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▪
𝐸

C+

• C+
−
B
• C+ A−

•
A− B−

•
▪
▪

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C+

C+

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^_^
▪ −

Pot Respuesta a X
𝐾A,X =
Respuesta a A

0.05916 Pot
𝐸 = cte ± Log 𝒜A + ෍ 𝐾A,X 𝒜X
𝑧A
X

F− 𝐾FPot
− ,OH− = 0.1

1.0 × 10−4 𝑀 F −

→ OH − = 3.16 × 10−9 𝑀 ≅ 0, ∴

0.05916 Pot
E = cte − 0.05916 Log 1.0 × 10−4
E = cte ± Log 𝒜A + ෍ 𝐾A,X 𝒜X = cte + 0.2366 𝑉
𝑧A
X
→ OH − = 3.16 × 10−4 𝑀, ∴
E = cte − 0.05916 Log 1.0 × 10−4 + 0.1 3.16 × 10−4 = cte + 0.2296 𝑉
229.6 − 236.6 = −𝟕. 𝟎 𝐦𝐕, ¡ Un 31.5% en la F − !
−𝟎. 𝟕𝟔 𝐦𝐕

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10

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E = cte + β(0.05916)Log 𝒜H+ (afuera)

E = cte − β 0.05916 pH(afuera)

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𝐸 − 𝐸S1 𝐸S2 − 𝐸S1

=
pH − pHS1 pHS2 − pHS1
= 59.16 mV a 25 ℃

−(𝑹𝑻/𝒛𝑭 𝐥𝐧 𝟏𝟎 𝑇 ≠ 25 ℃

= 𝛽(59.16) mV a 25 ℃

−𝛽(𝑹𝑻/𝒛𝑭 𝐥𝐧 𝟏𝟎 𝑇 ≠ 25 ℃

𝐄 = 𝐜𝐭𝐞 − 𝛃 𝟎. 𝟎𝟓𝟗𝟏𝟔 𝐩𝐇

𝐸 − 𝐸S1 pHS2 − pHS1

pH = + pHS1
𝐸S2 − 𝐸S1 ^_^

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KH2 PO4 Na2 HPO4

𝐸 = −18.3 mV 𝐸 = 146.3 mV
20 ℃
𝐸 = 50.0 mV

𝑅𝑇
− ln 10
𝑧𝐹

𝑅𝑇
𝑚=− ln 10
𝑧𝐹

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•
±
• 𝑬𝐮𝐥 ~
•

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±
±

± ± u 𝒜 H+ ±

IrO2
>

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F−

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𝑏𝑐S
𝑐X =
𝑚𝑉0

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H2 S
𝐸 S 2− 𝑉S
Na2 S 𝑐s = 1.78 mM 𝑉0 = 25.0 mL
𝛽 = 0.985

S 2−

𝑏𝑐S (0.43916 mL)(1.78 m𝑀)

𝑐X = , 𝑐X = ,
𝑚𝑉0 (0.74485)(25.0 mL)
𝑐X = 0.042 m𝑀 S 2− .
S2− = 0.042 m𝑀

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𝐸−𝑏
Log 𝑐X =
𝑚

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