The temperature of the system influences the speed of a reaction.
In general, a rise in temperature results in an increase in reaction rate. When the temperature of a sample of matter is increased, the particles that compose it acquire a greater kinetic energy. Increased displacement leads to more effective collisions and, consequently, a faster response. The reverse is also true: if we cool a system, we slow down the movement of particles and the reaction rate is decreased. This is also the reason why food is stored in the refrigerator: a cool temperature slows down the rate of food degradation. The influence of temperature on reaction rate can be illustrated using the Maxwell-Boltzmann distribution curve. The graph below represents the velocity distribution in a gas sample at two different temperatures. It is observed that an increase in temperature flattens the distribution curve and shifts it to the right. The average speed of the particles is then greater at higher temperatures. Also, more particles have more energy than the activation energy when the temperature is higher. The reaction then proceeds more quickly.
The higher the temperature, the greater the number of particles
with the minimum energy to react. Thus, the reaction proceeds faster (the reaction speed is greater). It is usually observed that an increase in the temperature of the reactants of 10°C doubles the rate of a reaction.
The effect of a catalyst
A catalyst is a substance that increases the speed of a reaction
without taking a direct part in it. It lowers the amount of energy needed to initiate the reaction. Some substances make it possible to modify the reaction rate without being part of the reactants or products: they are called catalysts. The catalyst is not involved in the reaction; It is found intact at the end of it. Rather, its role is to lower the activation energy required for the reaction, allowing more particles to collide effectively and thus be able to react. The speed of the reaction increases. The influence of a catalyst on reaction rate can be illustrated using the Maxwell-Boltzmann distribution curve. The graph below represents the velocity distribution in a gas sample in the presence or absence of a catalyst. It can be seen that the activation energy required for the reaction is decreased in the presence of a catalyst. Thus, more particles have an energy greater than the activation energy. The reaction then proceeds more quickly.
There are substances that have the opposite effect to catalysts:
rather than increasing the speed of a reaction, they decrease it. These substances work by increasing the activation energy of the reaction. This can slow down certain processes. These substances, sometimes called negative catalysts, are inhibitors.
A homogeneous catalyst is a substance that is in the same phase
as the reactants. A heterogeneous catalyst is a substance that is in a different phase than the reactants of the reaction it catalyzes. Catalysts are used for several purposes. The yeast that is added to bread produces substances that catalyze the emergence of bread. In the food industry, inhibitors are often used to slow down chemical reactions that cause food spoilage. Some carnivorous plants, in order to be able to digest insects, produce substances that accelerate this digestion. The chemical reactions taking place in our bodies are dependent on biological catalysts called enzymes.