Professional Documents
Culture Documents
Wi. ay naa att 3) [SIS IV >I oo 4) WV >I >T>dT 49:\ ‘The major product of the following reaction will be oh ' Page eye OH 2 Ox =) » oe 4) : ; Ht is wiht 50. ‘ es 3 or * SOAS own .” The major pa (A) in thie above reaction is * " Ng Hy \ TRIOS te eeaSy Gini ap lege oe yor. Q oi : aes. Gag i : Dee ne Cl oye © scanned with OKEN ScannerSECTION-II (NUMERICAL VALUE ANSWER TYPE) ‘This section contains 10 questions. The answver to each question is a Numerical value. If he Answer in the decimals, Mark nearest integer only. Have fo Answer any 5 only out of 10 questions and question willbe ; evaluated according to the following marking scheme: Marking scheme: +4 for correct answer, I in all other cases. 51. ‘The ratic of number of o'-bonds to number of 2 —bonds in toluene is 52.’ A hydrocérbon of niolecularférmula C,Ef, gives x number of structural isomers. The value of x is . d ’ 53. An alkyne (A) is treated with Lindlar's catalyst and Ho to give @ compound (B). (B) reacts with HCl to give another compound (C) which on reaction with ‘Na/ether produces compound (D) of molar mass 86g mol. Molar mass of (A) is__g/ mor 4 (Given atomic mass ; C:12.0 u, H:1,0u) 1 ‘ 54, A saturated. polytialogent. compound (A) on heating with zine gives: 2-Butyne, What should be thé minimum number of halogen atom(s) in one molecule of the reactant (A) to give the product? ina 55. Examine the structural formulae shown below and find out how many compounds cannot give friedel-craft reaction Sey ko Rhy 2 © >) © ee eae ae Leo 56. Identify the number of substituents those are deactivating but ortho sind para directing Re 0 Sy 1 cr; Wik; ~CH=CH~C-OH,-8-GH, oO -cacn-bhn COOH, ~CH,Ch ~N. © scanned with OKEN Scanner57, . Sum of sp*,sp? and Sp. hybrid: ‘orbitals in thecompound - CH, ~CH'=C=CH-~CaC-cH, ae Acetylene can be Prepareid by heating iodoform With silver powder. How many moles rc of silver iodide will be produced for the formation of 26'g of acetylene? 59. One mole of 1 58. -Dibroinopropane on treatment’ with x moles of NaNH? followed by ~ treatment with ethyl brotnide gave 2> pentyne. The value of x OO Nos : 7 See mo, In the above reaction, 3.9 g 0 ofbenzene'on nitration gives 4.92 itobenzene, The percentage yield of nitrobenzene in the above reaction is (Roundoff to the nearest integer)... (Given atomic mags :C:12.0.u, H:1.0u, O: Ou, N:14.0u), Fhahy a ‘ 4 |S (SINGLE CORRECT ANSWER TYPE) We ©) GECTION-1) This section contains 20 multiple choice questions Each question has 4 option (1, (2), (3) aiid (4) for its answer, out of which ONLY ONE option can be cotrect. ‘ Marking scheme: +4 for correct ariswer,0 if not attempted aid -1 if not correct. iv salle ‘MATHEMATICS -_ G1. _ The solution of the equation se (Gn) es A’... Here, A refers to 62.” 63. © scanned with OKEN Scanner64, TEwe: consider only the principal values of the inverse | trigonometric functions then the value of ta( os pis Sv * un 3 4) 9 65. Ifa is the only real root of the equation, x! bx? +ék+1=0(0'3) sins 4) cotd : . 70. The valie’of 2sin(12°) — sin(72°) is." 3 a 0 S08), fa ys 9 8 5 TL Af tant5° ++ =2a, then the vale of ae ! ‘is is tan 75” i 14 3) 4-23 > 72. The value of ew'(#}cos(2F) si (2) io) is : nt a V56 ay : oF Y © scanned with OKEN Scannersal oc 28 )es (28) 73. The value of 2s) (2) n( 2) 1 Soy tt : 4 eR ay 74. The value of indi Sin"( 5 tis equal © ai ‘ a2 é 33 4) 6. : i 5 a i 75. af Stan's = p, then the value of tan i Cae ete cos 1) 100- jt 50. 4 1100 a ) i020 76.+ mS : x - eae 27 = 78. If insecttan! sy Jogi vi tan?s 1SPeaye |i « Hexcseom'2) ener) andy tan! “TEA then || eau to (Lis denoted greatest integer function) * é 2° DBE 83) 4 a be hs BYS 79. - The solution set of the equation Tén!x— Cor r= Cos-'(2-x) is fs 2 DW enay 2)" ayy +, 43) ; De de oe sage! . 80, Thivalve of cost eos +cosSF sequal o a a . 1 a Ya ; 3-5 i Fae 7 © scanned with OKEN Scanner(NUMERICAL VALUE ANSWER TYPE) ‘This section contains 10 questions. The answer to.each qué decimals, Mark nearest Integer only. Have to Answer any evaluated according to the following marking scheme: Marking scheme: +4 for correct answer, +1 in all other cases. 81... tan? Z-33tant 2. an an’ 9 33 tan’ og a ta 9 82." tan9* ~tan 37° ~tan 63° + tan 81" 3. Ihaa3s, C -<1s*and 84. If the sum of the Solutions of tan Be) (EE) 88, The value ofsint 7 +cos!75 58 Then R= : < Ledsin IQ? sin 70° 5 The value of the expression “STEEN is 90. If siné +cos@ =Futhen 16{sin(28) + c0s(40) +sin(60)] is equal to restion is a Numerical value. If the Answer in the 5 only out of 10 questions and question will be 40°, then’ tan 4.tan B + tan B.tan C+ tan C.tan Zisexcharo is a- oot i-¥ thenais | , i " 85. soi in°(3) 2a ovis equal to. * 2(a-n " ia 2 oot cia 86. © If cosec"| | 4D e05 cotSat|sec*™ | kar then k= (aan 2 2 |i tan (= 87. Forx-e (I, 1}; the-number of solutions of the-equation sin''x +2 tan"! x is equal to wld ages ons © scanned with OKEN Scanner