching han khi dinh dang crém dudi dang crdm oxyt C1205 thi sai s6 do mat Ling két tiia khi phan tich tmg véi su mat 2Cr/Cr03.1= 104/152 = 0,7mg Cr). Cén khi xée dink crom 6 dang BaCrO, thi hnong mat tong img ciia crom li Cr/ BaCrO,.1= $3/253,3 = 02mg Cr. ‘Nhu vay viée sir dung BaCrO, lam dang can tot hon Cr,0, 7.3. Dé dinh lwong Canxi thi dang can nao sau day cho két qua tot hon : CaC,04; CaO; CaSO, : CaF: (nghia la v6i mot luong mau da cho sé cho s& thu durge khéi long dang ean Ion nit) Me,e201 = 128; Meso = 56: Measou = 136; Mears = 61 > Do trong ca 4 dang can déu chi cé 1 ngnyén tit Ca Dang nao cé khéi lrong phan tit Ion hon s€ cho két qua 6 sai s6 bé hon. Va CaSO, c6 phan tir tong lon nat. Tuy nhién do pK casos = 5.04, c6n pKeac2os = 8.64. Nén cn ett vao diéu kign eta dang ket tiia thi két ta phai cé tich sé tan cang bé thi phan ‘mg cing dinh Irgng, Vi thé dé dinh long Canxi thi nén chon dang edn CaC,O, 7.4. Chuan hoa dung dich H,SO, bang phuong phap khoi hrgng bang cach lam ket tia ion SO,” duéi dang BaSO,, Biét ring 50,00 ml dung dich axit cho ta 405,6 mg BaSO,. 1‘Huéng din giai Bai Tip Hoa Phin Tich . Khoa Cong nghe Hoa Hye Tinh nong 46 mol/lit cia H)SO, Khai rong dang can BaSO, a mg thu durge tir Vesis 1a: 405,6 mg => 405.6 * 10° g Khéi ligng dang can xac dinh (g) trong Vinjy : a 10° * F = a* 10° * Mysoa/ Maasos Ojtrong Vingy = a* 10° / Massos 46 mol/lit etia HySO, = (a* 10° / Mg,sos) * (1000/ Vniu) = (405.6 * 10° * 1000); (233* 50) = 0,0348mol/1 Sé mol ‘Non 7.8. Nude bign clita 885 ppm S dudi dang SO. Tinh khéi hong BaSO, c6 thé thu duge tir Lkg nude bién. Nude bién chita 885 ppm S = 1kg nude bién c6 885mg S = Ikg mide bién c6 885* (233/32)mg BaSO, = 6443.9 mg =6.44 g BaSO, 7.6. Tinh the tich BaCl, 0,0600M can ding dé lam két tia ion SO,” tir dung dich thu duge khi hoa tan 1,010 g mau chita 20% S (duéi dang SO,2-). Can phai ding dur 20% thude thir so véi luong tinh theo ly thuyét. Pt phan tmg : SO,” + Ba” = BaSO, Goi % S cé trong mau la P (%) So gS cé trong m g mau la m*P/100 S6 g BaSO, thu ditoe tir mau : (mv*P/100)* (233/32) Sé mol BaCl, phan tg vita di véi SO. (m*P/100)* (233/32)* (1/233) =(m*P/100)*(1/32) $6 ml dd BaC]; 0.06M BaCl, phan ing vita dit voi $O,”" dé tao ra sé g BSO, tinh duge @ tren: =(m*P/100)*(1/32)* (1000/Cygpaciz) = (1,010 *20/100)*(1/32)* (1000/0.06) =108.21ml. dé tao ra sé g BSO, tinh duoc 6 ten $6 ml dd cin sit dung &8 6 dur 20% so vai ly thuyét : 126.25 ml 7.1. Tir 0,5606g quing kém ta thu duge 0,7506g Cd:P20; va Zn,P. thu duge ZnSO, va chuyén ra ZnO thi dure 0,3983 g. Tinh % ki Cd 6 trong quang Tir hon hop na long cia Zn va ‘Mang = 0.5606 Min cr mzn0 = 0.3983 Y Men = Myno X ZH mznzp207 = 22 Mzno Mzno a A = = Mano y, MznzP207 Mat hie mcazp207 = ™Mnonrop — MznzP207 = Mronhop ~ jane * 2Mca = x ™Mca = Mca2P207 Measpzo7 Meno 2207, 2Mca Mca = (Mronhop — )x 7 Meno Meazv207 Mn Min 100 (6) Zn = = x 100 = mano X 'quang mo Mquang‘Huéng din giai Bai Tip Hoa Phin Tich . Khoa Cong nghe Hoa Hye (Wz = 03983 x 8 100 en Oe 81 * 0.5606 = 57.01 Mea M20 Merarzor , 2Mca 100 (%)Cd X 100 = ((?Mponnop — Mauang Mino 2 Mcazp207— Mquang 0. 7506 —2 3983 x 304, 2 x 112.5 03983 x 304) 2 x 112.5 (96)¢d = 2 x 87___388— 5 190 = 0.82 BS: 57%; 0,32 7.8. Ché héa 0,75 g mau thude tri stu DDT (C)sHoCls ) véi HNO: bée khoi va lam két tria Clo théat ra dudi dang AgCl due 0,239 ¢ AgCL rir sau, Tinh % khéi hrong DDT cé trong thud Hg 6 chuyén F= [(Metsscis)® (1/5)]/Maget m, 1 0.239xX354.5 x100 %DDT = EX 100 = eas ma 5 = 15.74 DS: 15,74% 7.9, Mot miu pyrit can nfug 1,7890 durge siy dén khéi lvong khong ddi la 1.7180. Can 0,3980 g mau pyrit ban dau, héa tan va tao tia, thu duge 1,0780g BaSOs. Tinh % S trong mau ban dau va n ry kho? DS: 37,20: 38,74% % S (mu ban du) = ———— 0,3990%1.7180 03980 g ama pyrit ban dau, néu say kh6 sé con = 87 % S (mu sy kh) itsoa * ile Baso4* Masoa 41,0780 x 32 = nana 10 0398017180 5, “I= 1.7890 7.10. Mot mau quing oxyt sit ning 0.5000g duge Lim két tua duéi dang Fe(OH); va nung thanh oxyt sit 3 cin nng 0.4980 g. Tinh ham lrong Fe dudi dang % Fe va % Fe:0,? 2Mpe _ 4 xFej04 Fre304 = TSipesos Fre = Mre203‘Huéng din giai Bai Tip Hoa Phin Tich . Khoa Cong nghe Hoa Hye Zire x 100 69 79 Mpe203 ™max % Fe = mpezos X 4 xFe304 100 % Fe304 = meas 6 Hoos : a 96.28% 7.11. Dé xac dinh ham long photpho trong mét mau quang photphat, ngudi ta hoa tan 0.418g quing va lam két tia photpho duéi dang MgNH;PO,.6H,0. Sau dé nung dé chuyén thianh Mg:P,0; . Khdi hrong Mg2P20- can duge bang 0,2208 g. Tinh ham hong PO; trong quing. Mpz0s P= — F205 idangcan 100 % P205 = Maang can * F X Timea = 33.79 DS: 33,79% P2Os 7.12. Tien hanh xac dinh thanh phan Fe trong phén sat amoni: Can chinh xac 1g 0 phén sit, tiém hanh qué tinh phan tich khéi long. Sau khi nung, sit t6n tai ¢ dang can 1a Fe,; va can drge 0,16g. Tinh % Fe trong mau ban dau. 2X Mpe Mpe.o, 100 % Fe = mang can X F X = 112 Mau 7.13. Xéc dinh lwong nude c6 tong mau BaCl,.2H,O, ngudi ta tién hanh ede bude thi nghigm va thu duge két qua sau: ~ Khéi lugng lo can: ~ Khéi rong lo cn + BaCl;.2H,0: 3,1gam — Khdéi long lo can + BaCl: 2,9gam. Tinh %H,O trong mau trén DS: 25% Hz0 7.15. Dinh hrong phot pho trong mau phan bén, cin 1.0000gam mau va tao tia didi dang MgNH,PO,. Nung tia 6 600°C die dang can Mg2P;0; ¢6 khéi hrong 0,2350gam. Tinh %P va %P0s trong mau phan bon Mp M, Froos = —Mraos 2 XMygnsror Mygnnaros P; 15,03%P20s 7.16. Mot miu da voi can nang 1,2300gam duge héa tan trong axit. Loc bé tap chit khong tan, dung dich qua loc cho tac dung voi NH,OH. Khoi htgng cae oxyt kim loai 4‘Huéng din giai Bai Tip Hoa Phin Tich . Khoa Cong nghe Hoa Hye hoa tri 3 (Fe:O, vi ALO.) thu duge la 0,0584gam. Nhom duge cé lap riéng va dang cfn thu duoc 14 ALO; nang 0,0232gam, tinh %Fe va %Al trong mau 2Mat 2Mpe Fy = Fre = —f At Mss Pe Mesa 0 % Al = Mai203 x Fax = = 0.0998 = 1 100 % Al = Mai203 X F 41 x = 0.0998 = 1 100 % Fe = (Mronnop — Marz03) X Fre x =2 , DS: 1% Al; 2% Fe 7.17. Phai dimg bao nhigu ml dung dich NH,OH 5%(d = 0,990g/ml) dé lam két tia hét Fe™ trong dung dich phan tich duroc hoa tan tit 0,200g quiing c6 30%Fe Fe + 3NH,OH = Fe(OH); + 3NH,* Mee = Mauang x0-3 = 0.06 Theo dinh nat durong Inong @ = AOsusow See 1000 __1000xmpe 1000Xmpe_ __ 100XmreXCuHaoH > Yunson = dev ~ ~~ DpexC%xd reXNNH4OH — Dex" Fe’ CNHAOH vy 100x0.06x35 NH40H ™ (§6/3)x5x0.990 Diy a so ml NH,OH tac dung vita di voi Fe**, Thong thong trong phan tich khoi Iuong ta thuéng cho dir thuée thir va trong tong hop nay nén cho du 20% . vay sé ml HOH can sir dung la 2.8 ml .3ml. 7.18. 0,8325g mot hgp kim Cu + Sn + Zn. Phan tich bing phwong phap phan tich kh huong, thu due 0,6728g CuSCN va 0,0423g SnO;. Xéc dinh theo % céc thinh phan trong hop kim. M R og oo Messe % Cu = meusens * Fou 2 u] % SN = Moroz X Fon X = 4.00% fi %Zn = 100- %Sn - % Cu =53.61 DS: 42,39%Cu; 4%Sn; 53,61%Zn 7.19. Phan hity 0,1500g mot hop chat hitu eo ¢6 cong thite CsHexCl, duuge ion Cl. Ket tia ion CT bang Ag” thu duge 0,4040¢ AgCI dang ein, Xée dinh x trong cong thire phan tir (hop chat hitu ec durge xem la nguyén chat) 5‘Huéng din giai Bai Tip Hoa Phin Tich . Khoa Cong nghe Hoa Hye Fei Met = Mage X Met Maget Met Magct Tir cong thite CsHe.xCl, Thiét lap duroe ty sé me 35.5 xx 35.5 xx _ 0.404 x 35.5 Mmau 7B—x4355x °° 7B+345x 1435x015 Giai phwrong trinh én x=4.15 Vi x la s6 nguyén nén x=4 7.20. Dé xac dinh ham lugng NiSO, va nude ket tinh tong mot mau NiSO,.xH,0. ngudi ta ding phwong phap phan tich khdi lrong: cén 2,71602 mau, hoa tan thank 100,0ml; lay 20,00ml dung dich trén tao tiia bang dung dich Ba”. Khoi long tia thu duge 14 0.45112, Tinh %NiSO, va xéc dinh tri s6 x trong céng thre phan tir (Ni Ba=137) 59. cin 2,7160g miu, héa tan thinh 100,0ml; lay 20,00ml dung dich trén tao ta bing dung dich B: NiSO, + Bi Khéi luong tia thu due 1 0.45112. Dang can la BaSO, va mp,soa = 0.4511 FE. Mnisoa Mpasos 100 % NiSO4 = mpasox x Fa x — x f | 155 100 % NiSO4 = 0.4511 *933 “27160 * 5 = 55.24 Dé xac dinh tri s6 x trong phan tit phai c6 diéu kién 1a mau mudi trén [a tinh khiét . Mau chi cd NiSQ,.xH,0 155 S6 g NiSO, c6 trong mau la 0.4511 x32 x5 = 233 155, > SO g mic 1a 2.7160 — 0.4511 x $2 x 5 = 1,2156 233 myisoa _ 155 Tir céng thite NiSO,.xH,O, thiét lap ty 1g thite —23S* = ™MuH20 xX16 1.5004 155 1.2156 xx 16 85. Do x la s6 nguyén nén x=8