Metal Courborgl May transition mmuctals forms eampleres with CO fo form metal cactbgl Homolaptic carbonyls cantcuins on CO ase Ligarel vahwrens halerolaphe ones contain otter LUsamds in addition fe lo such as No- Lions ‘al Usgand C6 ts copalile of stabilising Yow ontdodion ob fromsition mete's whieh is On mek & me ee Lomotnes it is also lover tam 6. For ax: on ee eta of motals in Tike! conboryh, iver cosbonyf 1° Cohomgh 0. (eCe)4] [Fe (co)¢) [orto] The : Me ane three main types of caahomal caplexe 5 + Mononuclear Menomen'e complone s : (wCe14], (eter) , Corte ] Yy Finuceay calemul or dinuclear cothoneh cempleres (H4myCeo9: 9) (Fer (9) , (6H (009g ) > Poly nuclear carhard couples’ (Fes Coin) (40212) Suche of CO: » From Vet’. ~ | Co hac 10 valence os: During formation of CO, tte hybridisation » ag tpe OMY 2p e : se gp thy Phe C 4+ +4 eer te oa ee fo Ube “ [- [r T by hy Tu pated e% ef both C’ gio? verdes in me of. Sp by vd abitads of bet ¢ % O uth, firms 2 Te otter hybod oattal of volt CLO ferms (ore. pals’oO e band + Uahghnd ed 2p aabilal writr me Covel, af beth CAO frm « ple land Ths © parr on 2p, orbiter? of ayaen condinate te corrdinaks empty 269 9 vite’ af- tater & thus A coordinate bral vc formed. * Ghuchwe of (o is ‘ C40' 2 CZ mole cl ay Orbital Gp proacl . Co has a totes of 14 00s which hac MO elation‘ o : v ols oS oad hae’ nap = nthy lpr ao Fst neh, = 2p, 2, < [ ‘ 4nd ogg a a a 4L- 18 ; Ig A < > here is @ Jone pair m tus bu A ° Row the dia gran Ht clear that ght orcepiod or MO. Tus Jona paix can be demaled fe 0 vacout arbited cf Tr wetak maleing (0 a (ours base apon fom vBT We can alco conclude. thief thangs potty CR 0" hase ane lene paiy vac, the lors pair ef “¢' car be dmaled Auving complex formation because of low dechonsgactivilS of C In the Licup vo1m fuera ys acct of arhbondy osbitale amemgst which 2p. f if 2by Leing charg, ane curtable to exceple 2 pair fom field otbikd Of otal moleiny (0 a furs arid, Therefne, CO 1 @ Sigma dever & 7 eceepter figanel @ Meet’, oo Ws called tad Ugered Tr mocday Jevew inEx Evplavahin fo bonding inf flere, ax dedin- Hate of Nios 6 sd 4p Nite) [epee] ial Put ih pacreuee of ! i+ conbigaaector charges as! oo ‘Pp ee) wate) (1 CEI | im hy byrdiiation Ue Le bls 460 melecules aflw covyclination fons 4 0=07M o bmds ’ Filled d-otbitals avent involved Jn hy brdnatien kako ena te complex 8 tefralrecdt rl d-atitals Wil undergo fehelodral splitting» / Threfre, hey ond da evbitals beng Laver in ensrgy ano move suitable fr back binding wilh tre yt lan oibital of co Thenefere , there Will be moleceel ton Nico T bmds: 60 otter, "3 Ture axe 4 CO molecules mh ES a cath of cohich capable of co acephna © pay th co Catpting pale tamugt, bask, o © inca The molecule wil exif 7 in state of veco n J F neorance 05 Shao. NS <9 UN a ; noo ® > N~ — w 0 AS 09 Za, 7 Re ce co io OG ye ay oo Heve 4 Usards are bod by 4 0C3Ni ober sy A 2pNixaco7 bende fe. or total off © bonds are involed tobind 4 Ligands + 4 Ugaude = 6 bards £80 [NI(COR] e | Ligand = Tr bondsBand order of Nid 6, ban Total No of bards in all the yosanahng chee pres folad one of yesorahng shelves oS 4 ct inde Bote i \ ‘pap oe ta a octahadact complex (6((0) & Cro) undowees do? hybardisatin veoulting 4 hy brie| artialt towhrh Co coordinate produciny 6 cot © bard <6 “neg fut in octaludral freld, d-oibital of Cr oleae undirgo spliting hon day dye & dex a pibitel will go in lower Chevy lovef wich ave sutabe for back Lerdung There wil be 3Cr 9 back banding - — Hoyo. also the prolecele with CXOL in A stl of: yooman ce je bg cro) 0: ot (r(<) = ate In case of (Fe (ore"] , Felo) cordenaieos dep bation on: ok As Ar reo) fa] fey (III In 0 eee presence re ts at iv 1 =sed Lt a oe co reo) papery 1 CI CL, . dsp ayo gabon pleteny metal Canton of Iba hype h(n» Me wotal mutt have even atenvic ao» +0 fulfil EAN vule- i WO, EAN = Joan: 46 In felo),, Fans Pro 2 36 a dn ty (Og, rts 2y4l2 a6 Mo (Ca), ptan: dort 44 A suedel with odd atomic number doosnt form simple. csdherngh For ex. Co’ in 0 oxidahin tale does fm mmornucloan cabanf but Co if accepts an © fiat to change ibs onidaben ¢tab 4-1, Hen can foam simple menonucloas caband . Va K | r(co), | geri tare? 3b a9 (en? _ M Dw = ge abou Sus ~y IGS Caine flame Lobos repunert emp otbitals & chaded foles vepaerent filled oibiteds. “ynergi¢ bonding inferachon in metal corhongk : In metal carbonyl The metal casbon bonds possess beth o- and ir chaacley , the U-C o bone js ferned | Vt the donation ef Sip: of 2” present in conbon Cavbon monoxide ite a vacant cubited of tt motes. Tae u-c nm bond is formed by the donation cf pair fiom Avo filled d-orbitale of aretal nto the ontibenel ing n® mo- of CO: MWe & called back boncling s The e@ flew from the metal to Co via N-inkevachon, inovearer the Aonoy propealy cL C0, at the sameime dae flaw of 7 fom Co to the meted via g . inleractivy pncvoase s Ae acceptor copacily ef FO. Therw fore wwe van gay ¢ bond chonaltons the tt bending amd vice Verta- f : i : alse interactions work together makes m-¢o bond + ne ner awic Typ? of Inlevachion i called cynergic effect or cpeigi bonding * Synagy, means fox tars work ing achiovin oxha chengty from ftvo oy iMeve ¢ doo ther actly than work ing alone 4 Proof of syneng ie bonding Ba 4 flow of © pair from motat fo ut MO. of Caubon co in metal will cause an Inevate in no: of antibonding ein mo: of (0 ; i ye No -of bonding @ - No of anh bonding & 2 “If In motal caaleony back bonding actually Jakes pla tun Bo: of CO in metal aaaponyt will bey des Ahan Aha bond ordey of (0 in ids free steite + ee = log " This excpetled that ¢-0 bond fendt m CO will awe, higher value in mefal carbony? than in its free Stote © In practice ibs found 4a be frue+ For ex: in wy feo slate ¢-0 bad lene in CO is WA pm whereas in quotal cateongl C0 bond fouls ig 15 pro Jo some extent Vibrecional fieguencg of a spring 1s paopostional to its shenglt- Tt covalent bonds ave considered fo be Like a cpring, Heen , higher the BO: - higher will be the no of aprings & higho Wi be the vibroctioned froqutng - In Co, tts free state having BO: 4 we have Inijher vilcchin el frequency. thon tha vibyahona| fueguency of C0 ffbecause in that case BO<3- ibuechonal wm motel cax bon Te ic found t be fue-+ In free CO tv frequency Of CO bond is 2143 om but in metal cavbonak this vibrational frogueny Lies firgen abeul- Lolereritedin a 2060 6m 2n0-1850 em in (Nicwg ] 6-0 vi byecional fucquenty is In [ev (to)¢"] . ” 4 2000 cm: an (trite) back bonding tales place threw b dy dyn? Ary oF j P c °% orbital wheat in (ni coia] bork lon ding take» place Mw dytyr apd dy! orbifal + MBO decreases mare in cane of (er(oe] Compared Ww (™ icq)» “ Vilvcdtoned fie srry of- (0 (),) 1, fen vom thak oF (niece) mononuclear motal carbons, (0 acts as rn] todd Ligand je- both donor 4s woll ar ov0pty A Upgamrd bub in case of dinuclear & polyrucharr tytel Conkous, CO in additen to its meacid Liga chanacler also acts a4 boelging 4% cases there is also @ metal- mo fel bod: & ClO, y a . (0 FAN = 04649 = 96 Seas <0 oc 3 & D4 \ c Foy ext nga ox Ai cobalt (0) cock termnad | 0 Hew, in octa carbon? | co donates tro &, each Ketonic bridge hind and | pach, motal- Matas bond Apreite 4 eo to certed cebal ax2 ( From co Digan) apn t ad tecrat fetal bens) 2 (F + 7 tn each Cobalt Vr EAN is ae berin case of Fe fOly phe chucliye is ve ‘ = “ — a ~ a. i ae ~ tan of Te OL—> Fe —— fos (e : fA JR vol xa (Prom 410) oo | - 4 1 (hom te be bund) t i fy ° 0 14 (from xe. bond 46 > Mn(tos + Mn (COs Mn (9 5 tn this compound +no square py rand dal mn (Co) 5 units are joined by a Ma-Mn bund €O. co (8 70 L/ I EAN of Mn ee Mne—- co oc Vi “a = 254 5K ( fom 5 co) +4 (fom pee) co = 36 oF : n state cant form mononuclear (ehalk In i#s 2ev0 oxtcata: it farms mononucleay but in its Zero oxidation ctete Caybont $ nibosil carbons compound , No contains 1$e L there fore. Ws an oda © molecule: when No donates 1 e? it becomes ( & isoshucteral With 0. © which is tse elechoni No there fana , NO cax atk as @ Ligand howing {40 abiti ore oe On ee vf tau concept it was oud nibosy| cobatHlo) |S fotmod » tan oo (fom M2) ~ 36 cobalt (0) Aft 7. te? fom NO abon stale to -1° that hricavkong [Co (codg no | EAN of fo = In this case chempes its oxid [Fetes ney SO i pewdker Agua 1 te osrium ovale (Z) suiphads[% CHD No] Sog porta aqua nitrosy! hon (2) palpate: