FREE ROTATION?

CONFORMERS OBOND-
A
-

&BOND X
↳ Free rotation
around
CI. Band
segma -
-

Ethere C246
conformes
Total = -

<- c CHy-O
I -
H 4
 U 4
I -
REPRESENTATION
*

C246 4
- c- a - H
I -M
H
SAW-HORSE NEWMANN
n

H
I
⑧
⑧

⑧ 4
4 -n
4
 *
CONFORMER OF
ETHANE STABILITY: -

ECLIPSED CSKEW G STAGGE

-c
ED
ENERGY: -

/ DAUEDRAL
ECLIPSED) SKEW) STAGGER
TORSUSNAL
4 ANGLE
ED
STRAIN
H

14
H ou
a
0
= 60 H - Total
H - a
-
n. ⑧
STAGGERED
H
I
4
4 H
4
confores
⑧
ECLIPSED 4
O H 08
4
I
-
⑧ SKEW
4 -
-
-

H I
4 4
CONFORMER
* BUTANE
OF AROUND C2-C3 i-

irz-Eu,-c-3
3 4

CH3
I -M3 M

H-

c -
C -
H

- ↳
TOTAL CONFORMERS -> N
 CH3
00
=

(43 CH3
60°
1143 608 4 688
3
↑

4
CH3

utified
2 4
⑧
7 7 -
⑧ ·

↳
4 H ya I
4 H
4 Ling 4 4 H

Fully CH3
-

H
Parbally
-

0 60
0 128
=

Gauche
=

ANTI
eclipsed
0 180°
=

--
Stably
=

FEC PEG Gauche [Anti

Enegy:-
FE] PE) Gauche 7 Anti
 -
GAUCHE
*
EFFECT F -
H

0 -
H

H-Bonding
is
->
If present, then N -4

Stability order: -

Gauche - Anti-PET FE

04
04....04
-1 M2
-

& H 4
I -4
on on
⑳ ⑳

H H
↳ ↳
4 OH

Gauche Anti
- --
- -
 FE

PE

⑰ Gaucher

Anti
 Total
conformers
-
CONFORMERS OF CYCLOHEXANE
NO ANGLE

STRAIN

form
chair -
-
Boat

Chair
TwistBoat
M
Half
-
 STABILITY ORDER Active
oftically
->
-

Chair Twist Boat> Boat

Halfchei
#
ANGLESTRAIN = 1098" -
X
ANGLE STRAIN
2

so
(10920'

- Ea
·
sp" (10928)

x 60
=
 Gauche
effect
-

·00.. -
-

X
Gauche Ante
-
-

X X
*

*
 2021
Puc
↳
exifsed
↳ 0 00
=
-
-
-

*
 NE02dus chem
35x4 ↳ 35 dues

⑩ Marks -
-

-
easy
↓
160
180
 REACTION/LIFE
OLD BONDS 7
NEW BONDS
FORMED
ARE
BREAK
 ⑦ Types of Band
Breaking
I Nitrolytic Bond
fission
> (EN) A > (N)s A B

A B
>ENACENIB AT B-
POLAR BONDS
**

POLAR SOLVENT
**
(eg. 420)
 IEN10
2) Tomolytic
band
fission
AB -

> A Bo
FREE RADICAL

Non
*
Polar Bands
Now
*
Pola Solvent
provide
by light
Favoured
*
and

dr 0 -

0
 SEN 40-Now Polar
·

DEN Fo-Polar
 ELECTROPHILE +
rely charged species
*
*

My, HT, Not

-> elutron
loving species
orbitals
-> electron
acceptor Having empty
*

Levis Acid BF3

->

Allz, SUL
F
D
B - F
/
M F
O
NUCLEOPHILE
*
#- re
charged species
->
Nucleus
loving species Or, MI, GF, Br, 2-

Base Lone Pain

Luis
->

election donor
↳
*
containingcompounds
48:, R-vius, Ron
-
-

R--R or
 * ELECTRONIC EFFECT: -

v V

Permanent
Inductive
Temporary
Etectromeric
*
*

·Hyperconjugation
Resonance
*
 Distance
* EFFECT
INDUCLIVE
-
Effect
saturated
Displacementof signa
*
electron
along a

carbon-carbon chain is known as Inductive

Effect
S-

C_s5F
Samejdass
 Bond.
Operates through
* I

distance and decreases with

distance
Depends
* on

electron
displacementof
Partial
*
C-1 (electron withdrawinggroup
EWG

> LAALCH1
-
-

> MOU EN
groups
-
I SERIES
CATION NEUTRAL

NiFz7-NTRs>-z7 -NO2<-(N<-coon>

F> u > Br > 1 z-OR>-04 >-C= CH > -N427

-
Ph > -
CH
M2
=

- I
CATION T NEUTRAL
a) -1 Selectron
DonatingGroup)
EDG
-
-

DAANVEER

group
-> Mor+I
*
Move-My
 &

ANSON NEUTRAL
0 M3

Ema>-xix<-o-3-0-o-3-c-cs
3-chas--all
a
-

as
7 -
CT37 -

CD3 7 -

CH3
+1

*
ANIONT NEUTRAL

MORE MORE +1
*

CH3 -

+
* 18 -

T7D>4
More
heavy
Nucleus
-
--