Equilibrium Calculations 1, N2Qne) €9 2NOoa ‘When 0.0350 mol of N2Qa is placed In a one litre flask, it was found that the equilibrium concentrations were [N2O4)] = 0.0292 moi/L and [NO2g) = 0.0116 moi/t. Calculate the equilibrium constant at this temperature. 2. PClsig) <> PClay + Clay In this gaseous system, the Kp= 1.05 at 250°C. Find the partial pressure of Cl2, if Preis = 0.875 atm and P pos = 0.463 atm 3. Hale) + lalg) <> 2Hilg) At a certain temperature, a mixture of H2 and Iz was prepared by placing 0.206 ‘mol of Hz and 0.200 mol of tz into a 2.00 litre flask. After a period of time, the equilibrium was established. The purple color of the lz vapor was used to monitor ‘the reaction and from the decreased intensity of the purple color, it was determined that at equilibrium, the 2 concentration had dropped to 0.0206 mol/L. What Is the value of Kc for this reaction at this temperature? 4, Halg) + lag) <9 2Hi(g) Amixture of 0.250 mol Hz and 0.250 mol Iz was placed in a 1.00 L flaskat 430°C. Calculate the concentrations of H2(g), Ia(g), and Hi{g) at equilibrium. The eqiillibrium constant for the reaction is 54.3 at this temperature. 5. 2H20{g) > 2He(g)+O2(g) Kes 7.3 x 10 at 1000°C if the initial concentration of H20 is 0.100 Mi, What is the Ha concentration? 5. HCaHsO2(aq) €> H*{aq) + CaHtsO2(aq) If Ko=1.8x10° at 25°C and the initial concentration of acetic acid is 1.0 M, whatis ‘the equilibrium’concentration of H'? 18) so () tothe let 804 04m, 0} = 7 War 136 x 10M CEO {og'= ede ac{80} : 44g {C0} = ea 2 0) = a, a (oq) aso a4) = anu ae ibxcass 346 [i] = 89 10° 4, [OR] = 89 x 10-30 1463 [CO] = 80 «10-420 1485 [Ch] = 0011.4, [8n) = 0911 1Ag8 PO = a0 %Ad! AL25 °C, Xe = 360 for the reaction AgCile) + Br-(e2) == AgBrs) + C(ea) 1 Haid gs det x sotto onan 010 2 Be ‘bat vil be the equilibrium conenizutions of B:~ and ia? — Mum Caleatatons Hei coca tener y= 058 fe ea PCg() + Cakg) == PC(g)- Seppo a reaction ‘vese} at this tompernimre contaised these three gases at the following conceateations: [PCI] = 0.0420 4, {Ch} = ‘00240 3, [PO] = 0.00500 A. {q) Ts tho eyiem ia stats of equlibcaie? (b) ifnot, which direction val the action ive to preseed | foget to ecru? {LAS At 460 °C, the zonation 80,4g) + NOz() = NO(E) + SOx(2) has K, = 850, A reaction flack a: 460 °C contains these aces at the following coroensrtions: [SO,} = 0.02250 2f, [SOx = 002350.42, [NO] = 0.0250 36, [SOs = 0.0400 Mt (@) 1s the reaction t oquiitxiam? (b) Hac, which way wil tha reaction have to proceed to A (Gyr At eran teapeatae ke rention CO(g) + ZEi(s) == CH:CHe) ‘bas Ke= 0.500. It reaction mixture ai sqoilibeium con- ‘xing 0.100 Af CC and 0.220 i Hira is tho coacontration of CHSOET VAS Ke = 64 forthe meiction Ng) + 3Ha6g) == INAe) st noortain teperatere, Suppose it was foend that an eae Iibsium méstuce of these gusts contained 0.360 M NHis and (0.019% Af Ng, Want wes tho concentration of fy im the mixture? 29 AE TAS °G, a seacion miatowe af CO(=), Hats), and ‘CiJOH(g) was allowed fo coor to equilcium. To fo lowing equitisdum concentrations, were thes smansured: [CO] = 9.105 af, [Fj = 0250.4, [CEJOH] = G002St 4. (Caleuets Keo ths reaction CO(g) + alg) == CHONG) 34.50 Bthylena, CaHLy, and water seost under appropiate ‘cousitions to give otberol. The reection is plea) + HaC(e) === CaHsOBta) ‘An cowilbeinse misture of there gases ai a certain tempo tar ip Be etorng ce O04 i, ts gaia {C24 05] = 0.180. What is the velob 461 The renetion 2HCi(g} == Fixkg) + Cig) hss Ke= 3.2 10"™ at 25 °C. i a roection vessel coutains inkiclly 0.0506 mol L~* of 2701 and then reacts to reach equilibrins, Sieas TA MnN he cmos Hd 8 certain temperate, = O18 for His allb- Ham FCM) Fug) PNG). as el ofl | ‘acd na 200 el this peri, wi te | ‘soacentration of PCs be at equim? Review Probleme [| 63 4431. At high temperatnre, 200 sant of 3r was placed in a 400 L costlier whore it decomposed to give tke equi” rim ZSBe(g) == Hy(g) + Bex%g). At equilibrium the ‘concentration of Sry was measured to be Q.49S5 Af. What is Ke for this scaction at thle terapecare? JASE A O0SO ml sexuple of formaldehyde vapa:, CHO, ‘yes placed in heated 300 ml, versal and rome offi decaut- ‘posed. Tae reeckfon is CH;O%g) — Hits) + COG). At Paitin, the CH,0(¢) concentration was 0.065 mat L-4, Calouata to vaive of K fer ta zezeion, 1453 The reaction NO,Q) +NOO=MOG + Oxe) reached equifosim at 2 certain high tesperature. Orig sally, tho reaction vesse contained the following intial com centrations: [NjOj = 0.184 Af, {O,] = 0377M, [NO,} = 05202, snd [NO] = 039434, The concentration of the 1NO,, the only colored gus in ta mixture, was monitored by following the intensity ofthe cotor. At equiibcium, the NOp ‘concentration hnd become 0.118‘. What isthe value of X fortis epction a this temperate? Sd At 25 °C, 00560 mol Op end 0420:moi NzO were placed in a 1.00% eontoinsr where the following equilib sim Was cotablistod. BO(@) + 304) = ANOaL) ‘At oqulibaism, tie NO, concentration was 0.020 2, What isthe value of K, for thisreaction? ASS AU25°G, Ke = 0.185 fr the seaction in te solvent COL: ZB = Bry + Ci. I the ital eoncentza- don of BrCl in the sohution. is 6.050 4, wiiat will the equiliS- sium conomtrations of Br and Cia be? JAS6 At 25°C, Xe = 0.145 ioe the following rosction ie the paivent CCL; HCL =Bry + Ca, If th intial eoscon- faedess of Bry and Clg are each (A250 2%, whot wl hair cequiltara conceniratisns bot 1457 Tho equlibelum constant, Tor the reaction SOx{g) + NO(g) == NOs) + SOxf) ves found to be 0500 ata carta touparatur. £0.240-mol ‘of $0, and O240 moi of NO ere placed in x 200 L cone tainec wna allowed 10 rea:l, what will be the eqailiieiom, ‘eoncustratin of ech zis? {AS8 Fc the reestion i the proton, 2 reaction amiztur 's prepared in witch 0.120 mol NOg aad 0.120 mol $0 ave placed in s 1.00 L vaste, After the syoism reaches fequliicinm, what wil bo the equlibrfum conoextrations of fll four gases? Liowr do these equllixium vahies compare jo those ealclsied in Problem 14572 Acsount for your ‘observation. 1459 Arn costa tempaabize the reiion COG) + HgD(g) == OOaKe) + Hike) nos X, = 0.460. Exactly 1.09 mst of eas gas was plooed in x 1G L vests! and the mixiure mndarwont reaction, What was ‘he equilixiur: conventralion ofeach gaa? “HS At 2000 °C, he decompeiion of On, 200g) = 2004) + Ce) has X, = 64 x 10-7, if 3 1001 comainer holding 1.0 X 10-* mol of CO, 5s heated to 2000 ‘eon sok "hat il bo te