6.

6-23

Basics Elkc
Reden (Reduclien
hocdamasty
t Oridation )
Onudalion
Loss e
Reduciona hydrgn
in eadalion umber
Rooucing agint (Reduclant )
eve element
Raduclion
e
> Reducien
’Addihon
> Decease eridalion nunber
’ Oriclsing agpnt (eudent)
’ Adciten etue element
>Nad Cidalion hal reslion
Na Not+ e eniclation hal eacton
Cl +e d neducisn haly aaclisn

clecoochemitty
Tke branch &cience whick
deals usith ke paoducion
elicbicihy engy alea
fromchemichl sed auoing
entanlos ruaclion lRodord
and elocbucal
 abod men
yonlancou Grch bany
Elecbochemsby
Elecbochmial cl cell
Ganc/ etaic koll
penlarsas

Damiell Coll

fhadla

ostZinc
02.3
Ekcan stential
The slhcital polenlal dillerence set
betsen hehe metalmetal and l's
in Jhe salaion knson
chcbodeolonlal
Joeluscn the locede
 pelonials
Lensbubuling
enoin bloctuchumical colle
Cel Aotalien
Reyoesentalon
AA
an elhcbuchumical coll
qalanie cell
suighting anede hre
Aos) Audation
uducien ecUas)a cothode

lost and then the

The cathade a cell s
Soy iing lcblyteb lost
gqresenlod
Shen the mdal sBlid
and
phase
Zn; Zn" CoR) Zn|Zn (oR) Zhlz(M)Ansale

Za Ansde "cbelyle Salt Cathedic Gathale

Grucalien

Emf Eall ER-EL

Ecol Erthode- Eareole
 CalZnlzn"r)l
culate hepshm) lPh
Kopxcsenlolien cll y call netalion

Oridalzon hol iaclion

sandand em a the
and -0:76 3v
Recluction hal seaclion hall 2e rwspeisdy
Crudaim ZAt
Overallcel Reaetion Roduclin hall seacin
Pbpb 42e pb Pb
Cati2Ag
Cell naation Zn tp Pb" 7Znt Pb
Cal cull2Al2A
Eg: P Zn -Hd Ece?
-0.126--0 763)
Oucatin hal adim Ecel
O126 +0763
O. 637

Reducten hal seaction

2H-ze H
Neunst Equalim
Miyt neMo
cll tlacion
Zn+ Ha
(oR)
Cell nolaton E(M IM) -E (MM)-203 RT lsg LMa

L o nx96500
chemcal cell
 l

3T 3.The 2:Caleulst
Gien 5Fesfesé
Fefee
eyuloium
constanlthelaund to AGnfE
-2X E
2303lgke2T Go
d
do 6500 2:71V srGo
29-212-3 -077
the X x5
2:71 l
Daniellcl the
KJ
at rüartion
252Callot has

tobaen

Emf
E'
Cll Ccal: -237v
gImg at70.93V Pat e
927)
7 34 O 2920.0-(-O.13)
- + K
2 Q:059 2:37 Malma(o-con

E-0.13/
og,
O.0001
Q-001 )
(o00
0001) o
 O001
2:71 b057
2

Ell= 2 6g05
3lla3 3.Ekcbruchemisky
NoCos V2 V.2
tercinaien Conducliily in Tenic Alcls Ve V. 3
soluton Cencenaaien

Cendluclsy the Cenauclance

Cm the seliien on A'Aa (6o0s
Concenbala, 2AP') +2d'Sa)
and u Lhe molan conductisdt at
Nacl are 9l:0,42
Dencenlralion! Colclat the amlan and 126:4 Scmthe
The imcrase mslan condacisit,
Dcid C cHs CooH) conductst acelie
due to the åt A'CHacoOH
hat feduct cemducsty d Acseco- tAn
solurneg hesolion coñlaing'y
: 91-0+ 425.9 -1264
390.5 Senal
enal The Smting melan conduculy a The molar tondutsly at
n
for NaI , Ag CHsGCONa inlinile dilute
he 12-69,9. 10 and 2.78 Snnd at 25'c
and Anien
 2.l9-10)
2(2 6)+12 78 -
25.b
231 O-02 ml
bok Back Selsed.
36 The
Corducsty cell
O-05 md L' NaOH
he
Bome and Senth sution
50 Um dhomstn
Beutien is 520 2oleubta the melar enductisty
Cinduclials and molan condulty S0 Urm
o-02ml Kd solton
R p
s0:5 m
A
(o7) eRA 5.55 Xo'nx DTP5
50 Cn ct2713524
lendulsty kel S.Cm'

0-01148 Scm
Conductist o02 ml' tel selution
reistance
-0.0u8Sca' lao-Cm? L
OD5 mel
-G129 O. 24 2Sm - 229-6 Sen ml
500
Cencenbshen o.o) mel!
Gs4 The melarconducisiy e kel soluhons
ot dlbrent concetiaiosat 2seK
Alscm' ml
20 malm3 0.00019g l4 P-61
0- 000 309 l -29
7520S 0000521 J47-8J
D. D00989 l47-09
Shes that eid is 45 Xi05s'
dinislion Callat h
An15o Sm nel
A -skge: 8746 SomP pllod le') AmK
C
.95. XIDX1000-4215 Scmnl
0 001028
248-15 0.12.33
3A0-5
K Ca0.00102g X(o1233) sI7R x
(-4) -O.1233
Totet Qustion

- 19:0 + 2(76-3) H+e3Ha

2
-271-6 S mtmel E(nhak) EnisHL) 0059

l06-0 - l6o.0 -0-Q059

266 Scmml
ED-O:059. (1D Lo Lo)-05RL
Ccnhaw) =-0:59v

5. Cllao he cn the cell in kl

=(4259 +9| - 126-4) Sem' l

 l05v-0059 The
2

E105-0:0512
2
alaled kondndoly
l-05- 0 0591 (4-602)
2

CulO.91V

2fest t 272fe+I2 Loncenuli DLM andocoM

0-236 V at 24s K , calulate the sonolad
3-6
Gubbs
Melan Cenicanbut
Conducana
2Fe2e>2Fet
2
Iyt2e 236
2-4554lcv 27:11

AG 245542T
45-55KT
X 36
271|

2 %32T

-5-55KT)
2303x B-311 1O X 7896 X105s/e Cleulot its mslan 3T

-7.422
298 Coenductiå ,A - 390.5 Sa/hseht
Am Ke Xlcoo
Melsaly
Why dos he omdutiusty Ilm: 7-996 XiD5 X/000.xo789% =3275
a 241
52-7 327 083
3905 3905
 Kc Cx
2

(o.083)
alalas H.w -Solwions
S3

Arsuson 1yne Buestians 00629

the modles