i reno (2/20 2058) HB Tabla 3-4 po a eit Webb -Rubin Constanes que aparecen on ls ecuacones de stato de Beatie Brdgeran y Bene Wet STE 2) Cuando Pest en KPa, essen mo, Ten Ky Ry = 8.314 KPa kal US a _e Beattie Bridgeman son as > ¢ Gas SST — aka ay gw eal emg} a mee ganUOL Hasse 1 Argon, Ar 130.7802 0.02328 ae 0.07235 6.60 x 105 DiGxido de carbono, CO, 507.2836 0.07132, 0.10476 0.0 40 Helio, He 2.1888 0.05884 dors 89, a Hidrégeno, He 20.0117 0.00508 Oe (0.00691 4.20% 108 ‘Nitrogeno , No 136.2315 0.02617, 0.05046 0.004208 4.80 x 10% ‘Oxigeno, 0, ‘151.0857 0.02562 0.04624 *a ‘0 ‘Fuente: Gordon 1. van Wyle y Richard €, Sontag, Fundamertas af Gls! Thermodraics version sates | isis tied, Women Wier Soe osere eas ') Cuando Pest en kPa, (esté en mmol, Testéen Ky R, = 8.314 KPa mvt» Ky las ocho constantes de la ecuacién de Benediet-Wedb-Rubin so: as a A ey a oe ‘butano, 190.68 1021.6 0.039998 012436 3.205% 10? 1.006% 10° 1.101 10 0.0340 Cety Didxida de . : carbono, CO, 13.86 277.30 0.007210 0.04991 1.511 x 10% 1.404 x 107 8.470x 10 0.00839 Monsxiso de carbono,CO 3.71 135.87 0.002632 0.05454 1.054 x 10" 8.673x 10° 1.350 x 10-* 0.0060 Metano, CH, 5.00 187-91 0.003380 0.04260 2.578 x 105 2,286 10° 1.244 x 10°* 0.0060 Nitrogeno, Np 2.54 106.73 0.002328 0.04074 7.379 10 8.164% 10" 1.272 x 10~* 0.0053 Tonsis Kannan Wa, Treraanics fa Roma Ye Nea, 196, p15, bla HEN Pubicdo expen H.W. Cover JHE cca, Hydotaron Pacomng 8, Gm 12 1967, 9181 Von der Waals 2consunes. | Esta y otras ccuaciones similares se laman ecuaciones de estado virales, Exacta. un intervalo Fnitado. | yjentras Jos eoeficientes a(7), 6(7), c(Z), ete., que son funciones vinieamente seane-tridgeman:Sconsanes. | 42 I temperatura, se Haman eoeicienss virales. Estos se determinan de trata prs P 208 forma experimental 6 terica a partir de Ia meciinica estadistica, de donde resulta obvio que a medida que tt presiGn se apronima a cero, los coeicientes Virals desaparecern y la ecuai6n se reduciré a la de estado de gas ideal El comportamiento P-v-7 de una sustaneia se puede representur eon precision Sobridge: 16 consuntes ‘on la ecvacin viral de estado en un émbito amplio gracias ala inclasin de ds accu at clos suficientes tminos. Las eevaciones de estado analizadas aut son aplicables ‘com computador. s6lo a la fase gaseosa de las sustancias; por Jo tanto, no se deben usar para Va pte ai Iiguidos 0 vapores himedos, a exact depen del ndmero ‘Complejas ecuaciones representa razonablemente bien el comportaiento etn a fu de ls susan, semis de ser muy adceuuss prt opciones de computadoras digitles. Sin embargo, para cdleulos manuales se sugier® ‘emplear por convencion las tabla de propidades o las cevaciones de estalo snis simples. Esto es cierto especialmente para cleulos de volumen espect Figura 2-55 feo por Las in ewan etre ene av con wale ines run itervalo ss ampli, las ec wieren on metodo de prucba y error. La precision de las ecuaciones J acs de estado. copies representan tao de Van der Waals, Beattie-Bridgeman y Benedict-Webb-Rubin se ilus- ion PT as pncvcon en Figura 356, cn la qu e evident qu la de Benedit-Weeb-Rubio mayor preciso por To comin ta més precisa. Aeneict-Webb- Rabin: 8 constanies Exacta pats 6250,TE OST Tabla Ad ‘Agua saturada, Tabla de temperaturas ap nop Volumen especie, Even intra, eee rg an ae she ung r Voor Th ¥ i a nr Ber at ean, attest, Bp ae, emp, sake sit, Evop, sat, sat, Eps ah, Teg pl lyn zB as749 0001 @sf09 25009 00000 5.156 9isee SO Soha Genta iercs ctor zoe soela 21020 24991 25101 00763 5187 Soais 3 eee face? tzoz2 20772 25102 ISI B78 ebs0y Bo LRM Sohime Seam Boge! za 3 Gasca 2asse 25283 0205 85559 a7ens 1 fos Gooron, “Trai Sasso Hames somes Gaoee aaeb4 sada OZ a8se9 are 2 tse Opolona Syrez S013 2318 Zanes eB 2% 31688 pooi0e 9H rakes 23043 24nd 10809 2447. 25S 367 Ne ass? So Xaaep Gooioae Soar aya amma asa 12574 2aza Ast0 % reo na? laset 2A178 28646 Os0s1 TEKS 62517 3 esol onnimes sms 6 6 95061 So sast cous iosis lors 2201 20204 16753 21060. 25735 8724 esse Baste Sas cootoio isest Teas 22007 2u361 Tesad 230 25604 06005 75247 BIER so i23s2ooolole2mas sons zane 24427 20934 23620 25913 07038 73710 Boma SS te7es ogoiuis “assess Zooze zaio1 24a. 2802s 25098 26001 O7G80 72218 75008 co Yau onnioin aero zeke Za0eT 21559 25118 25577 26088 O83I3 70769 Fo0eo SS boned ooolead Gisns | 27a zis03 24624 27212 Pause 2617 08857 65060 Tae bo Rasa ootcea Saupe Zone 21788 24689 29307 25930 26061 09881 87985 750 75 38957 aooicgs 41251 31399 216L3 20753. 31403 73006 26545 0188 56685 e812 % aie Gootam —Satea autor 21408 2uehs S3802 2080 26400 10rse 85988 TellL © Sys Gootose eas) sess 21st 21678 Sseo0 oss 26514 Lowe saoeD 75408 $2 Yous) Gooioas 2ses0 Sreoy 21170 2usK0 S770e Zens. 26806 Lia20 Souss rare ; SS ate Booiow —iaere Sun0o Zloe acon sonon Z2ene 26028 12808 Giea? 7415) yoo 10142 ogo1ous 15720 41806 20670 28050 41917 zas64 26756 1207 60470 72512 os 12090 Otoiour ls aoe forte asiiy awnze zaual aeane aca Sou fase No 143s Ouotose 10a Met.27 dose 25177 Wola2 22007 2eOlA Las Seles 72300 Tis tesa Oooiows Yosmn dszaafotod send densa azleo aeons Laver Soe 1el9 12) 18667 Oto10s) Gusta Smaeo ana asano sosal zate! zoeo 1270 E6013 Flaw 125 ziz23ogoloss a77o12 seed amma 25043 ssa? aim 27131 186 54956 7071 Ho 27028 ooLovo Goate Scio gga as00s Saga airs? or2o1 Teste apts Jovws 135 51azeGootors osslve. serail 15773 dean? Serae alent z7209 Leare S901 Gor7s Wo 36153 0001000 Gsos%0 477 m09 25en6 Sen16 sees ares ISe%0 sisal came Ms discs Dooioes Gated 0.19 ioua assaa loge laa? aya98 Laeee ants Cast 10 47616 OoD10n1 03004 165 1274 25591 3218 21138 27459 eNIe. éomsa EAaTl Tis S049 Goole oaaees Gas ipiag sees 62598 agg arate Leese sees Coes 1661823 onolinz oavean 67479 iesno sera e7a7 aoee0 arene Ieise taeee Oot 15 70093 QdoLIGe Oaveud eaeae isrea 219 waren aoceE o16e8 Letes a9I C7Oe7 Mm 7o28 Ogoltte oatzso Tiaz0 iesrs 59 Tivas dows arei9 Sony tess Sete 5 epa60 ogolizi oziee9 14002 msoa 25794 race 0017 27727 20806 4e588 E62H2 Jeo tors ouoliz7 alosee. 7eis2 mmo 2a eats fola2 a772 Zines tania est 15 15 oaolise o17sm0 7eisi intel asee0 festa loses saea Shese SAMs Son Jo tzss2ouoliéi —aistap, soo 130 25690 ras lama sess Sasee tae Ese 15 Kase olla, o140H9 2518 636 2917 eens 18690 SoDR amit taDe) eae 200 15519 OnDNIS7 271 Boas Ina aemka BE296 Noses =eeeS SESE AIBHT Baeyr 09, hi aga, wo) de operates (consi sit! volumen espectio, Energia interna, Entaipla, Entropia, ee Er seg sug K La. Vapor Lia. Vapor Liq, Vapor Liq. Vapor a ‘sat, sat, sat. Evap., sat, ‘sat, Evap., sat, sat, Evap., sat. we ie rier sommes 011808 67286 17238 25864 e74sy T0200 zrose 25776 40164 63000 WAS Qootira totes 8948 ira faves Sorel Ison? croys pants nia 63503 432 Qouler OoBeso ice Losi asa senso teres 2993 parla. Sate) 63000 202 Sporiso coseost — $1079 leans 2013 oesss tanya anol sire seed eam ase Georg Cores 96870 eine fezas seers issue canes 25639 hoses cams fer 0001209 0.071505 98676 16161 26029 950.14 18128 28029 26100 3.6028 6.2128 Pere 001219 0.086900 10100 15882 26032 10137 17895 78032 26850 3.5216 6.1775 Miro 0.001223 0059707 10334 15698 26031 1037.5 17655 28030 27018 3.4405 61428 Sar2 9.001240 0.054656 1056.9 1845.7 2602.7 1061 17408 20022 27476 3.3596 6.1072 Bip? 0.001282 0.050085 1080.7 1621.1 2501.8 10857 17153 201.0 2.7933 3.2788 6.0721 vu29 0001263 0045941 1104.7 14958 25005 11101 16890 77991 2.8390 3.1979 6.0369 Gie23 0001276 00N2175 11288 14699 25587 11348 16618 27965 2es47 3.1169 6.0017 fiers 0001289 0.038748 11533 14432 25965 11598 16337 27935 29004 30358 5.9562 HBbo 0.001203 0.038622 1177.9 14157 25937 1@H.A 1608S 27897 29762 29512 59305 SMee 9001317 0.082767 12029 13874 25903 12107 15745 27852 30201 24723 Sand e166 0.001333 0.030153 12282 13582 25864 12367 15432 27799 30881 2.7808 58579 Ghes 0001349 04027756 12537 13281 25618 12631 19107 27737 3.1144 2.7066 58210 Stars 0001366 0.025854 1279.7 12969 25765 Izme 14769 27067 3.1608 26205 5.7834 Wyes0 0001384 0.023528 13060 12645 25705 1317.1 14als 27587 3.2076 25374 5.7450 Hers 0001408 021659 132.7 12309 25636 13408 140ks 21495 3.2548 24511 5.7059 se094 0.001425 0.019932 | 13600 11959 25558 1373.1 13663 2730.4 3.3028 23633 56657 58650 001447 0.018333 1387.7 11893 2647.1 14020 13289 27279 3.3506 22737 5.6243 tosse 0001472 0016849 1416111211 25372 14316 12834 27150 33994 21821 55816 ize 0.001499 0015470 1445.1 10919 25260 1462.0 12385 | 27006 3.4491 20RB 5.5372 Jos] 0001528 OO14183 14750 10385 251324 14534 11910 26843 *34998 1.9911 5.4908 0 12858 0001960 0.012979 16057 9985 2490.2 15258 11803 26560 35516 1.8906 5.4422 53 13707 0001887 0.011848 1837.8 945.5 24830 15894 10860 2645.4 3.6050 1.7857 5.3907 MO edt 001638 0.010783 15707 93H 24GAS 19946 10274 26220 3.8602 1.6756 5.3358 BS Isst —oo1685 0.009772 16055 837.7 24432 16317 9634 25951 3.7179 1.5885 5.2765 0 16529 Gool741 O.00ge0s 16424 «7759 24183 16712 8927 25639 37788 1.4326 S214 85 1757 0.001808 0.007872 16822 7064 23086 17180 8129 25269 38442 1.2942 5.1384 BO 18665 9.001895 0.008950 17262 625.7 23519 17615 7201 24816 3.9165 1.1373 5.0537, SS sez goozm1s o.00s009 1777.2 $264 23026 18172 6055 24227 4.0004 949 49493, me ziots —Boozai? oodess 18445 3856 22901 1891.2 443.1 23343 4.1119 0.6890 4.8009 Mes z068 9.003106 0.003106 2015.7 0-«20157 043 0 «A0BAI 4.4070 0 44070 (SRS mis 4 A. amon gerade ular pogama para escherecacanes de ingen (EES) dearolade por S.A Kien y FL Avot {sind ono eatculgs esta atm precisa Seat INPS, aus neta a Formulas 198 paras Propidaces Tenrdimcs de la ‘SSctl Ordara pra tsa Gniicey Garr etage por The internal soca ote Properties of Water an Say IAPWS). Eta [Suns Tegpct erie ea Ra Clg al (NOSE Stan Tes, erophee Pubsig Ca, 1983), 1c nt obi "82 6183 come anata STEAM, Lo ruere mole 3e sn eno cntaires e Saul Wage Pry, Cham Re Data, 1,893, 1887) con ESPNS ma nivina a ae iran orp ce 190, sacs etn deren por Ware Pr. Phys hem Rl ‘Bu S039 Lt pode le xen a nod yet, Termin he Team oper! he Straed Phas ot ‘teATSIIS ASHRAE Tans, Pat 2A, Paper 2793, 1988806 CS eA TE Tabla A ‘Agua saturada, Tabla de presiones Volumen espectco, Energia interna, Entropia, mh kg Temp. Lig. Vapor te Vapor Lig Vapor Pres. sat. sal, sat, sal, Evap, sat, sath Evap,, sat sat, Evapu, sat, PHPa Tue" vy \ ieee a tg eS 10 697 0.001000 129.19 29.302 23652 23645 29.03 24844 25137 0.1059 8.8690 89749 15 1302 0.001001 87.964 54.686 23381 23928 54.688 2470.1 25247 0.1956 8.6314 88270 20 17.80 0.001001 66.90 73.431 23255 2398.9 73493 2450.5 2552.9 0.2605 84621 8.7227 25 2108 O.001002 $4,242 aaa? 2515.4 24088 BAA24 2451.0 2539.4 03118 83302 8.6421 30 2408 0.001003 45.654 100.98 2306.9° 2407.9 100.98 2443.9 2548.8 0.3543 8.2222 8.5765 40 28.96 o.o0100¢ 34.791 121.39 22981 24145 12139 2432.3 2553.7 0.4224 80510 84734 50 32.87 0001008 28185 137.75 2282.1 2419.8 13775 24230 2560.7 0.4762 7.9176 8.3938 75 40.29 0.001008 19233 16874 2261.1 24298 16875 2405.3 25740 0.5763 7.6738 8.2501 10 4581 0.001010 14670 191.79 2245.4 2437.2 191.81 23921 2582.9 0.6492 7.4996 8.1488 15 5397 Goo1D14 10.020 22893 2222.1 2448.0 22598 23723 2598.3 0.7849 7.2522 8.0071 20 60.06 0.001017 7.6481 251.40 22046 2456.0 251.42 2357.5 2608.9 0.8320 7.0752 7.9073 25 64.96 0.001020 6.2034 27193 21904 24624 271.96 23455 26175 0.8932 6.9370 7.8302 30 69,09 0.001022 5.2287 289.24 21785 2467.7 28927 2335.3 26246 0.9441 6.8234 7.7675 40 75.86 0.001026 3.9933 31758 21588 2476.3 317.62 23184 2636.1 1.0261 6.6430 7.6691 50 81.32 0.001030 3.2603 M049 2142.7 2483.2 340.54 2508.7 2665.2 1.0912 6.5019 7.5931 7 91.76 0.001037 2.2172 364.36 2111.8 2496.1 384.44 2278.0 2662.4 1.2132 6.2426 7.4558 100 9.61 0.001043 1.6941 417.40 2088.2 25055 417.51 2257.5 2675.0 1.3028 6.0562 7.3589 101325 9997 0.001043 1.6734 41895 2087.0 2506.0 419.08 2256.5 2675.6 1.3069 6.0476 7.2545 i 125 108.97 0.001048 1.3750 44423 20588 25130 444.35 2240.6 26849 1.3741 5.9100 7.2841 150 111.38 0.001053 1.1594 466.97 2052.3 2519.2 467.13 2226.0 26931 1.4337 5.7694 7.2231 175 116,04 0.001057 1.0037 486.82 2037.7 25245 487.01 2213.1 2700.2 1.4850 5.6865 7.1716 200 120.21 0.001061 0.88578 $0450 20246 25231 $08.71 2201.6 2706.3 1.5302 5.5968 7.1270 205 12397 0.001064 0.79329 520.47 20127 25332 52071 2191.0 2711.7 18706 55171 7.0877 250 127.41 0.001067 0.71873 $3508 20018 25368 535.35 2181.2 27165 1.6072 54453 7.0525 275 130.58 0.001070 0.65732 54857 1991.6 2540.1 548.86 21720 27209 1.6408 5.3800 7.0207 300 133.52 0.001073 0.60582 $61.11 19821 2543.2 56143 21635 27249 16717 5.3200 6.9917 i 325 13627 0.001076 0.56199 57284 1973.1 25459 573.19 21554 2728.6 1.7005 5.2645 69550 350 138,86 0.001079 0.52422 58389 19646 2548.5 $84.26 2167.7 27320 17274 S.2128 69402 375 141.30 0.001081 0.49133 $94.32 19566 25509 $9473 2140.4 2735.1 1.7526 5.1685 6.9171 400 14361 0.001084 0.46242 604.22 1948.9 2553.1 60466 21334 27381 1.7765 5.1191 68955 450 147.90 0.001088 0.41392 622.65 1934.5 2557.1 623.14 21203 2743.4 1.8205 5.0356 6.8561 500 151.63 0.001093 0.37483 629.54 1921.2 2560.7 640.09 21080 27481 1.8608 4.9603 68207 550 15545 0.001097 0.34261 655.16 1908.8 25639 655.77 2096.6 27524 1.8970 48916 6.7885 600 158.83 0.001101 0.31560 669.72 1897.1 25668 67038 2085.8 27562 1.9308 48285 6.7593 650 161.98 0.001104 0.29260 683.37 1886.1 2569.4 684.08 2075.5 27586 1.9623 47699 6.7322 700 164,95 0001108 027278 696.23 18756 2571.8 697.00 20658 27628 1.9918 4.7153 6.7071 750 167.75 0.001111 0.25652 708.40 18656 2574.0 709.24 2056.4 2765.7 20195 4.6642 6.6837wok tala. J reins (Conca) 2 Volumen especie, Energi nana Trapt Enron = ASN, A ABE ike tung pe Uy Voor Voor tig oper apr ee SS Te TT RE EN we et, keen oe i jet oe ee re ge ee ae Cee fee) eS y7o.4i 0001115 0.240385 719.97 1856.1 25760 72087 2047.5 27683 2.0457 4.6160 66616 17294 0.001118 0.22690 731.00 1846.9 2577.9 731.95 2038.8 27708 20705 45705 66409 GS 17538 0001121 0.21489 741.55 1898.1 2579.6 74256 20305 27730 20941 45273 6.6213 g 177.86 0.001124 0.20411 751.67 1829. 2681.3 752,74 20024 27752 21166 44862 6.6027 7988 0.001127 0.19436 761.39 1821.4 2582.8 76251 20146 27771 21381 44470 6.5850 18408 0.001133 0.17745 779.78 18057 2585.5 781.03 1999.6 27807 2.1785 4.3735 6.5520 18796 0.001138 0.16326 796.96 17909 2557.8 79833 19854 27838 2.2159 4.3088 65217 19160 0001144 0.15119 813.10 17768 25899 A1459 1971.9 2786.5 2.2508 4.2428 6.4936 19804 001149 0.14078 828.35 1763.4 25918 82995 19589 27889 22835 41840 6.4675, 196.23 0.001154 0.13171 842.82 17506 25934 a4a.s5 19464 2791.0 23143 41287 64430 20572 0.001166 0.11344 876.12 1720.6 2596.7 878.16 1917.1 2795.2 23848 4.0033 6.3877 21238 0.001177 0.099587 905.12 16930 2599.1 908.47 18898 2798.3 2at67 38923 6.3300 21841 0.001187 0.088717 933.54 16673 2600.9 93621 1868.3 28005 2.5029 3.7926 6.2954 22335 0.001197 0.079952 958.87 16432 2602.1 961.87 1840.1 2801.9 25542 3.7016 6.2558 23385 0.001217 0.006667 1004.6 1598.5 26032 10083 1798.9 2803.2 26454 315002 6.1856, 24255 0.001235 0.057061 1045.4 1557.6 2603.0 1049.7 1753.0 2802.7 27253 3.3991 6.1244 25035 00001282 0.049779 1082.4 1519.3 2601.7 1087.4 1713.5 28008 2.7966 3.2731 6.0596 25394 0.001286 0.039448 1148.1 1448.9 259710 11545 1639.7 2798.2 2.9207 2.0530 59737 27559 0001319 0.032449 1208.8 1386.1 25809 12138 15709 27846 3.0275 2.627 5.8902 28585 0.001352 0.027378 1256.0 13230 2581.0 12675 1505.2 27726 3.1220 26927 5.8148, 29501 0.001384 0.023525 1305.0 1268.5 25705 13171 1441.6 2758.7 32077 25373 5.7450 30335 0001418 0.020489 13509 12076 25885 13637 13793 2742.9 32865 2.3925 56791 31100 0.001452 0.018028 1393.3 11518 25452 14078 13176 27255 33603 2.2556 5.6159 31808 0.001488 0.015986 1433.9 1096.6 2530.4 14502 1256.1 2706.3 3.4299 2.1245 5.5544 32488 0.001526 0.014264 14730 10413 25143 1491.3 11941 26854 3.4964 1.9975 5.4939 33085 0.001566 0.012781 1511.0 9855 24966 1531.4 11313 2662.7 3.8606 1.8730 5.4336 33567 0.001610 0.011487 1548.4 9287 2477.1 1571.0 1067.0 2637.9 3.6232 1.7497 5.3728 34216 0.001657 0.010341 1585.5 870.3 24557 1610.3 1000.5 26108 3.6848 16261 5.3108 34736 0.001710 0.009312 1622.6 809.4 2432.0 1649.9 931.1 2581.0 3.7461 1.5005 5.2466 35229 0.001770 0.008374 1660.2 745.1 24054 1690.3 57.4 2547.7 3.8082 1.3709 5.1791 35599 0.001840 0.007504 1699.1 675.9 23750 17322 77.8 2510.0 3.8720 1.2343 5.1064 36147 0.001926 0.006677 1740.3 598.9 2839.2 1776.8 689.2 2466.0 3.9395 1.0860 5.0256, 35575 0.002038 0.008862 1785.8 509.0 22988 18266 $85.5 24121 4.0146 0.9164 49310 36983 0.002207 0.004996 1641.6 391.9 22385 18880 450.8 2338.4 4.1071 0.7005 4.8076 37371 9.002703 D.ODIe4e 1951.7 1408 2092.4 2011.1 161.5 2172.6 4.2942 0.2496 4.5430 37395 0.003106 0.003106 20157 0 20157 20883 0 208K.3 440700 4.4070