Se EEE cum caine eiok sys} Q.1 Which of the following have identical bond order .( CN- a o, (II) NOt (Iv) CN* AA) I UL (BLU (1m (D)1, 0, Q2 How many unpaired electrons are present in N,*: SA)1 (B)2 ©3 4 Q3 The species which does not show paramagnetism is: (A) 0, (B) 0, * 4@) 0,2 ()H,* 4 ans Q eNom : SS (1 AC} 2.5 (D)3 Q5 Which ofthe following'species isthe least stable ~ (ao, (B) 02 -(©o0" @)o, Q6 Pt-Cldistance is2.32A.CLCI distance in] and Ilare: NH, NH, @c cl q@ ci NH, NH; a MO) 4.64.4,328A (B)5.64A, 4.644 Q7 Which ofthe following facts regarding change in bond lengthis correct ? -A) Increases in going from N, to 'N*,, decreases in going from 0,10 0*, (B) Decreases in going from, toN’; i increases in going from 0, to 0, (C) Increases in going fromN, toN*, and O, to", (©)3.28A,4.64A — (Dy None is comet (D) Decreases in going from, to’, and 0, to 0°, Q8 The common features among the species CN-, CO and NO* are (A) Bond order three and isoelectronic (B) Bond order three and weak field ligands (C) Bond order two and x-acceptors (D) Iscelectronic and weak field ligands (Rae IIT Academy @ Werske waarQUs (Q.16 4ie@ ‘The nodal plane in the 7-bond of ethene is located in The molecu (A) Themolecular plane (B) Aplane parallel to the molecular plane (C) A plane perpendicular t« ‘I ( aa mae lar to the molecular plane which bisects the carbon-carbon o-bond at (D)Aplane perpendicular to the molecular plane which contains the carbon-carbon c-bond ‘The species having bond order different from that in CO is (A)NO- (B)NO* (cn ON, ‘The increasing bond length of O—O bond in0,,0,[AsF,,andKO,is (A) O,ASF,]< KO, <0, 4B) 0,[ASF,].< 0, < Kt * Laseel (©) KO, < O2[AsF,] < 0, (D) KO, < 0, < O,{AsF,] ‘The correct order in which the O—O bond length inceases in the following : (A) H,0,50,<0, — (B) 0,Of (@)R=0F <0; ).31 Which ofthe following statementis true? 4A) F,> OF > OR< ny, , Ti w, ‘The energy associated with doubly degenerate 2p orbital is Lislessthan 2p, in N, 2. is greaterthan 2p, in O, 3.isequal to 2py in C, AVL & 2 only (B)1.&3 only (C)2.&3 only (D)3 only CEs \s are present in antibonding MO's in CN* ion? 2 pa How many e CES ULES When two oppositely charged ions approach each other closely, the positively charged cation attracts tha nntanmact alastmane Fel an andranal its nacitivalchanad nnalane Thic racnlts in the dictartinnqustratior ne decomposition femperitiye YW, be Woe Yb if Us tie 7 WNL, bi Wi PY MA Ube Wo9s Vt) SPP olution? ‘As Li’ ion is smaller than Pia! Wy vy ee LI LN), Ndi wanna) Aang) dace Hey Aas OBES i,C ‘0, and hence Ht hus Jower aa at a oo i Le Pp Meappardiers ine te A A ODN coi aS Peed sy? Qu ‘Compound having lowest mnelting pot Ss (A) BeCl, (1) MgCl, yA o = Q.2 Out ofthe following which one Jas maxinnunn ini Suen? a A) KCI sy Nuc’) (ce, 3 3 Whichofthe following compound ave maniynirn oolect z A)LICI AB) NaCl Gea pe 3 gd Whichofthe following increasing ander core fox covelec SRS 3 (A) NaCl < NaBr Ay . Outofthe following which Se nites foeK TT Can Ve Sy (A) ZnCl, (By LaCl, (cyBaCl, AD) Excl Q.7_ Thecorrectorder ordecreasingpolarizabily ofionis: ) cr, Br. b.F @ FF Br, Ci 4€) 1, Br ChE wo ra BAT Qs “Which ofthe fllowingign navy asin nO bE] G ea 2 oY ALi? (aa hur) BINS (aq) (CEOK' OX) we 9° Whichofthe following oriet correct for ionic character”? {Ay LiCl Bec, BEN? CCl (c) Licl =BeCl, Kis cu JAK > Cue As 4eycu>Ag 7K ens (jg =cut = BK ‘ | QUI The decreasing corssiyor eine ge ee oh Ay anti > ApCl = Api Al As > Za eCl> Agr > Agi Ag AD) Agr Anh =Aph> Apel P WWW FR OHT ROamor compo Gert Yee ee @Rao WT Academy Citra we Q.12, Which ofthe following statements is/are true for BaO and MgO? . {AA)BaO is more ionic than MgO 4B) MgO is more ionic than BaO. Ly ON (2) Ba0 has a higher melting point than MgO. £0) MgO has a higher melting point than BaO, On heating to 490 — 500°C. relatively unstable hydrides and carbonates decompose. Which of the Fete At hyeliele Ome Crys lang following will decompose when heated to 499 — 500°C? Sebieh E Snir 8 Sap Bl Ro 0, ya, C0, “ayer Which ofthe following substances are expected to be covalent{{ mile ¥ (A) BeCl, B) SnCl, @% 258... -®) ZnCl, QAS Which ofthe ollowinghavean (1§+2}elecronconfiguration? Sky Coed Cro 7 (A) Pp (B) ca © Bi (D) so? PEIN esas Passage - 1 Inthe ionic bond, the cation tend to polarise the electron cloud of the anion bypulling electron density towards itself. This causes development of covalent character in ionic bond because the electron density gets localised in between the nuclei, The tendency of cation to bring about the polarisation of anion is expressed as its polarising power. The abilit y of ion to undergo polarisation is called its polarisability. The polarising power of cation and. Polarisability of anion are decided on the basis of Fajan nules as given below : ‘ @ —_Smallerthe cation higheris its polarising power. Gi Cations will pseudo noble gas configuration (nsénp‘nd!®) have relativity high polarising power than those with noble gas configuration (ns'np®), . (ii) Large the size of anion higheris its polarisabilty. Q.16 Arrang: Rao IIT Academy -—A Division of Rao Edusolutions Pvt. Ltd. ¢ the following species Ag*, Cu‘, K* in increasing order of polarising power? {AYK"> Cu’> Ag® BYAg> KS Cur _(C) Cu’ > Ag*> Kt SP)Ag’> Cur Q.17__Amongthe following MgCl, NaCl, Na,S,MgS compound havitig least melting point andhighest melting pointare respectively: AA) MgS & NaCl {B) NaCl & Na,S , SOPMgCl, & NaCl (B) NaCl & MgS + Q.A8 The correct order of polarisability I-, Br, Cl, F- is: (A> Br> Cha $B) I> > Br = Cl;> F fOW=Br=Ch>F (PI-=Br< Cr=F1 (4 QS Q6 Q7 Qs Qo Qu Single answer choice t: How many hydrogen bonds can a water: molecule make? (AVL (B)2 (3 (D4 Contrary to other hyulrogen halides, hyxtrogen fluoride isa liquid because (A) Size of Fatomis small (BY UBis weak acid (C)HF molecule are hydrogen bonded (D) Fluorine is highly reactive Which of the following compounds in liquid state does not have hyutrogen bonding, (A) H,0 (B) HE (CNH, (DCN, Hydrogen bond energy is equal to / (A)3-7 cals (B) 30-70 ea (C)3-10 keal (D) 30-70 keals The bond present in CuSO, SH,Owill be (A) ionic bond and hydrogen bond (B) covalent bond (C) coordinate bond (D)allof the above Which of the following has zero dipole moment ? . (A)NH, (B) HO (Bel, (D) SO, A molecule MX, has zero dipole moment. The orb ised by M in the formation ofc bond will be= (A) pure p (B)sp* (C)sp, (D) sp'd Increasing order of dipole moment in H,O, NH, NF, and CCl, (A) CCI, < NF, NF, > NH, > H,0 (C)NF, >H,0 > CCI, > H,0 (D)all the fourhave equal dipole moments Molecule having zero dipole moment is (A) CH,Cl, (B) NF, (C) BF, (bd) clo," Q.10 Thedipole moment ofa molecule of the type AX, havi quare planar geometry is (ayo (BaD (2d (D) none of the above NF, is (A) non-polar compound (B)electrovatent compound Q.12 Intermolecular H-bond (© having low value of dipole moment than NU, (D) ha ing more dipole monrent than NH, One or more than one type (A)highbp. liquid (B) dibasic (© with unique property attacking glass, (D) strongest acid out of HE, HCL HBrand HL 7Rao lit Academy “PYT Wad suonnjosnpg oFy Jo uorstug y—Amapesy LI OFa e X S 43, Rao IIT Academy —A Division of Rao Edusolutions Pvt. Ltd. ECL @Rao IT Academy Q.13 _ Inthe context of van der Waal’s forces, which is/are the correct statement(s)? ! & (A) These forces arise due o instantaneous dipole induced dipole attractions in nonpolar molecules, Q(B) Theseare the forces associated with the interactions of permanent dipoles in polar molecules, Z a (C) The magnitude of these forces increases with the increase of total number of electrons inthe frolecule, . x Ah nm eet yet gah) POM) q PyTne strength of these forces is independent of the molecule shape. Q.14 Which ofthe following molecules have intermolecular hydrogen bonds? \\° ~ hey a (A) NaH,PO, —_(B) NaHl,PO, (©H;B0, (D) (CH,),BO, =e Q15 Point outthe correct statement(s) amongst the following: onl Lai pd plow Y (9) Sodkin Salts arahich more soluble than ammo eel pw 8) SnCl, is moreionic than SnCl, A©)N-H bond in NH has lesser polar character than in BF, - NH, complex. $P) Calcium fluoride is more ionic than calcium iodides Q:16 "Which ofthe following factors are responsible for van der Waals forces? 4A) Instataneous dipole-inducéd dipole interaction, 48) Dipole-induced dipole interaction and ion-induced dipole intettion, (© Pipole-dipote interaction and ion-induced dipole interaction, ©) Small size of molecule pot Q17 Which of the following are true? 4A) Van der Waal’s forces are responsible for the formation ofmolecular crystals, ) Branching lowers the boiling points of isomeric organic. ‘Compounds due to weaker van der Waals forces of attraction. ACTin graphite, van der Waal forces act between the carbon layers, Sa iN fous ( aN (®) In diamond, van der Waals forces act between the carbon layers. Q “He Ge Q:18 "Intermolecular hydrogen bonding increases the enthalpy, of vaporization ofa liquid dueto (A) decrease in the attraction between molecules 8) increase in the attraction between molecules, (© decrease in the molar mass ofunassociated liquid molecules, B) increase in the effective molar mass. ofhydrogen bonded molecules, Q19 Which of the following molecules have intermolecuar hydrogen bonds? fs) CH,CHO ~(B) H;BO, AO) CH3COZH (DY CHLON at: (tans s} Q.20 Dipolement of certain diatomic molecule xy is 0.38D, Ifthe xy distances 158 pm, percentage of electronic charge developed on X-atom is: Ciao WT Academy GG) worst marmeraantcar thememcal Boning ‘ _ @Rao HT Acadeniy 21. [ABC] 22. [AD] 23. [B] 24, [AC] 25. [ABQ] 26. [ABC] . 27. [A] 28. [ABD] 29. [A] 30. [A] 31. [A] 32. [4] ‘ se atx “a fA] 21M 3. [A] 4. TA] 5. By 6. (D] 7. {C] 8 [A] 9. [B] 10. [C] ll. B] 12. [AC] 13: [BC] 14. [ABCD] -- 15. [Aq] % 16. {C] 17. [A] 18. [A] : 3 1 DI 2. Ic. 3. DI 4. (C] 5. Dl 2 3. 6 [C] 7. Bl 8. [A] 9% [Cc] 10. [A] 3 i. [Cc] 12. [AB] 13. [ABC] 14. [BC] g 15. [ABCD] 16. [ABC] 17. [ABC] 18. [BD] 19. [BCD] 3 20. [5] a 14 2 _ yee < pees oe? “a “8 g : Q Mees 5 ay 4 Vp 3 yor ea qt FB - Se Sa S “Jean: ae