Nama : Muhammad Fadhil Muchtar Nasution

NIM : 102321049

Mata Kuliah : Metodologi Penelitian

TUGAS REVIEW JURNAL

Tema : Enhanced Oil Recovery (EOR)

Judul Jurnal : The Use of Surfactants in Enhanced Oil Recovery: A Review of Recent Advances

Terbit : 2020

Penerbit : Elsevier Ltd

Surfactant's Formation Experimental

No Other Chemicals Performance
Name and Types Type Conditions
Sodium Dodecyl Alkyl Nanoparticles Various experimental - SDS with 0.2 wt% silica NPs
Sulfate (SDS) Sulfate (silica NPs, ZnO conditions including achieved incremental oil recovery
NPs), 1-dodecyl-3- high salinity and of 4.43% following
methylimidazolium temperature waterflooding.
chloride (M12) - SDS with 0.2 wt% SDS and 0.2
1
wt% silica NPs achieved
incremental oil recovery of 9.11%.
- Flooding with 0.2 wt% SDS and
0.05 wt% ZnO NPs achieved 35%
increase in oil recovery.
 Internal Olefin Anionic - Various experimental - IOS surfactants (C15−18 IOS,
Sulfonates (IOS) surfactants conditions including C19−13 IOS, and C24−26 IOS)
2 temperature and salinity can withstand harsh reservoir
conditions of temperature and
salinity.
Alpha Olefin Anionic Linear alpha- Various experimental - AOS surfactants exhibit high
Sulfonates (AOS) surfactants olefins, sulfur conditions including biodegradability and low toxicity.
trioxide (SO3) core-flood experiments, They have excellent wetting,
3
presence of CO2, and dispersing, foaming, emulsifying,
addition of clay NPs and and stabilizing abilities.
hydrophilic silica NPs
Alkyl Aryl Anionic Propylene tetramer, Various experimental - AAS surfactants are anionic
Sulfonates (AAS) surfactants benzene (for early conditions including surfactants and the most common
preparation), core-flood experiments, type of sulfonate surfactants.
4 nonferrous metal presence of nonferrous Surfactant solution increased oil
nanoparticles metal nanoparticles recovery by 1.7–2.1% of OOIP,
(NPs) (NPs) which was then increased by 6.9–
8.5% of OOIP using the NPs
Cetyltrimethyl Cationic - High salinity conditions - CTAB is a cationic surfactant
ammonium surfactant (brine with 3 wt% NaCl) also known as cetrimonium
Bromide (CTAB) bromide or hexadecyl trimethyl
ammonium bromide. CTAB
decreased surface tension of
aqueous solutions, with a higher
5
effect in brine (3 wt% NaCl)
compared to distilled water. IFT
between brine (3 wt% NaCl) and
oil decreased with increasing
CTAB concentration, resulting in
an EOR of 32.1–54.8% of OOIP.
Dodecyltrimethyl Cationic - High temperature (92 - Molecular formula: C15H34
6 ammonium surfactant ◦C), high salinity BrN. Using a formation brine with
Bromide (DTAB) formation brine a salinity of 196,014 ppm, oil
 recovery was 8% of OOIP.
Adding 0.5 wt% DTAB to the
formation brine raised oil recovery
to about 55.9% of OOIP in
spontaneous imbibition tests.
Using 100 times diluted formation
brine in the presence of 0.5 wt%
DTAB achieved even higher
levels of oil recovery. Factors
influencing limestone wettability
include brine dilution, the use of
DTAB, and the presence of sulfate
and magnesium ions
Alkyl trimethyl Cationic - Various salinities up to - Molecular formula: CnH
ammonium surfactants 223802.8 ppm (2n+1)N + (CH3)3Cl−.
Chlorides
- Three studied surfactants:
- Dodecyl trimethyl
ammonium chloride
(DTAC)
- Tetradecyl trimethyl
ammonium chloride
(TTAC)
7
- Octadecyl trimethyl
ammonium chloride
(OTAC)
.
- DTAC had the lowest
adsorption, similar to TTAC,
while OTAC had substantially
higher adsorption attributed to its
stronger hydrophobic force from
its longer hydrophobic chain. This
 makes it easier for OTAC to leave
the water phase and adsorb onto
limestone

Referensi:
Massarweh, O., & Abushaikha, A. S. (2020). The use of surfactants in enhanced oil recovery: A review of recent advances. Energy

Reports, 6, 3150–3178. https://doi.org/10.1016/j.egyr.2020.11.009