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CN104745766A - LF Refining Process For Deoxidizing According To Colour of Furnace Slag - Google Patents
CN104745766A - LF Refining Process For Deoxidizing According To Colour of Furnace Slag - Google Patents
Abstract
CN104745766A
The invention discloses an LF refining process for deoxidizing according to colour of furnace slag.
China
Slag bonding operation is carried out during refining, and the following operations are carried out
according to colour of the bonded furnace slag: (1) when the furnace slag is black, replenishing an
aluminium-containing slag former in a ratio of 0.4-0.6kg per ton steel and silicon carbide in a ratio of Download PDF Find Prior Art Similar
0.2-0.3kg per ton steel; (2) when the furnace slag is brown or grey replenishing silicon carbide in a
ratio of 0.1-0.2kg per ton steel; and (3) when the furnace slag is white or grey white, deoxidization is Other languages: Chinese
complete. The LF refining process for deoxidizing according to colour of furnace slag has the
Inventor: 刘鸿旭, 沈俊杰, 闫卫兵, 刘占玲, 邓建新, 张玉海, 刘明远,
advantages that the slag bonding operation is carried out, deoxidization degree of molten steel is
蔡飞, 梁佳
judged according to colour of tapped slag, and online operation of a worker is guided, so that the
worker can be guided to rapidly judging oxidability of refined steel slag and deoxidation degree of Current Assignee : Xuanhua Iron and Steel Group Co Ltd
the molten steel, optimization of the refining furnace deoxidizing process is realized, cost is saved,
standardized operation degree is improved, and simplicity, easiness and strong guidance are
Worldwide applications
realized.
2015 CN
Status Pending
1. carrying out a LF refinery practice for deoxidation according to slag color, it is characterized in that, in described refining process, carry out dry slag operation, carrying out
following operation according to gluing the slag color:
(1) when slag is black: add containing aluminium slag former 0.4 ~ 0.6kg/ ton steel, silicon carbide 0.2 ~ 0.3kg/ ton steel;
(2) slag be brown or grey time: add silicon carbide 0.1 ~ 0.2kg/ ton steel;
2. the LF refinery practice carrying out deoxidation according to slag color according to claim 1, is characterized in that, the described predominant quantity percentage
composition containing aluminium slag former is: CaO 36 ~ 45%, SiO 2≤ 9%, Al 2o 320 ~ 30%, Al 20 ~ 25%, water≤0.5%.
3. the LF refinery practice carrying out deoxidation according to slag color according to claim 1 and 2, it is characterized in that: described containing in aluminium slag
former, the weight of granularity > 30mm and the weight of < 5mm are all not more than containing aluminium slag former gross weight 5%.
4. the LF refinery practice carrying out deoxidation according to slag color according to claim 3, is characterized in that: the described granularity containing aluminium
slag former is 5mm ~ 30mm.
Description
Technical field
The invention belongs to steel-smelting production process technical field, especially a kind of LF refinery practice carrying out deoxidation according to slag color.
Background technology
The quality of characteristic to refined molten steel of ladle refining slag has a direct impact.LF refining furnace mainly by make high alkalinity, high reductibility, low
melting point liquid slag wash heat is carried out to refined molten steel, thus realize absorption steel inclusion, deoxidation, desulfurization, air-isolation, prevent molten
steel to be too oxidized and inhale the object of nitrogen.The component of refinery scum, basicity, fusing point and oxidisability are directly connected to the height of
Molten Steel Cleanliness.At a certain temperature, the FeO content ratio in steel and slag is a constant, and in slag, (FeO) content can reflect the quality of deoxidation of
molten steel degree.If the FeO content in refinery scum is high, then the FeO content in molten steel is also corresponding high; Otherwise, then low.Generally, when (FeO)
content is greater than 1% in refinery scum, easily cause deoxidation of molten steel bad, cause strand subsurface bubble, the defect such as loose.For refining steel
grade, if take every stove to determine oxygen operation, although the dissolved oxygen content in molten steel accurately can be judged, the significant wastage of
material can be caused, need the deoxidation degree of a kind of rational working method to molten steel and make effective judgement, Instructing manufacture.
The technical problem to be solved in the present invention is to provide a kind of LF refinery practice carrying out deoxidation according to slag color can making
effectively judgement to deoxidation degree.
For solving the problems of the technologies described above, the technical solution used in the present invention is: carry out dry slag operation in described refining
process, carries out following operation according to gluing the slag color:
(1) when slag is black: add containing aluminium slag former 0.4 ~ 0.6kg/ ton steel, silicon carbide 0.2 ~ 0.3kg/ ton steel;
(2) slag be brown or grey time: add silicon carbide 0.1 ~ 0.2kg/ ton steel;
(3) when slag is for white or canescence: show that deoxidation is complete, without the need to adding containing aluminium slag former and silicon carbide again.
The present invention containing the predominant quantity percentage composition of aluminium slag former is preferably: CaO 36 ~ 45%, SiO 2≤ 9%, Al 2o 320 ~ 30%, Al
20 ~ 25%, water≤0.5%.
Preferred, described containing in aluminium slag former, the weight of granularity > 30mm and the weight of < 5mm are all not more than containing aluminium slag
former gross weight 5%.The described granularity containing aluminium slag former is preferably 5mm ~ 30mm.
Adopt the beneficial effect that produces of technique scheme to be: the present invention is operated by dry slag, to the color of bits after coming out of the stove to
judge the deoxidation degree of molten steel, instruct workman's on-line operation.Thus workman can be instructed to judge the oxidisability of refining slag and the
deoxidation degree of molten steel fast; Realize the optimization of refining furnace deoxidization technique, cost-saving; Improve standardized work degree; There is
simple and easy to do, that directiveness is strong feature.
Embodiment
Below in conjunction with specific embodiment, the present invention is further detailed explanation.
In different steel grade slag, (FeO) content and slag color comparator relation are in table 1.
Table 1: actual (FeO) content synopsis in refining procedure slag color and slag
As shown in Table 1, (FeO) content in refinery scum and refining slag color have certain corresponding relation, effectively can instruct refinement and deoxidation
operation.
(1) slag is black, shows (Fe0) content > 2% in slag, also needs great dynamics deoxidation, need add containing aluminium slag former 0.4 ~ 0.6kg/ ton steel, silicon
carbide 0.2 ~ 0.3kg/ ton steel;
(2) slag is brown or grey, shows that in slag, (Fe0) content is 1% ~ 2%, still needs further deoxidation, adds silicon carbide 0.1 ~ 0.2 kg/ ton steel;
(3) slag is white or canescence, shows that deoxidation is complete, without the need to adding containing aluminium slag former and silicon carbide again.
(4) can adopt containing aluminium slag former conventional containing aluminium slag former, preferably adopt following main component (weight percentage)
containing aluminium slag former: CaO 36 ~ 45%, SiO 2≤ 9%, Al 2o 320 ~ 30%, Al 20 ~ 25%, water≤0.5%; Wherein, the weight of granularity > 30mm and the weight of <
5mm are all not more than 5% containing aluminium slag former gross weight; Granularity is preferably in the scope of 5mm ~ 30mm.
Embodiment: Xuan Gang 180T-LF refining furnace adopts present method to carry out the smelting of 55# steel.
First time dry slag operation is carried out after A, refining furnace enter the station, discovery slag is black, namely (FeO) > 2% in slag is judged, need great dynamics
deoxidation, now add lime 2.85kg/ ton steel, argon flow amount is adjusted to 250 ~ 350 NL/min, carry out submerged arc to power on, in stove, lime 5.7kg/ ton steel is
added again in power up, fluorite 2.0kg/ ton steel, energization slag starts in backward stove to add containing aluminium slag former 0.48kg/ ton steel altogether for 5
minutes, wherein adds once every 1.5 minutes, divide and add for four times, add containing aluminium slag former 0.12kg/ ton steel at every turn; Silicon carbide adds
0.30kg/ ton steel altogether, wherein adds once every 1.5 minutes, divides and adds for three times, add silicon carbide 0.10kg/ ton steel at every turn, carry out great
dynamics deoxidation.
B, to stop power supply after 13 minutes, carry out sampling, after thermometric operation, carry out second time dry slag immediately and operate.Find that bits are
beige, the thick > of slag 0.8 centimetre, surface is more coarse, have block pimple one by one, hard not easy-weathering, can judge that in slag, (Fe0) is 1% ~ 2%, needs
further deoxidation, simultaneously bits do not change, bits poor fluidity.Instruct workman to add energization slag after fluorite 0.5 ~ 0.8kg/ ton steel, conduction time is
be advisable for 8 ~ 10 minutes.Require that energising one minute rear platform operative employee starts in stove, add silicon carbide 0.30kg/ ton steel altogether
again, added once every 2 minutes, add at twice, carry out deoxidation operation.
C, after 8 minutes, the chemical analysis of first time refining composition is uploaded in laboratory, and again stop power supply, adjustment argon flow amount is 400 ~
500NL/min, adds iron alloy and carbon dust, carries out trimming to molten steel, and the fine setting time is 2 ~ 3 minutes.Afterwards, argon flow amount is adjusted to
250 ~ 350 NL/min, continues power supply and carry out material at least 4 minutes.
D, after 4 minutes, to stop power supply, after sampling, thermometric, carry out third time dry slag and operate.Now find that slag is canescence, show slag (Fe0) ﹤ 1%,
in slag, oxide compound major part is reduced, and deoxidation of molten steel is good, does not need to carry out deoxidation again.But bits thickness is at 5 ~ 6
millimeters, changes slag not good enough, still need energization slag, but do not need to add slag charge.Instruct operator to carry out the electrochemical slag of
confession, insulation with 20000 ~ 25000A small area analysis gear, power-on time is be advisable for 6 ~ 8 minutes.
E, power supply are after 8 minutes, and the chemical analysis of second time refining composition is uploaded in laboratory, and chemical composition meets steel
grade requirement, now stops power supply, last dry slag operation before carrying out thermometric and departures.Find that slag is still canescence, surface
smoothing, thickness is 3 ~ 5 millimeters, weathering rapidly after cooling, illustrate that deoxidation of molten steel degree is good, now molten steel reaches target
temperature, start soft blow operation, soft blow argon gas requirement of strength controls at 200 below NL/min, and the soft blow time is 20 minutes.
F, after 20 minutes, soft blow is complete, and ladle is transported to continuous casting and steps into row casting.
When not using and use this LF refinery practice, LF refined molten steel slag system analysis in table 2 and table 3.
Table 2: when not using present method, LF essence molten steel slag system is analyzed
As shown in Table 2, before not using present method, during the departures of 55# steel refining, in slag, FeO content is higher, and mean value is 1.025%, and
deoxidation of molten steel is incomplete.
Table 3: after using present method, LF refined molten steel slag system is analyzed
As shown in Table 3, after using present method, comparatively strong to workman's deoxidation operation directiveness, during the departures of 55# steel refining, in
slag, FeO content is lower, and mean value is 0.574%, and deoxidation of molten steel is complete.
CN102051441A * 2011-01-21 2011-05-11 储鸿文 Quick refining process for LF (ladle furnace)
Title
Cited By (2)
CN107794345A * 2016-09-06 2018-03-13 鞍钢股份有限公司 A kind of LF stoves produce the secondary slag practice of low silicon aluminium
killed steel
CN108546798A * 2018-03-16 2018-09-18 马鞍山钢铁股份有限公 A kind of LF furnace foundations are in the quick Slag modification method for
司 seeing slag
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Priority And Related Applications
CN201510143004.XA 2015-03-30 2015-03-30 LF refining process for deoxidizing according to colour of furnace slag
CN201510143004.XA 2015-03-30 LF refining process for deoxidizing according to colour of furnace slag
Legal Events
2017-04-26 WD01 Invention patent application deemed withdrawn after publication Application publication date: 20150701