~ Copler'=O~ Chena Kerelies reels Chersécod Kerelics #5 a Learch of chemés By hich dents ith Me shedy & she ables oF the chemtcal weackions, She nechanisee by which they foke place asd fhe fackess which enfluene the wale, Types OF Reackions :y thew axe Rha Apes of Reackons- (2) Trstonfereous Reachions fash Renckon iy These axe Ble xeackots which axe coopfeked abence . ody Preceperailion oF s2Qew chRoréde . Nactegy + ANC) —> Aehod Mean (b) Medenaile Reaclions iy These one. fle soackion hich proceed af meogurable rates. The wake o such xeackions an be méasused. eq7 The. hghatisas o& ethyRacekate an_ presence of leur Iyebsottle- CH,Coogts + Nac —y CH,COONA + GHSOH @ Sedzuwn acchate) > These axe Phe = ae uihich Ske a Tog |enexgyy eS uae Such ceackeons proceed ak SH Soke, RE OF Reackion te pe oF a reackank specees consumed or Me ecw Rehy Fa etn fesmed en unsk Ki i chemecad seackéon % cated the Vee o& Rhe seackzon . 7 Consedes a eo reeackter A—>8 Around oF fe Consumed ~ 49) Rae oF ~seackeon(s) = — Teme Raken ~ De Rosle of weackion (5) = Arvount oF B prodused ie: Afe) Tee Faken Ata Bene = Ades nok ale] _ Cae 6 eee alec] _ +a{ro) . » alta) TE AR Ae” itreone Rade] Ty as defeved os Phe rave of chomge of Concenteakkor er nek Reme . Menage fale = chasye oF Conconkrsafton =n a. ares Peme Time foken = i oe mel | a , mae age whew L) avd p and % ane ghe ¢, eat ao Be wee vocenteattons. Of ciel adl aes Prsfordoneous Fae }> Te es cefened as Phe sake of chanse of one of ghe weackask of £he poeduct species enskank of REMC. Concertvo200 of one ) ad shot paseecudas : Hose we cadeuinde wo8e of weackeon af a Small enterwd of kemede, Suppose (Jy? zs smatt change 20 Concerdsokeon ab 4g’ theo Teme =Tp order fo defeswine Lhe wale of weackon ue love eee ger Bie Concenbecsions alors y- outs ond Gasesponde Fene alorg X- 8S. 2 Fend fhe code of seackion of a poses Rene by desi oaerk fo fhe come Cwsseepordinga £¢ fal fime. ai joer We fhe whe of wsche of fa oe ; Scanned by Cofapemala):p- Wath eerste fenpersasuse Fhe wate of fos even ioe ese eo Pempemtuse, Me wbe OF Be rseachion sneweases” double ox Somabémes Reine. Goash):> A cabodysl S a cubshane ehes® presence encseases she ose of ghe chewicad reack con, buh Kee does of eudenp Chase an ghe chemtcak Cree a0 Be end of the wacheon, A’ sabssfance chose psesene fous doum fhea rake f fe chemical reachion 26 comted an enhebefore O© ia alah. pf Sopshooce cohese yoesence speed up ghe wale of fhe i ed weackion 2 Ed x acke alos on poshve cabot ch 4S. dace eza)y With fhe srosense: in surface er. | Phe ~<éockion incseases. the ~seoson is Grol foc Meee nae Sulaskonce , foges Surloce oA 2S provided. the wes of Grloin sseackeons awe ae of sodtodion, ise oe 1 cL ane andy, cov Ard Rohe Gns kar iKe Rab Come Kant of Phe weaken. “has ate Gonskor® of a porkecutas weackeon es detinal af fhe wade of seackon when mbes Grcentirdeon of ich weackawk ened. Qre Rad Dp Rake aus aves fhe ackuad or observed rake oF Sach, Conseder a x worad reenckeon cA dBi CGualD Py 6 fe 6 ts atin Rade of wenchio = Keay [ ie Ra according Ro rake Gw : na) aa enh x andy roy — wef be eat ® fe Co-etteceen@s Yrond b oF cachark, = KPAP*LRIdOF a Reackeon| ‘> The order of reachéon <8 defénal ag he Sus of he foress fo whech Pe concenkection fees oe warsed em the mle Law expression om ak equcdkion of fle senchad. i racfion, the onder of a neackion mo, be cuboke numbers, FeacRion os zero. as Reackion of fexck orcdlere-2y Tn Rhese weackeons, onfy one cackon® molecule unnderrpes cherzcal darge : 24> hos —p rho, TFOn Pe sc) w= Ta 4 ee = KIM order of reackéon = | the cecood onder’ ty fhese neackion Phe sors @ocentent Be gu Kockank spaces sere Chage js t Naot —> CH,CoeNa +6 HOH [cHacoogi)' [Woot | rey ordery Ty fhese weackéons fhe onder of | —> Procduch4, Zero Order Reacikion i Tr Bese eacRiens, the Bar of ahe do vck enPouence She woke of reockeon, ce Aley ‘do nok change oppsecea lly ducseng Phe leer H+ —> 2Hck | 2NHy —> Ab 13H, Ty Bhese reackign, fhe cmcunis of reackan® specées do charge bug gheiz Concenteakion Remain cor . (lees Ce Oo a Rencfeon + Dh be defined as Phe numbes of reacheng species ( molecules, atoms o zovs ) which Coftécle ~sewulRaneousfy fo bei about ae chemecol reackeon. DF a reackéor envibies Phe decompaséfeon oka senpe species , Gaited Unimofecuies. 4 7: vabes he colkeston of Suto Speess) iP LN ( OF REACTION | mavecuLARDTY exponent of Khe > recut i is Rhe number of of Phe seacfork bee the seockost species Akane zn a gengle Pep Cheick q | Te rosy be whale nurhes, Zero, or én Yrachon, Scanned by CamScannerPie iki pe OS General fn = (ieee) of rag ce my Fos fexsé onden ReaReon sec! os 2° onder reackion > 2 mol-!sé fos gt order rea.ckio & is ols order reackion > rook Ble f | fos Zero | Bieyeotel Bale Guateee (a) Zero onder. Reockéon ++ Grstder a Zeno onder reschion A— Prnduck “ a) = KAT =k ae k= rade conskourl De Concentartion of A’ af or ers Scanned by Ca = — Wher) 2-0, (a7= fA], = lnifiad concentention of © Sabstehaden, Fhese en qo@ we ge fal, = Kxore > c= fA], SubRehSing fhe volue oF ‘C! in equakion (3) we ae (A) = rf], ——@ s Ke [4] -[41. KA= (Ah - fa] we ke Oe & Bi sty Manns tied) Pans 2 gop dehesen PA] ogsinc R, we get g Pre wikh spe =-k asd ontescepe ope Re (Al, : qT “1, 7 Teme —- , Hose siete Ported fhe Reme en Farce has wack . a Scanned by CamScaAthen (HI, fT & ike fay, - Ul~ a Al, 7 Ay, eit hy, thus hatf fete pewtod of zero order reackeon t& aie pooposReonad fo he eneRead concenteobeon of seackon?. (8) Rae pee x Fash ele. Reacten 2 Conseder a Fens® onder reackion A— > Bre oe AT “a < oat = KLAT ~ dpa] =K de east wf) 4] bebhthe sede etl Rr) oF Infepeston [Al > -901, kxot ee Scanned byushers fhe vobue of (Cin pale @ weg —Lof A], = KP bof), a kh ~ haf do] + may A . el * oa [+ oa fab = Bo Big keeas— fh on tA] s 9. 303 ‘Te | pelt) - ‘ Kis COmRG (TheFfeckive Coktésien) : (Peter Gottiscon ) Fntluxe OF Cottiséon Th aid 7B Forks fo explain She abnaatty hegh vatues of rage conshmng Fos some seackons, > Te forks &o exfain fhe reonckioo eke of veverSibfe rencKors, pay Gees values of K. eet) Suppheed fo Phe seackank mekcules £0 abfain 4 fo ender chemical reackten %5 Catted ackeredion Threshold eres — Average kenekc - w odes net ur amount of enengy of poachan’ ab reeackeon. | > Las ackeveRéon HOR 4a > Heh ache vation POP |Apphicabicn :> WDependeny upon fhe value of ackevaeon ener we con deSesmines Phe condifionc fos weackio® fo Sake place and the a Aages of reackion. Degentence Ok Rote ( 6 Rake ConsBane(K) On a —Arnhentg The quantefohive er bekueeo the snfe conse Respernbose zs ave waited Arerchentus equation « Ree Nese A= ree fackow and is conskant x= Ackevekion exe = absolve Fempescducse ya es conskank akherg Wothsede of epation oO k= Rofl « Soe RVET = Inf — En/RT = 2-38 fag 3 a/R ey a 2.363 RT @ of sksaeght Rene weth shore se Leah.=e ‘os o sseockon , if k, ts the we conskan® af Aenpesoiune ae k, w He wie BA ok aaa RO ae Sa —o fog ka = mS se Subskocting equation @ eee eo we a = A- s 0 2. =e i D> 263PT ae E. a piece es DBBRT Scanned by CScanned by CamScanner Seamed nthConscanee Seanne wth Carseat