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Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 2 1 1 1 2 3 3 2 2 3 4 2 4 3 2 1 2 3 4 1 4 2 1 1 3 4 3 1 3 2
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A. 2 1 1 4 2 1 3 3 2 1 2 1 4 2 2 1 4 2 4 2 2 2 3 2 1 2 4 4 3 3
Q. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
A. 1 2 1 1 3 3 3 1 4 1 4 4 2 4 4 4 4 2 1 1 3 1 1 1 4 1 3 4 1 2
Q. 121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150
A. 4 1 1 3 4 3 4 1 3 3 2 3 4 2 4 2 1 3 4 3 2 1 4 1 1 4 3 1 3 2
Q. 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
A. 1 4 2 1 2 2 1 1 3 1 2 3 2 3 1 3 4 1 4 1 4 4 2 3 3 3 3 2 3 2
Q. 181 182 183 184 185 186 187 188 189 190 191 192 193 194 195 196 197 198 199 200
A. 3 1 4 4 4 2 3 3 4 1 2 3 4 4 3 1 3 2 3 2
HINT – SHEET
P H2 −
−−→ −−−−→
−2 x −H2 O
⇒ 7 × 10 =
1−x − H +
⇒ 0.07 − 0.07x = x −
−→
0.07
⇒x= = 0.065 atm
1.07 35. Ans ( 2 )
19. Ans ( 3 ) Reactivity towards EAR ∝ Stability of carbocation
Presence of common ion decreases solubility of intermediate
the salt
SECTION-B
24. Ans ( 1 )
ΔH = nCpΔT
36. Ans ( 3 )
70 = 2 × Cp × 5 Bond polarity (ΔEN) N – F > N – H Bond
Cp = 7 cal/mol K 37. Ans ( 3 )
25. Ans ( 3 ) H-Bonding (inter)
Fact Based 38. Ans ( 2 )
Position of elements in P.T.
26. Ans ( 1 )
Both compounds have same configuration that 39. Ans ( 2 )
is (R) Concept
27. Ans ( 3 ) 40. Ans ( 3 )
It has chiral centre and differently di substituted
double bonded carbon atoms.
28. Ans ( 4 ) 41. Ans ( 4 )
NCERT Pg. # 375 h
λ= , for Be+3, m = 9 mp
29. Ans ( 2 ) √
2mqV
EDG increases basic strength. q=3e
30. Ans ( 1 ) For proton, m = mp
generally HOH ∝ No. of π bonds q=e
1 λBe+3 mp q p mp e 1
∝ (if bonds equal) = √ = √ =
Stability of alkene λP mBe qBe
+3 +3
9 mp .3e 3 √3
HS-2/11 1016CMD303122084
ENTHUSIAST, LEADER & ACHIEVER COURSE/PHASE-ALL ENTHUSE & MLA, MLB, MLC, MLD, MLE, MLF, MLG, MLH, MLI, MLJ,
MLK, MLM, MLN, MAZA, MAZL, MAZM, MAZN, MAZO, MAZP, MAAX & MAPA/14-04-2023
43. Ans ( 4 ) SUBJECT : PHYSICS
n-factor for Mohr's salt is 1 when Fe+2 goes to Fe+3
number of gm equivalents of Mohr's salt = Number SECTION-A
of gm equivalent of KMnO4 51. Ans ( 4 )
n × 1 = 0.5 × 0.4 × 5 → ×B → = AB sin θ
A
n=1
1 → B
if A|| → , then A
→ = kB
→
So mole % = × 100 = 25%
4
52. Ans ( 2 )
44. Ans ( 3 )
Here, v1 = v2 = v
ΔH = ΣΔCH(R) – ΣΔCH(P)
So, Δv = |→v2 − →v1 |
ΔH = –337.2 – 68.3 + 363.7 θ
Δv = √v2 + v2 − 2v cos θ = 2v sin
ΔH = –41.8 kCal/mol 2
45. Ans ( 2 ) 53. Ans ( 1 )
AB
KW [A+B] = [L], [AB] =[L2], [ ] = [L]
h= √ C
ka × C A
10−14
and [ ] = [L0]
–4 (B + C)
⇒ 10 = √
=
1 2
g1 g2
50. Ans ( 1 ) 2 2
5 3
Rate of SN2 is 1° > 2° > 3° =
9.8 g2
Rate of SN2 depends on leaving group tendency. g2 = 3.5 m/s2
1016CMD303122084 HS-3/11
TARGET:PRE-MEDICAL 2023/14-04-2023
59. Ans ( 3 ) 64. Ans ( 4 )
By COME
1 2
mv = mghB
2
v = √2ghB = √2 × 320 × 10
v = 80m/s
ω = ω0 + αt T2 = (24) × (2√2)hrs.
5 3
1/2
(container), ρa decrease and hence P decreases.
RS 5
=( ) 76. Ans ( 1 )
RH 3
71. Ans ( 2 ) uplift = (P1 – P2) A
τ
ω = αt and α= As
I
1 1
τ 1 P1 + ρ v = P2 + ρ v
2 2
ω= .t or ω∝ 2 1
2 2
I I 1
2 ⇒ P 1 – P 2 = ρ [V − V ]
2 2
ωcylinder 5
mr2 2 2 1
= =2:5 1
ωsphere mr2 ⇒ (P1–P2) A = ρA [V − V ] 2 2
2 2 1
72. Ans ( 1 ) 1 2 2
⇒ uplift = (1.3) (2.5) [(70) − (60) ]
for a solid sphere ; 2
= 2.11 × 103 N
Ecenter = 0
E∞ = 0 78. Ans ( 2 )
3GM
For constant thermal current flow
Vcenter = − dT
2R A = constant
V∞ = 0 dx
80. Ans ( 2 )
Vmax = 0 (at infinity) 1 Q−q
W
= =
73. Ans ( 4 ) Q 6 Q
q 1 5 T
=1− = = 2 ....(1)
Q 6 6 T1
Now,
q′ 1 1
1− = 2( ) =
Q 6 3
Fnet = F √2 + F ′
q′ 1 2 T − 62
=1− = = 2 ....(2)
Q 3 3 T1
GMm 2 √ GMm
= + Solving eqn. (1) & eq. (2) for T1 & T2
2 2
a (√2a)
GM 1 T1 = 372 K = 99°C
= [√ 2+ ]
a2 2
T2 = 310 K = 37°C
1016CMD303122084 HS-5/11
TARGET:PRE-MEDICAL 2023/14-04-2023
81. Ans ( 2 ) 87. Ans ( 4 )
For an adiabatic process, For 5s weight of the body is balanced by the
U = a + bPV given force. Hence it will move in a straight
U = a + b(nRT) line as shown.
du
CV = = bR
ndT
so Cp = (b + 1)R
CP 1+b
γ= = ( )
CV b
u2 sin 2θ
82. Ans ( 2 ) R= + (u cos θ)(5)
g
2
(i) Case → Volume = constant ⇒ ∫ P dV = 0
=
(50) . sin 60∘
+ (50 × cos 30∘ )(5)
10
(ii) Case → P = constant ⇒
2 V
1
2 V
1
= 250 √ 3m
∫ P dV = P ∫ dV = P V1
V 1
V 1
88. Ans ( 4 )
83. Ans ( 3 ) After cutting string, net force on block B is mg
2 2
γ =1+ ⇒γ−1=
f f upwards.
2
⇒f= 89. Ans ( 3 )
γ−1
85. Ans ( 1 ) tr = nts ... (1)
v = 2n (ℓ2 − ℓ1 )
= 2 × 500 (49.2 –16) × 10–2 d=
1 1
g sin θts = (g sin θ − μg cos θ)tr
2 2
...(2)
= 332 m/s 2 2
86. Ans ( 2 ) 1
⇒μ=1−
Zero error : n2
Least count of circular scale = 1 = 0.02 mm 90. Ans ( 3 )
50
Reading of main scale = 0.0 cm 3t2
P=
Number of division coincied = 5 2
reading of circular scale = 5 × 0.02 dv 3t2
mv =
Zero error = 0.10 mm = +0.010 cm dt 2
For diameter sphere : V2 3t3
=
Reading of main scale = 1.2 cm 2 3×4
2 2
Let mass A moves with velocity v and collides ⇒ 8gR = vt + 4gR ⇒ vt = 4gR
2 2
Tt = − mg = m × 4g − mg = 3mg
R
mvb 2
m
Tb = + mg = × 8gR + mg = 9mg
R R
93. Ans ( 1 )
(P) Velocity of point P is resultant of rω and
Vcom, and angle between these two vector keep
According to problem mass A moves in a on changing.
(Q) As angular velocity is uniform, so there is
perpendicular direction and let the mass B moves at
only one acceleration, ω2r due to rotation
angle θ with the horizontal with velocity v'. radially inwards.
(R) Only centripetal acceleration due to
Initial horizontal momentum of system (before
rotation is there, radially inwards.
collision) = mv ....(i) 94. Ans ( 1 )
Final horizontal momentum of system (after collision) M1 = M2
= mV' cosθ ....(ii) 4 4
π R ρ1 = R ρ2
3 3
3 1
3 2
1016CMD303122084 HS-11/11