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Introduction To Chemistry 3rd Edition Bauer Solutions Manual 1
Introduction To Chemistry 3rd Edition Bauer Solutions Manual 1
5.2 (a) combination reaction; (b) activity series; (c) chemical equation; (d) product; (e) ionic equation;
(f) neutralization reaction; (g) precipitation reaction; (h) net ionic equation; (i) double-displacement
reaction
5.3 Substances that are formed as a result of the reaction are the products. This reaction produces solid
aluminum oxide, Al 2 O 3 (s). You should pay attention to the substance formed and the state of the material
if it is given. The reactants are the substances used to form the products. The reactants are aluminum
metal, Al(s), and oxygen gas, O 2 (g) (i.e. “Aluminum metal reacts with oxygen gas”).
5.4 Substances that are formed as a result of the reaction are the products. Nitrogen gas and solid iodine, N 2 (g)
and I 2 (s), and energy are the reaction products (i.e. “Nitrogen gas and solid iodine form in an explosive
reaction”). You should pay attention to the substance formed and the state of the material if it is given.
The reactants are the substances used to form the products. The reactant is nitrogen triiodide, NI 3 (i.e.
“when nitrogen triiodide is detonated”).
5.5 Image A represents the reactants because it contains both fluorine and xenon. Images B-D show product
molecules, but only image C represents the products. In a chemical reaction, mass must be conserved. In
image A there are two xenon atoms and eight fluorine atoms. In order for mass to be conserved, the same
number of each type of atom must be present in the products.
5.6 Make sure you look carefully at the images to distinguish between the chemical formulas for ozone (three
red spheres) and oxygen (two red spheres). Image C represents the reactants because it contains both ozone
and carbon monoxide. The products are represented by image D. Images A and B represent mixtures of
reactants and products.
5.7 Mass must be conserved in a chemical reaction. In order for mass to be conserved, the same number of
each type of atom must be present in both the products and reactants. The image is not accurate because
mass is not conserved. To fix the image, you first need to count the number of each type of atom. Here’s a
summary of the atoms present in the reactants and products:
Atom Reactants Products
5−1
H 10 12
N 4 4
The numbers of hydrogen atoms do not match in the reactants and products. If you add one hydrogen
molecule to the reactant image, the numbers will balance and the molecular-level diagram will be accurate.
5.8 Mass must be conserved in a chemical reaction. In order for mass to be conserved, the same number of
each type of atom must be present in both the products and reactants. The image is not accurate because
mass is not conserved. To fix the image, you first need to count the number of each type of atom. Here’s a
summary of the atoms present in the reactants and products:
Atom Reactants Products
H 10 10
O 6 5
5−2
The numbers of oxygen atoms do not match in the reactants and products. If you add one hydrogen
molecule to the reactant image and one molecule of water (H 2 O) to the product image, the numbers will
balance and the molecular-level diagram will be accurate.
Atom Reactants Products
H 12 12
O 6 6
5.9 The law of conservation of mass is obeyed when the same number of each type of atom is present in both
the products and reactants. In the product image you could have 5 molecules and one unreacted atom.
5.10 The law of conservation of mass is obeyed when the same number of each type of atom is present in both
the products and reactants. In the product image you could have 1 unreacted molecule and 5 unreacted
atoms. Two molecules of product should be shown.
5.11 One oxygen molecule (two oxygen atoms) and two sulfur dioxide molecules must react for every two
sulfur trioxide molecules (SO 3 ) produced. Since there are four sulfur dioxide molecules, both oxygen
molecules will react. This means that none of the reactants remain after the reaction, and we should show
four sulfur trioxide molecules as the reaction products.
5−3
5.12 One oxygen molecule (two oxygen atoms) and two NO molecules must react for every two NO 2 produced.
Since there are six NO molecules, all of the oxygen molecules will react. We should show six NO 2
molecules as the reaction products.
5.13 Three signs that a chemical reaction is occurring are evident: (1) a brown gas is forming, (2) bubbles are
being produced, and (3) the solution is changing color (assuming that the liquid was not green to start
with).
5.14 Two signs that a chemical reaction is occurring are evident: (1) the color of the mixture is different than the
color of either solution and (2) a new substance (the yellow solid) is forming. You can tell a solid is
formed because the solution becomes opaque (i.e. you can’t see through it).
5.15 We are starting and ending with CO 2 , so no new substances are formed. A chemical reaction has not taken
place. What we are observing is a change in the physical state of CO 2 .
5.16 There are several signs that a chemical reaction has taken place: the formation of “a blue solution” indicates
that a color change occurred. In addition, formation of a “black deposit” indicates the production of a new
substance.
5.17 There is a rearrangement of the atoms into new substances. Since new substances are formed, a chemical
reaction has taken place.
5.18 In the image on the left, the molecules are composed of one red and two white spheres, just as they are in
the image on the right. When a chemical reaction takes place new substances are formed. A chemical
reaction is not occurring here, because no new substance is formed.
5.19 The solution shown on the left has the spheres placed closer together, while in the solution shown on the
right the spheres have moved farther apart. Since no new chemical substances have formed, a chemical
reaction has not taken place. This is what you would expect to see in dilution.
5.20 A rearrangement of the atoms in a substance is an indication that a chemical reaction has taken place.
Since the molecules have different shapes in the reactant and product images, we conclude that a chemical
reaction has occurred.
5.21 A chemical equation is a chemist’s shorthand way of showing what happens during a chemical reaction. It
identifies the formulas of the reactants and products and demonstrates how mass is conserved during the
reaction. You can think of a chemical equation as a chemist’s recipe for making new substances. The
reactants are the ingredients (i.e. melted chocolate or solid chocolate chips) and the products are what are
produced by the reaction (i.e. fudge or cookies). Like a recipe, the chemical equation indicates the states of
the materials and the quantities of substances that are used (the reactants) and produced (the products).
5.22 A chemical reaction is any process that produces a new substance. A chemical equation is the shorthand
that chemists use to describe that reaction. The chemical equation includes the quantities and physical
states of the substances used (the reactants) and produced (the products) in the ideal reaction.
5−4
5.23 To decide if a reaction has taken place, we have to determine whether a new substance has been formed.
(a) This equation represents a chemical reaction. Carbonic acid, H 2 CO 3 (aq), has been formed from the
reaction of carbon dioxide (CO 2 ) and water (H 2 O).
(b) This equation represents a physical change. The chemical compositions of solid water (ice) and liquid
water are the same, so a chemical reaction did not occur.
(c) This equation represents a chemical reaction. Even though the same atoms are present in the reactant
and product, the order in which they are connected is different so the substances are different
compounds.
5.24 (a) This equation represents a chemical reaction. New substances, Sn(OH) 4 (aq) and HCl(aq), are formed
from SnCl 4 and H 2 O.
(b) This equation represents a chemical reaction. Solid K 2 O forms from the elements K and O 2 .
(c) The process of dissolving a salt in water is usually considered a physical change. Salts are composed
of ions (for example, NaCl(s) is actually a collection of Na+ and Cl− ions). When a salt dissolves, the
ions are separated from each other by water molecules. However, the structure of the ions does not
change.
5.25 Balancing a chemical equation demonstrates how mass is conserved during a reaction. A balanced equation
is a quantitative tool for determining the amounts of reactant(s) used and of product(s) produced.
5.26 Chemical equations are descriptions of particular chemical reactions. Changing subscripts in the formulas
of reactant or product species changes the identities of the substances involved in the reaction the equation
is describing.
5.27 In balancing the equation, we add coefficients so that the number of each type of atom is the same on the
reactant and product sides of the equation.
(a) To start with, we write the skeletal equation for the reaction:
NaH(s) + H 2 O(l) → H 2 (g) + NaOH(aq)
When we count the number of each type of atom in the reactants and products, we find that this
equation is already balanced.
Atoms in Reactants Atoms in Products
1 Na 3H 1O 1 Na 3H 1O
The chlorines are not balanced. To balance, we need to find a common factor. The smallest factor
would be 6. We use coefficients of 3 and 2 on Cl 2 (g) and AlCl 3 (s), respectively
Al(s) + 3Cl 2 (g) → 2AlCl 3 (s)
Atoms in Reactants Atoms in Products
1 Al 6 Cl 2 Al 6 Cl
5−5
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personalities it was possible to definitely determine beyond question the
antagonistic ideas of one personality which voluntarily induced the
conflict and, by the impulsive force of their emotion, caused the amnesia
in the other personality.[38] The same phenomena were observed in the
case of B. C. A. As memory for the forgotten experiences in these
instances returned as soon as the conflict ceased, conservation of them
necessarily persisted during the amnesia.
Perhaps I may be permitted to digress here slightly to point out that
this same (in principle) phenomenon may be effected experimentally by
suggestion. The suggested idea which has the force of a volition or
unexpressed wish, coming in conflict with the knowledge of previously
familiar facts, inhibits or represses the reproduction in consciousness of
this knowledge as memory. It is easy to prove, however, that this
knowledge is conserved though it cannot be recalled. Thus, I give
appropriate suggestions to B. C. A. in hypnosis that she shall be unable,
when awake, to remember a certain unpleasant episode connected with a
person named “August.” After being awakened she has complete
amnesia, not only for the episode, but even for the name. The
suppression of the memory of the episode carries with it by association
the name of the person. In fact, the name itself has no meaning for her.
When asked to give the names of the calendar months after mentioning
“July” she hesitates, then gives “September” as the next. Even when the
name “August” is mentioned to her it has no meaning and sounds like a
word of a foreign language. The memory of the episode has become
dormant so far as volitional recollection is concerned. It can, however, be
recalled as a coconscious process through automatic writing, as in the
preceding experiment, and then the word in all its meanings and
associations is also awakened in the coconsciousness.
The same phenomenon may be observed clinically in transition types
standing halfway between the amnesia following emotional episodes and
that produced by external suggestion. Auto-suggestion may then be a
factor in the mechanism, as in the following example: In a moment of
discouragement and despair B. C. A., torn by an unsolved problem, said
to herself after going to bed at night, “I shall go to sleep and I shall
forget everything, my name and everything else.” Of course she did not
intend or expect to forget literally her name, but she gave expression to a
petulant despairing conditional wish which if fulfilled would be a
solution to her problem; as much as if she said, “If I should forget who I
am my troubles would be ended.” Nevertheless the auto-suggestion with
its strong feeling tones worked for repression. The next day, when about
to give her name by telephone, she discovered that she had forgotten it.
On testing her later I found that she could not speak, write, or read her
name. She could not even understandingly read the same word when
used with a different signification, i.e., stone [her name, we will suppose,
is Stone], nor the letters of the same. This amnesia persisted for three
days until removed by my suggestion. That the lost knowledge was all
the time conserved is further shown by the fact that during the amnesia
the name was remembered in hypnosis and also reproduced by automatic
writing.