Hannah C- Taoaiiag CAE 362 -V2. Problem Sek 2 1) Given: T= GOK Th=F72K T= 790 E, AZ BS XID T fh sk RG Yrot k 2 Gwen: 0 feaction vate rise Ne Sits $0, Solvtinn: \ GOW we be (& (e)C-4) . wo 1+ kLNO] Ex Asked: Figs KE) Order o€ the eackion ae — 175 000T/mol Solution. 8344 T7rnol aE ~ a) t = 0.5093 N09 Nh, + 304 (low con) fe owns or toe HO +0 7 N, + 04 (hign cone?) Wee 4 Ole : tes Hep’. And oer In - las ODT /mnol 2nd Step: Ist order y Gq T/nol KK oar a te 0-666 Overall omer OF Veaction: \ Vy = 0.70605 - = 1x Step ~ 2nd slep = — 2Q-) - 6, = 0-066 Ga) ; al =| Wye (5052, +s The onder of reaction js Ay order.3) Solution: + Ratt of Formation of NO, ° fro’ K, {i205} - ky [Noz(no3 | - Ks (po*][os4] “Rate of Aisappecirance oF NADs : ~ N05 = -K [0s] + Kylie.) {wo¥] Rate oF intermediate: Fi, > Ka] - i] 8] - Gos] - Ko] G0] T*NO,= © i> 0 i] 05] - G5] KaGie5] 0%] 0K fia05} t,o 0%] —K 0s] K, [NOS] o*] K lva05} = Kp, ] (005) + og] + Ke [NOS] [WF] titel __ [oe] (KeWod + ty KO) (Kaos: Kees fy (eed Gene * O° “tip = O “othe 6) io) 0=‘she!)-4e) to Sahvet] WO] = Ke[NO§] oe 2 Sher He]K, [N05] (KaWor} + K+ Kq[Wo5)) K, [N05] © oe = [hot] (Kaftor] + K+ 442) b K,[N.05} = (yot] Ka{ioz] + 2K, ~PW0s = ~KL,es) + Ky fho,] [nos] “P05 =~ Kilns) + sto) fos + 2K; K - wale we gga) Kx [No.] =k (halt Gages.) = KN] K,fho})- 2K, Kun Ky{ioal + X, - K(N,0s\(0 “) ~WN0s = -Ki(N,05] Fst order reaction = [yor]