DPP NO-12 Free Radicals: Wurtz. Reaction: R—x Ha RER Mechanism:~ (Free radical Mechanism) (1) Na——>Na" +e (2) R—-X+e—oR+x@ @) R+R— >R-R (Ionic Mechanism) (1) Na——>Na’ +e °° @ R=X+2e0—>R+X @ RO#R-x—5R—R+K at ch—a 8, C]). —Chy ee eee a3 cH—cl+et—c1 chet nM, Q4 (Ph). Cl ah a6 az as as 10 ant ar a3 a4 ass ase a7 Time: 15 minutes >< we Lt oc. oh Cte AS cl—ater> - ph—o Ne Pack (fiting Reaction) (rerave CH Ne, om oe i ee op ab Br Br Ca AgiPowder, |\_—-( = CH cl CHe—CH=CH—CH, WOKS --DPP NO- 14 Time: 15 minutes Kolbe Electrolysis:— 9 i! R—C—OH —_,Ns0H —aecroyss? ROR + CO. +H ‘aide Cathode Mechanism:— (1) i eX 7H R—C—0-H*+ of = R_d_o- + H Anode:— I . ~~ R—¢€—o- —>R-C—O+e Q R—C—d6— R00, @ R+R—>R-R Cathode:— _ (1) 2H,0 + 2e- —+20H + Hy Q1 — CH,COOK —tessousis, CI) =! ak .2 Et — COOH__NaoH a aware“ as 000 tse — = Cha a4 as a6 az as as ato an coon aon aati --- cooH coo oye aa te 1000 Naooe7 coona—Sleettolysis. TNA A ioce_sles 3 Kos sox “me nS electrolysis, Naooe’ GooHDPP NO- 15 Time: 15 minutes Q.4 Matrix Reactions ch — Na (A) CHy— GH, — Gl Na, Pp cl 8 cu c N (© HC =CH—cH.—cl_ Na, A © AA ow R Number of dimerization product {excluding stereoisomers) P) 4 @ 3 R) 6 (8) None Q2__ Identify major products. cl Br ” “am ot he ‘Br ene Dry ether Se publ fnDPP NO-17 Time: 15 minutes 1. Compound Number of monochloroproduct Number of monocloroproduct {excluding stereoisomer) 1. a 2 | NS © NO ‘ DON . Dn XK . OC 7. 8 9 Compound Number of Dichloroproduct {including stereoisomer) ‘Optically active product 4. | 1-chlorobutane 2. | R-2-chlorobutane 3. | 3-chloropentane 4, | R-2-chloropentane 5. | S-2-chlorobutane 6. | R & S-2-chloropentane R & S-2-chloro butane