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    Chemistry Senior Inter Baby Bullet Q

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    bheemasaisurya976

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    ¥/¢/Most Favourite Book for Inter Students ¥/Rocking All over AP & TS -? / Gun Shot Qs with Easy Answers aouae } eater ch Pate eae eee PAC Ue ore Cae ead Ceres Ee Raid ee ners v eo Seed nn v a r cr) v Bullet Baby Book Paar Re) ‘Al THE KING, SRI PUBLISHERS 2022 new IPE BLUE PRINT .- SR CHEMISTRY | CHAPTER(Total Marks) | vsA@2m) SAGKM) LAQem) | Total Marks | 1. | SOLID STATE (4) | - 4 - fa 1 2 | SOLUTIONS (5) 2 3.1 | ELECTRO CHEMISTRY (10) 2 8 |. 32 [CHEMICAL KINETICS | «| sURPACE cHEMSTAY papa | GPOF METALLURGY (0) 2 4 ~ ja |pBLOCK ELEMENTS (10) a) fa | “081 Biock Elements (9) | 2 fat - |e [POLYMERS «) - | ae lw) - fa "CHEMISTRY IN EVERYDAYLIFE (1) | Po ye wlonganccmewsreriy | @ | 4 | 8 | The Blue print is prepared according to the ‘Modet Question Paper’ issued by B. ] Please, note that, at times, the public question paper gets slight deviation from the above given Blue Print, IPE TRENDS FROM BULLET BABY BOOK | AP May-22 | TS MAY-22 | AP MAR-20 2ortGMarks | 4 > 16 Marks 3 > 16Marks |2-16 Marks Gyatmors | 12 +24Manns| 4s t6Manks [7 +24 Man ~~ an \ 7-4 14 marks | 12->20 Marks | 6» 12 Marks ene | 44 Marks. 54 Marks. 60 Marks Index) Laa | CHAPTERS | 2. | pesLocK ELEMENTS @ Wars) 3 | OFGaNc CHEMISTRY (@ Marks) i. SAQ CHAPTERS | SOLUTIONS — 6._| SURFACE CHENSTAY % | G.P OF METALLURGY. 8 PBLOCK ELEMENTS (a Merks) 9 (SIBLOCKELEMENTS —(aants) (Marks) | 12, | cHemstrYINEVERVOAYLIFE (Mans {13 | ORGANIC CHEMISTRY (4 Marks) U eS ill. VSAQ CHAPTERS (aa. [So.uTIONS (2 Marks) 15. |EC&CE (2 Marks) 16. GPOFMETALLURGY _(2 Marks) [17._ P-BLOCK ELEMENTS (2¥2 Marks) 48, |G8fBLOCK ELEMENTS (2 Marks) 19. POLYMERS - (Marks) BIOMOLECULES (2 Marks) | CHEMISTRY IN EVERYDAY LIFE (2 Marks) 21 *BAB 1AQ2, LAga aoa Laas. LAQS. LAQT. LAT 1AQi LAQL LAG, Lage. YY BULLET-o = 5 CiA0 wr ust } TOP T11LAQ ——— SSS **ELECTRO CHEMISTRY/CHEMICAL KINETICS(@ MARKS]##* VAG I. State and explain Koblrausch's law oF independent migration of om, (h)Whatare Gal vanie eels? Explain the working af Galvanic cel witha neat sketch ting Daniel cell as example, (aiGive a detailed account of callision theory of reaction rates of bimolecular ‘Bascous. reactions, (0) What is oe a oa eatin? ow isitlifeent tom ‘ord ofa reaction? Name one bimolecular and one timoleeular gaseous reactions. % * &P-BLOCK ELEMENTS[@ MARKS] * * * How is ammonis manuf ued by Haber's provess? How does ammonia rect ith () 20804, (1) CuSOg,,, (i) ABCs, How is mri aid manufactured by Ostwald process? How does Nitric Atid reset with (i) Copper (ii) Zn_ (iil) Sg (iv) Py How is ozone prepored? How does ozone react with (CaHg Ging GNKI GvjHe Gy PES Describe the manufseme of HaSOq by contact process. stow is Chlorine prepared in the laboratore? How Chlorine is prepared in Deacon's process? Explain reactionsof chlorine with (a) Colt and dil, NaOH ¢b) hot. con. NAOH. (0) Fxcess NH (d)Sloked lime (eNanS05 sow is Chlarine prepared in the laboratory? How does chlorine react with Gjlron (ijacidified FeSO4 (i) odie Gv)Hy8. (9) KT dee KORGANIC CHEMISTRY(S MARKS] * * Waite the following named reaetions with one example for each, (2) Williamson's synthesis «Reimer Tiemann reaction fe)Carbylamine reaction (d) Kolbe reaction 0. Writ the fallowing named reaetions with ane example each: (a) Decarboxylation ¢b) Wurtz -Fiting React (c) Cannizearo reaction (a) Aldol condensation resction. 1. Explain the following named reactions. (@) Diazotization (b) Sandmeyer reaction, {c)Gattermann reaction, (a) HVZ reaction LAQ 12. — Explainthe following named reactions, (a)Esterification (b) Fricde] Crafts Alkylation (e) Friedel Crafls Acylation (4) Wartzreaction 3. (a) Explain the agidie nature of phenols and compare with that oF alcohols (b) Write two methods of preparation of phenol. SR.CHEMISTRY * fer pay) bP 120) Je? 3G lor? 13041 oP 1465) jt i foeP 154691 JorP 16079) [oP 178 | tonP 19099) lor P 19(10)) lo P 200119] fer 2102), for ® 22(13)1 [oP 23014) or P 24015) | #SR.CHEMISTRY = BABY BULLET.O* SAQ HiT List TOP 30 SAQ WIG: Bede’ * ID STATE|4 MARKS]*®** L SAO?) Explain ae es Des Iz SAO 3, Describe the 180 main types of semiconductors and anit thir conduction mechan, | > * SOLUTIONS(4 MARKS]*® | SAQ4. Define Molar Calculate mola ofa sohitos containing Sof NaOHin SO0mmlofsation, | |. P 2818) SAOS. DefineMobi Cakubiemoliintmyr dgmarGinm Hl y209)inMgmof Wer? — || # 28,205) | SAN 6, Define Mole fiation. Cateulate the mole faction of Fig$0q in 98% HaS0y. i | SAQ 7 Whmisreisivelowerine ofvaparpesre? Howisituehitioddaminettemobemesofaschae? | | | JOR X SURFACE CHEMISTRYI4 MARKS]* * * SAQA. Define adscmpion? Give any fourdiorenes baweenPhysiscrpion & Chemisorpion, | |» P 304 28)] SAQ9. Whitiscalyis? How iscalsisclasied? Gvetwoexamples foreach ype ofcatlys. | |.» .26)] SAQ 10. What are Emulsions? How are they classiticg? {lor sxe #* GENERAL PRINCIPLES OF METALLURGY[4 MARKS]** SAO 11, Differentiate roasting and cleiation with examples. 2 32090 SAQ 12. Explain the purification of sulphide ore by Hoth floatation method 2 P 3203091 SAO 15. Explain briefly the extaetion of minum: from Bauxite {or 300) 7% P BLOCK ELEMENTS [4 MARKS]** | SAG 14, How are Xef'y and Neg prepared? Give theirstrctures [top a0) SAQIS, Howare XeO3 and XeOg prepared” Give thei structures. Wo 37(39) “dt dit BLOCK ELEMENTS|4 MARKS]*** | S406, ite the characteristis properties of wanstion clement fo P 840 SAO 17. Explain Wem’ theory of conrdination compoainds with suitable examples oP 3w4n SAO 58 Using IUPAC norms write the systematic names ofthe following (@[PUNH)2CUNHs CHAVICL GO INICIP” GHOKSIFEKCNYGI (ivdKatPUCHg] — | foe s9eaay) + * POLYMERS|S MARKS]* | SAQ 18, (@)Whatisadditionpolyer? Giveoxarple (by WhatsPHBV? Howisitusetitioman? | jot 4014) Sg 20, Write the mes and structures ofthe monomers othe following polymers | ja. F at¢sih} G@Buna-S (i) Bunw-NGii)Dacron Civ) Neoprene | ‘% * BIOMOLECULES[4 MARKS]* * | SAQ 21, Name the sources and diseases caused by the daticiency of vitamins A.D. EK | oF 42053)1 S022. Write notes on vitatnins [er a2r54)] SAO 28, Whatare hononss? Give an example for each ofthe following: lier 43155) Detewtdhommones b)Polsperide kornones c) Amino cia decwatves | 4% CHEMISTRY IN EVERYDAY LIFET4 MARKS]* * { ‘Write notes on Antiseptics and Disinfectants, HiorP 44160) Define and give examples of (a) Antacids —(bvTranquiizers jah 45160) ‘Write notes on (a) Aricial sweetening agents (b) Food preservatives oP 4516391 * ORGANIC CHEMISTRY[4 MARKS]* 4027. Explain S81 seastion wthexamples arP 45653) S40 28. Explain $N# reaction with examples Hire 40665 SAG 29. Explain a) Carbylaminereietion (b)Sandmeverresetion [fre 47679 SAG ao, Define i) Rasemiemiats (i) Ensatiomers fe P4166) BABY BULLET-Q ysaqi YSAQ2. VSAQS, Vsaqs. sags. YSAQ6. VSaQ7. vsags VsAQ9, sao t0. VSAQ It VSAQ 12 YsaQua VSag 14, VSAQ IS, VSAQ U6. VvsaQi7, VSAQ 18 Vsaqis. VSAQ20. vsaQ21 Vsaq22, Vsaq2s, VsAqz4. ‘I VSAQ HIT ust TOP 57 ¥VWSAO ek SOLU ONS[2MARKS]* * + State Raoult'staw, State Hemr'staw, ‘What is Osmotic pressure? ‘What oe sotonie sotutions 2 Whats ywering of 2 4 XELECTRO CHEMISTEY CHEMIC ‘tote Eras first law of eletrulsis? Stute Karadav's second Jaw oflectrolasis, ‘Whats « galvanic cell er-voltaie cell? Give one example. Define grr of reaction, Give one example. Give two examples fr gnscous Zero order reactions, Whatare pseu first order reactions? Give one example > *GENERAL PRINCIPLES OF METALLURG’ NETICS|2MARKS] #4 [2MARKS]* + ‘Write any two ones with formulae of the following metals i) Aluminium ii) Zine iii) Iron iv) copper Explain poling’, ‘What isthe eole of eryoliin the metallurgy of ebeniniun? Give the composition ofthe follosingallows. i) Brass ii) German silver iii) Bronze ‘What is matte? Give its composition, ‘What is blister copper? Why is it so called? 3 4 P-BLOCK ELEMENTS[2 +2 MARKS] & * * ‘Whats Allotropy? Nitrogen molecules highly stable. Why? ‘PH 3 bas lower boiling point than NH. Why? ‘What is a tailing of mercury? How is itremoved? Why is H0 a liquid while HS is gas? ‘What happens when Cly reacts with dry slaked lime? ‘Write the reactions of Fz and Cl, with water. SR.CHEMISTRY* Lo? 49669) [oP 490709 [orP 49071) or? 49072)) [oP 49073), (oP 50(78)} orP 50(79)] forP $0(80)} arP 50(82)) forP 51(83)) {or P S1¢85)i for P 52(90)} IP 5209) Jar P $2(92)] lo 52(93)) lor P 52(98)} LarP $2,961 lar P $3098)1 Lo P 53(99)) Lar 53(100)] Jor P 53(103)1 lo P 54105) Jo 54(106)] fa 54(107)) *SR.CHEMISTRY - sages. VsAq26, vSAQ27. YSAq2g, VSAQ29, VSAQ 30. YSAQs. YSAQ22, VSA033, VSAQH VSAQ 5, VSAQ%6. VSAQ37, YSAQ38, VSAQ39. YSAQ40. VSAQ4I YsAQ42, SAQA, SAQA. VSAQ4S. YSAQ46. vsao47, VSAQ 48. VSAQ 49, VSAQS0, VSAQ5t NSAQS2. YSAQSS VSAQ 54. VSAQ5S. VSAQ 56, VSAQS7. CL @ How isehlorine manufactured by Deacon's method? List out theuses of neon, Woite the structure of 203 Jn modern diving apparatus, a mixture of He and Qs used - Why”? + 4 & d&f BLOCK ELEMENTS [2 MARKS] * * Why Za?* is diamagnetic whereas Mn? is paramagnetic? ‘Whats am alloy? Give example, ‘What's Lanthanide contraction? What is Mischmetal? Give its eomposition and uses What isa Ligand? * * POLYMERS [2 MARKS}* * ‘What is PHIBV? How ist use to man’? Whats wuleanisation of Rubber? ‘What are copolymers? Give example What are te repeating monomeric units of Nvlon 6 and Nylon 6.6? ‘Whats biodesradable polemse? Give onc example ‘What is PDE Poly Dispersitv Inde)? ok BIOMOLECULES [2 MAFIKS]* + ‘What is Zwitter on? Givean example. ‘What are amine acids’ Give two examples. ‘What are essential and non-essential amino acids? Give ane example for each, Differentiate hetween globular and fibrous proteins. + 4K CHEMISTRY IN EVERY DAY LIFE(2 42 MARKS]# # ‘Whatare antacids? Give example ‘What are antihistamines? Give example, ‘What are antibioties? Give example ‘What are antisepties? Give example. What are artificial sweetening agents? Give exemple ‘What are food preservatives? Give example, ‘What are Antiferility drags? Give example What are analgesics? How are they classified” ‘What are tranguilizers? Give example. 4 * ORGANIC CHEMISTRY[2 MARKS]* * ‘What are ambident nucleophiles? Whatace Bnantiomers? Howis Grignard reagent prepared Write about Carbylamine reaction Write the structure of the folowing compounds (9 2-chloro-3-methyl pentane Gip-bromo chloro benzene BABY BULLET-O% soy Bu er 54.10%) Lor $4109) fo? StQt0y] lore stn Loe? 55(115)1 [or P S618), lor? S6ULI9), lo-P 86(120), Jor P 87(124)} jaP 51(125)] [oP S112) [oP $7128) [or P S729) oP S7(130)1 Jer P S813) or P 58(132)] lor P S8(135)) bor P SIC jar? S913] Jor 591389) for P 591399] Jar P 590149) lor P 89140) lor P 59(143)) jerk 440601 lorP 45(62)| Jor P 60144) for P 60(145)], fo Ponca, Jor P 60(148)] for P 6a * BABY BULLET-O r. 8. ra. 6, P, va. P9, Pua. Pia, {3}-—____sn.chemstay ** SOLUTIONS * Define Motarity Caleulate the molarity ofa solution containing 5 g of NaOH in 450 ml solution. Caleulate the molarity ofa solution containing Sy of NaOH in $O0m of solution, Caleulate the molarity ofa solution euntaining 10 g of NaOH in 500 ml solution Define Moti, Calculate molatity(en} of 10gm of Glucose (CH 0g)in 9g of Water. Caleatate molatity of rams of Flhanoie Acid (CH COOH in75 gramsof Benzene, Deine Mote fsction Caleulate the mote faction of HS, in solution containing 98% #150, by mass Caleulte the mole fraction of sodium hydroxide in 10% (/w) NaOH solution Caleulate the mole fraction of ethylene glycol (C'9Hg02) in asolution containing 20% af C2609 by mass, Calculate the ass of a nonvolatile solute (inokar mass 40g mor!) which should be Uissolved in I 14g Octane to reduce is vapour pressure to 80%, ‘The vapour pressure of pure Benzene at a certain temperature is 0,850 bar. Anon-volatle, non-electolste solid weighing 0.5 p when added ty 39.0 y of benzene (molarmass 78 g moll). Vapour pressure ofthe solution, then is 0.845 bar ‘What is the molar mass ofthe solid substance? *ELECIHO CHEMISTRY * sxio-l4y A first onder reaction i Found fo have arate constant, Find the half life ofthe reaction, A reaciion has a life of 10 minutes. Caleulate the rate constant tor the first order reaction, A solution of CuSOy is electrolysed for 10 minutes with a current of 1.5 amperes What is the mass of copper deposited at the cathode? ‘kd BLOCK ELEMENTS Calculate the magnetic moment ofa divalent ion in aqueous solution sits atomic numberis 25. Cateuatethe'spin only magnetic momentof Fe2*aqy ion, | | i | | | Ans-Page bar P m1) Jor POUNSH) lor Pousti [op 28a0) fa P 6153 toh 2821 Loe? S5(140)1 fe P S540) JP 2923) lor P2904), lor P5186), ier P 51087) [oP s11a8)) lar P 5601289) * SR.CHEMISTRY — BABY BULLET-O® fe Hi SENIORS! How are you? By the way, lam your favourite BULLET BABY BOOK. {like you very much and | was born only for you! Now, ! am 6 years old. | always wish you get Good marks in IPE! “Every Page in me is set beaulifuly so as to make you Read and write easily” “Every answer is written in Simple steps for your Pleasure reading *, OB STEP revision PROGRAM LAQ Section [P 12 10 P 24): Infact, LAQ might be your Most Favourite Section. Practice each and every Q 8A of LAQ Section. Finish one after another, by taking as ‘much time as you requite, Later irish the LAG Hit List (P 5) without seeing answers. SAQ Section [P 25 to P 47}: Some SAQs are really very easy!, They save you when the paper is Tough. You should have grip on some Easy &lmportantSAQs.Do | ‘as many as you can from SAQ Hit list (P6). If yau do this, you are in ‘Safe Zone STEP 3: VSAQ section[P 48 to P 60 |: Cute Cute simple VSAQs are very easy to learn and © remember. They are ‘True marks Gainers’. Do all the VSAQs in Hit ist & Problems. (P 710 P 8). If you dothis, you arein ‘Super Safe Zone’ STEP 4; Bullet Model Paper [P 76 to P 75]: Now, its tum to do your most favourite ‘Bullet © __ Modet Paper’. You can take 2 to 3 days to finish each section. Within 10 days you ~ should complete this Task. This keeps you in ‘Sate Pass Zone’. STEPS: Guess Papers [P76 to P 80]: Finally, practice all the 8 Model Guess Papers. © Answer each paper separately on white sheets as it i's like in Public Exam. That's. it, You did a wonderful job! No one can stop you from scoring ‘Super Marks in IPE’. VIKA) ‘THETICK BONES TECHNIQUE [V [VV Very ‘powerlul and successful method’ for 'Effective Revision’ - Tick Box Technique How to use the Tick Boxes? Put one Tick (¥’) in the frst box, when you can write the answer ‘without seeing it 2 sigan, earn GRAS Bh, WOO inSNOKD BANDAS Bue ES oe OF ayod. Puttwo Ticks ( V’} when you are able to write the answer without any mistake’ 28; mistake tin tisoce wana PESNOAGS 2088 emlyét Coty BE ated, Put Three Ticks (7 Vv’) when you write ‘as itis- Dito Answers’ with 100% Confidence, ng maypotim, "100% Seay, SO BOS BOK eo NONE Ha eS ands BR So. + Justtry this Technique and you see hew MIRACLES happen in your Revision programme. Bo Honest in putting the Tick Marks. © 8&8 ALL THE BEST IN IPE & & y Py * BABY BULLET-Q e ELECTRO CHEMISTRY & CHE KINETICS (8 Marks) P-BLOCK ELEMENTS ORGANIC CHEMISTRY Easy Chapters: P-Block Elements Imp Chapters: Electro Chemistry & Chemical Kineties SR.CHEMISTRY-LAQ * ‘#SAL.CHEMISTRY-LAQ = BABY BULLETOy [,) State and explain Kohtrausch's law of independent migration of ians. Zn(OH), + (NH,)250, (Ammonium sulphate) iy Ammonia solution on reaction with Copper sulphate gives deep blu complex compound CuS Oa) +4NHs =*{CuINHS), 0,9) (Teraaminecopper Sulphate) i8) Ammonia solution on reaction with Sitverchlorie gives a complex compound AgCl +2NHy —S{A(NI}91 CL wniepee aa) courte” (a) * BABY BULLET-Q a SR.CHEMISTAY-LAQ * 6(a) Hows nitric acid manufactured by Ostwald's proces Manufacture of Nitrie acid by Ostwald’s process : © ont osTWALO! Oastersa ©sstaces 1) Step-1: Ammonia on oxidation gives Nitric oxide ANF yg) 50a AND ig, +5420, “SK, Ota 2) Slep-2: NO on oxidation gives NO. Tick 2NO¢q) + Orgy) = 2NO ng) 3) Step-3: NO) on hydrolysis gives dil. HNO; NO 2g) + HO) ——2HINO jag) + NOcey ro 4} Concentration of Nitric acid in three stages: Boxes (ji) Stage 1: The diluted FINO) is concentrated by distillation to give 68% HNO3 (ii) Stage 2: 68% HINO3 is dehydrated with pure cone, 13804 to give 98% HINOs, (Gil) Stage 3: 68% HNO, on cooling ina fieezing mixture yives 100% HNO in erystal form, Jd react with the following? (i) Copper (i 6{b} How does nitric A: Reactions of Nitric a §)(a) Copper on oxidation with dil, Nitric acid gives. Nitric oxide. 3Cu+8HNO; —>3Cu(NO3)2 + 2NO+411,0 (b) Copper on oxidation with cone, Nitric acid gives Nitrogen dioxide, Cut 4HINO;—9CU(NOs)) +2NO3 +2130 ii) (a) Zine on oxidation with dil. Nitrie acid gives NO. 4Zn +10HNO;——34Zn(NO}p +5H,04N0 () Zine on oxidation with cone, Nitrie acid gives Nitrogen dioxide. Zn+4HNO;—$Zn(NO3)2 + 2H,0+2NOz iif) Sulphur on oxidation with Nitric acid gives Sulphuric Sy +48HNO, —>8H,80, + 48NO3 +1630 iv) Phosphorus on oxidation with Nitric acid gives Phosphoric acid. P, +20HNO; —>4HPO, +20NO, +4H,0 #SR.CHEMISTRY-LAQ BABY BULLET-« ial if is Ozone prepare (b) How does it react with () CyIL, Gi) KI ( As (a) Preparation of Ozone: 205; A= +142 kJ mob! (b) Reactions of Ozone 1) Ozone reacts with Ethylene to give Ethylene ozonide. D “Zn Os + CH= ct —5 Me be Orme ign Etiyleeoronide ii) Ozone oxidises moist Potuss{um lodide to tod 05 +2K1+ H,0 —+2KOH +1, +0 iii) Ozome oxidises Mercury to Merewrous oxide, (This reaction is called as "Tailing of Mereury’.) 0; + 2Hlg—Hg,0+0 iv) Ozone oxidises black leadsulphide to white leadsalphate 403 + PbS —+PbSO, +40, ¥) Reaction with NO :Ozone oxidises nitric oxide to nitrogen dioxide, NO(g} + 03(g}——9 NOp(g) + On¢g) vi) Reaction with Ag : Ozone oxidises silver to silver oxide, 2Ag+O;—>Ag,0 +02 © KEEP OZONE ©iN SAFE ZONE (O00: IAP 18] a BABY BULLET-Q El SR.CHEMISTRY-LAG & 8. Describe the manufacture of H,S0, by contact process ea Manufacture of Sulphuric acid by Contact process aq 1) Formation of SQ,: Sulphuris burnt ina tw form $0, $+, 80, 2) Formation of SOs: SO) is oxidised ie air to form SO, Pe TE. 2804) + 0x4) PISO 5) AH = -189) 3) The above reaction is reversible, exutheric and it leads to a docrewse in volume, So, Le-Chatelice pi pte is applicable, 4) Eeet af Temperste As the reaction is exothermic, low temperature is favoured, Eifect of Pressure: As the renction lends to deorease in volume, high pressure is favoured, 6) Optimum Conditions: (a) Low Temperatore:679K-723K (b) High Pressure: 1.5 02 atm 1) CatalystiV,0e(0r) Pt 8) Formation of Oloum: SOs is absorbed in 98% cone. H,8O, to form Olewm. 80) +H 1s HyS;0; (Olevm) 9) Formation of Hy8Oq : Olenm is diluted with water to form cone, HzSO, H,S,0 + Hj0 > 24,80, ee = BABY BULLE *SR.CHEMISTRY-LAQ i cl 9. Howis chlorine prepared ia the laboratory? AP 47,18,18 How Chlorine is prepared in Deacon's process TS 16,16,19,19,22) How does it react with the following? } {) Cold dil, NaOH (ii) Hot cone. NAOH (iii) Excess NHs ' ; © | (iv) Staked time (v) Hypo( Na8;0,) cece @preraneme|| | © AB? A: 1) Preparation of Chlorineia the laboratory One ‘Chlorine is prepared in the laboratory by heating a mixture of sodium chloride, manganese Shove an coe HeS04 | 4NaC I + AHy$04 + MnO; > 4N@HISO4+MnCh, + 2H30 + Cl j 11) Deacon's process: Chlorine is prepared by the Oxidation of hydrogen chloride gas by !mospheric oxsgen inthe presence af CuCl catalyst at 723K produces chlorine | 4 | 4HCI+0, pramew @vsagaiso HI) Reactions of Chiorine: i) Chlorine reacts with cold and dilute NaOH to form NaCl and NaOCl. SNaCl+ NuC}O3 + 311,0 | i i) to form Ny NaxS0, 428145 j yee Boxes i j ——SS a ill * BABY BULLET-O = 10, SR.CHEMISTAY-LAQ * 11s How is chlorine prepared by electrolytic method? Explaia its reaction with (tron Gi) acidified FeSO, (iii)lodine (iv) HS (KE 1) Preparation of Chlorine by Electrolytic Method: 1) Chlorine is prepared by the electrolysis of brine -————_—____________, solution (10% NaCt Solution) in Nelson cell, | 2) Nelson cell consists of *U’ shaped, perforated stcel vessel. | 8) The Brine solution taken into vessel acts as electrolyte, 4) A graphite red, dipped inthe brine solution, acts as anvide, 5) The coll itself acts as cathode, as tiboratod at che 1d Hy wt the cathode. Nelson celt 6) Duringelectrolysis, € tor so ts ethos 7) Vonisation: INaCi > 2Na +2Ct Asbo rine solation A Naot sion eoistad 8.Cl uy 8) Electrode Reaction: pater . ett At anode :2C) > Ch*2e- Sec 9 Giaphite ame At cathode: 2H,0+2e = 20H + It | Noneed to draw this in IPE 2Na" + 20H” > 2NaOH A) Reactions of Chior i) Ch reacts with fi serie chloride. 30h, +3 22PeCly i) Cfyoidises ferrous sulphate to ferric sulphate inthe presence of HaS0q, Chy + 2FeS04 + 1,80, + Fey(804)3 + 2HCL iii) Chy reacts with fodine in the presence of water to form todic acid SCly +1 + 6H,0 > 2HI03 + LOC! Nad by) Claas with HS orn Sulphr pretpiate, | 5 +S 9 2HCL+S ¥) Ch displaces lodine from KI solution, Ch 7 2K 9 KCI Ly Boxes = BABY BULLET-Q4 4SR.CHEMISTRY-LAQ a A Weite the following nanted reactions with one example for each. (a) Willian is (b)Reimer-T (¢) Carhylamine reaction nann reaction. Son's synth {a)) Kolbe reaction {a) Williamson's synthesis: tig! Natides react with sodivia nikoxide to give ether ‘AP. 15,16,18,19,20,22 Faz Methyl iodide reacts with sudiom Pthaside to give inethoxyetiiane CH31-+.C;HsONa—+CH; ~O-C3H, + Nal ana reaction: Phcnal is treated with CHC/, in the presence of sodium on () Reimer-Ti hydroxide to give « Salieyladebyde (©) Carhylamine reaction: Anitineis heated with ethanolic KOH and chlorofoem to give Fhenytisncyanide ier 2 Cen: cues Boor voi hide Bromo bene (4) HZ. Reaction: Carboxylic acids halogenated atthe a-postion on treatment with chlorine (er) bromine in the presence of red phosphorus to form a-halo earboxylie acids vba: RCH, ~ Coon —222Redpospons -e-c00H GIO x swhere, X=Cl, Br echydrocarboxylie acid [ ee im Lt BABY BULLET-@ fm ‘SR.CHEMISTRY-LAQ * 14. Fyplain the following named react (a)Psterifieation 4b) Friedel Crafts Alkylation (€) Friedel Cratts Aey (4) Warte reaction A: (a)Ester 1: Carboxylic acid reacts with alcohol in the presence of Cone, HjS0,4. to si a << Ex: CHyCOOH+ C,HsOH CH, COOCzH5+H20 ‘Acslicacid —Elyllecol Erhylaceate (0) Friedel Crafts Atkylation: Anisole reacts with methyTehtoride in | anhydrous A/CI5, 10 form ortho and para sulsstituted ether. oct oars ge a seep Ny + CHSC —eapaioay ” alkylation) _ Methyl ‘o-methyi methoxy, CH Anisole chloride benzene (minor) P-methyl methoxy benzenetmajor) (c)Friede! Crafts Aeylation: Anisole reacts with acetyichloride in the presence of anhydrous, AICI, to torm a mixture of o-methoxy acetophenone and a oes OCH; cHs Nel, ‘COCH, LERLE I fs Sion? Anise o-methoxy coc acztaphensne p methoxyaceepheneae {aon (a) Wurtz ren ther to form ethane. Methyt iodide is hested with sodiuny metal in the presenee of éry © 1WASIN 2CH yh + 2Na— 228 5 CoH, + 2Nal sce © Methyl iodide Ethane «a ‘Tick Boxes oo Dp ee ee ASRGHEMISTAVEAG fia Is, BABY BULLET.Q4 dd compare with that of aconols. Oa aa J just oF ph ios and oxidation of phenol, (AD Explain the acidic anture of ph (8) We (C) Write products (A) Comparison of acidic ature of Phenols and Alcohols: 1) Phenols and alcohols both react with active metals. So phenols and alcohols are both acidic, 2) Only phenols reaet with Ag, NaOH, but not alcool. So phenols ee more acidic naan ene 3). Phenols exhibit resonance fut not alechols. So phenols are minre seis. 4) In phenols. hydoxyl group is directly attached 10 sp? carbon on benzene ring. Whereas in alcohol its tached to sp? carbon, 5) In phenols, benzene ring acts as electron withdrawing group. Whereas in alcohols alkyl group acts as electron donating group. oparat nol: §) Action of Beazene: Benzene on oxidation in the presence fair aver V305 at 315°C gives phieaal . ®) 2CGHy +O» Benzene Phenol ii) Action of Cumene: Cumene on oxidation in the presence of air gives cumene bydrogenperoxide, This on hydrolysis with dilute acid gives phenof and acetone. om, cn, 1 I CHC 0-0-1 on 9 | tI « o HO” oC “6s G-Cthy (©) i) Reduction: Phenols on distitlaiion with zine dust undergo reduetion to form ber ou OC)» Oxo ii) Oxidation:Phenol on oxidation with chromic acid forms eonjugated diketone, nzene on 5 | a m0 0 q * BABY BULLET-Q SOLID STATE (4 Marks) *#4 5, [SOLUTIONS (4 Marks) | 28-29 ioe 6 | SURFACE CHEMISTRY (4 Marks) | 90-31 WUEDLE SECTION HITE BHR AREE BASES SECTION-B SAG CHAPTERS ra SRA is fz CHEMISTRY-SAQ & GP OF METALLURGY (4 Marks) | 32-34 p-BLOCK | ELEMENTS (4 Marks) | 35-37 oe | CHEMISTRY IN EVERYDAY LIFE (4 Marks) .| ORGANIC CHEMISTRY (4 Marks) (4 Marks) | 40-41 ls BIOMOLECULES (4 Marks) 42-43 Easy Chapters: Sold State, Solutions, Surface Chemisty Imp Chapters: P-Block Eloments, d & f block Elements BABY BULLET-9x =~ + SR.CHEMISTRY-SAQ — oe ***4 SOLID STATE (“aMarks ~ ) Derive Brage's equation, =< REEERERELE SESSA Ray-t 1) Suppose two X-rays of wavelength 2.are incident on ‘6¥0 parallel planes of a erystal surface. 2) They both undergo dittraction, 3) First x-ray is diffracted from point ‘A’ in the frst plane. ‘Second ray i diffracted from ‘B" in the second plane. 4) Here, the second X-ray travels some exira distance than the first The extra distance (path difference) travelled by the second X-ray= CB+BD. 5) When two waves undergo constructive interference then according to Bragg, the path difference must be an integral multipte of the wave tength(2). CBYBD= nh... Here n= 1,2,3.... is known as order of diffraction. ©) IF 8 is the angle of incidence and 'é! be the distance between the parallel planes then sin 2B 5 s0,. from AABC, AB~ gq ~ CB=dsin®.....(i) Bb _ aD Sen BOHM. i) In AABD, sin’ *. from (ii) & (iii), CB+BD = dsin® + dsin® = 2dsin8 © from (i), wi = 2dsin® ie Paras 17. Explain Schottky & Frenkel Defects with structures. A: 1) Schottky deferts Tt is a point defect in which an from its normal site in the atom or ion is mis crystal lattice. 2) Ex: NaCl, CsCl, AgBr ete. 3) Frenkel Defeet: It is point defect in which an atom or ion is displaced, trom its normal site to interstitial site 4) Bx: AgCl, AgBr, Zns ete ean * BABY BULLET-0 A 18. Describe the two main types of semiconductors and contrast their conduction Fe SR.CHEMISTRY-SAQ & mechanism. 4) Intrinsic semiconductors: These are the conductors whose conductivity increases with rise in temperature . £x: Pure solids like Si and Ge. Types of Semi conductors; 2) Extrinsic semiconductors: These ste the conductors whose conductivity inereases with the doping of certain impurities. Fx: Py As ; B, AL Extrinsic semiconductors are of two types: 4) n-type semiconductor: These are the semi conductors in which majority charge cariers are electrons. Uf pue Si is doped with a VA group clement like P (or) As, some of the “Si” ators are replaced by *P® for) *As‘atoms, ‘VA group clement has 5 valence electrons where as “Si* has 4 valenee electrons. So, Sth electron is free to move through the voids of crystal. The conduetivity of these semi conductors is dus to the presence of delocalized, negatively charged electrons. »y p-type semi conductor: These are the semi conductors in which majority charge carriers ace positive holes. If pure Si is doped with a IIA group element like B, A/ (or) Ga, some ofthe ‘Si’ atoms are replaced with IMA group atoms WA group element has 3 valence electrons Where as ‘Sit has 4 valence electrons. So, an “electron vacancy” or ‘positive hole” is formed. The conductivity of these semi conductors is due to the migration of ‘positive hole’ from one atom to otter. 4 SA.CHEMISTRY-SAQ at BABY BULLET.o« © BABY CHAT: One: ‘one Simple problem gives 'U' 4 Marks 19. Define M II4 Given GMW of solute (M,)-40; Weight of solute (=? My 100-80 wy 114 Wa? 10” 40a 24. ‘The vapour pressure of pure benzene at a certain temperature is 0.858 bar. A non- Volatile, non-clectrolyte solid weighing 0.5, when added (0.29.0 g of henzene (molar mass 78 g mol), Vapour pressure of t molar mass of the solid subst Sol: Given that p?=0.850bar, p> ~ 0.845 bar: Mg = 78 gol! w O.850-0.845 _ 05x78 0850 M, x39 From Raoul!’ lew, 52.005 tL, ‘o8s0 My Mg=170gmort BABY BULLET-Oy Sey HSRCHEMISTAYSAQ SS ***6, SURFACE CHEMISTRY’ ** @uasycnar- an 25. Define adsorption, Chemicat adsorption Discuss the differences tretweet wand Chi p Physicat adver A: 1) Adsorption: Its the accumulation of gas or liquid molecules on solid or liquid surface, Ex: Paints on various surfaces, Corrosion of metals, Adsorption of Hy on charcoal (— Waite on Pape 1) Physical Adsorption Vs Chi sab Adsorption: (Grnsten ener Physical adsorption iis dos to weikvandsr Waals Toes | 1) mis dus to avong chemical bonds 2) Itis reversible | 2) ltisimeversible 3) Toecurs at low temperature 3) Itoccurs at high temperature 4) Te decreases with rise in temperature. | 4) 1 increases with rse in temperature. 1s Pants om various surfaces. | Ex 4: Corrosion of Metals. a x 2: Adsorption of Fy on charcoal. | | | Enhapy ofaisorptonishigh. | | | 26., What is catalysis? How is catalysis classified? Ne two examples for each type « catalysis, ‘AP 16,16, 1) Catalysis: tis the process of speeding up of reaction by adding catalyst, 0 Jes elassified into two types, 2) Homogencous catalysis Is the catalytic process in which the reactants and the catalyst are in the same phase, Ex 1: 2803(e)+O2(g) 2® 5950,¢g Bx 2; CH,COOCHS (+120 ()—"_5CH,COOHKag) + CHOHag) 3) Heterogeneous catalysis: Tt is the catalytic process in which the reactants and the catalyst are in different phases, Ps Ey 1: 280 3%) + 021g) 24 2805 7 Tick Boxes Ex 2: Noggy + 3Hig) > 2g LAL LLE ERE I a oe * BABY BULLET-O = a SR.CHEMISTRY-SAQ & 27. What are Emulsions? How are they classif Desi 'e the applications ofemulsions, 4) Emulsions: These are the colloidal solutions in which both dispersed phase and dispersion medium are liquids C20 + CO Froth Floata y 4) » 6 » %) % tion method. CRE plain the purification of sulphide ore by froth float on method: This method is used for removing gamgue from sulphide First a suspension af the powdered are is made with water, ‘Minera froth ‘To this euspension, froth eollectors(pine oil) and stabilizers(eresols) are added. He Pulp of oe + ol SH pact tram m ait ‘Then ‘ore is wetted by oil! and ‘gangue is wetted! by water A rotating paddle is used to agitate the suspension and ai is blown into it. “The mixture agitated and siris blown int i, ‘As & result, froth is formed which carries the mineral particles. ‘The froth is light and is skimmed off. ‘The sulphide ore particles are then obtained from the froth * BABY BULLET-O ME Explau brietly the extrac Na AWOW ug) CO ag) > ALSO5 NHsO,,, + 2NIHCO 4a 1470K> The insoluble hydraced AlO, is then Ac Extraction of Shunuistinn from Bausite AO, 20,0) EXTRACHON OF ; ALUMINIUM ) Concent iest, Rausite ore is powdered and then 3, Bait powdered andl th Hauxite 10,2110 eoncenttated With a solution of NaOH at 473-529K Concertration with NaOH Then, Soxhuns aluminate is formed NafAWOHj4) MQ + 2NAOH sg) #3H3O,), > 2Nal ACOH) § hagy C05 gas 2) Passing through CO) aay: The alkaline Sodium aurninate : | innewiteeny dng Bergh 8 AlOsaHt,0 Then, hydrated ALLO; is formed Vesting at 1470 K Pure Alumina(Al03) filtered, dried and hewed at 1470K. Then, pure okwning is | | piectrotpyiae Boxes __SA.CHEMISTRY-SAQ eae formed L 70k 4) Electrolytic refining: Pure alumina on electrolysis gives 32. Write any 2 ores with the formulae of the following metals?(a) Al (b) Za A: a) Aluminium © Bauxite Al03.21120 Kaolinite Alg05.28i0).2H30 hy Zine Zincblende 208 Calamine ZnO. ote Hematite Fe,05 Sidesite COs 4) Copper Copper pyrites Cues Malachite COO, CMON)» A1,0;-4830,, 2K 91304.) + 5H20ig, ® Pure Aluminium Metab Na need to draw this ia Exam fey Peid) Cu a << xSR.CHEMISTAY.SAQ = —_—_—— args ne the principles of refining of metals by the following meth . Zoue refining by Elec d)Vapour phase refining 1 Zonerefinin XeO; + 6HF 2) Preparation of XeOP: XeF¢ on partial hydrolysis gives XeOF, XeFy + H2O > XeOF, + 2HF by Struetres: 1) Structure of XeO,: ‘ oi {i) in Xe0s, the central atom Xe atom undergoes yp hy bri oF So to form sp yb orbitals Gi) I forms three o bonds and thvee m bonds with three oxygens, (Gi) The shape of XeO} is pyramidal (iv) The bond ange is 103°, 2) Structure of NeOF, reo {© In XeOFg, the central atom Xe undergoes yp%a hybridisation to form sis spid? hybrid orbitals {@)It forms four o bends With four fuorine atoms and ‘one & and one x bond with oxygen atom (it has five bond pairs and one lone pair: (vjAccording to VSEPR theory, the shape of XeOF is square pyramidal (v)So, the bond angle is 90". BABY BULLET-o% © BABY CHAT: 'd' for Dear & ‘for Fine 40. Write the characteristics properties of Transition elements. Ac "Thecharncteristiss properties of Transition metas:

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