7 Gas detection technologies ‘The Riken Keiki has many gas sensor technolagies in order to deal with diverse ‘environments and gas types in a wide range of industrias. In this document, we will introduce the following 13 types thet are typically used in industry. 1. Catalytic Combustion Method 2. New Ceramic Catalytic Method 3. Semi-Conductor Method 4. Hot Wire Type Semi-Conductor Method 5. Thermal Conductivity Method 5. Potentiostatic Electrolysis Method 7. Membrane-Separated Electrode Method 8, Membrane Type Galvanic Cell Method 9. Non-Dispersive Infrared Method 10. Interferometer Method 11. Chemical Tape Method 12. Photo-lonization Detector 13 Pyrolysis-Particle Detection Method7. Gas detecion echnologies 17.2. Catalytic Combustion Mathod ers 1 Bet desenpnon This senor detects gas basedoon heat generated by combust gesburving eran aa Se Sansone ceo ~ — Sanne 7 suucta andmicipin [Streture Kocead nrnge sete sot Srememtaateneemncemmegime ores See Saonaceansiec cite Se i Et tocioate eee pen = Eenise lose ee : | Seater ase cen Ira ‘Seon lea epson Tas srt cect ac 3. Sronee Principles} ‘Sot re, evansato geo be saree oe ‘Songer renames Ine cs charge rm prapon e a Siecncrtanon to eT tile tom we FH Se shai isp anda hee i 2 Fenure[he eneor W209 ae an an) Somers epee, nm nim vers, "| 7] SES ESS” on =soee | =e =es Sere aie a, | Seacece ecmateten 'eemme Sat ‘0 Catayst development Fd ecto ‘Toa detertovelermates eal! promctes eww ato’ comet Dimi rescon Having boon developadinoure ot tarsi ite pacar wre | Ofte (soraors hs clay ralon use! cr proptly Slemas he iriacesibe Se Krowtow. proving lrgtem sabity ‘ge tet rd be Posome ino Son nein Sang acrpencoay. : (© Stationary products {GO-As0 CARO S-Type <>) ‘S0-052-D0(Type GF),S0-2600 (© Pomtable products ome. ‘ep-10ce 50.5 ype oP)7.3. New Coraric Catalyic Metrod 7, Brief description “Tho sersoruses autrestomizd oxidn casyst (een crani)tedetarign ina vide args ofcorcertatons oma low le (pm) the lon-xObsenaent LEU), Nisan epocheaningwrou: noeperdertycevlopedby us ava aesacr Geared soc conte 2. Stewie and prinipies Srevewet sence comiasts ites! sommt Seta Sa toe shear SRwd sone oot Canata we comnacaore ‘Sonne "apo The erat tre orton ry Sac Se ceyptesia send ommmn aa teceaene Se eras re risctesenm mete metormai grammes scomeaamnes soumane ese oon [Ridge ese Monee tem wre corte se cn den» noc, een | ‘Bitar Temes grbanncnte wetrhs st = septa uc wes soe ean somone Settee nenscleweneaspeecss % SUNS Team eoecrnans eee era Scigenza casa neemer ett tor ometon oo a 43. Features(of the sensor NC-6239 as an example) Coupuuremtee Oremenareend mame pen vy ——p Seats os one Seis a Seeman oy] ae See’) Eas 4 Se ath | <— Seecr I Onanpechenee gy SO Ske, Ee Seneoee Q oemcan concours Soman’ & Ebert ‘tidoncivet and then transfers. "ty ‘ow levels (opm) te high levels (% LEL). meacntarar © Stationary products {GD.A80, GADD, 604 (Type NC) 'SD-258-D6 TypeNG) © Portable products (GF-03,ox-2009, ‘Gantz et-a000Gas detecton technologies 7.4. Semi: Conductor Method {sthogas conceniatcn tia generd-puposesenortha detects al pon cfgesee tangng tern tone geoea a cortuetbl come SS 2. Structure and prineipies [Stucture} ‘The soteorcorsaisotahestercolanda metal one Semicendutr(Sn3, formed an aura tae, Thatba ie Seuppecith wo Au elecrodesdt ts endato measure He fesitares ota semicondictor Principe) Fran cttad srt ste ne ie scx 0 tome 10 on O°: soracndcar bapa «cons rar, Sis 10-2 + 240 2 6 ‘Ser ce ence Mere hs 3 © Output characteristics ecimarsatccmnme (Gon at canst ‘Sic non cere bed he ener enc watt hoo: om Son © Aging cheraetoristios “The sentria stat over he ong amath ng lite Compareduith he cific combustonoaned wane, {tatype sensors high revttato lly are evere arosshare [Conceptualrencering of the sensorlemen's} sermon ive ciruig "ese Features [of the sensor $6-8521 as an exar © Detection of toxic gases Cangas hfe aurber of elecrensara te etocton Imabity te soso: cofocte vay of gases incon (le gases, neh procuceless certbstonedt. 0 Gas selsctiviy, sang an mourty othe semiconductor rater changes fReimederence efoc Ts characerate sto he enscrio selec detectsome geses ‘5 Products ofthis tyne (examples) 0 Stationary produote (GD.AgO, SD-ABCDY, 60-700. ‘S0-1GH SO.DSE0C-GH1. Brief description ‘Ths sens uses a metal xe semicenducts which changes resistance hen it Comasitocottactwah ¢ cetncobe ges. The ses tec he change in ontarce ‘ibe gos corcervaton a nghsenatiy gus sens iain comers. 2, Structure and principles [Structure] [Concoptualrendering ofthe sonser eloronts) Callstapeecicus-moal(e. lstrum) ie suds metloxite— =T™EI wt Stricenducto arered ent col anes conpessaionelemet 1 ‘in a materal inact apart dtectane gaesstoredoe etiam el | Fart dee sere series mat amt peter yereranO Hy ofthe preccuseal vir cok, The cect ea sloments hewed300% to 400% by the recourmatalwre [Gridge circu 40H nase 250 > Do te ‘Te caret it tov cass he rcctonecion 3 Thea Comrade one by fe resn nd om cup ome ‘tpi tein. The sensorovout is roportonato he oxygen TS xe, 3. Features (ol the sensor OS-B11 as an example ©Output characterises © Aging charactoristiss Thecgenconermaans 9° Ywatonite te soma cmb cay nodooK0 propatensiote cent thee yon Wace Thoserorcomens Ronen § ‘hage voue bore Sesinnameogen Saar Ecnantora eet. Pepetonlt be eras encenaans) Eteainierenge temeet th a too ay ——— > Tesersousesathomiior Qiewearaiveness Syucearprasin 2 Wierangrmapeneessees, 5, Liew ahemtcenearge og Re sensorecesiacncy oat smoet dot dependon a aee nde. eee ‘operat. ‘eee CBT SEFSAA GORA ‘eso SOI0X 0 Portable products ‘Sean cxznr2 Gx B200(TPEO3 LN, ‘Sxcs, or10. Non Dispersive Infrared Method Sine sso rae ser 4. Brief description ‘nso cl tc hago mse ke ym eon Tesanesy dec attract a peu vavungh ngewe! Spang Conaey | asemn oo 2, Structure and principles {structure} [StUCHUE] —casnee cannons ro cw at oe nin Bloc The arb sores emt and Wt ch pesos ‘ooh tems El od el tobe Sta by ho at ara oe iar sacty ome ered B| ‘toma th he tape Senco aan as 5 rat D ogeatene Psa ps east yt ca and asa ran ‘svete bo anact vneswctgn ssa oytwcns, KEalbration curve eeampey] Sensor Sane lo gus wi Be concer: a Koen ccd sere fe sear (ateson cane) kamen ‘Reseawuenntrecightommntent he once ech Oeenmin ‘icin mr Winona cine sr ae concn siesta 2. Features (ofthe sensor DE-2912.5 36 an example Couswerancwtiis O gngetarntttce By aeinsctee schwinn 0 iY Se commeeh eases beeen cd inveadng accuracy overme. Depending Be iTmcaipreooy Stems con Stee SISTER. 8, Star Reema tee Conc tawae! Fate Bpscinauctilr ay estes © Yompmaeaniey onmpustemens te Oa vangensnmnctome Sfosem seprmarcrcine, "(a Rncarmemioy 7 Loe] © armamtyeaes” 7 | Sale Sica” igumamee | meee” AL | Sis a] Siac Treen "enguase) 7. Detectable gas, molecular formula, model, nddetection range examples) ‘8 Products of this type (exemples) © Stationary products a ear 0 Ponabie products a = eT = 33000, AX E500, RK-9700, ce aR ol7. Gas detection technologes 1. Brief description ‘Ringe ton et aig emcee crim aan n Inca mes. was used side coal ines ic measure metaveconcenatin anain cent as is ndaly used te measize solvent corcenatons or hed! Guarttes ous gases sch aati es {[Sructure} ‘Thelin source enti, ache split by apamie plane (Concepualrendering of the sensor elements} ‘Ror eto woth aya(A an) andefactay ara where he Jtectieges fs and ray Bates one ound === {rown he ges chember €vhere be feence 20101. pat ‘Thetwoightays Asn, mesteachatwr at pantcfe ne my, ere plane ror, anc forman rterarencepetern onthe image serarinregh nema andar {Principles} An inteternce patton movesinpropertontothe dflernce Lge inine roracive dey emean De detctableges ant oS 0 ‘nessuresihe dstncethenererence poem hes vale tn = (Dieters be refactne nde ofthe detecule gs ard ae 2. Features: ‘The tava datece tthe itederance pater, 30, 9, Outputcharacteris tics, _maasiredby this sensor's represented as the ‘Stncarraan te soraorprondesavaryhgh wary ‘Seuaton deb 0 Responsiveness 2aL(neas—nate), 273.15 Pes chaoer nna wre GOs Sm Sonoma a 0 ews 34010 sss an 890% wep i Crongeceree «eau Ext mamesnomeraemance tus feaincseSteaenieon — Eehatatawt itera cate wy qeviteecesiectentat Sr Seas maha tenance ta PP ieemcnes been eee meant 5 Seo eerste t petie Srecesnnortae kann ong tn ao ir eperangen he grt, '5 Products ofthis ype (examgles) 4. Measurement ype, detectable gas, molecular formula, and detection range (examples) 0 Stationary products Reocete | maces ar | SS Stasonany Peo Pemymmnnen — [Banas [oe oes © Porable products = teen [ene 07-12. Chemical Tape Method 1. Brief description “Tipsters one pe pgs wi acaba ie cuacie gm roe | [Team [Dame pa Aiea by aoury a pc gh atta tan sche none ced inh tia on ae coo’ caused ye eat bowen o a Tor ad Gabe one {st arin Tecopceeeyow conanwons eon 2, Structure and principles [stucwure} Theserocrhas «ges chabert tan detectble gen. Tis ‘hantarisatghtresivant conden ts seraly ranged and heeds that the ight soutenardighreceving scten can ‘ecagnzethe tare col The senso conte of got creer tndotercomponests such sare! rechanatorreinding ape ‘es eachmeacurement, [structure] ‘natn gn comes ncn wth pe ngage ‘ler Forexamne.fphoaphine PH) comasinie cont wth shaun inte formula belo, {using a c0bnrg mr oappes onto fap, Phy AgCIO, > Ag? PO, + 12 Op The sense appns ght tobe spot en te ape at Yas cored dctarmnathe chang efecto nena eforondaerne Sey afhe detectable gate acetal qusiine eg OTemperature and ‘numidiy characierbtieo ‘poser tne detectonsecton the tot Sas fo clo and he ete ‘yadualy neteases Scene Sereordeernnee changes fete, be auburn ‘eure eoarg a be ‘ Two peng erga oe Oman Aging characteristics ‘O Features ofthe tape-based sensor Contmints ning tess sensrinse at Ma Wi Vey mgnastanen wh exci sieeity re detwioatoni ox srs. provides abe Use of casetetaps whch eos) epace tretsuerer| “Tape ood apermessiramestbass, Wet alows ro hyteess "Teen cause by dtacisbe gas secur on ne speech wenn lv cones “4 Detectable gaa, molecularformula, model, and detection ‘ange (examples) ‘5, Products of tis ‘ype (examples) “Daecube ges [| Mobcunr emule | ocl® | Uewchon range OS tetbrars erect = we reuse [Se reo SBM. = se er ieee (Sip 2S een eng ——7:12. Prato lonization Detector 4. Brief description ‘Sen amar une ogee, reecn obey a rane ot ‘agwive elecodes fer detectns os carer. [Principles] LUemisie igh fom te Ightaowce (ravi lamp) The cases (be go oaiseesestrone,gevertng cation, The generated {ons and electonsare denn byte pote and neste Secrodes sch couse 9 curet'o be gererted Since Currents poportonato the ges concen, te sensor Ireasureatve curtis 9 cntrine ne concetaton ote ‘Dect geclonang# detec gre equresspeatn ef boar energy larger han the ization enray spec toa as is expostedin be enteleston ok eV) Th Eancentatonneteasna linear ‘nth he gas cencenraton The detectable gas enters easton rambo 9d i posed ogee taper {Soucture and principes) O lonization energies of typical substances Dy apoiyg ston energy lagen te gape laa ereay euch ase serserinaaae ‘pealy anes lamp oft ever 72V, © Urravistet lamp “eshoonenst) a Foam] (cristae: [asenas] wiosunae [ay lemeis dteinedby [oun | swnee | 34 tecononatonahe Sacreeante” [Loom [tereamiene| 06 tewlonpvirson” (= [wm [or 4, Detectable gas and molecular formula examples) 5. Produetsofthis te exampes) cams [tee] ees ear Ties cak—| extrinciwrr —| Sor ee GRO] Sakae aac] || O Ponable products oe | bop ar See Tg Tr Slect Pectin eG. —| Games a Tre oe a To = S| [eta a os4. Brief description ‘td ia sich ror asin SoBe kg fis on ec Ivieune reste a vepnsranen tapas nel or sane Pct 2, Structure and principles {structure} ‘Ths sts spear a conbinion feet deconpose and pails rete caress ects QE NON WEP ‘a puice rst an lation ea meee crater wach ently gers nero tang ys nt 8 carers Santor Deeley ers ye meeuronet chao Ite cowoendion chaner enon be moses (Principles) etane e Sues pastes eaten See ‘Stcome ontad ed ens price src thie mewsrmet tae a yc oy, ac fs ts datos ho fn cre sing dure enor OUD rs new rut en oer Sorse avout casedby omeraite hendty andor esse Meat decompose) onmes mia 7°" oe Paves) usr on on © Outputcharacteristics ‘The sensor sup deponeson the concent oft prices produced though het a Seconposton The senscuses § ‘Stelbrfoncuve soft thegst = Eencennton wl bees win fespectatie reading s © Responsiveness Sheethe gastat erterstie ‘eect sectonis ; irmadineyondzedinthe nti tighrespowespeed | [ew trdercelertrepodvcbay. St EL) (0 Aging characteristics fas very longa, apronratly 0yeus one 130 saves comaunniy hardy Seterontanin erermance or te, © Temperature charactorstice ‘The senaorasestte Compensatansnamberte Comperssttemperaure nde emibee tcelert temperature Shorcerstes 2 borne, ‘setine oe) (Otationary products ‘co-T00" FLUO