TOC DO PHAN UNG - CAN BANG HOA HOC ‘Cau 1, Gitta mudi dicromat (Cr,0;-) , 6 mau do da cam, va mu6i cromat (CrO;>),, co mau vang tuoi, c6 su cn bing trong dung dich nude nhu sau: Cr,03 +H,O==*2CrO;+2H" (uu decom) (as eg) Néu ly éng nghiém dung dung dich kali dicromat (K,Cr,0,), cho tir tir dung dich xit vao dng nghigm trén thi sé c6 hign tuong gi? A. Thy mau dé da cam nhat din do ¢6 su pha long cia dung dich xit B. Khong thay c6 hign tuong gi la, vi khong c6 xay ra phan img C. Héa chat trong éng nghiém nhiéu din, mau dung dich trong dng nghiém khéng di D. Dung dich chuyén din sang mau vang tuoi ‘Cau 2. Cho phan mg héa hoe sau: 2SO, (k)+0, (Ik) ==280, (k) Khi néng 46 cia SO, ting 1én 3 lin thi téc d5 phan img thuin thay déi nhu thé nao: A. Tang 3 lin B. Tang 6 lan C. Tang 9 lin D. Giim 4 lan (Cau 3. Ménh dé nao sau day khong ding? A. Sur thay d6i ndng d6 chat phan ig lam chuyén dich can bang. 1B. Su thay d6i ndng d6 chat phan tng lam thay déi hang s6 cin bing. C. Sur thay 46i nhigt d6 phan ting lim thay déi hing sé can bing. D. Su thay d6i nhiét d6 phan img lam chuyén dich cn biing khi phan tmg thu hoc tba nhiét Cau 4. Cho edn bing sau:SO, +H,0 =H" +HSO;. Khi thém vao dung dich mt it mudi NaHSO, (khng lam thay d4i thé tich) thi cdn bing trén sé A. khdng xée dinh. B. khdng chuyén dich theo chiéu nao. C. chuyén dich theo chigu nghich 1D. chuyén dich theo chiéu thud C4u 5. Cho céc cin bing sau: (@ 2H) AHyy) Hy; (I) CaCOy,. =X Cady, +CO 4,3 (Ill) FeO, +CO,, == Fe, +CO. (IV) 280.4) + Oy, 2280.) 4)? (V) Nog + 3H yy) ——P2NH yg 5 (VD CO, +Cly, G=ECOCI); Khi ting dp suat ca hé, s6 cin bing bi chuyén dich theo chiéu thuan li AO. BAB C2 DA Cau 6. Trong méi trudng thich hop, cic mudi cromat va dicromat chuyén héa lin nhau theo mot can bing: 210} +2H* ==Cr,07 +H,0 ‘Chit ndo sau day khi thém vio, Lim edn bing phan img chic chiin chuyén dich theo chiéu thuin? A. dung dich NaHCO; _B. dung dich NaOH C. dung dich CH;COOK D. dung dich NaHSO, Cau 7. Khi nhiét 6 tang lén 10°C, téc 6 cia mét phan tg hoa hoc ting lén 3 lan. Ngudi ta ndi rang téc d6 phan img hod hoc trén cé hé s6 nhiét d6 bing 3. Didu khiing dinh ndo sau day la ding? A. Téc d6 phan ting ting lén 256 lan khi nhiét dé tang tir 20°C lén 50°C. B. Téc dO phan tg tang 1én 243 lan khi nhigt dO tng tir tir 20°C 1én 50°C. Trang |©. Tée do phan img tang 1én 27 Lan Khi nhigt do tang tw 20°C 1én 50°C. D. Téc dO phan tng ting 1én 81 Lan khi nhigt d6 tang ttr 20°C len 50°C ‘Ciu 8. Cho hé phan tig sau 6 trang thai edn bing: 20, +0, ==2S0,,, AH<0 Néng d6 ciia SO sé ting Ién khi: A. Giam néng dé cita SO> B. Tang néng dé cia O> C. Tang nhiét dé 1én rat cao D. Gidm nhiét do xudng rit thap C4u 9. Dai véi mét hé 6 trang thai cin bing, néu thém vao chit xite téc thi: A. Chi lm ting téc d6 phan (mg thuin B. Chi Lim ting tée dO phan img nghich C. Lam ting tc d6 phan mg thudn va nghich véi sé lin nh nhau. D. Khing lam tang téc dé cia phan tng thudn va nghich CAu 10: Trong phan img tng hgp amoniac: N,,,+3H,4,—==2NH,,, AH <0 ‘Dé ting higu sudt phan img ting hop phii: A. Giam nhiét d6 va dp sudt B, Tang nhiét d6 va ap sudt C. Tang nhiét d6 va gidm Ap sudt ‘D. Gidm nhiét do vita phai va ting dp sudt (Cau 11. Cho phan img sau 6 trang thai cn bing: H,,,, +F,,, —=2HF,,AH <0 Su bién déi nao sau day khéng lam chuyén dich can bing hod hoc? A. Thay déi ap sudt B. Thay déi nhiét do C. Thay déi néng d6 khi Hy hoac Fy D. Thay déi ndng do khi HF (Cau 12. Hé phan img sau 6 trang théi can bing: H.,) + 1y) —==2HI,, Bigu thite cia hang sé cn bing cia phan img trén la: 2H] HI AL Ke acu BLK, CO. Ke= [HE] 2[H1] [H}{h] Cau 13. Thue nghiém cho biét t6c d6 phan tng: A) + By > 2AB duye tinh theo biéu thire: V = k [A)][B2]. Trong cic diéu khang dinh dudi day, khang dinh nao pha hop voi biéu thite én? A. Téc d6 phan img hoa hoc duge do bang sur bién déi néng d6 cac chat phan img trong mot don vi thoi gian B. Téc d6 phan tg ti 18 thuan v6i tich s6 néng d6 cdc chat phan img C. Téc d6 phan mg giém theo tién trinh phan tg. D. Téc d6 phan img ting lén khi c6 mat chat xtic tac. ‘C4u 14, Trong cée khing dinh sau, khding dinh nao phi hgp voi m6t phan img thudn nghich & trang thai can bang? ‘A. Phan img thudn da két thie B. Phan tg nghich da két thie C. Ca phan img thuiin va phan img nghich da két thic D. Téc d6 phan tng thuan bing tdc dé phan img nghich ‘Ciu 15. Dinh nghia ndo sau day 1a ding Trang 2A. Chat xiie tac 1a chat lm thay déi tée d6 phan tng, nhung khéng bi tiéu hao trong phan ting. B. Chat xite tac 1a chat lam giam téc d6 phan ing, nhung khong bi tiéu hao trong phan tng. C. Chat xiie tac 1a chat lm tang tée dé phan img, nhung khéng bi tiéu hao trong phan img. D. Chat xtie tac La chat kim ting téc d6 phan img, nhung bi tiéu hao khdng nhiéu trong phan ing Cau 16. Khi cho cing mét lrong Magie vao céc dung dung dich axit HCl, tic 46 phan ting sé lon nhat Khi ding Magié 6 dang: A. Vién nho B. Bot min, khudy déuC. La méng D. Thoi lon. (Cau 17. Cho phan img thudn nghich 6 trang thai cn bing: H, (k)+Cl,(k)—==HCI, AH <0 Can bing sé chuyén dich theo chiéu nghich khi ting AL Nhiét dd B. Ap suat C. Nong 46 Ha 1D. Nang dé Cla (Cau 18. Cho phan img: Ay, +B, =2C,,+Dy, 6 trang thai cfn bing. O nhiét d6 va dp suat khéng d6i, nguyén nhén nao sau day lam néng dé khi D ting? A. Su ting néng d6 khi C B. Su gidm néng d6 khi A C. Sur gidm néng dé khi B D. Su gidm néng d6 khi C Cu 19. Cho phan img thudn nghich; 2HgO(r) = 2Hg(1) + 0,(k), AH > 0 Dé thu duge long oxi 1én nhat edn phai: A. Cho phan img xay ra 6 nhiét d6 cao, dp sudt cao B. Cho phan ting xiy ra & nhigt d6 cao, ip si C. Cho pha D. Cho phan tng xay ra 6 nhiét dé thap, ap suit cao ‘Cau 20. Cho mot cuc da voi nang Ig vao dung dich HC12M, 6 nhigt d0 25°C. Bién déi nao sau day khong lam bot khi thoat ra manh hon? ‘A. Tang thé tich dung dich HCI lén gp doi. B. Thay cuc da voi bing 1 gam bot dé voi ©. Thay dung dich HCI 2M bang HCI 4M D. Tang nhigt d9 1én 50°C Cau 21. Su ting dp sudt co anh huéng nhu thé nao dén trang thai can bang hod hoc ctia phan img’ ting xay ra. mhigt dé thdp, ap suit thip Hyy + Bty) == 2HBh, ‘A. Can bing chuyén dich sang chiéu nghich B. Cin bing chuyén dich theo chiéu thudn C. Phan img tré thanh m6t chigu D. Cin bing khéng thay di ‘C4u 22. 6 nhiét d6 khdng ddi, hé can bing nao sé dich chuyén vé bén phai néu ting dp suit: A.2H, (k)+0, (k)==2H,O(k) B. 280, (k) == 280, (k) +O,(k) C.2NO(k)==N, (k)+0,(k) D. 2C0,(k) == 2CO(k) +0, (k) ‘Céiu 23. Cho hai hé cin bing sau trong hai binh kin C(r)+CO, (k)=22C0(k); AH =172 kT CO(k)+H,0(k)<==*CO, (k) +H, (k); AH =—41 kJ C6 bao nhiéu diéu kién trong cdc diéu kién sau day lam cde cén bing trén chuyén dich nguge chiéu nhau (gidt nguyén cae diéu kign khic)? Trang 3(1) Tang mhigt do. (2) Thém khi CO, vao. (3) Thém Khi Hp vao. (4) Tang ap suat. (5) Dang chit xiic tac. (6) Thém khi CO vao. AS. B.2 C4. ‘Cau 24. Cho ba mau da v6i (100% CaCOs) c6 cling khdi rong: miu 1 dang khdi, mau 2 dang vién nhé, miu 3 dang b6t min vao ba céc dung cing thé tich dung dich HCI (du, cing néng d6, 6 diéu kigén tuong img 1a 1), b, ty gidy. So sanh nao sau day ding? thudng). Thdi gian dé da voi tan hét trong ba Alt 0;AH,>0 —D. AH, >0;AH, <0 A. AH, <0;AH, > 0 Cau 27. Cho gidn dé ning lung sau: Gian dba Gin 45 b Trang 4Va cho phuong trinh nhigt hoa hoc: 2Na(r) + Cla(k) + 2NaCl(e) ‘Theo gian dé trén, nang lugng ca phan (mg (1) A. ¢6 thé dugc thé hién theo gin d8 (a) B. c6 thé duge thé hign theo giin dd (b) C. c6 thé duoc thé hién theo giin dé (a) hodc theo gian dé (b) D. kh6ng thé thé hién theo gian dé (a) hode gian dé (b) (C4u 28. Cho gian dé niing lugng sau: Phat biéu nao sau day 1a sai? A. Khi tgo nén 2 mol NaCl tir kim logi Na va khi Cl:, phin img thost ra $22,2 KI. B. Khi to nén | mol NaCl tir kim logi Na va khi Cl, phin img thost ra 411,1 KT. ©. Khi tg0 nén | mol NaCI tir kim loai Na va khi Cl,, phin ting ly thém 411.1 KI. D. Pay Ia phan ting toa nhigt. Cu 29. Cho gidn dé nding lugng sau: Ngudi ta cho 46g kim loai Na téc dung véi 44,81 khi Cly (dkte) thi thu duge ning kong Li: A. AH = 822, 2kJ B. AH =-1644,4kI ©. AH =—41L 1K) D. AH =411, 1k) AH =-822,2kJ (I) Gian d6 a Cau 30: Cho m6t la sit nho tac dung voi dung dich HCl, thay ¢6 khi Hy thoat ra. Thé tich khi Hz thu duge tuong tg véi thai gian do durge nhu sau: LThé tich khi Hp thot ra manh nhat 6 khodng thoi gian ndo? A. Tor phiit thir 2 seal phat thir 3 DB thj biéu dién sw phu thudc thé tich Havao thai gian B. Tir phiit thr 7 dn phiit thir 8 1004 —_ C. Tir phat thir 1 dén phat thir 2 go ve eit * an Sn Ah a 0. D. Ca 3 dap an déu sai =° /* 2. Phan ting héa hoc két thiic sau thoi gian bao liu? — = 5p ALT phit B. 8 phat # | 2» oar ir CL) C.3 phut D. khOng thé xée dinh Thai gian (phi) Cu 31, Khi dua miu Natri néng d6 vao dung khi Ce . : : DO thi bigu dién sy phy those khdi lxong Ch, Neudi ta thu duoc khéi luong mudi an theo thoi 3 mae ie gian nh sau: ; & a 1.Thé tich khi Cl, tdi da (dktc) phan img véi Natrila 2 8 . os bao nhiéu? e a A. 5,6 lit B. 33,6 lit g° C.22,4 lit D. 12 it fo Lots} | eemnenan 1A] | tele t Trang 52.Hoa tan muéi an thu duge va cho tac dung vi dung dich AgNOs du thu duge 71,75 gam két tia tang. Mui an da ly 6 thoi diém? A. 3 phat B. 5 phat C. 4 phat D. 6 phat ‘Ciu 32, Xét phan tg sau xay ra trong CCl, 6 45°C 2N,O, =2N,0, +0, ta c6 dd thi sau 1. Téc d6 trung binh cia phan tg tinh theo O, (v,) va tinh theo N2Os (v2) ¢6 méi quan hé nhur sau: nae aes ea A.y> V3 B.v, H,0 Khi do can bang sé chuyén dich theo chiéu kim ting néng 46 H*. Vay mau ciia dung dich sé chuyén tir da cam sang vang tuoi. Cau 2. Dap an Biéu thire tinh van tée phan img: v = '$O2)[02} Do do khi néng d6 cia SO> ting lén 3 lan thi tc d6 phan img thudn ting 9 lan. Ciu 3, Dip ain B Hing s6 cin bing Ke chi phy thudc vao nhiét d6, khi nhiét 46 thay ddi thi im thay d6i Ke. CHEM"? Khi ting hodc gidm 4p sudt chung ca hé can bing thi bao gid can bing cing chuyén dich theo chiéu lam giam tic dung cia viée ting hode gidm ap sudt d6. (Trong trudng hop nay, khi ting 4p suit chung cua hé, cn bang chuyén dich theo chiéu lam giam s6 mol khi) Khi hé cn bang cé sé mol khi & hai vé ca phuong trinh héa hoc bang nhau hodc trong hé khéng c6 chat khi thi viée tng hodc giam dp suat chung khéng lam cho cén bing chuyén dich. Ciu 4, Dip an C Musi NaHSO, phan li: NaHSO, —> Na* +H" +SO? Do dé khi thém mudi NaHSO, vao dung dich thi lim ting ndng d6 H*. Do dé cin bing sé chuyén dich theo chidu lam giam ndng d6 H’ 1a chiéu nghich. Cau 5. Dip din B Khi tng dp sudt ca hé, cdc edn bing bi chuyén dich theo chiéu thuan la: (IV), (V) va (VD). CHEM"? NaHCO; la chat ludng tinh; 14 mudi axit nhung dung dich pH > 7 (mdi trudng bazo). Ciu 6, Dip an D Trang 7A. Dung dich NaHCO; tén tai hai cn bing: HCO; ==CO? +H" K, =10"* HCO; +H,O==H,.CO,+OH K,=107* Vi Ki < Ke nén trong dung dich cof OH” ] >[H" ] Do dé khi thém dung dich NaHCO thi sé lim gidm néng d6 H* cia dung dich ban dau nén cén bing s& chuyén dich theo chiéu lam ting néng dé H’* 1a chiéu nghich. B, C. Hai dung dich NaOH va CH;COOK déu c6 méi trudng kiém, khi cho vao can bing sé lim gidm néng d6 H* nén cin bing chuyén dich theo chiéu Lim ting néng d6 H* 1a chiéu nghich. D. Dung dich NaHSO, c6 mdi trudng axit, khi cho vao cn bing lim ting néng d6 H* cn bing chuyén dich theo chiéu Lim giam néng d6 H* 1a chiéu thudn. Cau 7. Dip an C Khi nhiét d6 tang tir 20 °C 1én 50 °C thi tc d6 phan tng tang: 3. = Cau 8. Dap an B Néng d6 SO; tang 1én khi cn bang chuyén dich theo chiéu thuan. A. Khi gim néng d6 SO; thi can bang sé chuyén dich theo chiéu lam ting néng dé SO2 1a chiéu nghich. B. Khi ting néng d6 cia O> thi cn bang sé chuyén dich theo chiéu lam gidm néng d6 ctia O2 1a chiéu thuan. c. Khi tang nhiét d6 Ién rit cao thi can bing chuyén dich theo chiéu phan img thu nhiét 14 chiéu nghich. D. Khi gidm nhiét 46 xudng rat thap thi khong dii diéu kign dé xy ra phan ing. CHEM"? + Can bing héa hoc la trang thai cua phan ing thudn nghich khi téc d6 phan ing thuin bing t6c 46 phan img nghich. Do dé 6 trang thai cin bing, phan ting thudn va phan mg nghich van dién ra. + Chat xtic tac khong Lim ng dé cdc chit trong cn bing va cing khéng lim bién déi hing sé can bing, nén khong lim can bang chuyén dich. Chat xic tac lm ting téc d6 phan img thudn va tée do phan img nghich véi sé lin bing nhau (nén khi phan img thudin nghich chua 6 trang thai cn bing thi chat xiie tac 6 tac dung lam cho can bang duge thiét lp nhanh chong hon). ‘Ciu 9. Dap an C Ciu 10. Dap an D + Mac dit phin ting thudn la phin img toa nhigt nén khi gidm nhiét d6 thi cn bing chuyén dich theo chiéu thugn nhung néu gidm nhigt 46 qué thdp thi lai lam cho phin tng khong xay ra. Do d6 dn gidm nhigt d6 vira phai + Khi ting 4p suat thi can bang chuyén dich theo chiéu lam gidm ap suat (gidm tong s6 mol Khi) la chiéu thud. Cau 11. Dip an A Vi tng hé sé cdc chit khi 6 bén phai va bén trai cia phurong trinh bing nhau (déu 1a 2) nén dp sudt khong ‘nh hung t6i trang thai cn bing ciia phan ing. Cau 12. Dip an C Trang 8CHEM"? Téng quat, khi mot phan img thuan nghich dat trang thai can bang: aA + bB===cC +dD. _[ch py ‘Thi hang s6 can bing cua phan img trén la K, = fap AP Cau 13. Dap an B A. Téc dé phan ting hoa hoc duge do bang néng dé cae chit phan img trong mét don vi théi gian. Khi sir dung cum tir “sur bién d6i” thi lién quan dén d6 chénh Iéch. B. Khing dinh phi hop véi biéu thite, cu thé khi [A2].[B2] ting thi V cing tang va nguge lai C. Theo tién trinh phan img, Iuong sn phdm AB tng Ién va long chat phan img la A va By sé giam dan. Tuy nhién néu trong tién trinh phan img, tai mt thoi diém nao dé ta cho thém chat phan tig thi khi d6 tich néng 46 cdc chat phan img tang lén lim téc d6 phan img tang. Nhu vay khang dinh nay sai. D. Phin img nay khéng néi 16 diéu kién phan img 6 cn chit xi tée hay khong nén khOng thé khang inh t6c 4 phan img tang 1én khi co mat chat xi tac. Cau 14. Dap an D O trang thai can bang cua phan ing thuin nghich, cd phan img thudn va phan tmg nghich vin xay ra vi tée dé cla chung bing nhau. Cau 15. Dap an C CHEM"? Cée ban c6 thé ghi nhé nhur sau: Néu chat xte téc bi tiéu hao sau phan img thi cling déng nghia né cing 1a chat tham gia phan img. Do d6 chat xtc tie khong bi tigu hao sau phan ing. Cau 16. Dip an B Khi tang dign tich bé mat chit phan img, téc d6 phan img ting. Khi cho Mg dui dang bét min va khudy du 1a ta da tang dign tich bé mat ciia chit phan img. (Cau 17. Dap an A ‘A. Phan ting thug 1a phan img t6a nhigt nén phan img nghich la phan tng thu nhigt. Khi ting ahiét 6, cn bing chuyén dich theo chiéu phan tng thu nhiét 1a chiéu nghich. B. Vi tng he 86 cae chat khi tham gia phan img va tOng hé s6 cde chat khi sin phim bing nhau nén ap suit khéng anh huéng t6i can bing nay. C.Khi ting néng d6 Hp thi cin biing chuyén dich theo chiéu Lim giim néng d@ H2 1a chiéu thudn. D. Tuong tu dap an C. Cau 18. Dap an D ‘Néng d6 khi D ting khi cn bing chuyén dich theo chiéu thudn. A. Khi ting ning d6 khi C thi can bing chuyén dich theo chiéu lam giam ndng dé khi C 1a chiéu nghich. B. Khi giam ndng dé khi A thi can bing chuyén dich theo chiéu Lim ting ndng d6 khi A Li chiéu nghich. c. Khi giam nang d6 khi B thi cn bing chuyén dich theo chiéu lam ting néng dé khi B 14 chiéu nghich D. Khi gidm néng 6 khi C thi cin bing chuyén dich theo chiéu Lim ting ndng d6 khi C 1A chiéu thudn. Cau 19. Dap an B ~ Khi cho phan tig xay ra 6 nhiét d6 cao thi can biing chuyén dich theo chiéu phan tng thu nhiét la chiéu thuan, Trang 9- Khi cho phan img xay ra 6 4p sudt thdp thi can bing chuyén dich theo chiéu phan img lam tang dp sudt la chiéu thuan. Cau 20: Dap an A C6 phuong trinh phan img: CaCO, +2HCl > CaCl, +CO, T +H,O. Bot khi thoat ra manh hon ngbifa la téc d6 phan ting ting. A. Tang thé tich dung dich HCI khéng anh huéng téi t6c d6 phan img. B.Khi thay cuc da véi biing | gam bot da vdi nghia la ta da ting dign tich bé mat cht phan img, do d6 téc 6 phan tng ting. C. Khi ting ning d6 chat phan ting, t6c d6 phan ting ting, 1D. Khi tng nhiét d6, t6c d6 ctia phan img ting Cau 21. Dap an D Vi tng hé sé cdc chit khi tham gia phan Ung va téng hé sé cdc chit khi sin phim bing nhau nén dp sudt Kh6ng anh husng t6i can bing cia phan img Cau 22. Dap an A O nhiét dé khéng déi, hé can bing s8 chuyén dich chuyén vé bén phai néu ting dp suit la hé cn bing 6 tong hé sé cae chat khi tham gian phan tmg 1én hon téng hé s6 cic chat khi sin phim tao thanh (vi khi tng p suat thi cén bing chuyén dich theo chiéu lam giim ip suat). Cau 23. Dap an D (1) Hai phan img trén c6 1 phan ting toa nhigt va mot phan img thu nhigt nén khi ting hay gidm nhigt d9 thi cdc cn bing trén déu chuyén dich nguge chigu nhau, (2) Khi thém khi CO, vao thi can bing thir nhdt chuyén dich theo chiéu thudn va can bing thir hai chuyén dich theo chiéu nghich. (3) Khi thém khi H, vao cn bing thir nhat thi tng sé mol khi ting Ién lam ting dp sudt chung ciia hé, cn bing chuyén dich theo chiéu lam gidm tng s6 mol khi. Do dé can bing chuyén dich theo chiéu nghich. Khi thém khi H2 vao can bang thir hai thi cin bang chuyén dich theo chiéu lam giam s6 mol H2. Khi 46 cn bing chuyén dich theo chiéu nghich. (4) Khi ting 4p suat thi can bang chuyén dich theo chiéu lam gidm téng sé mol khi. Do d6 can bang thir nhat chuyén dich theo chiéu nghich va cin bing thit hai khéng chuyén dich. (5) Chat xtic tic khong lam chuyén dich can bang hoa hoc. (6) Khi th8m khi CO vao thi cn bang thir nhat chuyén dich theo chiéu nghich va can bing thir hai chuyén dich theo chiéu thudn. Vay cae digu kign théa man la (1), (2) va (6). Cau 24. Dap an A Dién tich bé mat tiép xtc giita cic chat phan tg cang lén thi téc d6 phan img cang cao, do dé thoi gian phan tng cdng nho. Cau 25. Dap an C ~ 6 gian dé (a) nhdn thay trong qua trinh phan ing nang long ctia cdc chat giim dan (chiéu mii tén ning Iuong di xuéng cho dén khi khéng déi la két thic phan img), do d6 day 1a phan img toa nhiét (mat nang lung dudi dang nhiét nang). Trang 10~ 6 gian dé (b) nhan thay trong qua trinh phan img nang Iuong cua cae chit tang din (chiéu mai tén nang lugng di ln cho dén khi khOng d6i nghfa 14 phan ing két thi), do d6 day 1a phan dng thu nhigt (thu them ning long duéi dang nhiét ning). ‘Vay phan ting theo gian dé (a) 1a phan img toa nhiét va phan img theo gidn dé (b) la phan ting thu nhiet. (Cau 26. Dap an A Tuong tu cau 116, ta co gian dé (a) thé hién phan img toa nhigt nén AH, <0. Gian d6 (b) thé hién phan img thu nhigt nén AH, >0 Ciu 27. Dap an A han thay phan tmg (1) c6 AH <0 nén day li phan tng t6a mhigt. Do dé phan img (1) 06 thé duoe thé hign theo gidn dé (a) (chiéu mdi t8n di xudng thé hién sw giim nang lugng, dén khi ning lugng khong thay d6i la phan ting két thie) voi nding Iugng mat di duéi dang ahigt ning Ciu 28. Dip an C Quan sat gidn dé nang Iuong ta ahdn thiy day 1a mot phan ting t6a nbiét voi phuong trinh phan img nhu sau 2Na+Cl—>2NaCl AH =-822,2 KI Do dé khi tao nén 2 mol NaCl tirkim loai Na va khi Ch, phan ting thot ra 822,2 KI. Khi tgo nén 1 mol NaCI tirNa va Cl, phan eng thoat ra © ALLLKS, 2 Cau 29. Dap an A Tir gidn dd nang long ta ¢é phurong trinh phan ing nhur sau 2Na + Cl; > 2NaCl AH = -822,2 kJ C6 ng, = 23mg, =2= My Khi d6 nang lugng thu duge la -822.2 kl CHEM™ Ngoai cdch quan sat d6 déc ctia dung thé tich biéu dién trong dé thi nhu trén, cée ban cdn ¢6 thé tim ra dap an ding bing cach tim thé tich chinh xc khi H, thodt ra tai mdi thei diém ri tinh thé tich hidro thoat ra trong mot khoang bang cach ly thé tich khi tai hai ddu mat cua khoang d6 tri cho nhau. Khoang nao 6 chénh Igch thé tich Ion nhit thi d6 1a khoang thoi gian khi thoat ra manh nit. ‘Cau 30. Dap an A, A 1. Khoang théi gian cé khi Hp thoat ra manh nhat la khoang thoi gian c6 46 déc eta dong biéu dign thé tich Hy déc nhat hay 14 doan ndi thé tich trong khoang thai gian d6 hop voi dudmg thing ding mét géc ‘ho nhat (do khi thoat ra cang nhiéu thi chénh 1éch luong khi tai hai thoi diém cang 1én nén dudng thang th hai thoi diém cang dic). Khi d6 thé tich khi Hy thot ra mgnh nhét 6 khoang thoi gian tir phat thir 2 dén phat thir 3. Cu thé nhu sau: ‘Tir phiit ther nhat dén phut thir 2: AV; =10-3 = 7 (ml) Tir phiit thir 2 dén phat thir 3: AV, = 50 -10 = 40 (ml) ‘Tit phiit thir 3 dén phat thir 4: AV; =78 - 50= 28 (ml) ‘Tit phiit thir 4 dén phit thir 5: AV, =85 - 78 = 7 (ml) ni thé Trang IL‘Tir phiit ther 5 dén phit thir 6: AV; = 89 - 85 = 4 (ml) Ter phiit thir 6 dén phit thir 7: AV¢=90 - 89= 1 (ml) ‘Tir phit thir 7 dén phut thir 8: AV; =90 - 90= 0 (ml) Vimax(AVi/ AV2, AV3, AV, AVs, AV6, AV; ‘Nén thé tich khi H, thodt ra manh nhat tir phat thir 2 dén phit thir 3, ‘2. Nhan thay tir phit thir 7 dén phit thir 8, thé tich hidro thoat ra khéng thay déi nén tai phut thir 7 phan ting két thi. ‘Viy phan ting héa hoe két thie sau thoi gian 7 phat Ciu 31. Dap an D, C 1. Quan sit dé thi nhin th4y lung mudi 4n t6i da thu durgc 14 58,5 gam ; vac = 9,5, = Myer 1 Moya = Vay thé tich Cl toi da phan tmg v6i Na la: Voy, nac = ),5.22,4 =11,2(lit) ‘Va2max $.22,4= 11,2 (lit) 2. C6 phan tig: NaCl + AgNOs — NaNO; + AgCl| 2 Moy = 71,75 Mage > Moy = 0,53 Myo, = 29,25 Do dé mudi an da lay & phit thir 4. CHEM"? ‘Voi cu niy, mot sé ban c6 thé mic sai lim nhu sau: Khi tinh téc d6 phan img trung binh theo mét chit, ngoai viée lay chénh léch néng dé chit phan img chia cho khoang thii gian thi ta can chia cho hé s6 ti luong cita chat dé trong phuong trinh phan img. ‘Cau 32. Dip an C, A,B 1. Téec d6 phan img tung binh Li nhu nhau dit tinh theo cht nao Vihé i Iuromg cia N30 vi O3 trong phan img lan lurot 142 va | véi 2 >1 Nén tée d6 phan img trung binh tinh theo Ny theo oxi ), nhé hon (bing mét ntta) te d6 phan tng trung binh tinh Khi dé cde ban chon dap An v, > va Tuy nhién cde ban can Iuu ¥ ring cit 2 mol N20; phan img thi tao ra 1 mol O2 nén chénh Igch ndng dé trong mét khong thai gian cla N2Os cing gap déi chénh Iéch ndng dd ea Oz trong khong thai gian d6, Vay nin téc d6 phan img tinh theo hai chat du nhur nhau: AC ya Owe 2ACy, AC, 2At At At 2. Téc dé trung binh ciia phan img trong 184 gidy diu tién: =1,36.107 3. Téc d6 trung binh cia phan tng trong khoang thoi gian tir gidy thir 319 dén gidy thir 526 la AC _1,91-1,67 At 526-319 16.10* Trang 12CHEM"? Thoi diém dat trang thai can bang 1a thoi diém toc do phan img thuin bang tc d6 phan tng nghich. ‘Cau 33. Dip an C Quan sat dé thi ta c6 thoi diém dat trang thai cin bing 1a thoi diém co dudng biéu din téc d6 phan img thudn tring véi dong biéu dién téc d6 phan img nghich. Do dé thoi diém cdn tim 1a gidy thir 10 Trang 13