JAWAHAR NAVODAYA VIDYALAYA RATIBAD BHOPAL

UNIT 13 – AMINES

REASONING
(1) Rearrange the following in an increasing order of their basic strengths:
(i) C6H5NH2,C6H5N(CH3)2, (C6H5)2NH and CH3NH2.
(ii) CH3NH2, (CH3)2NH, (CH3)3N and NH3
(iii) C6H5NH2,(C6H5)2NH, (C6H5)3N
(iv) C6H5NH2, C6H5NHCH3, C6H5CH2NH2
(2) pKb value for aniline is more than that for methylamine.
(3) Ethylamine is soluble in water whereas aniline is not soluble in water.
(4) Primary amines have higher boiling points than tertiary amines
(5) Aniline does not undergo Friedel Crafts reaction.
(6) Acetylation of aniline reduces its activation effect.
(7) CH3NH2 is more basic than C6H5NH2.
(8) Although NH2 is o/p directing group, yet aniline on nitration gives a significant
amount of m-nitroaniline.
(9) Arrange the following in increasing order of boiling points:
(CH3)3N, C2H5OH, C2H5NH2

NAME REACTION
(1) Ammonolysis of alkyl halides
(2) Carbylamine reaction
(3) Hoffmann bromamide degradation
(4) Coupling reactions
(5) Gabriel phthalimide synthesis
(6) Diazotisation
DISTINGUISH
(1) N,N-dimethyl amine and N,N,N-trimethyl amine
(2) Aniline and ethylamine
(3) Ethanamine and N,N-dimethyl amine
(4) Aniline and ethanamine
(5) Ethylamine and N,N-dimethyl amine
(6) Aniline and methamine
(7) Methamine and dimethyl amine
(8) Aniline & benzylamine
(9) Aniline and N,N-dimethylaniline
(10) Aniline and N-methyl aniline
 COMPLETE FOLLOWING EQUATION

(1) An aromatic compound ‘A’ on heating with Br2 and KOH forms a compound ‘B’ of
molecular formula C6H7N which on reacting with CHCl 3 and alcoholic KOH produces
a foul smelling compound ‘C’. Write the structures and IUPAC names of compounds
A, B and C.