UT-5A_Paper-2 (Code-B) JEE (Advanced) CoE (XII)-2021-22

 VQ  VA  
3
B R 2  V B  V S  3B  R 2
2
3BR2
V B  VO  BR 2 I 
r
VP  VS   2B  R 2

PART – II : CHEMISTRY
21. Answer (3) [M(AB)3]
HNO2  HNO3 + NO + H2O

NH4NO2   N2 + H2O + NaCl

NH4NO3  N2O  H2O
+
NO3  Fe2+ 
H
Fe3+  NO [M(AB)2(a)2]

P4O10 + HNO3  HPO3 + N2O5

22. Answer (1)
Complexes a, c, d, e, f are diamagnetic
complexes a, b, d, e,. f, g involves 3d orbital in
hybridisation
23. Answer (4)

29. Answer (B, D)

groups exerting maximum trans-effect

To get substitution, Cl should be anti to Br

30. Answer (A, D)
On adding base some H+ will get neutralised so
equilibrium get shift towards forward side –OH is
a weaker ligand than H2O, may increase 0
value
24. Answer (1) 31. Answer (A, B, D)

c  Both Cu2+ and Cd2+ belong to group–2A

a b 
 
V  CO 6 Cr  CO 6 Mn  CO  
 6
32. Answer (A, B)
 CO 1859 1981 2101 Density of Co  Ni  Cu
25. Answer (3) V > Ti > Sc
CuF2, CuI does exist 33. Answer (C, D)
26. Answer (4)
Fe3+  I–  Fe 2+  I2

FeSO4.7H2O  Fe2O3 + SO2 + SO3

FeCr2O4  Na2CO3  O2  Na2C2O 4  Fe2O3  CO2
LiNO3   Li2O + NO2 + O2
27. Answer (5) 34. Answer (A, C)
CdS, PbI2 and AgBr are yellow in colour 2773 K
Ln + C  LnC2
28. Answer (7) 
Ln + X2  LnX3
gly is AB type of ligand

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JEE (Advanced) CoE (XII)-2021-22 UT-5A_Paper-2 (Code-B)

35. Answer (B, D) 38. Answer (B, D)

Complex formed is Ni(CO)4 It is sp3 hybridised, K + Co NH3 2  NO2 4 
–
molar conductivity
Tetrahedral. EAN = 36
equivalent to 2 particles
36. Answer (A, C, D)
3K + Co NO2 6 
3–

[Ni(dmg)2] structure is as will not give NO test

Co NH3 4 Cl2  Cl  2 geometrical isomers

39. Answer (A, B, D)

40. Answer (B, D)
Solution for Q 39 and Q 40
P is ZnS
S is PbS
37. Answer (A, B)
Q is H2S
Molar conductivity of CaCl2 is equivalent to 4
T is [Zn(OH)4]2– : sp3
charges Ca2+ + 2Cl–
R is ZnSO4
 Molar formula for complex CoCl3.5NH3 should
Zn2+ belongs to group-(IV) hence can be
be [Co(NH3)5Cl]Cl2
precipitate by (NH4)2CO3 + NH4Cl
Molar conductivity of LaCl3 is equivalent to 6
charges.

PART – III : MATHEMATICS

41. Answer (6)  f '( x )g ( x )  g '( x )f ( x ) 
 
( g ( x ))2
1 x 4 I   dx
 (1  x 4 )3 2 dx  f (x)
  1
 f (x)
1
 g (x )  g( x )
Take out x2 from the Dr, it will come out as x3 f (x) f '( x )g ( x )  g '( x )f ( x )
Let 1 t2  dx  2t dt
 g ( x )
2
1 g( x )
x
x3
 32
dx
I   (t
2t dt

2  t 
tan1   C
 1 2 2
 2)· t 2  2
 2 x 
x   f ( x ) 1 
 2 tan1   C
1  1   2g ( x ) 2 
Put  x 2  t 2  2  x  3  dx  2tdt
x2  x   f ( x )  g ( x ) 
= 2 tan1   C
t dt 1 x  2g ( x ) 
 3
dt   C   C1 as f(0)  C1 = 0
t t 1 x 4 Hence, m = 2, n = 2

x 1 1 2  m2 + n 2 = 8
Now  dx 
2
sin x  C2
43. Answer (5)
1 x 4
But g(0) = 0  C2 = 0 x2 1 x2  3  x2  3
 x 4  3 x 2  9 dx  2  x 4  9  3x2
dx
1 1 2
g x  sin x
2  3  3
dx   d x  
1  x 1  x
2
 1    2
  2
Hence, g    k 6 3 2  3
 2  12 2k x  x  9 x  x  3
   
42. Answer (8) 1 x2  3 1 x2  3 x  3
 tan 1  ln 2 c
6 3x 4 3 x  3 x3
{f '( x ) g ( x )  g '( x )f ( x )}dx
We have I  
{f ( x )  g ( x )} g ( x )(f ( x )  g 2 ( x ))  A
1
,B 
1
 12  A  B   5
6 4

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