CHEMICAL BONDING Motion DPP-1 ‘Rortaring potentai through eaucation JEE [MAIN + ADV.] DIVISION 1. Among the following which property is commonly exhibited by a covalent molecule (A) High solubility in water (B) High electrical conductance (©) Low boiling point () High melting point 2. The possible structure of monothiocarbonate ion is : @ ©) ao 3. How many bonded electron pars are presen tfemolecule (Ae (B)7 (Cs (D) None 4. Which ofthe following is conde as physical bond ? (a) Metalic bond (8) Covalent bond. (H-bond (0) Alofthese 5. In equilibrium conaiforrot bond formation ~ (A) Only altraction operate (©) Only repiilsion operate (C) Bothlaltraction & repulsion operate bit attraction dominate (D) Both altraction & repulsion both are equally dominate 6. Bond formation prdtess is ~ (A) Always exothermic (B) Always endothermic. (©) Can be exo or endothermic (D) None ofthese 7. Ideal condition for bond formation. (A) Maximum altraction maximum potential energy (B) Maximum altraction minimum potential energy’ (C) Minimum altraction maximum potential enefay (©) Minimum altraction, minimam potential énergy 8. Which of the following is an execption of octed 7 (a) Pcl, (B) XeF, (QUAIK, (0) All 9. Example of super octet molecule is ~ (A) SF, (B) PCI, or, (D) ALI 10. Which of following species follows the octet rule for all ofits atoms. (A)BeH,-dimer (B) TeF, (©) XeF,, (O) GF 24. The maximum covalency can be achieved by Br-atom is ays (B) 6 (8 (0)7 Corporate Office : Motion Education Pvt Ltd, 394- Rajeev Gandhi Nagar, Kota © 8003899588 | Page? I12. 13, 14, 15. Which of the following ion has minimum value of ratio of valence electron and proton. aH (B07 oa (oy n> ‘Which of following is most unstable species. au (B)N- oc (Oo Which of the following molecule has co-ordinate bond in it’s Lewis structure. (a) Co, (8) So, (NO, (D) HCN ‘Which of the following has total 5 lone pair electron in molecule? (a) co, (6) SO, (ar, (0) [xeF- 4S NY Corporate Office : Motion Education Pvt.Ltd, 364- Rajeev Gandhi Nagar, Kota © 8003899588, Page: 2CHEMICAL BONDING Motion DPP -2 ‘Rortaring potentai through eaucation JEE [MAIN + ADV.] DIVISION 1, Which of following do not represent correct structure according to Lewis octet rule? N-H Select the molecule which has maximum lone pai (a) NH (8) BF, (©) HF (0) cocl, Which of the following moleculélis not hypovalent but complete its octet? (aac, (8) AIF, (C)albr, (D) All are hypovalentiand complete their octet. What is the covalenéy of sulphur in SF,? a2 (8)3 o-4 (0) 6 ‘The sum ofthe number of lone pairs of electrons on each central atom in the following species, if they fallow the Lewis octet rule. HCO, CO, SF, CF, (a) 04 (B) 33 (02 (0) 34 How many total number of following compound which has peroxy linkage? H,0,, H,5,0,, H,S,yy HpS05, HCIO,, HPO, ae 3) (a (o)5 Which of the following moleculélean neither be Lewis acidifor be Lewis base (a) SF, (e)sici, (C) AICI, (0) NH,* Which is correct Lewis structure? (8) (0) Which follows octet rule - (A) FeCl, (B) BCI, (©) acl, (0) Pcl, Corporate Office : Motion Education Pvt Ltd, 394- Rajeev Gandhi Nagar, Kota © 8003899588 | Page? I10. 11. 12. 13. 14, 15. In which of the following compound extension of octet takes place during its formation ? (A) SF, (8) co (CBH, (0) PH ‘According to Lewis structure the number of lone pair & bond pair of electrons in SO,2- ion. (A) 12,6 (8) 12,4 (©) 10,8 (0)8,8 In which of the following molecule expanded octet is present : (a) SCl, (8) 0, (OHS (0) SiO, ‘The compound completing its octet by transfer of electrons is (a) Mgo On (8) CH (oycei, Which of them is hypervalent ? (a) Pcl, (8) AICI, (osici, (cir, Which of the following pair will not have same Lewis dot structure: (A) 50, 0, (B)NO,, CO, (C)N,0,N, (D) Ns. 05 LE > Corporate Office : Motion Education Pvt.Ltd, 394- Rajeev Gandhi Nagar, Kota © 6003899588 | Page: 2CHEMICAL BONDING Motion DPP -3 artring potential reugh eavestion JEE [MAIN + ADV.] DIVISION 1. Which of the following orbital combination form « bond when internuclear axis is 2-axis. (A) + Pe do etdey (Op, +50, (0) day + day 2. Which of the following follows Lewis octet theory : (A) BeF, (B) BCI, (©) alc, (D) AIF, 3. Which of them form = bond, if internuclear axis is x (A) 34,, + 34, (8) 342 +3dy (©) 34,, + 3p, (0) 34, + 3P, 4, Select hypovalent species with lone pair on central atom. (A) BF (B) Sncl,, (cg) So, (D) SO, 5. According to VBT, which of the followifig overlapping may results x-type covalent bond in O, molecule formation, when Z-axis is internuclear axis? (a) 2s - 25 (8) 20, ~ 2Py () isis (0) 2p, - 2p, (E) 2p, - 2p, (A) AC (B) BE (CYyB)D, (0)0,E 6. INNO, ion, The number of bond pair and lone pair of electrons preston Nitrozen atom are (A) 2,2 (8) 3,4, (43 (0) 4,0, 7. How many,tonded electron pairs are present in IFy/ii6lecule? (A) 6 (8)7 (C5 (D) None of these) 8. Number and tYpe of bonds between two carbon atoms in CaC, are (A) one sigma (@)jand one pi (e) bond (8) one c and two = bonds (C) one o and one anid.a half x bond (D) one & bond 9, The number of « and = boris in dicyanogen (CN), ar (A) 20 + 3x (B) 30 #2 (C) 30 + 4x (D) 40 + 3x 10. In OF, number of bond pairs of eleétrons are = As (8)3 (C2 (oa 11. Which is correct Lewis structure with formal charge on particular atom? Corporate Office : Motion Education Pvt. Ltd, 347 Rajeev Gandhi Nagar Kota @ S003699508 | Page12. 13. 14, 15. Which of the following obey's lewis octet rule? (ayco. (8) No (C) No, (0) BF, Which of the following species is having 2c and 2n bonds in their Lewis structure. (A) SO,2- (B) SO, (C) H,PO,~ (D) CO, How many compounds violate octet rule ? CO, , PCI, , SiF,, BrF, , IF, , PCI, , H,SO, , BF, (ays (8) 3 (c)2 (D)2 ‘Which one is the electron deficient compound : (a) Ic (8) NH, (© Bal, (0) Pcl, 4S NY Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 Page 2CHEMICAL BONDING Motion DPP - 4 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 10. Which of the following statements is not correct for sigma and pi bond formed between two carbon atoms? (A) Free rotation of atoms about a sigma - bond is allowed but not in case of a pi-bond (B) Sigma -bond determines the direction between carbon atoms but a pi-bond has no primary effect in this regard (C) Sigma-bond is stronger than a pi-bond (D) Bond energies of sigma- and pi-bonds are of the order of 264 ki/mol and 347 ki/mol. respectively. Which of the following overlaps is incorrect [assuming z-axis to be the internuclear axis] ? (@)2p,+2p,>%2p, (b) 2p, +2 p, > 0 2p, ()2p+2pox2p. (d) 18 +2p,>x(15-2p,) (A) ‘a’ &"b" (B)‘b’ &'d" (G)only ‘a" (D) None of these Effective overtapping will be shown byt (A) eore0) ©) 8g (©) ered (0) All the above Indicate the wrong statement according to ValenGejbond theory: (A) A sigma bond is stronger then x - bond (B) p-orbitals always have only sidewise overlapping (C) s-orbitals never form x ~bonds) (D) There canbe only one sigma bond between tivo atoms Co has, (A) two oanithtwo = bond (B) three o and one = bond (©) two cand one = bond (0) two « and three x bond Which of the followinglis not correct (A) A sigma bond is weaker than » bond (B) A sigma bond is stronger,than = bond (©) A double bond is stronger than a single bond (D) A double bond is shorter thania single bond Maximum overlapping takes places betWeen two _d-orbitals in xy plane, if internuclear (A) Axial, z-axis (B) Axial, y-axis (€) Non-axial, y-axis (D) Non-axial, x-axis Read the following statements : (i) The total number of lone pair electrons in XeF, are 'x’ (ii) On the basis of Lewis dots structure the maximum number of n- electrons in H,SO, molecule are ' (ii) The minimum number of electrons in parallel spin in the ground state of Cr-atom Is ' The sum of (x+y + 2) is: (a) 18 (14 () 12 (0) 20 Which of the following species do not exist (a) OF, (8) H,0° (C) NH, (0) BF, Species with highest ratio of lone pair on central atom to total lone pair in molecule is = (A) XeF,, (B) NF, (Q) soci, (0) H,0 Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 600389958811. 12. 13. 14, 15. In following structure if each atom has six valence electrons in their valence shell then identify the addition of formal charge of x, y, z and p elements according to Lewis. a -. (Ay +t (B) 0 (-1 (0) -2 Which one of the following orders is correct for the bond dissociation enthalpy of halogen mol~ ecules? (A) F, > Cl, > Bry > ly (8) I, > Br, > Cl, > F, (Cd, > Br, > FL >] (0) Br, >> F, > Ch, Select the correct statement: (A) P, is tetrahedral but shape around each P is bent. (B) P, is tetrahedral and shape around each P is also tetrahedral. (©) P; Is pyramidal and shape around each P is also pyramidal (0) P; Is tetrahedral but shape around each Pils pyramidal. What is the ratio between 7 and o bonds in H,S,Op? (A) 0.33 (8) 1.33 (2 (0) 3 Select correct order of bond stfength between two carbon atoms of a molecule: [INA (A) 25-25 > 2,-2p, > 2p4-2P, = 27.-2P. (8) 2p,-2p, > 25-25 »2py-20, = 2p,-2p, (©) 20,~20,>20,-2py > 2P,-2P, > 25-25 (0) None of these Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588CHEMICAL BONDING Motion DPP-5 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1, 10, a1. Sea ee (A) sp? ~ sp? (B) sp - sp (C) sp ~ sp* (D) sp?- sp Specify the hybridisations of central atom in the following species respectively (N,", NOCI, N,O} (A)sp, 5p", 5 (B) 5,5, 5p (C)sp*, SP, sp (0) SP, Sp, Sp. In pent-3-en-1-yne the terminal carbon-atoms have following hybridisation (A) sp & sp (B) sp? & sp (© sp? & sp. (D) sp & sp° S, : [XeF,}* has sp'd? hybridisation S, : [PCL] has sp2¢? hybridisation S, : [SF,] has spt hybridisation S. + [PF.]* has sp* hybridisation (A) TFET (B) TT FT (C) TENT (0) FFFT BF, + F > BF, What is the hybridiation statel@F®B in BF, and BF, (A) 5p, sp (8) sp, sp (CSBP (0) sp", spr Identify the correct(statement (A) single N-N,Bond is stronigerithiallSinglé|P=P\bond (B) single N4N bond is weaker than single P-P bond! (©) Nethis weaker than P=P (D) None ofthese Which statement Is.correct about hybridization 2 (A) In hybridisation ofbitals take part. (B) In hybridisation electrons take part. (C) Hybridised orbitals only eontains bond pair electron. (D) All are correct. Find number of sigma bonds and pi bOhds in CH, =(€ = C = CH, (A3,8 (8)7,3 (©) 310 (0)5,3 ‘The order of size of the hybrid orbitals is (A) sp? < sp < sp (B) sp < sp < sp* (©) sp? < sp? < sp (D) None of these In which of following species d-orbital is not used in bond formation : (a) Po, (8) SF, (© clo, (0) AIF, If formal charge on A is +1 then, A belongs to which group of long form of periodic table. B An, p- “Sc (ay 14 (B) 15 (O16 (0) 17 Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I12. 13, 14, 15. ‘What is the hybridisation of xe0,. (A) sp" (6) spd (©) spe (0) se The element A has 3 electrons in valence shell and its principal quantum number for last elecron is 2 and element 6 has 7 electrons in valence shell and its principal quantum number for last electron is 3. Which option is true for compound of element A and B. (A) Compound is AB, type (B) Compound is non planar (C) Compound has 107° bond angle. (D) All are correct If z-axis is internucleus axis then which of the following d-orbital used in a x-bond formation (A) dy & doy, (8) p, & PL (C) 4,84, (D) all of these Which of the following pair of orbitals have electronic density along the axis? (A) By 3d (B) 3422.34, (©) 3dy.30,. (0) 34,345 LE > Corporate Office : Motion Education Pvt. Ltd, 394 Rajeev GandhiNagar, Kota © 6003699588 | Pages?CHEMICAL BONDING Motion DPP - 6 orang potential trough eaueaton JEE [MAIN + ADV.] DIVISION 1. Orbital which is not participate in spd? (Pentagonal bipyramidal) hybridisation? (A), (8) dy (Cd () 4, 2. Which of the following triatomic compound has spd hybridisation? (A) SF, (B) Sncl, (©) [(EN),] (0) 1c, 3. Molecule which has distorted octahedral geometry with spd? hybridisation (A) Br (@) IF (C) xeF, (0) All of these 4, Which is not correctly matched? (A) OFF; central atom is sp'd hybridised (©) 10,F; —; dp used in hybridisatioinof central atom (©) XP; Total number of bonds = Totalinumber of hybrid orbitals (0)xeF, —;_— Central atomin 4* excited state, 5. InCH,~ C= CH molecule, th@ correct statements (A) H-C-H angle iss@pproximatety 120°, (8) C-C-C anglé is less than 180°. (©) All CEH angles are perfectly 1802 (0) Alithé'carbon atoms are in 1% excited state. 6. Which orbitals neither used in trigodal bipyramidal nor in pentagonal bipyramidal geometry ? (A) da (8) day (dy, (0) dy 7. The d-orbitals involved in)Sp°d hybridisation in trigonallibipyramidal geometry (A) de (B) de (C) dy (D) 4. 8. ‘Two hybrid orbitals have a inter orbitalangle of 120°. The % of s-character in the hybrid orbital Gya% (0) 33% (0% (0) 66 % 9. Which of the following leads to bonding ? (A) “ork paxdial (Bsa perbital—(c) peghial paxdial (0) Povbial CTA 10. Which of the following p-orbitals overlapping would result in the strongest bond : 0 0 q “ b. ® os OSD © CoD ( Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I11. 12. 13. 14, 15. Which of the following atomic orbital overlappings are not allowed : 5) >) wn Ww (i) city 78 MOMS 0 / ) e aE (yall (8) Gi) Gi) OMG ~™ (©) (ii) only Which of the following statement is true - (A) Shape of hybridised orbitals is different from parent atomic orbital (B) Only those atomic orbitals can hybridised which has approx same energy (©) Hybridised orbitals allways form o-bond (0) All of these Correct order of bond angle is — (A) SP < SP? < SP? (B) SPi> SP? > SP? (©) SP = SP = SP» (D) Nonelof these Which does not have sp hybridized central atom (A) XeF, (8) Cay (C).c05 (0) Bert, What is the hybridisation of central atom of perxennate ion, (A) spd (8) sp'd2 (O) sp (0) No iybridisation Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 Pager?CHEMICAL BONDING Motion DPP -7 SCNT 2EE [MAIN + ADV] DIVISION 1. Select the correct oto of bond length aed to given figure { CL rae ici i (arbre @erd>a Carerd— Wo>era 2. Compare bon eth fr th loving mec: ' ee \~ , (A)x ( y (D) Can't predict 2. ni orn lonng al pects do ot EE (A) BFS, Sl (B)CsxeF,, HN, (C)XeHy, XeF, (DY PEL, NCI, 4. tn whe of mails c+ SERS haat wen OO eine (oncom 5. select paar sede avn on UNE hyd orbits Senta sya en oy, 6. whch o ne hig can BE Ee tone: Finer melee naif nbriasaon o central atom. (A) Bond angle around central atom < 90° (B) Two bond pairs and three lone pairs on central atom. (C) Axial and equitorial bond lengths are same (0) Axial and equitorial bond lengths are different. 7. Which of the following is not having §B#4,hybridised/eentral atom : (a) PCI, (8) SF, (O.* )Iy 8. Which of the following is different in shape from other three? (A) NH? (B) 50, (©) SIF, (0) BrF* 9. Which of them have Bent-T shape ? (a) BF, () NCI, jar, (0) Alc, 10. In which of the molecules C-H bond has maximum % s-character. (GH, (6) CHF, () CHI, (0) HCOOH 11. Which type of x bond is formed in NOF, ? (A) pr ~ px type (8) pr ~ dr type (C) dr ~ dr type (0) No x bond formed Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I12. 13. 14, 15. Which of the following pair of compound have same hybridisation but different shape of the molecule (A) BeH,, XeF, _(B) BCI, SO, (C).CO,,BeCl, ——(D) XeF.,, SeF, In which case, first compound has no existence ? (A) Pls, PH, (8) OF,,, OF, (C) SF, OF, (0) PCI., NCI, Which of the following is planar? (A) NH (6) PF, (©) SIF, (yar, ‘What is the shape of SF, molecule. (A) Linear (6) Bent (TBP (0) See-Saw LE > Corporate Office : Motion Education Pvt. Ltd, 394 Rajeev Gandhi Negar, Kota © 6003899588 | Page: 2CHEMICAL BONDING Motion DPP -8 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1, 10. 11. Compound which has See-Saw shape - (A) xeor, (B) PCI, (© xe0,F, () SOF, How many following total isoelectronic species have same shape and same bond order? Nz, NO, , CO, , O,, CN, SnCl, a3 4 os (02 SbF, react with XeF, and XeF, to form ionic compound [XeF,]* [SbF,]” and [XeF,]* [SbF] respectively . The geometry of XeF,,* ion and XeF.,* ion respectively. (A) Square pyramidal, T-shape (B) Bent T-shape, Square Pyramidal (©) See-Saw, Square pyramidal (D) Square pyramidal, See-Saw Which of them has highest O-O bond energy? (A) H,0, (8) F,0, (4, (0)0, Shortest S - O bond length is preset in (a) So, (8) So, (9) so? (0) So, Highest bond angle is obsérved in (A) CH (8) S0,?- (dao,- (B))NO.- Select planar molecule (a) xeo, (8)CH=C=CH, —/(C)CF=G=G=CF; (0) both (2) and (3) Which of following have different bond/anglélthan others: (a) co, (8) NOs (©) sik, (0) BF, The correct order of bond length (C - 0) Is (A) C0, < CO < CO, (8) CO2% a > 120°(B) 180° > B > 120°(C) 90° > a>0° — (D) B= 180°, a =120° Here : Axial Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 600389958812. Consider the following molecule : Cl \ yeg= wt 2 Ng If r-electron cloud of C, ~ C, is present in the plane of paper then. (A) Fluorine is perpendicular to the plane of paper. (B) Chlorine is present in plane of paper. (©) e-bond of C,-C, is perpendicular to the plane of paper (0) m-electron cloud of C,-C, bond and Cl is present in same plane 13. P-F bond length is maximum in - (A) PFS (B) PF,CI, (2 PFS (0) POF, 14. In which of the following flourine atom is present in equatorial plane (A) PCLF (B) PCF, (C) PF,(CH3)5 (D) PCF 45. Ina compound BO “2 ne Nc. the number of sigma (A) 19, 11 Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 Pages?CHEMICAL BONDING Motion DPP-9 ‘Rortaring potentai through eaucation JEE [MAIN + ADV.] DIVISION 1. Which element 'X' has following order of bond angle? XH, < XF Where H and F are hydrogen and fluorine respectively. (A) Nitrogen (B) Boron (© Phosphorous (D) Carbon 2. Which process represents decrement in bond length? (A) K(s) + 0,(g) —-> KO,(s) (0-0 Bond length) 1 (B) NO(Q) +5 0,(4) ——> NO,(g) (NO Bond length) (©) NH, +H* —> NH,* (N-H Bond length) (0) CO, +20H- —+ CO, + H,0 (CO Bonditenath) 3. The correct order of bond angle is (A) PF, = PCI, = PBr, = Pl, (6) PF, > PElp> PBr, > PL, (C) PF, < PCI, < PBry < PI, (0) PF, < PCI, =)PBr, < PI, 4, The CORRECT order offbond angles in BF,, NH, , NF, and PH, is (A) BF, > NH, > NES PH, (6) PH, > BF, > NE, < NH (C) BF, > PH, >NH, > NF, (D)INH, > NF, > BF, > PH, 5. Whichifiai of species does not exist (A) CF, BFF (8) CIF,, BF, (Gr, err, (0) CIF, BrF 6. Formation of whiehmolecule is nat explained by overlapping of pure atomic orbital? (A) H,0 (B)H,5 (©) HSe (OyHTe 7. Which one of the following molecule has the smallest bond,afgle ? (a) NH, (HS (©) PH (0) H,Se 8. Which of the following has same angle But differefit bond order in given set of species ? (A) S0,,CO,% ——(B) SF, Te, (CYINO,*,CO, (0) SO,2-, NO, 9. Which of them is correct order of % s - character in lone pair of central atom. (A) NH, > PH, > PF, > NF, (B) PH, > NH, > PF, > NF, (C) PH, > PF, > NF,> NH, (D) NH, > NF, > PF, > PH, 10. Shortest $ - O bond length is present in (a) So, (8) SO, (Eso (0) 0,2 11, Which of following have different bond angle than others: (a) co (8) NO, © sik, (0) BF, 12. The species, having bond angles of 120° is (A) PH, (8) CF, (Encl, (0) BCI, Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I13, 14, 15. Match the interhalogen compounds of Column I with the geometry in column II and Assign the correct code. Column 1 Column 1 (a) x ()Teshape (b) XX,’ (ii) Pentagonal bipyramidal © xx, (ili) Linear (a) XX,’ (iv) Square-pyramidal (v)_Tetrahedral Code : (a) (hb) (©) (a) (a) (b) Ce) (a) @ Gi) Ww @ Ww eee © om Ww Gi @ oO ™ a @ @ Which of the following pairs of compounds is isoelectronic and isostructural? (A) BeCl, XeF, —(B) Te, XeF, (C) IB, XeF, (0) IF, XeF, ‘Which is not correctly matched? (A) XO, ;—_Trigonal bipyra bent T-shape (©)XeOF, «Square pyrai (0) XeF, py; Linear shape yY Corporate Office : Motion Education Pvt. Ltd, 394 Rajeev GandhiNagar, Kota © 6003699588 | Pages?CHEMICAL BONDING Motion DPP - 10 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1, Consider the molecules CH,, NH, and H,O. Which of the given statement is false ? (A) The H-C-H bond angle is CH, is larger than the H-N-H bond angle is NH, (B) The H-C-H bond angle is CH,, the H-N-H bond angle in NH, and the H-O-H bond angle in H,0 are all greater than 90° (©) The H-O-H bond angle in H,0 is larger than the H=C-H bond angle in CH, (D) The H-O-H bond angle in H,0 is smaller than the H-N-H bond angle in NH, x 2H yy HO, Tho IFY is H,PO, then structure of X and Z respectively are (A) Cyclic, Chain (B) Chain, Cyclic _(G)|Ghain, Chain (0) Cyclic, Cyclic 3. Which statement is correct for following conversion Hj" CHF, (A) C-H bond length increas@s while H-C-H bond angle inerBases (B) C-H bond lenath decreases while H-C-H/bond angle increases (C) C-H bond lengthyinereases while H-C-H bond angle decreases (D) C-H bond length decreases while H-C-H bond angle decreases 4. Which of thént has highest bond angle? (a) CH (8) CH, (cH, (0) CHF 5. Which of them has highest $8[éhiaiaeter in NO bond? (a) NO,* (B) NO, (C)NO, (0) NOFS 6. Which of them has lowesB\GIO bond order ? (ayo, (8) ClO (©) C10, (0) clo" 7. Which of them is least stable structire of N,O ? ae (8) Ken (D) All are of equal energy 8. Which of them has all hybrid orbitals are equivalent ? (ay Pcl, (8) NCI, () XeF, (0) TeF, 9. No hybridization take place in (A) NH, (8) PH, (cH, (0) SiH, 10. A compound having AB, formula can never be (a) T-shape (B) Trigonal planar (C) Trigonal pyramidal (0) Tetrahedral 11, Select molecule in which e- geometry is same as molecular geometry. (a) xeF, (6) SF, (©) clo, (0) so, Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I12. 13. 14, 15. In which of the following molecule / ion all X-O bonds are equal ? [X = Central atom] (A) 05 (8) Mn,0, (©) cro (0) HNO, Which of the following chain structure is open book like structure ? as (8). (© (SCN), (0) P.O, Select correct statement about phosphite ion - (A) Tt forms acidic salt with cation. (B) Basicity is one. (C) Phosphite ion is. sp? hybridised and tetrahedral in shape. () P-O bond order is 1.5. ‘The hybridisation of Xenon in XeF, in solid state Is - (A) sp (8) pa? (© pas (0) sped? LE > Corporate Office : Motion Education Pvt. Ltd, 394 Rajeev Gandhi Negar, Kota © 6003899588 | Page: 2CHEMICAL BONDING Motion DPP - 11 ‘aruring potential ough education JEE [MAIN + ADV.] DIVISION 1. AIF, is soluble in HF only in presence of KF. It is due to the formation of (A) KAIF] (8)K [AIF Hs] (C) K, [AIFe] (0) AIH, 2. If Lis dissolved in aqueous KI, the intense yellow species, I, is formed. The electronic geometry of f, ion around central iodine Is = (A) Square pyramidal (B) Trigonal bipyramidal (©) Octahedral (0) Pentagonal bipyramidal 3. Which one of the following contains all ionic, covalent and coordinate bonds? (A) NaOH (8) Nact (C) NaCN (0) NaNo, 4, As compared to covalent compounds, electrovalent compounds generally have - (A) high melting point and low boiling point. (B) high melting point and high boiling points (C) low melting point and low boiling points (D) low melting point and high boiling point. 5. Consider following Born Haber’s cyéle 24 (9) + + Big AEs etsy SHES 24" (aqyeB™ (aq) an a, 2A (e) +B Select correct reason if A,B is completely soluble in water. (A) AH, Nat(g) + (HI) Clg) ee? 2e1 (9) (IV) Cl(g) +e er (9) (v) Cr(g) + Nar(g) > NaCl (S) Tate eoney Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I10. a1. 12. 13. 14, 15. ‘The enthalpy of formation of NaCI will be D D (A) aH, = S +1 -E-U (8) AH, = S +145 -E-u E E (©) AH, = -S = LD+> +0 (0) AH, = -S-1-D -F-u Give the correct order of initials T or F for following statements. Use Tif statement is true and F if itis false. (1) The order of repulsion between different pair of electrons is fp ~ Ip > Ip ~ bp > bp ~ bp (i) In general, as the number of lone pair of electrons on central atom increases, value of bond angle from normal bond angle also increases. (ii) The number of lone pair on O in H,0 is 2 while on N in NH, is 1. (iv) The structures of Xenon-fluorides and Xenon-oxyfluorides could not be explained on the basis of VSEPR theory. ae (8) TFIF (TFT (0) TFFF The interhalogen compound that cannot exist is (a) IB, (®) Ici, (OuF, (0) err, The oxide does not have coordinate bond/is (a) NO (8) No (C) NOs (0) No, Which compound has electrovalént covalent, coordinate a& well as hydrogen bond. (A) NH,Cl (8) HNO, (©) CuSO,.5H,O (0) BeCl,.2H,0 Bonds present in N,Og((hitrogen pentaoxide) ar (A) only ionic (B) only covalent (©) covalent andéoordinate: (D)scovalent and ionic Which of thé following statements is correct in the context of the allene molecule, C,H,? (A) The central carbon is sp hybridized, (B) The terminal carbon atoms are sp? hybridizes (C) The planes containing theCis.groups are mutually perpendicular to permit the formation of two separate m-bonds. (0) All correct Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588CHEMICAL BONDING Motion DPP - 12 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 10. "Solubility of Alkali metal fluorides increases down the group" Select correct explanation for given statement. (A) Hydration eneray increases and lattice energy decreases down the group (B) Both energy decrease down the group but decrease in hydration energy is rapid (C) Both energy decrease down the group but decrease in lattice energy is rapid (0) Both energy increase down the group but increase in hydration energy is rapid NH, (hydrazine) combines with (CH,),N via (A) an ionic bond (B) a coordinate bond (C) acovalent bond (D) combination is not possible The correct code for stability of oxidation states for Sn and Pb is [1] Pb? > Pbé=, Sn2* > Sné [IN] Pb? < Poe, Sn®> < Sné> [in] Pb2* > Poi) Snz* < Sut [IV] Pb2+ = Pot) Sn2 > Snt* [IV] Sr < pb, Sné* > Pos EVID Sn2~ < pb?s, Snt> < Pbé (a) (v) & (VI) (8) (ptimy, (v) 8 (vt) ©) om & (v] (©) TH & OV) Select the compound which hasithe shortest N ~ N bond|length. (A) NH (8) Natty (ONE, (ON, Which of the following statement is incorrect? (A) Oxidizing powerorder : SiCl, < SnCl, < PbCl, (B) Ionic character order : GsBr>:RDBr> KBr> NaBr > LIBr (C) The ionic,character of lead (1) halides decreases with increase in atomfityno. of halogen (0) The oxidation state of T/in 7/1, is +3, Which Is the correct order between bélow three bond angles = ? ° mr | TN \ (A)0,<0,<0, — (B)0,290,<0, — (C) 0, < 0, < 0, (0) 0, = 0, Which of the following pair of specis II having more,bénd length than 1? = be] (AGH, Gf, (C~ C Bond length) (8)0.F, O,H, (0 - © Bond length) (OC) CHF, CAF, (C- H Bond length) (0) Pci,* —Poct, (P - Cl Bond length) Incorrect option regarding SO,Cl is (A) 080 > 08c1 > CSCI (Bond angle) (B) Number of pr-pz bond is less than number of pr-dz bonds. (C) Number of pr-pr bond is more than number of px-dr bonds. (Hybridisation of central atom 'S' is sp? Which of the following option is correct regarding C - 0 Bond length? (A) G0, > CO > CO, (B) C,0, < CO < CO, (©) CO C,0, < Co,? (0) CO = C0, = Co, Select the combination of orbitals having highest strength. (A) 2p, = 20, (B) 3p, 2p, (©) 3p, ~ 3p, (0) 4s - 4s Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I11. 12. 13. 14, 15. Select the ion having pr-dr bond (A) 80,7 (8) PO, (o.co,- (0) All of these ‘Among the following fluorides, which is least soluble in water? (A) Ber, (8) MoF, (©) CaF, (0) SrF, If the number of a-bond and x-bond in NOBF, molecule are ‘a' and ‘b' respectively than find the value of 'e'. [¢= a-b] (yo ©)3 js (5 Which of the following does not have, N - N linkage? (@) No (©) NO, (N,0, (0) 4,N,0, ‘The total number of pr-dr bonds in SO, molecule is ao (1 (2 (0)3 LE > Corporate Office : Motion Education Pvt. Ltd, 394 Rajeev Gandhi Negar, Kota © 6003899588 | Page: 2CHEMICAL BONDING Motion DPP - 13 tring poten ough easton JEE [MAIN + ADV.] DIVISION 4. Polarsing power is estimated by (ay lone charge (q lone charge (c) (lone charge)? (gy Howie rains (Ionic radius) (lonic radius) Jonic radius Tonic charge 2. Out of list I select the cation which has less polarizing power than Ca?* and from list II select the anion having more polarisability than S? List: Mg?*, Sc, K* se iy ee Ce ch (A) Mg, (8) K*, (©) Se, (0) Mg?*, ct 3. Higher polarisation in case of AgCI compared to KCI is due to (A) larger size of cation (B) smaller size of cation (C) inert gas configuration of cation (0) Pseudo inert gas configuration of cation. 4. Calculate the % ionic chardéter for metal fluonidélwhere the el@ctronegativity of electropositive element is 2.1 (A) 43.03 % (B) 56.8 % (©) 50% (0) 12)% 5. Which of theféllowing has highest melting point? (A) Be (8) CaF, (©) Mor, (0) BaF, 6. The correct éfder of bond angle is (A) Lt < IBrjt QUCL,* (B)IA> Ier,* > Ic1,* (©) Gy > ICl,* > IB: (D) IBF» > 1* > 1c* 7. Select pair of compounds}in which both have differentlhybridisdtion but have same molecular geometry. (a) BF, BrF, (8) IC“, BeCl, (©) BCI, PCI, (0) PCI,, NCI, 8. Which of the following has minimum solubility (a) KF (8) KCl (c) Ree) (oy cscl 9. The hybridisation states of carbon and oxygen atoms in C,0, are (A) sp both (B) sp and sp? respectively (©) sp? both (D) sp? and sp respectively 10. Which of the following order is correct regarding melting point. (A) SiO, < NaCl (B) CaCl, < ZnCl, (C) HgCl, > CdCl, (D) CaCI, > ZnCl, 11. Choose correct order according to the properties mentioned. (A) MgF, > CaF, > Sif, > BaF, > BeF, (Melting point order) (B) BeO'> MgO > Ca0'> S10 > Ba0 "(Melting point order) (C) BeS0, > MgSO, > CaSO, > SrS0, > BaSO, (Solubility order) (0) U,CO, > Na,CO, > K,CO, > Rb,CO, > Cs,CO, (Solubility order) Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I12. 13. 14, 15. ‘The compound having maximum number of px - dx bonds is : (a) so, (8) H,S0, (©) HNO, (0) HCIO, Which of the following has regular octahedral geometry? (a) SbCl,2- (8) XeF, (OIF, (0) PF,C1~ ‘The correct order of thermal stability is (A) BeCO, < MgCO, < CaCO, < SrCO, < BaCO, (8) BeCO, > MgCO, > CaCO; > SrCO; > BaCO, (C) MgCO, < CaCO, < SrCO, < BaCO, < BeCO, (0) MgCo, < BeCO, < Caco, < SrCO, < BaCO, Which of the following species is not distorted octahedral? (A) XeF, (8) IF, (© XeF, (0) BrF, 4S NY Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 Pages?CHEMICAL BONDING Motion DPP - 14 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1, 10. ‘The bond length of the S-O bond is maximum in which of the following compound. SOBr,, SOCI,, SOF, (a) soc, (8) SoBr, (© sor, (0) All have same length Which is wrong statement? (A) The decreasing order of thermal stability is CSOH > RbOH > KOH > NaH (B) The decreasing order of bond angle is BF, > PF, > CIF, (©) The decreasing order of bond dissociation energy is Cl, > Br, > F, > I, (0) The decreasing order of melting point is NH, > (CH,),NH > CH,NH, > (CH,),N Which order are correct 7 (1) Thermal stability : BeSO,< MgSO, < CaSO, < SrS0, < BaSO, (Il) Basic nature : 2nO > BeO > MgO > Cao (111) Solubility in water : LIOH < NaOH < KOH < RbOH < CsOH (IV) Melting point : MgO > CaO > Sr > BAO (~) 0) (8), & (YE (CY ay, OM) (0) All are correct Which is correct statement? AAs the s-character of a hybrid orbital decreases (I) The bond angle decreases’ (II) The bond strength increases (II) The bond length increases (1VyjSiz@of orbital increases (a) (1), (1) and (IV) (B) (ID), (It!) and (1V) (C) (1) and (11) (D) All are correct Which order aré correct ? (1) Thermal Stability : BeSO,< MgSO, < CaSO, <|S'SOy=)BaSO, (II) Basie nature : Zn0 > BeO > MgO > C20 (11D) Solubility in water : LOH > NaOH S KOH|S RbOH > CsOH (IV) Melting point : NaCi > KCL > RbCl > CsCl > LiCl (a) @, Gy (©) @), @ aay (© ah, am (0) All ar€ correct Which of the followinglorder fs correct of the glven|property. (A) NaCl > KCI > RbCI> GsCl > Lic! melting point order (B) Ber, < MaF, < CaF, < Sif, < BaF, solubility order (C) NO* > NO” > NO = NO&S,No* bond length order (D) Ba0 > S10 > CaO > BeO > Mgo basic character order The correct solubility order is / are (D CaCO, > SrCO, > Baco, (U1). U,CO, < Na,CO, < K,CO, (Il) K,CO, < Rb,CO, < Cs,CO, (WW) Na,CG, > K,CO,'> Rb,CO, (ay, @rw (on, nv (6) 1,1, tt Choose the correct melting point order: (A) NaF > MgF, > AIF, (8) BF, > BCl, > BBr, > BI, (C) H,0 > H,S°> H,Se > H,Te (D) NaCl > KCl > RbCI > CSCI > LiCl In which of the following cases the covalent character and the melting point order are same. (A) BeCl,, CaCl, BaCl, (8) NaCl, MgCl, AICI, (© MgBr,, SrBr,, BaBr, (D) NaF, MoF,, AIF, Which of the following properties is having incorrect order. (A) CaSO, < S150, < BaSO, ; solubility order (B) CaCO, > S1CO; > BaCO, ; solubility order (C) NaF > KF > LIF > RbF > CsF ; m.p. order (0) CH,Cl > CH,Cl, > CHCl, > CCI, ; dipole moment order Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I11. 12. 13. 14, 15. Match List-I with List-IZ and select the correct answer using the codes given below. List-1 List-11 (a) H,0 < H,S < H,Se < H,Te 1. Bond angle (b) H,0 > HS > H,Se > HyTe 2, melting and boiling point (©) H1O >> AS < Hise < Ate 3. acidic strength fa) () “Ce fa) (b) (e) (A) 1 3 2 (B) 3 2 z= © 3 1 2 @) 2 3 2 Select the correct property for given, (A) AGCI > KCI (os Fe. given) Covalent character (B) CaC,0, < SrC,0, < BeC,O, Solubility order (C) Lind, < kNo, <'CsNo, Thermal stability order (0) All are correct Select the correct order of melting point. (A) NaF > NaCl (B)AIF,>MQF, (C) CaF, > CaCl, (0) All are correct IF, + BF, > DX] What is the shape of cationic and anionic part ih. ionic compound [X] respectively? (A) Trigonal bipyramidal and Octrahedral (B) Trigonal bipyramidal & Tetrahedral (C) Octahedral & Tetrahedral (0) Pentagonal bipyramidal &Tetrahedral Which of the following isifon polar and pentagonallplanar species? (A) XeF (8) XeOF, (C)XeFs (8) XeF, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588CHEMICAL BONDING Motion DPP - 15 ‘aruring potential ough education JEE [MAIN + ADV.] DIVISION 1, Assuming the bond direction to be z-axis, which of the overlapping of atomic orbitals of two atom (A) and (B) will result in bonding? (1) s-orbital of A and p, orbital of 8 (Il) s-orbital of A and p, orbital of B (11D p,-orbital of A and p, orbital of B (IV) s-orbitals of both (A) and (6) (a) Land 1V (8) fand (©) Land Iv (0) Hand Iv 2. _N, and O, are converted to monocations N+ and O} respectively, which is wrong statement (A) In Nj, the N-N bond weakens (B) In O§, the 0-0 bond order increases (©) In Of, the paramagnetism decreases (D) N? becomes diamagnetic 3. According to MOT (Molecular Orbital Theory), the molecular orbitals are formed by mixing of atomic orbitals through LCAO (linear combination of atomic orbitals). The correct statement(s) about molecular orbitals is/are Statement (a) : bonding molecular orbitals are'formed by addition of wave-functions of atomic orbitals Statement (b) : anti-bonding moléculer orbitals are formed by subtraction of wave-functions of atomic orbitals Statement (c) : non-bonding molecular orbitals do not take part in bond formation because they belong to inner shells Statement (d) : anti-bonding molecular orbitals provide stabilityto molecules while bonding molecular orbitals make the molecules unstable. (A) Statement af (B) Statement a, b, c (C) Statementiay b, 4 (D) Statement 2, » 4. Which(6fthe following species is/are diamagnetic. oF (i) 0, (a) 0; Wo; (A) 03,03 (B) 0, and OF (OQ) OP only (0) OW OF 5. Which Is incorrect accordifg to MOT. (A) Hj and Hey have same stability (8) H, is stabler than H (C) He} may exist while He, cannot (D) same bond order of two species do nétsmeafi they have same bond energy 6. Which of the following order is not correct? (A) Thermal stability: LIOH > NaOH > KOH > RbOH (B) Dipole moment: BF, < H,S < HO (C) Polarity of the bonds : Sbit, < Ast, < PH, < NH, (0) Melting point : CaF, > CaCl, > Cabr, > Cal, 7. Pick out the incorrect statement (A) N, has greater dissociation energy than N,* (B) 0; has lower dissociation energy than 0," (C) Bond length of N,* is less than N, (B) Bond length of NO* is less than if NO. 8. In which of the following sets, all the species are diamagnetic in nature? (A) [OF 03", NF] (B) [Cz,03 NF] (CINE .03,03] (0) [N3,0;°.B.] Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I10. 4. 12. 13, 14, ot Read the following statements for above diagram: (i) They form constructive interference. (ii), They form antibonding molecular orbital. (iil) They form gerade. (iv) They form molecular orbital which has two nodel plane. (v)__ They form molecular orbital which has less stability as comapre to AO” Select correct statements: (A) (i), il) and (iv) (8) (i), (id, (iv) and (v) (C) Cid, Gil) and (iv) (©) Gil}, (iv) and (v) In given figure, by which of the following orbital overlap p-d_ - antibonding is form ~ coc ©) 88 © #8 ©) exact Identify the least stable amongst the following: (aur (8) Be (Oe (oc Which of the followifig Is the correct combination of atomic orbitals acéording to MOT. oO BO -FS@® ABMOW) BMO(uz) ABMO() OC) ABMO(e) Which of the following is true for 0, and C, molecules according to M.O.T. (A) both are having 1c and 1n bond ~——_(B) both are of same bond length (©) both are having same bond order —_(D) both are having two x bonds In which of the following ionization processes, the bond order has increased and the magnetic behaviour has changed? (G2 Cl (B)NO>NOr — (C), > (D) N, > N} Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 | Page: 215. Which of the following diagram results antibonding molecular orbital. Ke I- feo. (©) { Y.. (D) None of these AA Corporate Office : Motion Education Pvt. Ltd, 394 Rajeev Gandhi Nagar, Kota © 8003899588 Pages 3CHEMICAL BONDING Motion DPP - 16 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1. Which Is incorrect in the following (A) Tonisation energy of F, molecule is more that of F-atom. (B) Ionisation energy of F-atom is more them that of Cl-atom (©) Electron gain enthalpy of F-atom is less (~)ve than that of Cl-atom (D) Ionic mobility of fluoride ion is less than chloride ion in water. 2. According to MOT the process N, (g) —> N} (g) + € is more endothermic than the process 0,(9)—> O$ (g) +e because (A) N has half filled electronic configuration which is more stable. (B) Nitrogen is less electronegative than oxygen. (C) Electron is removed from anti bonding molecular orbital in N, where as electron is removed from bonding molecular orbital in O,, (0) Electron is removed from bonding miéleeulaPjorbital in N, where electron is removed from antibonding molecular orbital in Os: 3. The bond energy order of He, sand HeH* is (A) He, > He" (B) Hell = He," (C) He? > He,* (0) Can't be predicted 4. —_Inwhich of the followifig set has same bond order. (AN, 0%, NO®, EN (B)Q,, N,2- , NO“, NO,* (C) NO, Np=9@,*, NO (D) All are correct 5. WhichVof the following species exhibitsithe'dlamagnetic behaviour? (A) 05 (8) OF (C) 0, (D) NO 6. When 0, is formed)from 0, then electron is removed from (A) B.M.0. (BYA.B.M.0 (©) N.B.M.O. (DY None of these 7. Inwhich of the following proéésses the magnetic moment ig/not getting changed. (A) K in fig, NH, > (8) N,—9Ny (c)o- —> or (Dy AgCI =~ 8. Which of the following has the highest melting point? (a) AF, (®) ACI, (©) Abr, (0) an, 9. Which of the following is correctly matched with the given property? (A) MgS0, < CaSO, < SrSO, < BaSO, (Solubility in water) (B) BeCO, > MgCO, > CaCO, > SrCO, > BaCO, (Thermal stability) (C) NaOcl > NaOBr > Naot (Oxidising nature) (0) F,> Gy, > Br, >I (Bond energy) 10. The O - O bond length is maximum in : (A) 0, (B) O,[ASF,] (OF, (0) H,0, Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages Ia1. 12. 13. 14, 15. Which of the following statements is/are correct? (A) The molecular orbitals are essentially Identical to the relevant atomic orbitals at very high energy differences. (B) Dominantly ionic compounds of group I have HOMO-LUMO energy gap in visible region generally. (C) Coloured covalent diatomic molecules have HOMO-LUMO energy gap in ultraviolet region. (0) All of these. Which of the following would have same magnetic nature whether sp mixing is operative or not? wc (6) 8, (0, (0) All of these Which of the following has the highest melting point? (a) sio, (8) cl Ob (0) dry ice Select the correct set of paramagnetic species, (A) No, Op, By (B) 0, Hy, C (© 0, B, NO (D) Lig, By, Cp Which of the following option is correct? [State ‘T' for True & 'F" for False] (i) 0,- is paramagnetic as well as it has fractional bond order. (ii) Tonization Energy of O > 0,. (iil) Absence of sp mixing, B, is an diamagnetic species. (iv) SO, and SO, both are planar aswell as polar molecule. (a THF (8) TTFT, (OFT (0) FIT Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588CHEMICAL BONDING Motion DPP - 17 ‘Rortaring potentai through eaucation JEE [MAIN + ADV.] DIVISION 1. Which of the following pair of molecule have same shape but different in polarity (Polar or nonpolar) (A)H,O&NH, — (B) SnCI,&SO, — (C) CO, &N,O (0) SO, &SO, 2. Which of the set of isomers of C.H,Cl, is having equal dipole moment with C,H.CI and C,H, respectively (A) ortho and meta (B) meta and para (C) ortho and para (0) para and ortho 3. Which of the following statement is incorrect for CO molecule. (A) Intramolecular Lewis acid - base interaction is present (B) Charge separation is present. (©) o-bond, x-bond and back-bond all are present together. (D) Direction of dipole moment is from 'C’ to#O" 4. Which of the following molecule / speciés is polar. (A) 0, (B) NO,* (C) paradichlorobenzene (D) None of these 5. Which of the following is anlféxample of a planarmolecule having a net dipole moment (A) NFS (8) CIF, (C) XeO,, (©)S0, 6. Inthe formula of PCI, (A) and PF,Cl, (B), if all Fratoms are replaced ByyBr-atom, then which of the product will Show zero dipole moment: (A) Product,ffom 'A’ (B) Product from ‘6° (C) Produet from both ‘A’ and ‘8! (D) Products from none 7. PCI,F,., mol@eule will be polar & non polar for what value of ‘x’ respectively. Polar Non pala (a) 2,3, 58 oa (8) 02,58 3p, 4 (C) 4,3, 08 2,04 eee 3,0, 5) 8. Choose the correct order of the ven property. (A) SIF, > SICI, ; b.p. order (B) MgCO, > SCO, > BaCO, ; Pco, Order when kept at fixed temperature in a closed container (C) XeF, > XeF, ' ; Dipole moment order (D) XeF, > XeF, ; F accepting tendency order. 9. Br,C = C = CBr, molecule is (A) Polar as well as non planar (B) Polar as well as planar (C) Non polar as well as non planar (D) Non polar as well as planar OH 10. or select the correct order of dipole moment for this molecule (A) Hobs > Heat. (B) Hons < Heat. (C) Hons * Heat. (B) none of these Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I11. 12. 13. 14, 15. Which of the following molecule will have the highest boiling point (in bracket yi, of the molecule is given) (A) Dimethyl ether (1.3) (6) Propane (0.0) (©) Methyl cyanide (3:9) (0) Acetaldehyde (2.7) ‘The correct order of Z HAH bond angle (where A’ is the central atom) is: (A) NH, < HO < HF (B) H,0 < NH." < HF (©) NH, < HyFY < HO (D) HF? < HAO < NH, The correct order of dipole moment is : a oa (A) POL F, > PFC, (6) > ‘cl (©) CHF y (Ox=y (0) can not be predicted ‘The hybridisation of C-atoms in tetracyanomethane is (A) sp, sp? (8) sp°, sp (@)sp°, sp (0) sp, sp? Which of the following option is correct about NO, & CIO,? (i) Both are paramagnetic species (ji) Both compounds dimerised readily (iil) Both have sp? hybridisation (iv) Both have Bent shape. 0, 0) (8) (i, (a, Gv) (©) (i, Hi), Gv) (©) only () Which of the following species are planar as well as nonpolar? (A) C0, (6) PCI, cca, (0) $0,2- The correct order of bond angle is (A) It > IBr,* > ICl* (8) Lt < IBr,* < 1C1,* (C) L* > ICl,* > 1Br,* (0) IBr,* > 1,* > Ic1,* Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I12. Which of the following mixtures has dipole ~ dipole interaction? (A) Acetone + ethanenitrile (8) KCI + water (C) Benzene + toluene (0) Cal, + cs, 13, The total number of z-bonds present in a single plane in the compound C,S, is at (2 (3 (0) 4 14. Consider the compound given below: iH 0 B Hl yl 7 q > y ‘The correct order of bond angles indicated would be = (a>B>y — (B)a>ry>B — (Cac NF, (6) H,0 < H,0, x x : > (C) (If X and Y (lf X and Y (B) All above are correct form H-bond) does not form H-bond), ‘The correct order of boili¥@ point is (A)He > Ne > Ar (8) HF cl, (0) 1c = Br, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 Pager?CHEMICAL BONDING Motion DPP - 20 urtring potent trough eaacation JEE [MAIN + ADV.] DIVISION 1. Find out the similarities between T,Cl, and Al,Cl, (A) both have 3¢ = 4e" bond (8) both have sp? hybridisation for the central atom (C) both are non planar (D) All are correct 2. Hybridisation of central atom is independent of the phase/state of the compound in case of (A) eH, (8) N05 (©) XeF, (0) PF 3. The type of overlap in the bridge bond existing In Al,(CH,), Is (A) sp? - sp3d - sp? (B) sp? - sp? - sp? (C) sp? 5 - sp? (D) sp? ~ sp? - sp? 4. Find the incorrect match. (A) AlCl 3e-4e bond is preséht (B) AL,(CH,), All carbon atoms are sp>-hybridised (LG. Nonplanar, (D) Al,Br, Nonpolat 5. Which of statement js{€orrect for compound like N(CH,),, N(SIH,); BaP(SIH,),. (A) N(SiH,), & P(SIH,), both,have 120°,bond. angle due to pr-dr back bond. (8) N(CH,), hia 110° bond angle due to steric repulsion of methyl group. (C) P(SIM;), has. 2px-2pr back bond (0) N(CH)gjhas._2pr -2px back bond! 6. __In which of followifig cases the extent of back bonding is most effectivél (A) BeF, (B)(CH,),0 (C) ASF, (OyC1,~ 7. In which of the dimerisation process the achievernent of the"Oetet is the driving force (A) 2 Bel, — Be,H, (8) 2 ACI, —Sal,cl, (©) 2A, —> Al,H, (D) NoneioF these 8. Choose the incorrect statement. (A) dec (IM CF.) < dec (1 CF) (B) The % p character of C-F bond in CF, is more than that of C-H bond in CH,. (C) The free electron of CIO, molecule is not present in 3d orbital of Cl-atom, (0) BH, Is an electron deficient molecule. 9. Which of the following overlapping is involved in polymer of (Be(Me),], (A) 5p ~ sp?= sp? (B) sp? ~ sp? ~ sp? (C) sp? ~ sp ~ sp? (0) sp? ~ sp? ~ sp? 10. Which of the following is an example of 2p, ~ 3d, back bonding. (aoc, (e)ccl, (© both (A) and (8) (D) None of these Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I11. 12. 13. 14, 15. Which of the following molecule has 3c~2e" bond (A) Bel, (8) AICI, (Abr, (0) None of these Select the correct statement. (A) In boron trihalide B-X bond have partial double bond character due to back bond. (Where X = Halogen) (B) :CF, is more stable compared to :CH, (©) Dimer of boron trihalide do not exist. (0) All are correct ‘The number of two centre, two electron bonds in a molecule of diborane is: (2 (B)0 o4 (0) 6 Select the correct statement, (A) An ionic bond is always stronger than a covalent bond. (8) Back bonding or synergic bond is formediby lateral overlap of participating orbitals. (C) In B(OH),” d-orbital is involved in hybridfsation.. (D) Complete hydrolysis of Sif, is possible. What will be the hybridisation(@f Sn in solid Sncl, ? (A) sp (8) sp? (C)sp% (0) spa, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588CHEMICAL BONDING Motion DPP - 21 ‘Rarturing potential through eaucetion JEE [MAIN + ADV.] DIVISION 1. Choose the correct statement regarding the given molecular orbital, (A) Itis formed by constructive overlap. (B) It represents anti-bonding molecular orbital (C) It has only one nodal plane (0) All of these 2. Select the species having bond order equal to one ui; (eB, (OF, (0) All of these 3. Select the incorrect statement regarding CO, NOMand CN molecules (A) All above three are isoelectronie species. (8) All three species has samesbond order. (C) Inall three species elettron is removed frome2p, bondifig,molecular orbital (0) Among in all three:speefes CN has maximum Bond length 4. The structure of @iborane (BsHg)/contalns’ (A) Four (2622e°) bonds and two (2C-3e) bonds: (B) TwO\(2C-2e") bonds and two (3C-2¢") bonds (©) Four (20=2e-) bonds and four (3c 28°) bonds (D) None 5. Number of S-S bondlinHS,0, On (®) (m-1) (©) (nea) (O) (n+ 1) 6. Identify the correct sequence of creasing number of aebonds in the structure of the following molecules. I HS,0, 1 H,5,0, mT fis,0, (AL Mand MM — (6), andi (GT Mand t= (0) T, TM and 7. NH, (hydrazine) combines with (CH,),N via (A) an ionic bond (B) a coordinate bond (C) a covalent bond (D) combination is not possible 8. The state of hybridisation of central atom in dimer form of both BH, and Belt, is, (A) sp2, sp? (8) sp°, sp (©) 5°, 50° (©) 502, 5p? 9. Hybridisation of central atom is independent of the phase/state of the compound in case of (A) BeH, (B) N,O; (C) XeF, (D) PF; 10. What is the hydrolysis product of hypo phosphoric acid. (A) H,PO, H,P,0, (B) H;PO, (C) H,PO, (D) H,PO, , HPO, Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages Ia1. 12. 13, 14, 15. What will be the transition state to get BF,CI and BCI,F from the reaction between BF, and BCl,, Fa Nat Fag oy cl a) 8 ON ® wa Na (C) (A) and (B) both (D) None of these Which of the following molecule having 3c - 2e bond - (A) GH (8) NH, (C) Bel, (0) AL,Br S = S linkage is not present in (A) 1,820, (B) HS20. (C) H,S,05 (0) HS Select the correct statement : (A) HSO; fon has one S-O-H linkage (B) Number of B-O-B linkages in Borax Is equal to number of P-O-P linkages in P,O,. (C) Hybridisation of both sulphur in H,S,0, (pyrosulphurous acid) is same but oxidation state of both sulphur are different (0) Tetra phosphoric acid has four P-O-P and n)P-P linkage Which of the following compoundifias maximum S ~ § linkage? (A) Na,S,0,, (B) Na,S50,, (©) Na,S,0, (0) Na,$,0,, Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 | Page: 2CHEMICAL BONDING Motion DpP - 22 ‘uring potent voUaT edueaTON JEE [MAIN + ADV.] DIVISION 1. In which of the following silicates, only two comers per tetrahedron are shared : (i) Pyrosilicate (ii) Cyclic silicate (iil) Double chain siticate {iv) Single chain silicate (v) 3D silicate (vi) Sheet silicate 10. 11. (A) (D, (i) and (v)_(B) (Iv) and (vi) only (C) (I) and (vi) only (D) (Ii) and (Iv) only Amphibole silicate structure has °x’ number of corner shared per tetrahedron. The value of x is a2 (8) 2% (3 (0) 4 Give the correct order of initials T or F for following statements. Use Tif statement is true and F ifit is false. (1) Br-P-Br bond angle in PCI,Br, is 180°, (1) NOS, NO, & NO5 species have O-N-O bond angle order, NO; < NO, < NOS (IIT) Oxy acid is not produced, when NCIg{undergoes hydrolysis. (IV) _ Silicones are very inert and water repellant. (a) TF (6) TFIT (© FFE (0) FFT (Si,0,)2*"anion is obtained wen (A) no oxygen of a SiO {aitetrahedron is shard with another SIO{ tetrahedron. (B) one oxygen ofj@/ SIO} tetrahedron is shared with another SiO'" tetrahedron. (C) two oxygéh of a SiO‘ tetrahedron are sharedwithyanother SiO‘ tetraliedron. (0) three oxygens of @ SiO tetrahedfon are shared with another SiO‘- tetrahedron. ‘The silicate aniofin the mineral kinolte Is a chain of three SiO, terahedta, that share corners with adjacent tetrahedra. The charge of the silicate anion is (a) -4 (B)-8 oO (oye Which of the following structure(s) is/are non-planar (A) Na,B,0,, (8) LC, (©) Sheet silicat@ (D) Inorganic graphite In which of the following structure, thejnumber of shafed O-atom per tetrahedron is two and half. (A) Pyroxene chain silicate (B) Amphibole chain silicate (©) Cyclic silicate (D) Sheet silicate In which of the following silicate structure, the number of corner shared Is minimum. (A) Pyrosilicate (8) Amphibole chain silicate (©) 3D-silicate (D) Six membered cyclic silicate Acyclic silicate anion is represented as [Si,0,]" ‘The value of ‘nis (A)3 (B) 4 (6 (0) 8 In which of following silicate structure, the number of corner shared per tetrahedron is '2’. (A) Four membered cyclic silicate (B) Pyrosilicate (©) Orthosilicate () 2D-Silicate 1f 25 [SiO,]*- units are arranged in chain form then what will be the formula of that chain, (AVTSIs075F* ——(B)[SizsQre]}*——(C) [Sins jeo}™® —(B) None Corporate Office : Motion Education Pvt. Ltd, 383 Rajeev Gandhi Nagar, Kota © 8003899588 | Pages I12. 15. tow many « bonds are present in compound (€) ? [A = Phosphoric acid] 2*A-H,O——*(B) Lito (A) 13 (B) 12 (C) 10 (D)8 Which of the following is correct formula of sodium di hydrogen pyrophosphate? (A) Na,P,0, (B)Na,H,P,0, — (C)Na,P,0, (0) Na,H,P,0, P40, & P,O,, are differ in (A) Number of P-O-P linkage (B) P-O-P bond length (©) Hybridisation of P-atom (0) All of these Which of the following molecule has 1 = 0 dipole moment? OH (A) IF (B) PCF, yY (0) Both (B) and (C) Corporate Office : Motion Education Pvt. Ltd, 384~ Rajeev Gandhi Nagar, Kota © 6003899588 Pages?