chemistry 2 Marks Dmportant uestion Answers.

hat elatine

Ihe natio
pesswe
to the wape
wapeu pe
Aolutiom nen - wolatle lete

selent caled elatine

vapou puesu (RLVP)

RLVP = P P

eaction.
Gine tuo enamples
der eaction
tnample
U30K
3a(5)
+

Photoyntheu uactien.
Theuma ducemposilien HD qotd dtace
H t

the Compoition the tolleuing olloy:

b) Bronye Geuman Sil

Bas - Go/» cu ), H0o zn

b) Buenze - 45-qo o cu, 10-a5 lo Sn.

(C Gman S er : 25-40o u, Ho -50°/o Ni,25- 35. zn

H)What happuns when white phosphe is heated ith

cenc NaOH soiem
 AIhn white phosphews ü hated with Conc NaoH
Aotien inet atmosphwu, it dissoes in
NaoH and qns phosphin

P 3 NaoH + 3H,o 3 Na H, PO
(Phosphine) (Sediun
haypophosphite)
Hew
chleine manuyactwud uy Seacon's method?
A chline
pepaud uy the oldation e H as
Juy atmosphuic Peene 1 cuclg catatyt
at 423K.

HHl+ O, 123 K

Ahat misch metal 9 Gine ita cempotion and

whlch contain

misch metal. t containd q5°/% lanthansld mtal and

5 Fe alsng with S, c,Ca and Al Tt iu

Wsed peduce l i , shs

Ma - acd aley to
and ighte tinti
hat is PHBV Ho to nn

PHBV mend
poly p- huydoy Jtate - 0-p-kydg
sedeqnadalie polymer
Usesi PH BV wwed in specialy packaging
ohe paedie olumices Ound conbueled eleae
 What (Paly ipuuity Snden) 3
mslecla nas
A The atio etwcen weight owcage
maleculan mat ( Mn)
(M,) and
a polym i callad poy dlpuulty Ender (PDI)
PDD= M.
Mn
The walue PDI tor polymeu ia in
Ond |·5.

hat Analgsiu ? Hew ae

The duug which educe aloih paun withsut
cauusing impaiment Consiune , mental contusien
|incooudination pavalyeu Mome sther distubances
Ayptem e Called
onalquie
Thec totlous -

) Ne nacoic
analqutu.
) Nancotie analgste.
Ihat antspti ? Gine enample
The chemical sultanes which Oe wsedo
penent the mico
ogoniam a e caled

ontiepties. Thuy to e pplid Lining

tise

q Ddtot (chlenoytenot + npinot), ithionol.

thlonat
Tinctwe 0 odine (ann aohol - water setion
ntaining -3% 1,)
Centainng D)
 What

enample
The suletances which ae scd ettute to
conts intake caloies caled

actiyiclal swtening oqut

tg
ta Apautame, Sacchain, Sucalose Aetome.
What - Natta Catalyt 9
mmitwe O Jithyl aminium and ttaniwm
tetachloide caled - Natta catalyt. ît
wsed poymuation
(
Nome tuo most
tamilia antioidants wed as
tood addetnes

Butylated hyday toluene (BHT) and Buylated

aissle (BHA) met tamilia antioidan
ydy
wed teod odditines
Wete the names the monre

the
polu.
c) Bakelite

(A SPhwns and tomaldehyde the menne

Jakelite. OH

H 0
ond
H
Phensl. F&maldehyde.
 and pthalc acld the nono,mun

COOH

Phthole acid
Ihat
Coloigatine puoputieu ? Gine any en e.
poputier o dte
dlte olutiens shich depend
wpen the soute pauticles bt et n thein
hate Coled
coligattue poputies.
fo couigatine poputies.
) Relate lonwuing wapo presua
) lenation Poinnt
) 9epsien tegng point
(iv) Oamtie pesse
Tdentty the weation
fom each the
fellowing nate Contani:
-6
) K= a.9 x io L mol s

i) The wnit Acend e nate

L mo K = 2.3 x 10 L ma
speienti
secend eactien

( ) The unt tiut oda ate contant is s

xo-M s epsen
eactien
( What ia ole Cyote in the metalwngy

nole cyolte in the mtallungy aluminiu

-m make alumina ood onducto
elctuiey and malting point q the
mintL
Mn2+
diamagnie whuuas
paamaqntie 9
ien

n no
unpaiud lectons so, t i diamagntie
nat
Mnt

Mn has unpaid electon so, itt is

natwe.
panamagnic
(9) Complele the
toleuing
Ca) xe Fut O2 Fa
(b) xe Fa+ H 0
+ O F -130 +

(b)2xePa taHa 0 a xe t HHF t O

(20
the hylidisation
Sulphn in
Ca) Soa (b) So (c) sFu (a) SF
(o) so,’sp. (b) 50,’Sp (c) SFy sp'd
(d) sP ’spa'.
 an). What Sthattky cegect ?
point dtect hi ises whn eoal nmie
cation and anienu then nomal

ites the lttice called Shtky degect

tq: Nad,Cscl, Ag Br, ete
aa)what Dsetonie sotton 9
esmetic
Sotion 9 dipnt sbslanes hawing
gunen tempuatune caled isotonic
Pessue

Bleed isotonic with Saline (o.4 lo Nal eution)

Wte the intuquated

Heactien (RJ, R J and 't!.

The der eation

k= 2 303 [Ro]
t [R]
whee
K = Fut 6der hate etant
CRo] Dnitial Concentuaten Heactount
[P] = Cencentation the atant
(24)
Gine eampls coloidal
Co) Liquid solid.
(b) Ga in Soid
(A (a) chese, Butteu, Jelles. (b) Puumice stone, Foam Ruu

esNgen he
molecule
atom
highdy stalee. why ?
un
Na moleeule ae uonded
 to eah the by coval
y sbong tuple conalet onds.

he ond oisoiatien etalpy this Lsnd

less Heactine t
high As a
tempatwe so, N taule
moleule i highly stalite.
(26)w
Wnte Ony to
Ues sed

psnide invt atmosphou in high

tempuatue mtallugical puocsse.
fling elacbaie
What nample
The neubal
moleules that donate pau
electons the Cental metal atem and tem
|cedinate Cevalent lond with it called
Ligand.
9- l , Br, NH , te
hat
ducing
Caehydates which redue Fehling's seltien and
called
Tolen's uducing sga.
futoe latto ,ete.

tnpiain Heaction wcth enample.

When chloeenzene tueated with sodiun metaL
he puesenee q dy the bipheyl foed.
This eactin called eacten.

+ &Na
Dy sthu + &Nal

Biphinyl
 what is Caxylamine
Anitine (puimay Amne) n
heating uwth chan
wtth ad
and Clcohoc KOH tom phenyl ioyanlde
caled Cauyt amine eatien

eHNH, t CHc t 3KOH O.

(ale)
(3) what Fnkel 9

A point dutect which aes when

Lattice eccupy intetial sites duauing dottiee stes
vacant caled
Funkel detect
Age, nS, Aq Br,ete
Hww
Gqis tnngy Ca) elated to tthe cell emf

(e) mathematically
Mathmatical xelatlenhip etwen
and Cell EMe (E) i A, G-nfE
Ccall)
ppes e
Caloe tuplin
Swt pautices
aleng wcth water wapo surpended n
scatte whih neachs
yor eye and
hence the le to

wsed
e
ati- cher nplain.
Hemme chloine
afte eaching.
Hence wsed atl chlo.

d, (Suphul chlouide).
36) D moden ining ppavatus ) mirtwe He
D
and wned. Why ?
 He ond

Jecawe Hllum wy low so

to Na
Jlood at high pesse compaud
36 moment
Calulate the 'spán onty' magntt
+ 2
ien

elecbonic
tegigwaien Fe en

The no 1

emet s

u= H BM
Ju = H.40 BM

3+) what anidnt nuleophila ?

The nucleophls which Can attack thicsugh wo

tes called amiidnt cleophiles.
and nituites

(38 the acetle acid, hloo

Compa
acetie ald, enzeic acid and phensl

A The acidic sngth

chloo ocetie acid Benzeic acid Autte acld

> Phens
(34) What Twttte ion ? Gine
eample
 ion and postine
neutal
tontaining gat
Cale Kusttte ion.
change
amino acids CooH qoup
puston to and qiues Zwitten

ion.

NHCHCO0 -NH,CHco0

Amino old
Ho
(40 hat Guyoscopic conitont 9
dutined depusnion peint
owe d molal soution nen- volatle

densted Du unit ae k Kq mol

H)hat a e peudo fut odu e

erample.
Fiut ushescc
ne a Caled peeudo fut
msleculaly
eation.
is me
than

wte wate
H
CHg 0oca H6 t H,o ’ CH c0o H + Ca H OH.

(Ha lhat the

dittuunce ewen Cnd a

Soaps Sodium
potasium salt highe
acids such
and palmitie
 whuas synthtee dutogunt
ong Chain olkyl phonate Jaenzene slphonat
Caunno t usith haud watea wh
-es. Seaps toam
with hand water
synttie ditnqnt qie tonan
(43) what
The nienie sites etupid
Buy wnpaid ele ctuons
Called F- Cenees They impaut colowu to
cyotoli.
Nal- Yelou Licl - Piink.
Ihat

An
doping 9

addition to a semicondtor to

inoeae the
called doping
si o Ge caied with P, As,
B, Al, ete
H5)
taction
Componunt
-d the atio no that compsnent
o he tetal moles the Componnt
selutionu.

ole paction a component

mo Ihe componnt

moles al cemp enenA solution

Total no.o
HO State
law te nen-oltle soute ;- Rasuls lau
states that the
 dilute soltion non- slatile soute is eqal to msle

the o l t e .

P'-P

whee)
P: Vapeu psswe pwe solent
Jolution.

ng No moles soute

set

Rasultl laws wolatile seute;"E a solution

wolatile auida the patial vapou pesse eah

Ceponint the soution puepotional to

mele solutien:
taction
A (0x)

law.
State Heny'a
The patial peswe the ao n napu phase (p)
peepotonal to the moe
faction the

the soution

Cotant
whe/ Henay'

The pusw eaaiud to e applied souti en

the
molece into setion
when the tion sepaated the soent uy
 memane Called Qsmotic pesswe (n).A
Aemipuumealle

Caleulate the mole

mas.
Containing 48/, Hg So4
mean pesent

Auion
1o09
Mas

No me H, Sou hs

NO0 moes

tuaction
n,tna

-0.9
lo

What ne
nample
The ccwmlation °1 molecla specis at the

9athe than in thhe lulk

Cale d adioptien.
O) Ha
chacoal a losed

The uitica empuatwe 630k and that

140K. hich
adoed easily
actinated
 qas asy adsoed actiuated chaceal Thi

de to coticol
Citical ternpanatwe g so, (630k) high
than that
CHy (190K)
59) hat

The phenemnon scatluuing light y coleidal

which the path q the
paticles eut

eam lecemes wislile callud Tyndal etct

taplain Poting.
( tning 9 the metal

|kawing impuity
Lend wtth Cao Pewd and
) Woen metal

stied with
Heleased the woed
calem und
the metal .
netal Oaide to
the
thii peress
Blistea Cepp

54) hat Bleste cepp ? Why is it so called 9

The
6talned a4tu Besemiation
caled tister Coppu ) which alout 4s
matte

pe Ceppen
the aisoved
Reaon
Cees to the Awyae and tons inteu. so
504
th enting eppe called eiste coppe
What is matte ? Gie it compoiton:
 the etuactien CePPu, the soauted
wing °1
heated last punae along wih pd

Pousdeud and sand. Then the meten mass

called
the fwnace i
at the ase
matte'
Cu,St Fes (ittle)
56 Wite
metals.

Ca) Auminium. (b) zinc Cc) Tnen (a) Coppw

() etal i Auminim
O Baunite ’ Foumula i ALgO, 2H,0

b) ine Metal

Oe- Calamne Foumlai nco,

(c) etal Don.

Ose i Haematte

Oxe Maqnetite Feumda Feg O

Cepp = Metal

Ceppu Pyites ’ Femula uFes,

Ohe i
lance. Foulai Cuy S
Uei Cpp
(6) Scandlum u tuaitien elmunt. But xine i
net. Why ?
 atomic tate as dncompletely feleá
Scondium

3d- uital (3d') so, it is egcoded

element But has Completely tilled 3d-otals
(3°) n atomie state as wel oldled
state . Hence hot coniided as tantion elemnt.
5s) What Ranthhaeide cbntuaction 9
the atomic Cund ioni ad
The
qular decese

with innaning atomic nemu

Knon danthaneid contuactien

yo puupau thl yanide and thiyl

Comnon halide ?
oyanide uom
Ethyl chleid tated wtth thanole petasium

cganide to yanide.
Ethans
+ KCN 7CH3CH CN t Kl.
tueated with cthanetic s e
thyl chlauide
yanide to ethyl isoyanide
thanol
CH, CHg
tthyl
chloide. Sioyanide.
What
When Cniline tuated with nite acld withh

at 943 a4 k
NaNo, and He ) Benzene dlazonium
chloide aled diazetiation
C6H6NH, + NaNo, + 2Hl CoHsNacl Nad +2H.0 .
(61) ite the eactien showing
nane (e) What u
acid and
calgyli
HVZ
ae

out &- positi en chleine

kalogunated eatmnt with

(o) emine pesence Amall anownt sed

phosphou to d -halo Caxieylie acid which
Kneun hell Volhad Zelinky action (HVZ)
R CH TcooH ’ RCH c00H + Hl

d- halecaieulie acid.
Wite the uctes
tolong compoundi
d) 2 -chloo -s-methy penlane
CH3

CHa-CH CH CHCHa

what

chemicl sustoce which peenent the *poliage

Jhe
to miccolial a e calld

precewatines
foed
t So dium Benyoate, salla q pepaneie acid

allotee
(64) hat
site ditont puom atine site whee a
melecwe Car ind and oteet th
the autine site u
 Called allosteic site

(66 What e antaid ? Gine enample

chenical Cowp ound which heutlese the e c s Ocid

maintan PH nomaL
stemach and

Caled antacidu
4: so dium kydegen Caulenate Wintwe AL(OH),

and M lo): , Omepnazsle

What

The steeo elated to each thhe nen

|dupuimposalle miset mage colled &nntiene.

with uspect to the Hotatien

plane polarind ight 4 ne

(der t)) the

deto otatouy tthe

|uotatoy
Co0 H CoOH

Ho

CH3
d- dactic aid l - latte aid

kuplain Wwty - Fitly eaction .

When chlooenzene iu tuated with okuyl halide ,

sedium metal ton alkyl
called Wuslg [Link] eaction .
 chloebenzene
the pesnee dy eth,chloolenne eacta

with methyl thloie and odium metal to tom

methyl Jenyene.
+ 2Na l
ethu
hat
Wwty eaction ? w ite an enample
the ethe, alkyl halide eact with
pceuce q diy
sodium metal to akane . Dt coled

Heactien
thhe Pesence chloide
cy ther, thyl
eacta sith Na metal to n- tane.
tom
Duy eh C H6 Ca H6 + Nal

AIhat

The comweuion

ouctine compoun into Hacennic mintwe

eptically
called hacmisation.
M9 ’A H B.
40) CH CHg Br
dy ethu
Bcompound.

cH CH, Br + Mg Dg athel cH, cH, Mq Br

(4)
CHacHg t Ma Cor)Br
’(e)
A’hyl magen omice B’thane.
 Polymers
ukat Nulcani2abon of nubbo?
A,
w callsd

vleanied ubber.

CH

One

A hex called o
kat can be decorpoed by backvria
En' PHBV

3,wL he name o monomus

A. ) nonomer
oH oH

+H
+ HCHO
OH
(o) Poua,
tho CA,OH
monomew diamin ord pde
ad,
 what Giwe
one (o) moe Koic amino

R -CH -c0oH
waline ele.

45. QHenta bls globalar ond dibxous okinw.

An

cGl.
’

becouwe

Aabibiolir au on

micaober.
on
HCHO
commondy
dinkan callhd on on
notnot ae
Erarmpl iasintaadi
Gie ane what 44.