Q PILLARS CU-ATS CAMP Chemistry TEST 2 3,5 JULY 2023a1page CU-ATS Chemistry Test » 1 Arrange the three compounds CaS0«, NaF and Li0 in order of increasing melting point. er et a A. Ca804< NaF < Lio 8. NaF «C8504 Lio ©. C3804 LL0 «NaF D. Un0- B. Different oxidation number of chromium Different ligand %_ D. Different coordination numberof chromium \ E Allof the above are true - Q PILLARSALP oee cipesenesecensspioyctnywensoenaaesie NPS meatal ‘Solvent Distance of compound (em) Distance of ‘solvent (em) x Y z | 1 So9 800 41 78» 10 2 1080 9.60 864 1” 3 72 @ | 720 9,5] 540 9) 9 4 1012 935770, u ‘The unkown sample is analyzed by paper chromatography and she result shown Solvent Re @/ |For “07 2 076 3 ost 4 o73 ‘Identify the unknown sample ‘A. Compound x 8. Compound ¥ (© compound 2 1D. Compound ¥ and Z . Compound X and Q PILLARSSiPase 12, Under the same temy reasrand volume gus XY and. . S ‘eprevent mole mass and diusion ret of ea, wha Statements cect? Molar mass vittuson rate A | Memome | Reo 8 My> Mic> Me a> By> Ra @ | MoM me Ru> Re>RY | MesMy> Me Rem | E Ma> Mao My a> RoR 113, What compound has both of ionic and covalent molecule? A. Bath ~ B. HaPO. E. Nacl 0 yo + 300PAN) 14. Theiomic las of elements tre ght of bromine atom and the numb nail ofan felon x hoy due of eaten nf Wat = crest prone or element x7 = ‘ (atomic mess of brominé Uo g/mal andatomieamberofc=6) 2; Fy Sc, Itis @ base when it forms oxide compound % B, Itlea semiconductor. Carbon dioxide gas will form when oxide of element X is added into sodium hyérogen carbonate. 0. Ithas electronegatvity higher than oxygen atom E, Xis transition metal THE U Pituars115. The ireversible reactionbetween Az and B2 produces AB. if 3 mol A: is san lito 2 mol Bz and the reaction is performed at STP. What isthe total volume (dm?) of {gas after the reaction complete? AZ oo SE AY Gog iy Be? ph mt J ay @©rv0 ‘Ano Qo) 116. Freezing point of pure naphthalene is 80°C. If benzoic acid dissolves in naphthalene and the concentration of solution is 2 molkg the freezing point ofthe solution mixture is 60°C, If phenyl benzene dissolved in naphthalene has freezing point of 76.6 °C, what is concentration in molal of phenyl benzene solution? A023 @ou gate |= (C10) os 2038 = (94) m2 09 E. 100 ke w10 4 Fex0s-8c0~2Fe #02 (unbalance) _11L.When 11.44 of solid sample Fe:0s reacts with excess CO, the reaction provides (0 got Fe, What is percent composition (by mass) of FexOs in sample? (Atomic {mass of Fe = 56, ¢= 12, 0=16 gil Sms = 140 ATs weed « 0.088 se 8. 26 el a cso Fee? 5 \ 7 D. 300 Fepy2 0.018 ee mee ) 250 i: w 4.2.44 18. Vitamin Ks contains 76.27% of carbon by mass. The molar mass of vitamin Ksis 178.21 g/mol. What is numberof carbon atoms in 1 molecule of Ks? AS @n oy hE x ae 405 3-4| nin 00 | t9,11809ofcacos reacts with 125m of 02 mol. HC. Whats themass of £2003 remain? (Atomic mass of Ca= 40, = 12 and O= 16 g/mol) A 2509 Caco, vB 9 @ CCl, + HOF COD 3758 ©5009 05 O0AS D. 4879 ~0.0125, oes £675 9 OBS mel 2 Sw ge 33s ‘eo 20, Compound 2s analyzed o figure out of the compostion andthe result shows 40,9 of earn. 6 g of hydrogen and 329 of oxygen atom. If the molar mass of tis Compound is 468 g/mol, what fs the molecular formular ofthe compound? (Atomiemass of H= 1, C= 12nd 0 = 16 g/m} ea ACwHaOw CH O Oo B)CwHwon 1 3R cou 5 4 = C a C. CisHs2013, mo4 Jed slgOy i Cano = (wh 1o-3)5 J Csr vd 0 Wb Core 21. eof wateris aed into 30cm of 08 M NaOH role mass= 40 g/m0}) What nal concertronnuw/v of NaOH solsion? ° a4 Cy ae ' auto wom Ns Ble J Mavs GS | See Gam O,0te9@ = 0, CHE = aepinlee 0. 002 00% com a" R 22. ati teal uber tons ard eecvons fone alot meron gs? A? - a2 ef Ha Lexb02~I0 ©. 60x10 yee © 2410 Oiass ess Q PILLARS> ereactionbetweerAand Bis VX! 22. The reaction betweerAand Bis» + ABs A 28 > 5 "45.5 mot of Solution A (10 mL) is added into 6 mt of 3 mol/L of solution 8. ‘U Afterthe reaction complete, what statement is correct? ra bx maining reagent umber fm Compound Number of moles of AB A 8 ax? 8x10" 8 8 exw? x10 e A exw gnaw? °. ‘ ex0* a5x108 e A ax! ax108 24, The hydride of element X is XH« which jé a gaseous state at room: temp ature and 1 at. if mass of 48 dm of XReis 628 g, what isthe atymic mass of ) PVenRt he Oe BRD gee | . whee ee aq Nw |e Caatag | Mee enioeig tg 42.8 | | Oe 4G om gNLY | a s w xr) | 25. Mass of 0.1 mol of compound Xs is 30g. cafulate number of atoms in0.6 g of @ iy cabarets) » )% a mls 2S «0.03 2 190 A 181410" 8, 241x10" | D. 248x102" —MWX = 300 | along 2 Q¥ 003K G.02% Wo E 5.48x10" 2 | Q PILLARS26, The reaction between lead (I) nitrate solution and potassium iodide solution is shown below Po(NOsbaq) + —=—«2Ki(aq) > ——-KNOs{aq) + Pos) ‘When the two solutions are mixed in atest tube the precipitate formed. Which combination of solutions would produce the greatest of the precipitate? a) mca ae A 50 20 40 | 100 | 9 20 [eps | ee ad 2s eo ©. 75 aoges| 50 gbaetso (| 50 40 go | 78 *haiwnso a ef 2 | pcl a0 foorso 27, 50 om of 0.35 M Fe(NO) is added into $0 cm? of Cr(NO,)s. the solution ‘mixture has concentration of nitrate ions 2.5 M, whats the molar concentration of x(NO3)a? —* Byas mal NO, = 2a FCN), + dermal GND, Bays ghey = ORY w axSt ©. 465 moe HR », 520 Qs (h@) «x (095*5) x 3x C507 © ee aso = ag t 1600 C2 14g 28, what solution has the highest concentration of cHoride ions? ‘A. 001 mol/L HG) 2 45" © rrr ewveacrioweasy oC . 1625 ppmFedts (x4'~ jp2.5) CFeCh) = 9.01" ALC) (acl 204M oLClT E 0.2349%w/v NaCl (mW © 55:5) 4 Cwatt ) = 0.04 7 Q PILLARS O28 0.03 D. 0885 gofNectin mL ofsoltion (6 BET) CH C1) Sg, |soeage 2x8 0. ane? 29. Saluton x compose of 20m of 001 ma/L NACL 30 mL of 0.01 ma cach and ‘50 mL of 0.01 mol/L AgNOs. What is the concentration (mol/L) of chloride ons in the x a solution mintue? A209 Ag a cr = Agel co Oe Re W ©.02 D, 002 7 \E)o003 0.3% ‘Compound Bolling Point (°C) Ky [water selo.| 100 ose | Ethanol 3) 7 (0.20 Ly, 30. Te boing point af ethonatin 279 of wate ‘ethonolin the solution? ism {2 °C, What athe mess () of (@) 7509 nL bg 0.0977 B59 fs apm) ©, 2509 bead ee D. 1259 at OIT) p, rane pee )ot 31. From the energy profil, which step is . ! i i= ate determining step? Orittarsailfaee Oisas| ‘System 1; No reaction occurs when of He and Os is mixed at room temperature, ‘system 2, Violently reaction occurs when sparks happen in mixture of He and O wnat sane cone ‘_ activation energy ofboth systems are the same XII The reaction is an endothermic IV. Kinet energy of bath aystems ie similar A. Lonly (B) ‘and tony . | and it ny . and oniy | E. Mand V only 33. The following rate data were obtained at 25°C forthe following reaction. If reaction is perfumed by using 0.2 mol/dm of A and 0.2 mol/dm'of 8, what is rate Constant ofthe reacton? 2A+0-996 Experiment (Al (mold?) [B}o (mol/dm?) Initial Rate of product 9 a (mové8) oq 010 20x10 2 [#20 | “oa0, sax10 3 ag = 60x10 : se A O1moPUst = fq 218% ta} Lposjtog) Bozmeres 3 HG" C. 1.0 mos? 4 POSE As peseres _ ee) E zomeuist 9 4 geuieY pee ns 3° Sa ea) x Q PILLARS 23‘34, The energy profile of reaction between is shown below. 60 +NO2-+ Cr+ NO Potential energy (kame!) ‘What is the correct conclusion? Reaction process ‘A. The reaction requires minimum energy of 316 ki/mol ‘B The eactionisan exothermic (216 ko! and requtes 128%./mol of eneray . The reaction occurs at room temperature because total eneigy of product is lower than reactant. The activation energy ofthe eaction is 128 kJ/mol and heat of the reaction is ~ 344 ki/mol _ The activation energy ofthe reaction is 128 k,/mol and 316k4/mol are released 35. vine of folowing i ot2closed systems and 2 open systems in oper beoker?\ © |. Add solid NaHCOs into 0.01 mol/L HCI — C.I. Mixing AgNOs solution with NaCi solution © I, Add sli sodium into NaC! solution C.1v. Tirate 0.01 mol/L NaOH with 0.1 moVL HCI CV. Add CO into lime water (uw anav Dung ©) tiv enav .dt.tdonav Q PILLARStion 1 [Activation energyofA+8»C+0 | Es-E | Ee-B UL [AatvationenergyofC+0->Aa+B | EE if &-E in, [Total energy of reaction [e-& | &-6 36, what statement covet? ‘tony (B tone ©. Vandi D.tlanai Uilandi '37. From the following chemical reaction and the reaction rate inthe same period of time. XX y¥ 922 rateX23.72mo\.s 2 48 mous 2 2amous 4 ‘what is value of x+y ~ 2? a2 3re- 4 Q PILLARSBroo > Oita $504) + 0x9) “18046) (unbalance) ae 38, In 10 of reaction container and at equilibrium, y mol of $O,x mo'of Oz and 2y mol of SOs are found. if equilibrium constant ofthe reactions 100, wat is value of Aa2 Ke tse™ way” e oan \ _8 on E 02y 2, oax 202) (OaFroe 438, Thea of the eagton below is negative Ms) + B(eq) = Glaq) +0) +{5) 4 P ‘The highest concentration of product Cis produced when Decreasing particle size of solid A, increase concentration of 8 and ecrease temperature B. Decrease volume of D, increase concentration of B and increase temperature C. Increasing panicle size of A reduce pressure and increase temperature “s D, Decreasing parce size of Aang catalyst and increase temperature E. Decreasing concentration of 8, adding catalyst and decrease temperature Free (00%) / Q PILLARSee Bea Chia) + 242000 spigot (aq +H:S040) —C,> 8%. cu{a) + Hasta) > 3HCNG) + (6) HS 280g) + H2S(Q)-» H2S0U) + 25(6) > Hs Petri iainstiageansicceenen eee oxidizing reagent? yal 2 Cy Ox. HS Strongest oxiiing reagent Strongest redicing gent A ce so: | és) oe hs © 80: Ge ° vas ce e so: Hs ‘41. What volume (mL) of 0.25 M HsPOs are used to ttrate wth 30 mL of 0.08 mol/L. Ba(OH).? 04 Banc! HPO, + darn! BalOHh, ®t Syoanw + tx0.29%02 ea vy A. 209 gmt 8. 91 gt rosy 0. 3m E, 3.0833 g/mL Cet =m at, OFituaasSse eee meron eatin see > A. Flammable 8) Biohazard ©. Radiation ©. ritant . Environment hazard Q PILLARS,