THE COPPERBELT UNIVERSITY ‘SCHOOL OF MATHEMATICS AND NATURAL SCIENCES DEPARTMENT OF CHEMISTRY 2017/2018 ACADEMIC YEAR ONEMISTRY CH 110 TEST ONE TIME ALLOWED Two (2) Hours DATE 04/12/2017 smesTRUCTIONS (i) ttempe a tne four questions each aurstion caries 15 Marks (2) All caicutoted quantities must have units and reporte (2) Do not open tll mstructed to do 50 (the correct muenber of segaicant feres. MAPORTAOET DATA: 1. wrancirseatettoce Piands constant Bo eRe Eee Ore TT Im Tes0ss4 602214 x10" 8316511 K mol (008206. atmnk™ mol 2017/2018 CH 110 ~ TEST 1 Question Parer Page tofGeis (2) Ifthe cant's oceans contain approsimately 1.36 x 10" L of water. ')Cakulate this vohime in cubic hiometres. a 2B) Use the appropriate pret to write the value of 1.36 10° L without ponents t () Coppertelt University (CBU is stated inthe town of Kitwe ip Zambia whose temperature on 25 ‘October 2017 at 14:23 hours was 30°C. What i this temperature reading i> i) Fahrenheit a ii) Kelvin m (©) By referring tothe periodic table provided, reproduce the tble below and correctly fil inthe chied and ‘ourth column. (Hint: The first rows 1s an example of how lo complete the table: 0.5 marks for each correctly filled cell) i ‘ Bement Tlement clase (metal —— Namter [Sonat [owtanslormaatny | ERM #080 7 [He Nonmesl | Nebiegas 2 Tse Perce 1 a € 3 Cu z —I 3 Tes: ; 3 [Br t = 6 Tas - (@) What isthe muctide symbol for a nucleus tha contains 38 protons ang 50 seutrons? Bl (©) Chromium. Cr, as the following isotopic masses and fractional abundances _ ‘Mass Number Tsotopie Mass Fractional Abundance (amy 3 49.9461 hans 32 31.9405 ‘0.8379 3 52.9407 0.0950 34 53.9389 0.0236 What is the atomie mass of chromium? (Give the answers tothe following questions i) State the laws of definite proportions and conservation of matter. a ii) Name the two types of properties commonly used to characterize or dentify substances Q (@) Perform he follwing calculations and round the answers o the correct numberof significant figures (units of measurement have been omitted) i) 2sen sa 0 (i) 541 ~0.398 (ii) 3.38-0.31 (iv) 4.18 —58.16 x (3.38 - 3.01)IESTION? 25 MARKS (2) The percentage composition oF caffeine is 49.5% C, 5.15% H, 28 %6N, and 16.5% {What i the empirical formula of caffeine? 2 ii) Determine the molecular formula of caffeine if its molar mass is 195g/mol fa) (®) A solution containing 3.5 gof sodium phosphate is mixed witha tlution containing 64 g of barium ') Write a balanced equation forthe reaction aking place ii) Write the complete mie equation forthe reaction taking place Til) Write ue net fonie equation forthe reaction taking place ix) Calelate the number of males foreach reactant, ¥) Determine the limiting reagent for ths reaction Vi) For the reagent in excess. calculate the mass that remains after the i) Calculate the mass of rium phosphate formed in this reaction (6) Iman experiment, 5.50 g of SOCL was obtained from the resction of 5.80 g of SOx with excess PCls according to the following reaction equation: SOz(1) + PCI(I) — SCH) + POCK i What isthe theoretical yield of SOC? a i Determine the percentage yield of SUL Bl‘uesnon - Aten {a Name tees examples of noeletraltes apa fom sigur and ako 1) Spanner Zale fom Rtusngutent Univesity made 1.0, oF 12M So the Sabo dik (these only 28 Lot i m ea see ie Seah paar hydroxide soilon is nesed rect completely with» sion somaining 1.00 go phases ae (4) Kombe Chis fm Lobos Units Kasama was ask to prepare phosphate trom the reaction fea chorie and shin phosphinis triok, What he iin pi cacy of a a What name is given t the ype of ration above? Waite the balaaced chemical equation fer the formation of eae pov {Write the ne ions equation fo show the Formation of caehim plesphat ()Wemtify the spaces tha are reducing and oxzing ages in each ofthe folowing wsetion DAS Sar 2A Cu 3} i) COR = 2H Cor LO 3} (f) Consier the redox reaction below Cr} (og) + BNOs(0q)» C04) 1-NOs (09) Write the balanced oxidation haf reaction ofthe equation abov 4) Write the balanced reduction half reaction of the equation above id) Write te balanced overal ection in asic medium ofthe equation above 2017/2018 CH 110 TEST 1 Question Paper Page dof