xt (Pani, GRB New Era Chemistry Class UESTIONS ——_ je: ETITION KIT : OBJECTIVE COMP’ the oxidation stat of ntogeny (Thee inno change nthe osiiage ot bxdoge ee © Y : a) nd is formulated ag Oxidation is defined as: (b) gain of electrons Ooh as ring complex compour mulated : State of iron is Beer ROME tetsu Ohioy Te den (ao eee onion 17. Rctaton of Soom mena guid ammonia is stongly 8 nga 1202 reducing de to he a eee (©) acide nue of Hy (@) sodium cont hydroxide AMkaline nature of fy. ium amide lecrons 8 The cman eg oe, i KFC 1% Iowan Of the following compounds, lowest dation Os eer @ Feso, (H,), 804 64,0 4 T8NECO),, the oxidation state of Ni () K4Fe(CN), a4 ©) Feng.0 The oitn suber iv, When dau With oxalic acid in acidic 8 . 4 ss te {elton the oxidation numberof Mi hanges from: © When Preacts with Droz ©) 704 eye @ 602 (pH2PO:. The reaction 70. In the following reaction, 8 reduction 3Bry + 6CO}- +3H)0=5Br- +BrO3 + 6HCO; (©) both oxi and () bromine is oxidised, carbonate is Teduced Whine atalisation (©) bromine is reduced, ee aenget ee (©) bromine bt Bry = (b) 2Na ©) Hels (9 neodisNS ich of @) 24s 0) 2810+ 0, (©) BaQ, + (@ 2kcio. {0 2kcio, of: (©) decomposition 10. In the Teaction, 2Na. cs as (9) red ©) oxic ing agent (©) oxidisis as well 8 reducing agent @ none offike pret, ne TL. Select ae ‘compound in ‘Which chlorine shows ‘Oxidation, state 47 @ Hci, (b) Hao, (© Hey @ Hao? R oie ot of he folowing 4 reducing agent? 13, $9, Ozone. (6) Chior (©) Feet. ® Naso. taf open in Nay, yy Nt 2803 2 S28 Oa ae (2 Phonas i 14 HBr and Rate eilphuric acid. HC\ na? educe wetter in amas (one so HF can rte i n ©8 wae © 41 @ ~ 1991 Kno, Tenet sass ofthe lectronegaty (© K,C0, (@) none of these Teach mag clement 1S. One Mole Of NaH loses 10 mole of electrons 10 form a aren Pe of te Se beoween Bag “HHASOs "W sompound ¥. Assuming ts nittogen appear inthe () Oand 1 ©) ~1 and 9 a ©) -2and0 @) 2 and $1re jpedox Reactions In the reaction, 4Fe +30; —4Fe* +607" which of the following statements is incorrect? {@) It is a redox reaction. {(b) Metalic iron is a reducing agent. (©) Fe°* is an oxidising agent. (@) Metallic iron is reduced to Fe?*. Which of the following halide ions is easiest to oxidise? @F Oc © @r yo. Which of the following compounds has hydrogen with ‘oxidation number -1? @ Ha (&) NaOH © LH (@) HBr 31. The oxidation number of chlorine in HOC! @-l (0) zer0 + (@) #2 32, In acid medium, the reaction, MnO; —> Mn?* is: (a) oxidation by 3 electrons (@) reduction by 3 electrons (©) oxidation by 5 electrons (@ reduction by 5 electrons 433, For the redox reaction, MnOj +C,03- +H* —>Mn?* +CO2 +10 the correct coefficients of the reactants forthe balanced ‘equation ar: (MP PMT 2010] ‘MnO; cor Ht (Ra 5 16 ) 16 a 2 ©. 5 16 2 @ 2 16 5 34. The oxidation number of phosphorus in PO”, P,Oyo and P.O} is: @ + w) 8 © @ 2 35. The oxidation state of Ct in K2C120y is: (+7 0) +6 8 @ #2 36, Oxidation number of ‘S* in NaS4Og is: (@) +05 ) 25 oO @ +6 37. Which one of the following is not a redox reaction? {(@) CaCO —> C20 + COz () 2H; +0) 9220 (© Na+H,O—>NsOH+ 5 He (@ MaCls —> MnCl + Cl 38. Which substance is serving as 2 reducing agent in the following reaction? MH + CxO} +3Ni—9 20" +7H,0-43Ni7" @ #0 ON ox’ @) CF 39, The oxidation state of iodine in H4lOG @ +7 @ -1 © +5: @+ 40, Oxidation numberof N in NH,NOs is: w3 (0) +5 (©) Band 45 @ Band-5 r. so 41. The element, which shows minimum oxidation number in its compounds, is (®) Fe (b) Mn (0) Ce Mk 42. In which of the following compounds, the oxidation ‘number of iodine is fractional? @ IF ty © IK @ I : 43. A compound contains atoms A, B and. The oxidation umber of A is +2, of B is +5 and of Cis -2. The possible formula of the compound is: (a) ABC (0) By(AC3)2 (0) Ax(BCQ)2 @ ABC )2 44, For the redox reaction, HgCl; + SnCly —> 2Hg + SnCl the correct coefficients of reactants for the OTT 12, ©22. O41 45. The value of nin the following ‘equation is: (Cr 0F +14H" +e — 2Cr°* +7H,0 @2 3 .@4 as 46. Why is the following reaction not possible? CyOF + Fe +H pntant (a) Both Cry0}” and Fe°* are reducing agents (b) Both Cry 07” and Fe’* are oxidising agents (©) Cr,0}" is a strong oxidising agent while Fe* isa weak oxidising agent (@) The solution is acidic in nature ‘one of the following statements is not correct? {@) Oxidation number of $ in (NH,)2S20x is +6 {) Oxidation number of Os in OsOy is + () Oxidation number of S in HpSOs is + 8 (@) Oxidation number of © in KO is — 48. The oxide which cannot act as a reducing agent, is (@) SOp () NO2 (©) CO @ co, 49. Which ofthe following is a redox reaction? (a) HySO, and NaOH from O> (b) In atmosphere, O3 (©) Nitrogen oxides’ from nitrogen and oxygen by 4. lightning (@) Evaporation of HO 50. Number of moles of KCr}0y reduced by one mole of ‘Sn?* jon is: @ 1B 3 us @6 ‘51. The metal oxide which decomposes on heating is: (a) 220. (0) HzO (©) Al, (@) Cuo 52, The standard oxidation potentials, E°, for the half reactions are as: Zn —+2Zn* 2c", E°= +0176 volt Fe—+Fe™+2e, £°=+041 volt ‘The emf of the cell Fe?* +Zn —> Zn7* + Fei: (a) +035 volt (0) ~ 0.35 volt (©) +1417 volt (@) -1.17 voltSandant reduction potentials at 28°C for the following half reactions are given agaist cach Zn?(ag) + 26 = SZm(s), 0.762 CPM Cag) #3 SS OH, 0.740 +26 Hy, 0.00 Fe ee on Which is the strongest reducing agent? : (@) Zn ty Cr) Hat) (@) Fe? ag) ‘$4 Four colourless salt solutions are placed tubes and a stip of copper és dipped in solution finally tuens blue” (@) PB(NOs)> (©) Zm(NOy)3 (8) CaINOs), Red hot carbon will remove oxygen from the oxide XO. and YO but not from 20.Y will remove oxygen from XO. Use this evidence to deduce the order of activity of the three metals X, ¥ and Z pulting the most active frst: UZ Ax wrxz — @ ZY $6 Which of the following metals doesnot give the following reaction? separate test each. Which, (b) AgNOs, 5s M + Water —+ Oxide ory. (2 tom (Som {8 Mercury sium 57. Which is the best reducing agent? co OE OF OB wr 2 spoon of copper metals paced in soho ferrous Ha spoon of copper mea is tio of fro (@)'Cu wi precipitate out {© fron wil preeipie (©) Cu'and Fe wil prcipate {@) 0 reaction wife pace Among Na Hg, S:Peand! electrodes in lectay te rdroxide + Hy 38. Braphite, which can be used as cells having aqueous solutions: (@) Hg and Pt (®) Hg, PL and graphite (©) NaS (@) Na Hg, S ‘The most reactive metal among the following i Al) Ni (©) Pb @) Cu ‘The standard electrode potentials of four elements A, B,C and D are ~3.05, 1.66, ~ 0.40 and 0.80 volt respectively. The highest chemical activity will be shown ber wa) B wc (Dd 62. The oxide which can be reduced by hydrogen ig @) NazO(b) C20 (@) K30 Wa) CuO 63. The reference electrode is made from which of the following: (a) ZnCl, (6) Cuso, (©) He2cl, (d) HigCly 64. K, Ca and Li metals ma ‘order of their standard el (@) K, Ca, Li (b) Li, K, Ca (©) Li, Ca, K (@) Ca, i, K More electronegative elements have: (a) negative reduction potential (b) tendency to lose electrons iy be arranged in the decreasing lectrode potentials as: 66. Bans electrons more easly &) Zn wart A (@) Nat 7 ae SRB Now Era Choristy Gass Wa a 67. ‘the postion ose ntl in he cette ie ster sletrponive Shas py i NS 7m Ax What happens Cea is ‘se 1 si solution of alumntam mage PE POOR (a) The spoon wil ge cone (0) Away of alubingan sag (©) The soon bones (G) There i no vache 6% HW one eed Panam cc pg m8? (OOF, is the strongest oxiaing agen ot? potential is high oa = CLI is the ‘weakest 70. Owtot Ca Ag Fea metal whic ethers rm nna slag MA ce Ore OC Ok | zm ‘Pes Hamdard reduction potentials a 25°C of Lu, Bal" /Ba, Na* / Na and Mg?* /Mg are — 3.05, 221 and -2.37 volt respectively. Whi | flowing isthe strongest ondnng agent” CMe OF BE () Na* (by Ba Ge) La 72. ‘The emf ofthe cell involving the following 2Ag* + Hy —>2Ag + 2H" is 0.80 volt. The nm (@) Mg? reaction, standard oxidation potential of sil 3 030 toh Potential of silver (@) ~0.80 vot (b) 0.80 vort (6) 0.40 voit (@) ~0.40 vort 73, Ina chemical reaction, K€ 0; +xH,804 + yS0, —5 K 350, #Crg(804)3 +2430 as r(SO4)3 +2 Hy (@) 13,1 © 414 © 3.2.3 (@) 21,2 74. When copper is treated nite acid nite oxide and in equal volumes according to x Gu +yHINOs —+ CUNO), + NO+ NO, +430 ‘The coefficients of x andy are O23 "O26 13 AA standard hydrogen electrode has Potential because: {@) hydrogen is easiest to oxidise (b) this electrode potential is assumed to be 20 {€) hydrogen atom has only one electon {@) hydrogen i the lightest clement 76. The standard reduction potential values of three metalic fations X, ¥, Z are 0.53,~3.03 and ~1-18 V respectively, The order of reducing power ofthe corresponding metas (@ ¥>z>x () Xov>z (©) Z>¥>x (@ Z>x>¥ 7. ‘The oxidation numbers of sulphur in Se. SpFy, HyS respectively are (@)'0,+1yand-2 (0) 42,61 and -2 (c) 0, +1 and +2, (@) -2. +1 and 42 1 certain concentration of gen dioxide are berated, the equation, = @) 3,8 ‘ero oxidation = vayy esox Reactions ‘A gas X at 1 atm pressure is bubbled through a solution ‘containing a mixture of | MY" and 1M Z> at 25°C. If the reduction potential of ZY > X, thet {a) Fwill oxidise X and not Z (b) ¥ will oxidise Z and not 7. in 46 oxida {LIE Sereening 2000) (a) MnO} (b) CCNIg. (6) NIFC) CrOZCly 30, The reaction, 3CIO"(ag) —+ C10} + 2C1 (aa) is an example of: (HIT Sereening 2001] {@) oxidation reaction —_(b) reduetion reaction {€) disproportionation reaction (@) decomposition reaction $1, Sundard electrode potential data are useful for ‘understanding the stability of an oxidant in redox titration. ‘Some half cell reactions and ther standard potentials are ‘given below: ‘Mn0j(aq) + 8H*(aq) + Se” —+ Mn?%(aq) + 4H30(0, ee-151V Cry0F (ag) + 14H(aq) + 6e” —> 2Cr**(ag) + TH;0(0 Be=138V Fe™*(ag) +” —> Fag) o77v 40v Ayla) + 26° — 201 (ag) Identify the only incorrect statement regarding the ‘quantitative estimation of aqueous Fe(NO3)2: UIT Screening 2002], (a) MnO can be used in aqueous HCL (b) Cr,0F° can be used in aqueous HCI (©) Mn0j can be used in aqueous HpSOs (@) Cx0F" can be used in aqueous H>SO4 For the decolourisation of 1 mole of KMnO,, the n0. of ‘oles of Hyp required is [ATIMS 2004] @ in — b) 32 (@) 72 © 52 83. In the balanced chemical reaction, 10} +al” +bH* —+cH,0+ dl ‘a,b ¢ and d respectively correspond to: [AIMS 2005] (@ 5.63.3, () 5.36.3 3.6 @) 5.6.5.5 ‘medium, CIO, oxidises to iy, and Op and itself gets redvced to CI”, How many moles of HzO are oxidised by 1 mole of C10,? ICPET 2005] @r O1s ]2s |W) 3S @s “The oxidation state of iodine in IPO, is JRE (Odsha) 2005} 1 8 4S 4 186, Nitrogen forms a variety of compounds in all oxidation stalls ranging from: TPMT (Himachal) 2006 (a) 31045 (b) 31043 () 31044 (@) 3046 87, Inalkaline medium, HO reacts with Fe? and Mn2* separately to give: isha) 2006] m1. 2. 93, 61 (a) Fe’ and Mat (hy Fe?" und Mn2* (6) Fe?” and Ma! (a) Fe" and Mn?” ructute as show 0 o of Fo 0 The oxidation number of (by #5 onium in the above [PMT (Kerala) 2006) (o) 6 i) 40 compo (a) 44 () 0 Which of the following chemical reactions depicts the oxidising behaviour of 1804? [AIEEE 2006) (a) 2HI+ HySO, —Ty +803 +2H,0 (b) Ca(OH) + HyS05 —+ Ca8O4 + 2H20 (¢) NaCl + HS0, —? NaHSO, + HCL (d) 2PCl, + HyS0, —> 2POCI; + 2HCI+ S020 required t0 oxidise one mole ic medium will be: [AIPMT 2008) (b) 0.2 moles (d) 04 moles 0, is: [VITERE 2008] (@) -033.-1 Number of moles of MnO of ferrous oxalate completely in ac (a) 7.5 moles (©) 0.6 moles Oxidation state of (@) 3.2 ) 10 ‘The reaction, y+ 3NAOH + 3H, —> 3NalH is an example of: {@) disproporionation reaction {) nevtrasation reaction {) double decomposition reaction {@) pyrolytic reaction iat Ooi rs of Pin PO}: of Sin SO} and that of Cr in Cr?” are respectively: [AIPMT 2009] (3 +6and+S (B45, 4Gand +6 Grdtoand+5 — +5,+3 and +6 Oxidation states of Pin HP;0s, HyP)O,, HaP2O> are oxygen in KOs, Naz ool igPO> + PHs [JEE (Odisha) 2008) respetively : [AIPMT 2010] iiss (45.43.44 a5. 3 ass Giidation sat of phosphorus in cyclotrimeta phosphoric arid is [PMT (Kerala) 2011] Gee sO} (+2 . Gran cl gas eats with no and conned som hyde solution, the oxidation number of chlorine changes from [AIPMT (Pre.) 2012] (a) zero to (+1) and zero to (~5) (b) zero to (=1) and zero to (+5) (€) zero to (—1) and zero to (+3) (qd) zero to (+1) and zero to (~3) sie the flowing esto = {MnO} + C202" +8" + Mn?" +2)C03 +520 ‘The value of x,y, in the reaction are, respectively : (JEE (Main) 2013) (b) 5,2 and 8 (a) 2, $ and 16 (@) 2,5 and 8 (©) 5,2 and 16GRB New Era Chemistry Class XI (Partll) eo ASSERTION-REASON TYPE QUESTIONS Zee In each of the following questions, two statements are given; one in Assertion (A) column while the other in Reason (R) column. Examine the statements carefully and mark the correct answer according to the instructions given below: (a) If both (A) and (R) are correct and (R) is the correct explanation of (A). (b) If both (A) and-(R) are correct but (R) is not the correct explanation of (A). (©) If (A) is correct but (R) is wrong. (a) If (A) is wrong but (R) is correct. 1. (A) Fluorine acts as a stronger oxidising agent than oxy- en. ®) Fiuorine is more electronegative than oxygen. 2. (A) PbClz is more stable than PbCl,.. (R) PbCl, is a powerful oxidising agent. 3. (A) An acidified solution of KCIO3 when boiled with iodine produces KIO3. _ (R) KCI0, is an oxidising agent while KIO; is not. 4. (A) Sulphur dioxide ‘and chlorine are both bleaching agents. (R) Both are reducing agents. ‘ [AIIMS 1994] 5. (A) Copper liberates hydrogen from a dilute solution of hydrochloric acid. . ; (R) Hydrogen is ‘above copper in the electrochemical series. [AIMS 1994) . (A) Pb** can be reduced easily to Pb?*. (R) Pb2* is paramagnetic. [AIMS 1997] 7. (A) Zinc displaces copper from copper sulphate solution, (R) The E® of Zn is -0.76 volt and that of copper is +0:34 volt. [ATIMS 1999} 8. (A) Zinc reacts with HSOz, to give Hy gas but copper does not. (R) Zinc has higher reduction potential than copper. 9, (A) Oxidation of carbon in all its compounds is +4. (R) Oxidation state of carbon is not fixed. 10. (A) Gold chloride (AuCI) solution cannot be stored in a vessel made of copper, iron, nickel, chromium, zine or tin, . (R) Gold is a very precious 1 etal. 11. (A) HCIO, is a stronger acid than HCIO3. ® Oridation state of Cl in HC1O, is +Vil and in HC1O3+ itis +V. 12. (A) Oxidation number of Ni in Ni(CO), is taken 2er0. (R) The oxidation number of CO has been taken to be er 13. (A) ons state of “H? is +1 in CuHy and is -1 in i (R) Ca is stronger electropositive than hydrogen.