440 Answers to Problems CHAPTER 5 2, 112 x 10 molest 112 mgititer as CaCO, 3. [gOH" 1x 107M (< HglOH] = 989 x 10-2) 4. (@) 0.40 x 10°? moles Ca(OH) iter (®) The amount in part (a) for coagulation plus 4.02 x 10-* moles Ca(OHfiter to raige the pH. 5, Using the equilibrium constants for the complexes as given in Section 5, 25% of Cry and 28% of Cyn ate in the form of sulfato complexes. 8, Assume 4{Qi(CN)¢-] > (HCN) 4: (CN) Knowing {HCN] + [CN] = IN] Caleulate [Ni] = 14 x 10-7 pune} Coa 7. (a) (MgEDTA*] = 1.1 x 10" M () [MgEDTA*) = 7.4 x 10-7 [CaEDTA] = 1.99107 M .. 5% of Cros is not complexed ct the equivalence point for calcium. Note that in the standard procedure for calcium titration, the pH Is such that OH" will complex somo of ‘the Mg. Thus, less EDTA than ealculated above will be associated with the Mg? and moze will be associated with the calcium, 8, pH = 5.6 (The concentrations of the Cu(OH),” and CulOH* complexes aro negligible.) 8, From Fig. 5-2, the trimer and hexamer complexes aro nogligible. Com = 04 [Pb*] + s{PbJOR),) (PbO) = 0.004 m4 CHAPTER 6 1. (@) 84 X 10-* moles of S:SO.y will precipitatefiter ) (Sr = 1.6 x 10-7 80.5) = 1.02 x 107M 2. (aq) From Fig. 6, pl = 10.65, () OH added: 7.38 x 10° 3, 8.98 x 10° moles Mg*iiter will preetpitato, 4. Using Fig, 64, when log (Cat) When log (Mg*] = 9.5, pCO, 8, pCO, = 4 (or (CO,*] = 10-4, (or (CO."] = 10-9,