()}—=299, (8). iti. SSN. Ga Wa gu venation: PC) =A (go) w2 uf towards the products (NET dene 15) rrease both retelan and products ne equilibrium constants for the reactions Ci, (g)+2140( 0,48 (0) an J 1,0(€)} C05 (2) (2) are Kan, esp ; scion CH, (8) 1L0(8) Te equilibrium cna fr CO(e) +30, (e) is Meteo INET Je 2015) x (0) KER KK a Ox, son the effetoFaddltion of ag, HClon the ui is 2 Eq A o 92 +a wil sit owardsight incase bth Aad | aula will shift towards eftimease of bot A and F gli am wil shift vss atin A and ein case of iva wilh towards ight Band ti ase of. INET June 2015) i reation, \ INET Dee 201 1.0,,—=H0'Q I highest vale of LX", whem X° is (oF wet (ono; ee North Detar 35-35; Mal Road, TDNsicher (eae any ; wate an) scene 50,9) ==250,0)401 (2) a besipmie s 2 png gins ne ica son oo we} fhe=80, (0) Ry=Sa s()e20 l= Eu OOK 0 (eNO EOL) 1—=22N, cm cont tance, 29, #320, ==22N0 34,0 nes RL a KKK oe ae a ‘Sout Deibi = A-ATI1, dim Sarak, NeweTT —_ in eS. 2060 151008, 2086000 Ge Noy Dear PRONE =ne pve above ows the atom ewe) he phat he sorte presumesequienmat25.A(@)*B(@) ==> C(8)*P(E) AH =S011- Theat 0) Shido the key cel es nai tby change presse cui which s NOT alfeted hy an inerease in pressures 1) 280, (6) -—=280,(2)+0,(8) (1.48) +1, 6) —==2HG) (©) C(2}+1,0(6)—2C0(9); Hh fe) =r Fa)2 HL OLE) == FeO. (9)+4t (a) ON, (8) 3H, (@)} —=2NH4 (6) (EN)? FH (NH) IHataparticulr temperature k,, and, af the equilibrium constants fr reastons (and (espn 2k, -K, Ok =k, reaction: Be, (2) + BE, (g)—» 281; (g) the equilibeiann constr at 2000 Kan Oars 525 by 11.86 (6) Decreases hy a factor of 1.86 (on rm (dh nereases by a ctr oF 8, Inachemical reaction, A (3) + B(e}—==C(e) {NET Jone 201] at quia 6am. The yale of equilibrium constants eH (36Of)“ H0(e): "eetons onl ~€Os(B)H, (yy 8) 0) =—Cof—), 34, ) eX, ant Kthe aban enon a0 Fhe reaction W(t)" 2H OE) 200, fan, gy eee 6) KK, (KK KK midrthe eation, (3) +0, (g) quidem can be shifted owardsy 1 ncreasing the amount oferta asin the Pressure ofthe syaton he oh a uibriun constant K forthe above eet a) 20h L (by L2molL——(@)0Smo|k1 (Amel + ished, iisobserved tae concriation of Aierases (byelther oF € inst be Sil Q (4) the rection W enters ton is exothermic (Gare203) lina SS met (pence INET Dec 2051 sides 10 () 2 2Fe(s) +300 (0) =O )—22C0(g) +04 (6): Ks=2900 0 (3) Ake) #308 ; foo" (b) 210 Tew ean Pl Mail a— 1. 2A ay anigoousl sre Afr the react nth ty ar cention 9 J AB ar memured and eee ao ent cule Wht sth mos appcpritesmeee eae ake. Then the pti are mesure again a the ne ithe rsa of his ex oo alte chemials and he than the abies bot (anes tare te ements oft chemical wl reas ofA and B, wilinrease, a that AB Wil crane and willdecremse, and that of AB willing [GATE 2019, 80; (g)+10, —=80,(e) A208, the standard molar Gibs energies of formation, AGG FSO, (8) and SO, (gare 300 and 7) mot respectively. The value ofthe equiv constant, K,,atthistemperatire isa (Roundofo the nearest eget) (Gas constant = 8.31 Jmol K) Consider he was phase eatin, 2A (g)+3B (g)—#2C (8) atagiven temperature. When 2.0m: are reacted with 2 Omoes of Bg, 0.8 moles of Cp) ars fa 12 Or The value of he equi const K, oF Us reac it Jed teva ttl presi ats given temperature is closestis (@03 (yng say (HI91 [NET Dec. 2019) ee 4 43 Forthe reaction, N,(2)+3H, (z) —>2NH, (a) the thermodynamic quantity which depends wpon th at vhich equilibrium is rived ats (superscript 0" represents standard state) 0) 40 (yn! (ky INET Now. 2020) (rato of moe rations, at equilibrium _ sai rr @ IFT ctr Staton, New Delhi, Pi O1-BGRS1008, 2686100, Dei 33-5, MallRewd, GTB Nagar Oppmite MeteGanto- ce peeeoe PSR 33S, MllRoad, GTB Nazar(Oppite Metre Gate No.3), Deir 9, Pe 9280017ent 2c er tthe reaction ct sara (©) decrees wi (mereases wie rconst emai the ili cnstang : " (X,) forthe decomposition ee. where p ah oh ESUNG, = exten of Sore corpo, W increases wth increases of p ©) Ky intense within ncreases with decreases of, ithinreasso (8), remains const withchage : Osta With cha pad sit the flowing eilityum nace con a ose container ,0 (2). vrafned temperate the volume fhe = 20,0) tion containers ae Forth hag, sts ot uv regarding he quit crs (ky) a dere cf sen syNeither not a changes (©) Bath jane ehange angesbut « does Potchange (4) x, does mt change au Hangs 11, = [eC] hy #38 «108 Feo Auth) Tk ration constant of AglNt Ti 0 8) 608i" (oysonet% Neve ofthese rect statement if Ny sade at elim confi sain wil shift frwardretionbecuse acorn Wl law rma he st neeases inte deton of pontansous reaction: The cnn for equi EUSA PR CE PSA ABE ober memset de pl pein Teens aera these egestas re nee Ty and that ockwar ton 8 catalyst which increases the ate ofboth the Tin catalyst wil merease the rate of forward he rate ofeither ofthe Catalyst will nota cin allowing reaconitbe tect ett principe peta change of aban seznam Ero= inte iscompressed N.0, (@) «2 2NO.(@) Yes, backward reaction i favoured jon is favourel positions predict econ RES by Yes, foward reat Nochange in equilib com J) No information is obtained about so? @-2 | atic aid = AKU | on. oles log Chatty Z wr Pt Phar iy ee Aod ctkate ] = = Bat pe Ae & . 11g Gapnt AOSD _ Ue gn 2nd x 28 = (a) 6.0 = 10 o 10 (a) 5.0 « 104, 3 Mad Mee aa. 76x19 xac Alto add: Hert RU be? | Aaknaly Sol: ik bhi, by bond rn a ee 2s ae a gt a7 an mtd cb ~ (noe 4 (ove ¢ kkm constant for the reaction CH3COOH(aq) + C,HsOH(aq) © CH3COOCHs(aq) + H,0(1) is 16. the initial concentration of each of CH3COOH and C,H 0H is two (mole/lit). Wha is the concentration of CH3COOC,Hs at equilibrium is mole/lit 2) 0.6 3) 1.6 4) 0.7TR. c0081 + c,11,081 = cr, cooe, Initial: 2 2 RandF (2-x) (2-x) At Equilibrium 16 8 4x= x x=3=16 [CH3COOC;Hs] = 1.6. ‘gH; + H,0rogen dioxide (NO2) is involved in the formation of smog and acid ain. A reaction that is important in the formation of NO; is 03 +NO & 02 +NO2;K, = 6.9 x 105+ - If the air over a section of M ontained Qe= LM NozIf02) (03) (NO) 1.0 x 10-°MO3,1.0 x 10-5M NO, 2.5 x 10-*MNO, and 8.2 x 10-3M 02 what can we conclude? 1) There will be a tendency to form more NO and O03 2) There will be a tendency to form more No2 and 02. 3) There will be a tendency to form more Nop and 03. 4) There will be a tend y to form more NO and 0»Since Q = $?- +25 23 2) 132 3) 1/132 4) 1/32alkaline solution the following equilibrium exits 3°; K = 12,$3° + $ = $3>; Kp = 11. Whatis the “rium constant for the equilibrium S3- = $?- + 2S 1) 23 2) 132 8) 1/132 4) 1/32the reaction A+B © 3C at 25° C a3 litre vessel contains mole of A,B and C respectively. Predict the direction of rez K, for the reaction is 10. 1) backward 2) forward 3) equilibrium 4) any direction eKne mole of SO3 was placed in a 1 lit reaction vessel at a constant temperature . The following equilibrium was established 2803 = 2802+02. At equilibrium 0.6 moles of SO2 were formed. The equilibrium constant of the reaction will be 1) 0.36 2) 0.452803 © 2802 +02 1 0 0 AtEquilibrium — 1-2x 2x x Given that, 2X =0.6; x=03 [s02]?[02] [S03]? KEY: 4gm of N204(g) in a closed one litre vessel and heated till the following equilibrium is reached : N,04(g) = 2NO2(g). At equilibrium 50% of N204(g) is dissociated. What is the equilibrium constant(in mole lit~!)? (M.wt. of N20, is 92). 01 2) 0.2 3) 0.4 4)2NsOyhmnoles = =O mole 92 N20, © 2NO, 0.41 0 gred and formed 0.05 0.1 0.05 0.1 [NO2]* [N204] KEY: 2mole of A(g) is heated to 300°C is closed one litre vessel till the following equilibrium is reached : A(g) © B(g). The equilibrium constant for the reaction at 300°C is 4.what is the concentration of B(in mol.lit~!) at equilibrium? 1) 0.2 2) 0.6 3) 0.8 4)0.1equilibrium mixture for the reaction 2H2S(g) = 2H2(g) + S2(g) ad 1 mole of H2S, 0.2 mole of Hz and 0.8 mole of Sz in 2 lit. flask. The value of K, in mol. lit~? is 1) 0.004 3) 0.016 2) 0.08 4) 0.16equilibrium mixture for the reaction 2H2S(g) = 2H2(g) + S2(g) ad 1 mole of H2S, 0.2 mole of Hz and 0.8 mole of S2 in 2 lit. flask. The value of K, in mol. lit~? is 1) 0.004 3) 0.016 2) 0.08 4) 0.16equilibrium mixture for the reaction 2H2S(g) = 2H2(g) + S2(g) ad 1 mole of HzS, 0.2 mole of Hz and 0.8 mole of Sz in 2 lit. flask. The value of K, in mol. lit~! is 1) 0.004 5) 0.016 2) 0.08 4) 0.16 a equilibrium moles Equilibrium cone. = “4 volumection : Hp(g) + Ip(g) at 721 K the value of equilibrium is 50. when the equilibrium concentration of both is 0.5M value of K,, under the same conditions will be 1) 0.002 2) 0.2 3) 50.0 4) 50/RTon : Hp(g) + Ip(g) at 721 K the value of equi ‘onstant K, is $0. when the equilibrium concentration off value of K,, under the same conditions will be > 1) 0.002 2) 0.2 3) 50.0 . 4 ; aos K,=K,since An ee41) When CO dissolves in water the following equilibrium is established. CO +2H20 = H30* + HCO} for which the equilibrium constant 3.8 x1077 and P = 6.0. The ratio of [HCO5| to [CO2] would be 1) 3.8 x10-1 2) 3.8 x10-8 3) 13.4 4) 6.0en CO2 dissolves in water the following equilibrium is established. - 2H20 = H30* + HCO; for which the equilibrium constant 10-7 and P# = 6.0. The ratio of [HCO3] to [CO2] would be 1) 3.8 x10! 2) 3.8 x10713 3) 13.4 4) 6.0 given that P" = 6 = [H,0*] = 10-6 [H:0*]1HC03} 3.8 x 10-7 > [Coz]41) When C sin water the following equilibrium is established. * + HCO3 for which the equilibrium constant 0. The ratio of [HCO;] to [CO2] would be 2) 3.8 x10-8 4) 6.0 = [H30*] = 10-6 _, [Hs 111103) (€0;]en CO2 dissolves in water the following equilibrium is established. + 2H20 = H30* + HCO} for which the equilibrium constant 510-7 and P# = 6.0. The ratio of [HCO] to [CO2] would be 2) 3.8 x10713 4) 6.0 giventhatP"=6 = [H,0*] = 10-6 ‘[H0*|[HCO3} 3.8 x 10-7 > [coz]42) At 27°C and 1 atmosphere pressure N20, is 20% dissociated into NO» find K, 1) 0.2 2) 0.166 3) 0.15 4) 0.1042) At 27°C and 1 atmosphere pressure N20, is 20% dissociated into NO» find K, 1) 0.2 2) 0.166 3) 0.15 4) 0.10 NpOaCo) = 2N02(9) ia] ex 2« ’ hte)i 1 atmosphere pressure N20, is 20% dissociated into NO» W) 0.166 3) 0.15 4) 0.10 the initialmoles be 1 if 20% of 1 is 0.2.43) 28g of Nz and 6g of Hz were mixed. At equilibrium 17g of N, formed. The weight of Nz and H; at equilibrium are respect 1) 11g and Zero 2) 19g and 3g 3) 14g and 3g 4) 11g and 3g43) 28g of Np and 6g of Hz were mixed. At equilibrium 17g of NHj was formed. The weight of Nz and H; at equilibrium are respectively 1) 11g and Zero 2) 19g and 3g 3) I4g and 3g 4) 11g and 3g43) 28g of Nz and 6g of Hz were mixed. At equilibrium/i7g of NHg|was formed. The weight of Np and H, at equilibrium a iy 1) Ilg and Zero 2) 19g and 3g WS 14g and 3g 4) 11g and 3g 2g 69 Sug + SH, = 2NH3 me OY 17g NH; is formed by 14g Nz and 3g Hp44) In the Re : 2803 (g)<>2S0,(g) + O2(g), S03(g) is 50% dissociated at 27°C, when the equilibrium pressure is 0.5 atm. Hence partial pressure of SO3(g) at equilibrium is 1) 0.5 atm 2) 0.3 atm 3) 0.2 atm 4) 0.1 atrep = Uh) aca 7 Hy,45) The value of AG° for the phosphorylation of glucose in kj/mol. Find the value of K, at 298K 1) 5.8 x10-5 2) 5.8 x105 3) 3.8 x1045) The value of AG° for the phosphorylation of glucose in glycolysi kj/mol. Find the value of K, at 298K is 13.8 1) 5.8 x10-5 2) 5.8 x105 3) 3.8 x10 4) 3.8 x10-3me 2805(q) © 2802%q) + Ong ep = ON, fr co, 0 0 At equilibrium45) The value of AG° for the phosphorylation of glucose in gl kj/mol. Find the value of K, at 298K 1) 5.8 x10-5 2) 5.8 x105 3) 3.8 x10 AG° = -RT InK, InK,= 5.569; K.=e"55 K,=3.81 x10-346) The equilibrium of the reaction : N>(g) + 3H2(g)<>2NH3(g) will shift to the product side when IK, >1 2)QK,46) The equilibrium of the reaction : N>(g) + 3H2(g)<>2NH(g) will shi, the product side when IK, >1 BQK,RELATION BETWE N K, AND Kp 47) The value of (K,/K,) for the reversible $03(g) at constant temperature T is tion : S02(g) +502(g) 1) (RT)'/2 2)RT 3) (RT)“1/? 4) URTRELATION BETWEEN K, AND Kp Phe value of (K,/K,) for the reversible re: 103 (g) at constant temperature T is tion : $02(g) +502(g) = 1) (RT)'/2 2) RT ~ 3) (RT)~1/2 4) URThe equilibrium : 2NOCI(g) <= 2NO(g)+Cl(g). The value of i 3.75x 10” at 1069 K. Calculate K, for the 3) 0.03 So 33, K, = K,(RT)*"49) At 27°C the K, value for the reaction : PCI; © PCI3 + Cl, is 0.65. its Kis 1 2) 0.6549) At 27°C the K,, value for the Kis :PCls @ PCl3 + Cly is 0.65. its 2) 0.65 4 0.026 K, = K,(RT)2"or the reaction : C7H;0H + Br © C,HsBr + OH", the equilibrium ill shift to the right on Exposing the system to light 2) Adding an alkali 4) Adding C,H;BLECHA’ 3 PRINCIPLE 50) For the reaction : C,H;0H + Br © C,HsBr +(QH_), the will shift to the right on 1) Exposing the system to light 2) Adding an all WB) Adding an acid ; ‘ Preece Addition of acid causes the decrease of [OH~] aIn a gaseous reaction 2A 3B on doubling the volume of con Siilibrium amount of product } er, the 2) Decreases 3) Remains same 4) Data ly Lechatelier’s principal.fion 2A 3B on doubling the volume of container, the of product ) 2) Decreases 4) Data insufficient s principal.Lal51) Ina gase 2A 3B on doubling the volume of container, the (equilibri 5 product ) Wh) increa 2) Decreases 3) Remai 4) Data insufficiLalh 2A 3B on doubling the volume of container, the f product } 2) Decreases 4) Data insufficiLal52) In the dissociation of CaCO, in a closed vessel, the forward reaction is favoured by 1) Adding of more CaCO3 2) Removal of some CaO 3) Increas ng the pressure 4) Decreasing the pre mixture ure by removing some CO) from the equilibrium52) In the dissociation of CaCO. favoured by __— 1) Adding of more CaCO3\ essel, the forward reaction is COLIN = CaO(S) +8) ne CO2 from the equilibrium 2) Removal of some CaO 3) Increasing the pressure -¥'4) Decreasing the pressure by ture Removal of product favor54) For which one of the following reaction is a combination of high pressure and high temperature helpful in obtaining a high equilibrium yield 1) 2NF3(g) > No(g) + 3F)(g) — 54.40 k. cals 2) No(g) > 3H2(g) > 2NH3(g) + 22.08 k. cals 3) Cl(g) + 202(g) — 2C102(g) — 49.4 k. cals 4) 2C1,07(g) — 2Cl,(g) + 702(g) — 126.8 k.cals54) For which one of the following reaction is a combination of high pressure and high temperature helpful in obtaining a high equilibrium yield 1) 2)3(g) > No(g) + 3F2(g) — 54.40 k.cals 7 oh — 3H2(g) > 2NH3(g) + 22.08 k.cals 3) Cla(g) + 202(g) — 2CI02(g) — 49.4 k. cals 4) 2Cl,07(g) > 2Ch(g) + 702(g) — 126.8 k. cals55) In the CaCO; 1) The equilibrium shifts to the right sociation of CaCO; after equilibrium is reached if some more dded to the reaction mixture 2) The equilibrium shift to the left 3) The pressure of CO. increases 4) The position of equilibrium remains unchanged.55) In the ociation of CaCO; after equilibrium is reached if some more CaCO; is added to the reaction mixture 1) The equilibrium shifts to the right 2) The equilibrium shift to the left 3) The pressure of CO. increases 4) The position of equ CaCOz is solid , its active mass is taken as 1.55) In the CaCO; 1) The equilibrium shifts to the right sociation of CaCO; after equilibrium is reached if some more dded to the reaction mixture 2) The equilibrium shift to the left 3) The pressure of CO. increases ep: position of eq ibrium remai s unchanged. CaCOz is solid , its active mass is taken as 1.56) Given the equation : AgCl(s) = Ag* (aq) + Cl” (aq). As NaC\(s) dissolves in the solution, temperature remaining constant, the Ag*(aq) concentration will 1) Decreases as the amount of AgCI(s) decreases ount of AgC\(s) increases 2) Decreases as the a 3) Increasing the amount of AgCI(s) decreases mount of AgCI(s) increases 4) Increase as the56) Given the equation :|AgCl(s) = Ag* (aq) + CL = J dissolves in the solution, temperature remaining constant, th, concentration will 1) Decreases as the amount of AgCI(s) decreases / ~¥5) Decreases as the amount of AgCK(s) increases 3) Increasing the amount of AgCl(s) decreases 4) Increase as the Apply Lechatelier principle mount of AgCl(s) increases57) If PCI; is heated in two separate vessels of volume 5 lit and 10 lit respectively at 27°C. the extent of dissociation of PCIs will be 1) More in 5 lit vessel 2) More in 10 lit vessel 3) Equal in both vessel 4) Can not be said57) If PCI; is heated in two separate vessels of volu respectively at 27°C. the extent of dissoc 1) More in 5 lit vessel 2) More in 10 lit vessel 3) Equal in both vessel 4) Can not be said57) If PCI; is heated in two separate vessels of volume 5 lit and 10 lit respectively at 27°C. the extent of dissociation of PCI; will be 1) More in 5 lit vessel 2) More in 10 lit vessel 3) Equal in both vessel 4) Can not be saida57) If PCIs is he: ely at 27°C. the extent of 5 lit vessel B) More in 10 lit vessel 3) Equal in both vessel 4) Can not be said PCI; © PCI; + Cly Low pressure is favourable for the