JEE Adv. August 2022 Question Paper With Text Solution 28 August | Paper-2 CHEMISTRY MATRIX JEE Main & Advanced | XI-XII Foundation| VI-X Pre-Foundatio1 Office : Piprali Roa a kar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.cOk MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 Ans. Sol. JEE ADV. AUGUST 2022 | 28™ AUGUST PAPER-2 SECTION 1 (Maximum marks: 24) This section contains EIGHT (08) questions. The answer to each question isa SINGLE DIGIT INTEGER ranging from 0 TO 9, BOTH INCLUSIVE. For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen virtual numeric keypad in the place designated to enter the answer. Answer to each question will be evaluated according to the following marking scheme: Full Marks ; +3 If ONLY the correct integer is entered; Zero Marks : 0 If the question is unanswered; Negative Marks : -1 In all other cases. Concentration of H,SO, and Na,SO, a solution is I Mand 1.8 « 10° M, respectively. Molar solubility of PSO, in the same solution is X « 10-* M (expressed in scientific notation). The value of Y is [Given: Solubility product of PbSO, (K,) = 1.6 * 10, For H,SO,, K, is very large and K,,=1.2 « 10°] ©) HSO, =H + ~~ -HSO, 1 0 1 1 HSO; == H + = S02 [nH |[so; “Trsos) 7 12% 10° ay HsO; == H+ )! 1 1 18% 107 +x 1-x 18 10?-x (18x10 -x)(1- 1.2 « 107 +x Since value of x is very low l+xel l-xal 1.8 107=x=1.2* 107 X=0.6 «107 [S02] = 1.2 « 107 MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.2Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 Ans. Sol. PbSO, == Pb” + $02 s s#12«107 s( + 1.2 * 107) = 1.6 « 10% s+1.2% 10% 12* 107 (5) (1.2 * 107) = 1.6 * 108 5-510" An aqueous solution is prepared by dissolving 0.1 mol of an ionic salt in 1.8 kg of water at 35°C. The salt remains 90% dissociated in the solution. The vapour pressure of the solution is 59.724 mm of Hg, Vapor pressure of water at 35 °C is 60.000 mm of Hg. The number of ions present per formula unit of the ionic salt is 6) P’-P, in Pp in+N 60~59.724 ixO 60 50.14 E3x10' 18 0.276 __ix0.1 “60 ix0.1+100 i 0.1 *0.276+27.6-6i _ Es, <2 640.0276 + a(n 1) {Where n= no. of ions produced by one formula unit of ionic compound} 1+09(n-1) 0.9(n-1) =4 Consider the strong electrolytes Z,,X,, U,Y, and VX, Limiting molar conductivity (A") of U,¥, and V,X, are 250 and 440 S cm? mot, respectively. The value of (m+n + p) is aa oF Lv x Given: 2°(Sem’mol') | $0.0 | 25.0 | 100.0 | 80.0 | 100.0 4° is the limiting molar conductivity of ions MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.3i MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 The plot of molar conduct s X, (S em’ mol ') 3 0.01 0.02 (A) of Z,,X, vs c!? is given below. 0.03 0.04 (mol L')'? Ans. (7) Sol. For U,Y,, 250 =m x 25 + p « 100 For VX, 440 =m « 100 +n 80 For electrolyte Z,X, Ig =A be. 336-339 © 0.04-0.01 Hence at a Cone. of 0.04 336 100 « 0.04 ao =340 340 =m x 50 +n = 80 a Q) =>b=100 GB) From equation (1), (2) & (3) m=2,n=3,p=2 Hence m+n+p=7 MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.4Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 4. The reaction of Xe and OF, gives a Xe compound P. The number of moles of HF produced by the complete hydrolysis of | mol of P is Ans. (4) hk ot) se ONS Cy ae = FN) Ps OXeF, + 12H,O > 4Xe + 2XeO, + 24HF + 30, Hydrolysis of one mole of XeF, (P) will produce 4 mole of HF. 5. Thermal decomposition of AgNO, produces two paramagnetic gases. The total number of electrons present in the antibonding molecular orbitals of the gas that has the higher number of unpaired electrons is Ans. (6) Sol. 2AgNO, > 2Ag(s) + 2NO.(g) + O,(g) NO, and O, both are paramagnetic but O, contains 2 unpaired electron where as NO, contains one. For O, 6}, of 63, o2 03, m3, =, a =a Total number of electrons in antibonding molecular orbitals = 6. 6. The number of isomeric tetraenes (NOT containing sp-hybridized carbon atoms) that can be formed from the following reaction sequence is SS 1, Na, liquid NH, oo E 2. Br, (excess) 3. alc. KOH Ans. (2) Sol. ‘S MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.5Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 CH, -C=C-CH, CH, Al Na, liquid NH, Sc=c7 a 7 Ncu, Br, (excess) FAG pC Ch C=C: “a alc. KOH oo CH,- CH -CH - CH, L Br Br + ‘Br Br H H Neue CY “cu = cu, 7. The number of CH, (methylene) groups in the product formed from the following reaction sequence is 1.0, Zn/H > ai Ie 2. KMnO, 3. NaOH, electrolysis 4, Cr,0,, 770 K, 20 atm Ans. (0) ,, Zn/H,0 IPN 2CH,- CH,-CH,-¢-H —KMnO._ cH cH,-cH,-¢ NaOH, electrolysis Ca Cena a. Sol MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.6.Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 8. The total number of chiral molecules formed from one molecule of P on complete ozonolysis (O,, Zn! HO) is Sol. ao OA CH, oO + i a | Il + CH,-C-H eK COX Na OT ax : Xe CH, OA MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.7Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 Ans. Sol SECTION 2 (Maximum marks: 24) T ection contains SIX (06) questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct answer(s) For each question, choose the option(s) corresponding to (all) the correct answer(s). Answer to each question will be evaluated according to the following marking scheme: Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen; Partial Marks : +3 Ifall the four options are correct but ONLY three options are chosen; Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are correct; a correct Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and option; Zero Marks : 0 If unanswered, Negative Marks: -2 In all other cases, To check the principle of multiple proportions, a series of pure binary compounds (P,,Q,) were analyzed and their composition is tabulated below. The correct option(s) is(are) Compound | Weight % of P | Weight %of Q 1 30 30 2 444 33.6 3 40 60 (A) If empirical formula of compound 3 is P,Q,, then the empirical formula of compound 2 is P,Q, (B) If empirical formula of compound 3 is P,Q, and atomic weight of element P is 20, then the atomic weight of Q is 45. (C) If empirical formula of compound 2 is PQ, then the empirical formula of the compound | is P,Q, (D) If atomic weight of P and Q are 70 and 35, respectively, then the empirical formula of compound 1 (B), (C) (A) If empirical formula of compound 3 is P,Q,. — 3M» 4190-40 3M, +4M, MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.8i MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 Hence for compound 2 3M, Weight % of P= 3g 571° 8M, 3x ea «100 3x si Q 8 = ~3-x100 = 34.78% 8 +5 Me 1602444 M, +My => 5M, =4M, For compound | — Mt _.100=50 5M, +4M, Element | Mass% | Mole | Relation ratioof atoms P so | 2 1 (D) aa 50 50 | 2 y 35 EF=PQ, MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No.9)Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 10, Ans. Sol ul Ans. Sol. The correct option(s) about entropy (S$) is(are) [R = gas constant, F = Faraday constant, T = Temperature] di R pe then the entropy change of the reaction is R (assume that entropy and internal energy changes are temperature independent) (B) The cell reaction, Pt(s) | H.(g, Tbar) H’(aq, 0.01M) || Hag, 0.1M) H(g, 1 bar) | Pt(s), is an entropy driven process (A) For the reaction, M(s) + 2H"(aq) > H(g) + M™*(aq), if (C) For racemization of an optically active compound, AS > 0. (D) AS > 0, for [Ni(H,0), (B), (C) & (D) }* +3 en [Ni(en),}* + 6H,O (where en = ethylenediamine), dE, AS= nF Se (A) ot A8=2F R= 2R (B) Cell reaction is [2H (aq.)] > [2H (aq) 9 0.01 01059 55 (0-01) _ 9 959 2 (01) Hence reaction is spontaneous and it is spontaneous due to entropy charge as AH is almost zero. (C) During racemisation of optically active compound, disorder increases. (D) In this process number of molecules increases hence entropy increases The compound(s) which react(s) with NH, to give boron nitride (BN) is(are) (MB (B) BH, (C)B.0, (D) HBF, (A), (B) & (©) B(Amorphous) + NH, ——> BN +H, B,H, + NH,(excess) > (BN), BO, + 2NH, > 2BN + 3H,0 HBF, + NH, > [NH,"] [BE, ] MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No. 10)Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 Ans. Sol Ans. The correct option(s) related to the extraction of iron from its ore in the blast furnace operating in the temperature range 900 - 1500 K is (are) (A) Limestone is used to remove silicate impurity (B) Pig iron obtained from blast furnace contains about 4% carbon, (C) Coke (C) converts CO, to CO. (D) Exhaust gases consist of NO, and CO. (A), B&O (A) Ca0 + SiO, > CaSi0, (B) In fusion zone molten iron absorbs elemental impurities and pig iron is obtained which contains 4% carbon (©)C+00, >2C0 (D) Exhaust gases consist of CO and CO, Considering the following reaction sequence, the correct statement(s) is(are) Zn/Hg, HCl SOcl. CO BZ0RMC, g __80ch_ ——> P R AICI, AICI, Zn/Hg, HCL —20/He, HCL a hydrocarbon s (A) Compounds P and Q are carboxylic acids. (B) Compound $ decolorizes bromine water. (C) Compounds P and react with hydroxylamine to give the corresponding oximes (D) Compound R reacts with dialkyl ().©, ium to give the corresponding tertiary alcohol. MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No. 11Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 fl CH, CH, ° Sol QW AICI, CH, ~CH,~ CH, ~ CCl oF | soci, —— ) jo Zn/Hg, Ss HCI So CH, - CH, CH, ~ ¢- Cl II R.Cd 0 . 14, Among the following, the correct statement(s) about polymers is(are) CH, - CH,- CH, = - OH l| oO a |" oF Q CH, ~ CH,~ CH, fre oO a (A) The polymerization of chloroprene gives natural rubber. (B) Teflon is prepared from tetrafluoroethene by heating it with persulphate catalyst at high pressures. (C) PVC are thermoplastic polymers. (D) Ethene at 350-570 K temperature and 1000-2000 atm pressure in the presence of a peroxide initia- tor yields high density polythene. Ans. (B), (©) MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No. 12Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 Sol. Ans. Sol. Ans. Sol (A) Polymerization of choloroprene gives synthetic rubber (B) Teflon is prepared by heating tetraflorroethene with a free radical or persulphate catalyst at high pressure (©) PVC isa thermo plastic polymer (D) Ethene at 350-570 K temperature and 1000-2000 atm pressure in the presence of a peroxide initia- tor yields low density polythene. SECTION 3 (Maximum marks: 12) This section contains FOUR (04) questions, Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer. For each question, choose the option corresponding to the correct answer. Answer to each question will be evaluated according to the following marking scheme: Full Marks : +3 If ONLY the correct option is chosen; Zero Marks : 0 If none of the options is chosen (i.e. the questi Negative Marks : -1 In all other cases. is unanswered); Atom X occupies the fec lattice sites as well as alternate tetrahedral voids of the same lattice. The packing efficiency (in %) of the resultant solid is closest to (A) 25 (B) 35 (C) 55 (D) 75 (B) Ba _ 33a _ ap Packing efficiency = 34% The reaction of HCIO, with HCI gives a paramagnetic gas, which upon reaction with O, produces (A) C10 (B) ClO, (©) CLO, (D) C10, «© HCIO, + HCl > clo, + cL HO (Paramagnetic) clo, Oo > ao+ o MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No. 13Ok MATRIX Question Paper With Text Solution (Chemistry) IEE Adv. August 2022 | 28 August Paper-2 17, The reaction of Pb(NO,), and NaCl in water produces a precipitate that dissolves upon the addition of HCI of appropriate concentration, The dissolution of the precipitate is due to the formation of (A) PbCl, (B) PbCl, (C) [PbCL (D) [PbC! Ans. (C) Sol. Pb(NO,), + Nacl——* PbCI, + NaNO, | excess HCI [PbCL] 18, Treatment of D-glucose with aqueous NaOH results in a mixture of monosaccharides, which are CHO CHO HO--H HO--H HO>-H HO--H CN) HOH” HO HOT—H H--0H H—-0H CH,OH CH,OH CHOH CHO CHO 0 HO-4-H Ho—--n H HoH HO lo Og H 3 a H—-OH’ H+—-OH HO-—H H—-OH H-—OH H-—0H MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No. 14CO: MATRIX] 25008 Paper With Text Sotution (Chemistry) JEE Adv. August 2022 | 28 August Paper-2 cHo cHo CHO nto u-bon — Hot+H HO--H = HO--H HO--H © yot+H > Hton 4! —t+on H+-oH H--oH ~~ -H—--0H CH,OH CH,OH CH,OH Ans. (C) HO, cHo Nn C —OH Sol. NaOH HO——H TTautomerisation H>-0H H——OH CHOH Converts into stable aldehyde and ketone , CH,OH CHO cHO cko Ho--H u—Lon HO: -H HO- H HO- H uton * H-+-on * HoH HoH H--0H H--0H (CH,OH (CH,OH CH,OH MATRIX JEE ACADEMY Office : Piprali Road, Sikar (Raj.) | Ph. 01572-241911 Website : www.matrixedu.in ; Email : smd@matrixacademy.co.in Page No. 15